CN106187596A - A kind of for desulfurated plaster modifying agent improveing carbonate salt-soda soil and preparation method thereof - Google Patents
A kind of for desulfurated plaster modifying agent improveing carbonate salt-soda soil and preparation method thereof Download PDFInfo
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- CN106187596A CN106187596A CN201610547323.1A CN201610547323A CN106187596A CN 106187596 A CN106187596 A CN 106187596A CN 201610547323 A CN201610547323 A CN 201610547323A CN 106187596 A CN106187596 A CN 106187596A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Processing Of Solid Wastes (AREA)
Abstract
The invention belongs to Saline-alkali Field Control technical field, it is specifically related to a kind of desulfurated plaster modifying agent for improveing carbonate salt-soda soil, by weight percentage, it includes following parts by weight of component to described fertilizer: desulfurated plaster 40 50 parts, feces of livestock and poultry and 20 30 parts of hay leaf, citric acid waste 5 10 parts, 15 parts of ferrous sulfate, 15 parts of flyash, perlite 15 parts, bentonite 5 10 parts, microbial bacterial agent 13 parts, ammonium nitrate 24 parts, potassium dihydrogen phosphate 0.5 1 parts, disodium hydrogen phosphate 0.5 1 parts, 12 parts of magnesium sulfate.Modifying agent prepared by the present invention is adapted to the improvement in carbonate salt-soda soil, and desalination is quick, and treatment cost is low, and using effect is notable.
Description
Technical field
The invention belongs to Saline-alkali Field Control technical field, be specifically related to a kind of desulfurization stone for improveing carbonate salt-soda soil
Cream modifying agent and preparation method thereof.
Background technology
Saline-alkali soil is solonchak and alkaline earth and various salinization, the general name of alkali-affected soil.Solonchak refers to soluble organic fraction in soil
Content reaches to a certain degree, it is possible to the g and D of plant is produced the great soil group substantially endangered.Alkaline earth refers in soil containing big
Amount commutativity ion, quantity reaches to endanger the degree of plant growing and growth, and makes the soil that soil property changes.
The salinization of soil of soil refers to owing in soil, a large amount of of salt basic ion accumulate, the process that soil types gradually changes to saline-alkali soil, its
Influence factor includes natural cause and anthropic factor.Easily there is the phenomenon that hardens in salt affected soil under normal circumstances, causes soil
Porosity diminishes, and the gas permeability of soil and water penetration are deteriorated, and badly influence the metabolism of Soil Microorganism, reduce the work of various enzyme
Property and carbon, the mineralization degree of nitrogen element, the conversion of soil with organic matter is slack-off, eventually results in soil the barrenst.Soil contains
The a large amount of salt ions having also can badly influence the normal physiological function of salt-soda soil plant, suppresses its g and D.It addition, with
The continuous aggravation of socioeconomic development and mankind's activity, salt-soda soil resource increasingly receives publicity, and irrational irrigation is made
Degree also results in Pedotransfer function aggravation.Second Committee International Sustainable Development conference is just pointed out, the following meeting serious threat world
Agricultural sustainable development is the salinization of soil in soil, desertification and the big problem of soil erosion 3.
Desulfurated plaster (English name desulfuration gypsum) is also known as flue gas desulfurization gypsum, sulfur Gypsum Fibrosum or FGD stone
Cream, main component is the same with the natural gypsum, for calcium sulphate dihydrate CaSO4·2H2O, content >=93%.Desulfurated plaster is FGD process
Side-product, FGD process is a technology using Calx-limestone to reclaim the sulfur dioxide in coal-fired or oily flue gas.Should
Technology is Calx-limestone to be ground make serosity, make after dedusting containing SO2Flue gas removed by slurry wash device
SO2.Lime slurry and SO2Reaction generates calcium sulfate and calcium sulfite, and calcium sulfite is oxidized changes into calcium sulfate, obtains industry
By-product gypsum, referred to as desulfurated plaster.
