CN107951732A - Rectorite tearing slurry mask - Google Patents
Rectorite tearing slurry mask Download PDFInfo
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- CN107951732A CN107951732A CN201711436906.8A CN201711436906A CN107951732A CN 107951732 A CN107951732 A CN 107951732A CN 201711436906 A CN201711436906 A CN 201711436906A CN 107951732 A CN107951732 A CN 107951732A
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- rectorite
- mask
- mud mask
- mud
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
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- Birds (AREA)
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Abstract
The invention relates to a rectorite tearing mud mask, which comprises a mud mask composition and a film-forming spray composition; the mud mask composition comprises: 30-40% of rectorite powder, 1-2.6% of sodium alginate, 10-20% of auxiliary material and 100% of water; the film-forming spray composition comprises solvent water and: 1-2% of calcium chloride, 0.01-0.5% of chitosan and 0.01-0.1% of sodium citrate. The novel prepared mineral slurry tearing mask overcomes the defect that the drying speed of the slurry mask is high, reduces the risk of skin minimally-invasive injury caused by tearing the slurry mask to the maximum extent, enables the slurry mask to be easy to clean, and improves the skin care experience of a consumer using the slurry mask.
Description
Technical field
The present invention relates to mud mask technical field, and mud mask is torn more particularly to a kind of rectorite.
Background technology
The a great variety of facial mask, can be divided into washing facial mask and mounted facial mask, only from mounted facial mask, so that it may be divided into biological fiber
Facial mask, non-woven fabrics facial mask, superfine fibre facial mask, bamboo charcoal fiber facial mask etc., washing facial mask are broadly divided into mud mask and non-mud
Wash facial mask (sleep mask, fresh and alive facial mask etc.).
Facial mask market is the market in a Monopolistic competition, has substantial amounts of seller and buyer on this market, largely
The facial mask of the variant type of enterprise's production, manufacturer enter and exit all relatively easily, and substantial amounts of manufacturing enterprise produces difference
Facial mask this feature apparently, applied from research and development of products to final in consumer's this process on the face, be not to be easy to allow consumption
Person determines which type of is selected, but a variety of inscape forms different buying motives.
How on the premise of the quality and safety of facial mask is met, facial mask effect is taken into account, solves consumer's skin care demand
Innovation will be basic.Domestic market is the huge market of a handling capacity.No matter at present how many attracting facial mask, meets
How many kinds of demand, reaches how many kinds of effect, as long as a new and the convictive mask product of tool, total energy open new disappears
Take space, meet consumer demand.
Mud mask is the important branch in facial mask segments category, is mainly grown with deep layer cleaning, mineral trace element
The experience for supporting skin is rooted in the hearts of the people, and enjoys consumer to like.For mud mask there is also the place of blemish in an otherwise perfect thing, mud mask is easy
Quick-drying, causes skin tight；Traditional mud tears facial mask, causes, easily infection minimally invasive to skin surface since strength is torn
Inflammation.Traditional mud face mainly uses kaolin, volcanic mud, deep-sea mud etc., lacks the strategic structural again to mud mask.
Therefore, the prior art still has much room for improvement.
The content of the invention
Based on this, the rectorite the object of the present invention is to provide a kind of new bi-component tears mud mask.
Specific technical solution is as follows：
A kind of rectorite tears mud mask, including mud mask composition and film forming spray composite；
The mud mask composition includes the component of following mass percent：Rectorite powder 30-40%, sodium alginate 1-
2.6%, auxiliary material 10-20%, adds water to 100%；
The film forming spray composite includes the component of aqueous solvent and following mass percent：Calcium chloride 1-2%, shell gather
Sugared 0.01-0.5%, sodium citrate 0.01-0.1%.
In wherein some embodiments, the particle diameter of the rectorite powder is 1-10 μm.
In wherein some embodiments, the molecular weight of chitosan is 8000-12000KD.
In wherein some embodiments, one kind in moisturizer, thickener, film forming agent or preservative of the auxiliary material or
It is several.