Gypsum Fibrosum powder is one of five big gel rubber materials, occupies an important position, be widely used in building, build in national economy
Numerous applications such as material, industry mould and art model, chemical industry and agricultural, food processing and medicine beauty treatment, are a kind of
Important industrial raw materials.Desulfurization gypsum powder is the different of physics from the differentiation of general Gypsum Fibrosum powder, in desulfurization gypsum powder
Possibly together with silicon dioxide, sodium oxide, calcium carbonate, calcium sulfite, limestone, calcium chloride, magnesium chloride etc..Compared with other Gypsum Fibrosum powder
Relatively, desulfurization gypsum powder has renewable, and granularity is little, stable components, and objectionable impurities content is few, purity high.Currently mainly
It is used for producing plasterboard together with the natural gypsum, is additionally widely used in terms of alkaline land improving.Its principle is to utilize
Ion exchange is theoretical, replaces the sodium ion in soil colloid with the calcium ion in desulfurated plaster.
Summary of the invention
Invention broadly provides a kind of for desulfurated plaster modifying agent improveing carbonate salt-soda soil and preparation method thereof,
The modifying agent of preparation is adapted to the improvement in salt-soda soil, and desalination is quick, and treatment cost is low, and using effect is notable.Its technical scheme is such as
Under:
A kind of desulfurated plaster modifying agent for improveing carbonate salt-soda soil, by weight percentage, it includes following heavy
Amount part component: desulfurated plaster 40-50 part, feces of livestock and poultry and hay leaf 20-30 part, citric acid waste 5-10 part, ferrous sulfate 1-5
Part, flyash 1-5 part, perlite 1-5 part, bentonite 5-10 part, microbial bacterial agent 1-3 part, ammonium nitrate 2-4 part, biphosphate
Potassium 0.5-1 part, disodium hydrogen phosphate 0.5-1 part, magnesium sulfate 1-2 part.
Preferably, described fertilizer also includes the acid-sludge of 5-7 weight portion.
Preferably, described microbial bacterial agent is salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and hay
The mix bacterium agent of bacillus cereus.
Preferably, the bacterium solution of salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and bacillus subtilis adds
Entering amount is 1:1:1:1.
Preferably, by weight percentage, described desulfurated plaster modifying agent includes following parts by weight of component: desulfurated plaster
43-47 part, feces of livestock and poultry and hay leaf 25-27 part, citric acid waste 7-8 part, 3 parts of ferrous sulfate, 2 parts of flyash, perlite 2-3
Part, bentonite 7 parts, microbial bacterial agent 1 part, ammonium nitrate 3 parts, potassium dihydrogen phosphate 0.8 part, disodium hydrogen phosphate 0.7 part, magnesium sulfate
1.8 parts, acid-sludge 6 parts.
Preferably, the effective ingredient of desulfurated plaster is CaSO4·2H2O, CaSO4·2H2Content >=93% of O.
The preparation method of a kind of desulfurated plaster modifying agent for improveing carbonate salt-soda soil, comprises the following steps:
(1) desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite, bentonite are carried out air-drying pulverizing, and mistake
Sieve processes；
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add the acid-sludge of formula ratio, microbial bacterial agent, ammonium nitrate, phosphorus
Acid dihydride potassium, disodium hydrogen phosphate and magnesium sulfate, carry out sealing and fermenting 15-20 days, turned over every 3-5 days and pushes away once, generates corruption
Mixture；
(3) in the mixture of corruption, the desulfurated plaster after pulverizing, citric acid waste, ferrous sulfate, flyash, Margarita are added
Rock, bentonite, be uniformly mixed, and obtains desulfurated plaster modifying agent.
Use above-mentioned for desulfurated plaster modifying agent improveing carbonate salt-soda soil and preparation method thereof, the present invention have with
Lower advantage:
(1) flyash is the main garbage in thermal power plant, and annual China flyash annual emissions has surpassed hundred million, and produces
Amount increases year by year.Local environment protection is brought the biggest pressure by the bulk deposition of flyash, the most also gives the life of people and moves
The aspects such as the existence of plant, growth cause serious harm.And containing abundant weight, boron, sulfur, zinc, copper, calcium, magnesium, ferrum in flyash
Deng trace element, and quality is loose the bigger space of existence, at the regulation soil moisture and pH value, increases and supplements soil nutrient
Composition aspect effect is unique；The aobvious faintly acid of citric acid waste itself can regulate soil, possibly together with a certain amount of organic matter, from comprehensively
Use desulfurated plaster effect also good than simple on exercising result；
(2) mix bacterium agent in the present invention can increase vegetation to Na+Absorbtivity so that it is be gathered under ground portion, press down
Salt manufacturing divides the transport to top, reduces relative amount, improves the ionic equilibrium in plant body, alleviate the murder by poisoning of salt ion, mixing
The infection ability of microbial inoculum and promotion host plant growth aspect will be more preferable than inoculation single culture effect.
Detailed description of the invention
Embodiment 1
1. for improveing the desulfurated plaster modifying agent in carbonate salt-soda soil
A kind of desulfurated plaster modifying agent, by weight percentage, it includes following parts by weight of component: desulfurated plaster 47 parts,
Feces of livestock and poultry and 25 parts of hay leaf, citric acid waste 7 parts, 3 parts of ferrous sulfate, 2 parts of flyash, perlite 2 parts, bentonite 7 parts, micro-
Bacteria agent 1 part, ammonium nitrate 3 parts, potassium dihydrogen phosphate 0.8 part, disodium hydrogen phosphate 0.7 part, 1.8 parts of magnesium sulfate, acid-sludge 6 parts.
Wherein, microbial bacterial agent be salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and hay spore
Bacillus prepares according to the bacterium solution addition of 1:1:1:1.
2. the preparation method of modifying agent
(1) desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite, bentonite are carried out air-drying pulverizing, and mistake
Sieve processes；
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add the acid-sludge of formula ratio, microbial bacterial agent, ammonium nitrate, phosphorus
Acid dihydride potassium, disodium hydrogen phosphate and magnesium sulfate, carry out sealing and fermenting 15 days, turned over every 3 days and pushes away once, generates the mixing of corruption
Thing；
(3) in the mixture of corruption, the desulfurated plaster after pulverizing, citric acid waste, ferrous sulfate, flyash, Margarita are added
Rock, bentonite, be uniformly mixed, and obtains desulfurated plaster modifying agent.
Embodiment 2
1. for improveing the desulfurated plaster modifying agent in carbonate salt-soda soil
A kind of desulfurated plaster modifying agent, by weight percentage, it includes following parts by weight of component: desulfurated plaster 40 parts,
Feces of livestock and poultry and 20 parts of hay leaf, citric acid waste 5 parts, 1 part of ferrous sulfate, 5 parts of flyash, perlite 3 parts, bentonite 10 parts,
Microbial bacterial agent 2 parts, ammonium nitrate 2 parts, potassium dihydrogen phosphate 0.5 part, disodium hydrogen phosphate 1 part, 2 parts of magnesium sulfate, acid-sludge 5 parts.
Wherein, microbial bacterial agent be salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and hay spore
Bacillus prepares according to the bacterium solution addition of 1:1:1:1.
2. the preparation method of modifying agent
(1) desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite, bentonite are carried out air-drying pulverizing, and mistake
Sieve processes；
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add the acid-sludge of formula ratio, microbial bacterial agent, ammonium nitrate, phosphorus
Acid dihydride potassium, disodium hydrogen phosphate and magnesium sulfate, carry out sealing and fermenting 20 days, turned over every 5 days and pushes away once, generates the mixing of corruption
Thing；
(3) in the mixture of corruption, the desulfurated plaster after pulverizing, citric acid waste, ferrous sulfate, flyash, Margarita are added
Rock, bentonite, be uniformly mixed, and obtains desulfurated plaster modifying agent.
Embodiment 3
1. for improveing the desulfurated plaster modifying agent in carbonate salt-soda soil
A kind of desulfurated plaster modifying agent, by weight percentage, it includes following parts by weight of component: desulfurated plaster 50 parts,
Feces of livestock and poultry and 30 parts of hay leaf, citric acid waste 8 parts, 5 parts of ferrous sulfate, 1 part of flyash, perlite 1 part, bentonite 5 parts, micro-
Bacteria agent 3 parts, ammonium nitrate 4 parts, potassium dihydrogen phosphate 1 part, disodium hydrogen phosphate 0.5 part, 1 part of magnesium sulfate, acid-sludge 7 parts.