In wherein some embodiments, the auxiliary material include glycerine, propane diols, butanediol, beta glucan, xanthans,
Sepic 350, niacinamide, decoyl glycine, arginine, titanium dioxide, Fourstamen Stephania Root extracting solution, allantoin and decoyl hydroximic acid.
350 special thickeners of Sepic, its composition are as follows：
| Component | Mass percent % | Remarks |
| Polyacrylamide | 40 | |
| C13-14 isoparaffins | 20 | |
| Laureth -7 | 5 | |
| Water | 35 |
In wherein some embodiments, the mud mask composition includes the component of following mass percent：Rectorite
Powder 30-40%, sodium alginate 1-2.6%, glycerine 1-3%, propane diols 0.5-2%, butanediol 2-4%, beta glucan 0.1-
1%, xanthans 0.1-0.5%, Sepic 350 1-3%, niacinamide 1-3%, decoyl glycine 0.1-1%, arginine 0.1-
1%, titanium dioxide 1-2%, Fourstamen Stephania Root extracting solution 0.1-1%, allantoin 0.1-0.5%, decoyl hydroximic acid 0.5-2%, adds water
To 100%.
In wherein some embodiments, the film forming spray composite further includes preservative.
In wherein some embodiments, the film forming spray composite includes the group of aqueous solvent and following mass percent
Point：Calcium chloride 1-2%, chitosan 0.01-0.5%, sodium citrate 0.01-0.1% and decoyl hydroximic acid 0.5-2%.
In wherein some embodiments, the mud mask composition includes the component of following mass percent：Rectorite
Powder 35%, sodium alginate 1.5%, glycerine 2%, propane diols 1%, butanediol 3%, beta glucan 0.5%, xanthans 0.2%,
Sepic 350 2%, niacinamide 2%, decoyl glycine 0.5%, arginine 0.5%, titanium dioxide 1.5%, Fourstamen Stephania Root extraction
Liquid 0.5%, allantoin 0.2%, decoyl hydroximic acid 1%, adds water to 100%；
The film forming spray composite includes the component of aqueous solvent and following mass percent：Calcium chloride 1.5%, shell gathers
Sugar 0.1%, sodium citrate 0.05% and decoyl hydroximic acid 1%.
It is bi-component facial mask that above-mentioned rectorite, which tears mud mask, including mud mask composition and film forming spraying combination
Thing, is first coated in skin surface about 10min during use by mud mask composition, then film forming spray composite is sprayed on mud
Facial mask surface, mud mask can form a film, and intactly from skin peeling, and not produce minimally invasive damage to skin.
Above-mentioned bi-component facial mask uses rectorite mud, and for raw mineral materials, using sodium alginate and chitosan, calcium chloride is
Moisturizing film forming agent, the New Mineral mud of preparation tear facial mask, solve the shortcomings that mud mask rate of drying is fast, to greatest extent
Reduce and tear the risk that mud mask causes the minimally invasive damage of skin so that mud mask is easy to clean, and improving consumer makes
Experienced with the skin care of mud mask.Small pox skin can cause Skin barrier destruction to damage, and above-mentioned rectorite tears mud mask energy
Promote wound healing, oil-control is antibacterial, accelerates the maintenance of small pox skin.
Above-mentioned rectorite tears core material rectorite, chitosan in mud mask, sodium alginate, unique machine of calcium chloride
Reason, effect and the excellent skin care experience brought, are summarized as follows：
1st, rectorite
Rectorite is dihedron mica and dihedron montmorillonite composition 1：1 type regularly interstratified mineral, its structure is by class mica
Elementary layer and the well-regulated alternately stacking of class montmorillonite elementary layer form.According to clay mineral textural classification, according to four sides chip
Classify with octahedral chip architecture stratotype, rectorite construction unit layer contains two 2：1 layer.2 in mica elementary layer：1 layer of interlayer
Cation can be Na+、K+、Ca2+；And the 2 of montmorillonite unit：It is Na that 1 interlayer, which contains commutative aquation cation,+、Ca2+、Mg2 +、Al3+、Sr2+Deng.Octahedral in two class elementary layers is largely occupied by aluminium, front three cation aluminium only occupy it is 2/3 octahedra, i.e., two
Face body subclass.The crystal structure of rectorite determines that rectorite mineral have unique mineral physics characteristic.