Wherein, microbial bacterial agent be salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and hay spore
Bacillus prepares according to the bacterium solution addition of 1:1:1:1.
2. the preparation method of modifying agent
(1) desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite, bentonite are carried out air-drying pulverizing, and mistake
Sieve processes；
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add the acid-sludge of formula ratio, microbial bacterial agent, ammonium nitrate, phosphorus
Acid dihydride potassium, disodium hydrogen phosphate and magnesium sulfate, carry out sealing and fermenting 17 days, turned over every 4 days and pushes away once, generates the mixing of corruption
Thing；
(3) in the mixture of corruption, the desulfurated plaster after pulverizing, citric acid waste, ferrous sulfate, flyash, Margarita are added
Rock, bentonite, be uniformly mixed, and obtains desulfurated plaster modifying agent.
Performance detects
1. use the modifying agent of embodiment 1-3 that carbonate salts alkaline earth carries out lab simulation shower test, add up after 20 days
Salt dynamics, the results are shown in Table 1.
Soil root system before and after table 1 improvement
As shown in Table 1, use the modifying agent of embodiment 1-3 to after processing carbonate salt-soda soil, soil middle soda content, contain
Total salt amount, porosity of soil, the soil weight all have substantially improvement.
2. use the modifying agent of embodiment 1-3 that carbonate salts alkaline earth is improved, plant Plantula Brassicae chinensis during improvement, simultaneously
At normal soil with without planting Plantula Brassicae chinensis on the saline-alkali soil of modifying agent, result of the test is as shown in table 2:
Table 2 soil improvement result
As shown in Table 2, modifying agent prepared by the present invention can reduce pH value and the electrical conductivity of soil, improves kind of a plant simultaneously
Germination percentage, germination index and vitality index, be beneficial to use to carbonate salt-soda soil.
It will be apparent to those skilled in the art that can technical scheme as described above and design, make other various
Corresponding change and deformation, and all these change and deformation all should belong to the protection domain of the claims in the present invention
Within.
Claims (7)
1., for improveing the desulfurated plaster modifying agent in carbonate salt-soda soil, by weight percentage, it includes following weight
Part component: desulfurated plaster 40-50 part, feces of livestock and poultry and hay leaf 20-30 part, citric acid waste 5-10 part, ferrous sulfate 1-5 part,
Flyash 1-5 part, perlite 1-5 part, bentonite 5-10 part, microbial bacterial agent 1-3 part, ammonium nitrate 2-4 part, potassium dihydrogen phosphate
0.5-1 part, disodium hydrogen phosphate 0.5-1 part, magnesium sulfate 1-2 part.
Desulfurated plaster modifying agent for improveing carbonate salt-soda soil the most according to claim 1, it is characterised in that: described
Fertilizer also includes the acid-sludge of 5-7 weight portion.
Desulfurated plaster modifying agent for improveing carbonate salt-soda soil the most according to claim 2, it is characterised in that: micro-life
Thing microbial inoculum is the mix bacterium agent of salt tolerant Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and bacillus subtilis.
Desulfurated plaster modifying agent for improveing carbonate salt-soda soil the most according to claim 3, it is characterised in that: salt tolerant
The bacterium solution addition of Azospirillum brasilense, cellulose-decomposing bacterium, Glomus etunicatum and bacillus subtilis is 1:1:1:1.
Desulfurated plaster modifying agent for improveing carbonate salt-soda soil the most according to claim 4, it is characterised in that: by weight
Amount percentages, described desulfurated plaster modifying agent includes following parts by weight of component: desulfurated plaster 43-47 part, feces of livestock and poultry and withered
Blade of grass 25-27 part, citric acid waste 7-8 part, 3 parts of ferrous sulfate, 2 parts of flyash, perlite 2-3 part, bentonite 7 parts, microorganism
Microbial inoculum 1 part, ammonium nitrate 3 parts, potassium dihydrogen phosphate 0.8 part, disodium hydrogen phosphate 0.7 part, 1.8 parts of magnesium sulfate, acid-sludge 6 parts.