(1) adsorptivity and cation exchange
The crystal structure of rectorite is formed by class mica and regular be alternately stacked of class montmorillonite.Mica is in high negative electrical charge
The interlamination region that tetrahedral sheet is coupled, the Na as charge compensation+、K+、Ca2+From being fixed, not commutative, interlayer is unexpansive
's.Montmorillonite is 2：1 type layer aluminium silicate salt mineral, the aquation cation of interlayer can by a large amount of other inorganic, organic sun from
Son exchanges, such as sodium, aluminium, single or compound example, its adsorbable various inorganic particulate, organic molecule, and the absorption such as silicon and
Exchange process is reversible.
(2) polymolecularity
Rectorite meets that water electrode is easily scattered, its particle diameter is less than 1 μm, and particulate film forming is smooth, and effect is more after adding a small amount of alkali process
It is good, and being capable of long-term suspension.
(3) ultraviolet is obstructed
The colloid index of rectorite is 50-90ml/15g, naturally possesses good ultraviolet and deadens ability, to short wavelength light
Or the absorption barrier effect of ejected wave is obvious.
(4) interlayer aperture changeability
Rectorite interlayer aperture can be modified it after ion exchange is carried out using different disposal agent.Calcium base is handed over
Change, synthesizing cross-linked rectorite, the layer column two-dimensional channel structure of the large aperture between 1.5-4nm can be formed, reaching interlayer aperture can
Become.Its physical property changes but structure inconvenience, and if clay mineral is hydrophilic in itself, and clay organic complex becomes oleophylic
Property, more contribute to deep layer cleaning, adsorb excess oil.
Selection particle diameter of the invention is the rectorite powder of 1250 mesh as core material.
2nd, sodium alginate
Sodium alginate is a kind of natural polysaecharides compound extracted from seaweed, be a kind of color is white to faint yellow
Powder solid, almost odorless, tasteless, low-heat is nontoxic, possesses strong hygroscopicity, and moisture holding capacity is high, is easily dissolved in water, warm water
In easily it is puffing, insoluble in ethanol, ether.It is guluronic acid (G sections) and its 2 kinds of stereoisomer mannuronic acid (M sections)
The construction unit linear block copolymers that (MM sections, GG sections, MG sections) are formed by α (1,4) glycosidic bond links in a manner of three kinds.
Ca is added in aqueous solution2+After cation, the Na on G segment units+After ion exchange occurs with divalent ion, the accumulation of G groups forms
Cross-meshed structure, so as to be transformed into hydrogel.
Sodium alginate extraction process is：The seaweed of harvest is dried, crushes, then through washed with impurities, obtains seaweed totally,
Add hot alkaline solution and dissolve seaweed, clean, add calcium chloride solution and be sufficiently mixed, obtain alginic acid calcium precipitate, add acid
Solution obtains seaweed colloid, adds sodium carbonate, obtains sodium alginate, and sodium alginate powder is obtained by dry milling.
Consideration of the invention based on filming performance and cost, sodium alginate concentration control range selection 1%-2.6%.
3rd, chitosan
Chitosan is to slough more than 50% acetyl group through deacetylation by chitin to be prepared, and chemistry is entitled poly-
(1,4) -2- amino-deoxidation-callose.It is unique alkaline polysaccharide in natural polysaccharide, has many unique physics
Chemical characteristic.Because of its good biocompatibility, minimum toxicity is economical, and enjoys study of pharmacy institute of various countries to pay close attention to.
Using there is substantial amounts of primary amino radical in chitosan molecule chain, there is substantial amounts of carboxyl on the strand of sodium alginate, quiet
Under electrical forces, polyelectrolyte film can be formed by positive and negative charge attraction.Film-forming machine is inquired into by differential scanning calorimetry
Reason.It is not that independent form is present in facial mask to promote chitosan and sodium alginate, but there occurs electrostatic interaction, with new
Be combined with each other state presence.Sodium alginate carboxyl and the electrostatic interaction of amino of chitosan quality inspection are the main of labyrinth
Strength.
Acted on using sodium alginate, chitosan both natural macromolecule amyloses by polyelectrolyte complex, form seaweed
Sour sodium/chitosan microcapsules, the active ingredient be conducive in formula are effectively sustained, there is provided long-acting moisturizing.
4th, calcium chloride
Calcium chloride, chemical formula CaCl2.Slight bitter, it is tasteless.It is typical ionic halide, is at room temperature white, hard
Matter fragment or particle.Colourless cubic crystal body, white or canescence, have granular, honeycomb is block, spherical shape, irregular particle shape,
It is powdered.Micro- malicious, odorless, mildly bitter flavor.Hygroscopicity is extremely strong, the easily deliquescence in air.It is soluble easily in water, while release a large amount of
Heat (dissolution enthalpy of calcium chloride is -176.2cal/g), its aqueous solution is in subacidity.It is dissolved in alcohol, acetone, acetic acid.With ammonia or second
Alcohol acts on, and generates CaCl respectively2·8NH3And CaCl2·4C2H5OH complex compounds.Solution crystallization under low temperature and separate out for six water
Thing, is then dissolved in the crystallization water of itself when being gradually heated to 30 DEG C, continues to heat gradual dehydration, and to 200 DEG C when is changed into two water
Thing, is again heated to 260 DEG C of anhydrous calcium chlorides for being then changed into white porosity shape.
Above-mentioned rectorite tears the calcium chloride water that mud mask uses 1.5%, various concentrations calcium chloride solution and sea
Mosanom forms aquagel fibre, slurry of mineral facial mask can be peeled off quickly from face so that slurry of mineral facial mask can
Easy cleaning is clean, brings the interesting and good skin care experience of consumer.
4.1 hydrogel mechanism
Sodium alginate is the linear anionic polysaccharide extracted from natural brown alga, mainly by α-mannuronic acid (M sections)
Linked with β .D guluronic acids by Isosorbide-5-Nitrae glycosidic bond for (G sections), and the copolymer formed according to different G-G, M-M, G-M fragments, when
In the presence of divalent calcium ions, calcium ion forms " core-shell structure copolymer " structure with the G sections accumulation in sodium alginate macromolecular, and crosslinking obtains three
Tie up network-like hydrogel.
Calcium alginate hydrogel is ion embedding type hydrogel, and sodium alginate is combined with the solution containing calcium ion, only
There are G units to participate in ionomer effect, two homopolymerization G units are acted on by consonance and combined, and the hydrophilic of brilliant is formed middle
Space, Ca2+Occupy these spaces and be tightly combined simultaneously mutually with interchain with multiple oxygen atom chelants on G units, alginic acid chain
Effect forms three-dimensional net structure, Ca2+Embedded in wherein forming " egg lattice structure " as egg, and the M blocks of homopolymerization cannot be with
Ca2+The structure is formed since its toughness is big, it is flexible the features such as.GM alternating blocks will be each embedding during hydrogel is generated
Section be chained up and and without directly effect.
4.2 hydrogel effects
Calcium alginate hydrogel network structure provides use except providing slurry of mineral facial mask and finishes, and is easily peeled off clear
Clean is convenient outer, has been also equipped with providing gentle environment for skin, it is allowed to the discharge of oxygen, protein and metabolite.Seaweed
Sour calcium hydrogel provides good physical barriers for skin, adds the moisture of skin surface, reduces moisture loss.
5th, effect of film formation factor
The influence of 5.1 chitosans
(1) molecular weight effects
Chitosan molecule amount includes the influencing mechanism of microcapsule membrane intensity, and chitosan molecule enters calcium alginate gel net
The extent of reaction between the diffusion rate and degree and chitosan molecule and sodium alginate molecule of network.The big chitosan of molecular mass
With larger link bulk, thus the resistance for diffusing into calcium alginate network is larger, so that diffusion rate and degree
It is all relatively low, therefore film formation reaction occurs mainly in calcium alginate gel surface, though on its chain link lotus positive electricity amino number
It is more, it is still relatively low with the extent of reaction of sodium alginate molecule, it is thin to form film；The low chitosan steric hindrance of molecular weight is low, into sea
Calcium alginate gel network is easy to, and the number of amino groups that the molecule amount of entrance increases while provides also increases, so that and alginic acid
The degree increase of sodium molecule reaction, the thickness of generation, anti-expansive force enhancing.