Desulfurated plaster modifying agent for improveing carbonate salt-soda soil the most according to claim 1, it is characterised in that: desulfurization
The effective ingredient of Gypsum Fibrosum is CaSO4·2H2O, CaSO4·2H2Content >=93% of O.
7. prepare as claimed in claim 5 for the method improveing the desulfurated plaster modifying agent in carbonate salt-soda soil, its
It is characterised by: comprise the following steps:
(1) desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite, bentonite are carried out air-drying pulverizing, and place of sieving
Reason；
(2) weigh feces of livestock and poultry and the hay leaf of formula ratio, add the acid-sludge of formula ratio, microbial bacterial agent, ammonium nitrate, di(2-ethylhexyl)phosphate
Hydrogen potassium, disodium hydrogen phosphate and magnesium sulfate, carry out sealing and fermenting 15-20 days, turned over every 3-5 days and pushes away once, generates the mixing of corruption
Thing；
(3) to corruption mixture in add pulverize after desulfurated plaster, citric acid waste, ferrous sulfate, flyash, perlite,
Bentonite, is uniformly mixed, and obtains desulfurated plaster modifying agent.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163950A (en) * | 2017-06-06 | 2017-09-15 | 清华大学 | A kind of alkaline earth soil conditioner |
| CN107216884A (en) * | 2017-06-03 | 2017-09-29 | 内蒙古中恒材料技术股份有限公司 | A kind of alkaline land modifying agent |
| CN107915522A (en) * | 2017-11-30 | 2018-04-17 | 潍坊友容实业有限公司 | Sandy alkaline land improving fertilizer prepared using thermal power plant's discarded object and preparation method thereof |
| CN108966723A (en) * | 2018-08-08 | 2018-12-11 | 天津海林农业科技发展有限公司 | A kind of comprehensive regulation method of barged-in fill desalination alkalization |
| CN109534929A (en) * | 2018-12-27 | 2019-03-29 | 天津亚德尔生物质科技股份有限公司 | A kind of charcoal mixed fertilizer reducing surface soil alkalinity |
| CN113387756A (en) * | 2021-07-06 | 2021-09-14 | 石河子大学 | Organic fertilizer and preparation method and application thereof |
| CN115322793A (en) * | 2022-09-21 | 2022-11-11 | 山东省农业科学院 | Saline-alkali soil conditioner capable of increasing soil organic matters and preparation method thereof |
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| CN104996115A (en) * | 2015-06-23 | 2015-10-28 | 潍坊友容实业有限公司 | Method for planting suaeda salsa at medium-low-cadmium saline-alkaline land and for extracting plant salt |
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| CN107216884A (en) * | 2017-06-03 | 2017-09-29 | 内蒙古中恒材料技术股份有限公司 | A kind of alkaline land modifying agent |
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| CN107915522A (en) * | 2017-11-30 | 2018-04-17 | 潍坊友容实业有限公司 | Sandy alkaline land improving fertilizer prepared using thermal power plant's discarded object and preparation method thereof |
| CN108966723A (en) * | 2018-08-08 | 2018-12-11 | 天津海林农业科技发展有限公司 | A kind of comprehensive regulation method of barged-in fill desalination alkalization |
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| CN109534929A (en) * | 2018-12-27 | 2019-03-29 | 天津亚德尔生物质科技股份有限公司 | A kind of charcoal mixed fertilizer reducing surface soil alkalinity |
| CN113387756A (en) * | 2021-07-06 | 2021-09-14 | 石河子大学 | Organic fertilizer and preparation method and application thereof |
| CN113387756B (en) * | 2021-07-06 | 2023-12-08 | 石河子大学 | Organic fertilizer and preparation method and application thereof |
| CN115322793A (en) * | 2022-09-21 | 2022-11-11 | 山东省农业科学院 | Saline-alkali soil conditioner capable of increasing soil organic matters and preparation method thereof |
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Application publication date: 20161207 |