(2) pH value influences
Sodium alginate-chitosan cyst membrane is led to by the carboxyl of the amino and sodium alginate M units that are protonated in chitosan molecule
Cross electrostatic interaction to be formed, the pH value of chitosan solution directly affects the distribution of charges and molecule of two kinds of natural macromolecular materials
Structure, when the pH value of solution and the PKA=6.3 of chitosan close, chitosan molecule is almost not charged at this time, and charge density is shown
Writing reduces, and molecule space stretching, extension is small, and coefficient of molecular diffusion is higher, can occur deeper into calcium alginate gel network
Polyelectrolyte complex is deep, so thickness；
(3) solution concentration influences
Calcium alginate gel is prepared under the same conditions, when shell in the strength solution and calcium alginate of increase chitosan solution
Glycan concentration gradient increases therewith, causes the diffusion kinetics of chitosan molecule to increase, diffusion and the extent of reaction are also corresponding
Increase, film thicken, anti-swelliong power enhancing.
Above-mentioned rectorite tears mud mask selection chitosan oligomer, molecular weight 8000-12000KD, based on cost and
The consideration of filming performance, the concentration range control of chitosan is in 0.01%-0.5%, its solution ph prepared is close to 6.3.
Mud mask composition is the film forming using rectorite, sodium alginate as primary raw material in above-mentioned rectorite mud mask
Spray composite is configured to solution with calcium chloride, chitosan, sodium citrate.The one-step method film technique that the present invention uses, by shell
Glycan, calcium chloride, the mixed solution of sodium citrate are sprayed directly on the slurry of mineral facial mask containing sodium alginate, allow alginic acid
Sodium sequentially form chitosan precipitation layer, chitosan sodium alginate complexing layer, calcium alginate coacervate.
Above-mentioned rectorite tears mud mask its application method uniqueness, and customer generally needs to apply 15 minutes using mud mask
Left and right, facial mask of the present invention apply mud mask 10 minutes or so, and sprinkling calcium chloride is molten under conditions of being sprayed at eye closing using calcium chloride
Liquid is on the surface for covering mud mask, then face mask film 5 minutes, you can mud mask monoblock is peeled off face skin, gives flesh
Skin deep clean oil-control, closes moisturizing, and brings good skin care to experience.
Brief description of the drawings
Fig. 1 reduces percentage for fat content and compares figure；
Fig. 2 increases percentage variation diagram for moisture；
Fig. 3 increases percentage for moisture loss and compares figure.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps
More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make
Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention
The normally understood implication of technical staff is identical.Term used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases
The arbitrary and all combination of the Listed Items of pass.
The present embodiment rectorite tears mud mask, including mud mask composition and film forming spray composite.
1st, mud mask composition
(1) formulation ratio
(2) mud mask composite formula technique
1) glycerine, propane diols, butanediol, beta glucan, allantoin, sodium alginate is weighed by formulation ratio to be added separately to
In deionized water, 80-85 DEG C is heated to, with 200-250r/min, stirs 25min；
2) temperature is reduced to 75-80 DEG C, sequentially adds niacinamide, decoyl glycine, arginine, xanthans, with 400-
500r/min, stirs 15min；
3) weighed according to formulation ratio and sequentially add rectorite powder, titanium dioxide powder, SPEC305, open homogenizer, with
8000-10000r/min homogeneous 10min, and keep the temperature 30min；
4) temperature is reduced to 45-55 DEG C, sequentially adds Fourstamen Stephania Root extracting solution, decoyl hydroximic acid, with 600-800r/min,
Stir 30min, be cooled to room temperature is sufficient.
2nd, form a film spray composite
(1) formulation ratio
| Recipe ingredient | Embodiment 1 (%) | Embodiment 2 (%) | Embodiment 3 (%) |
| Calcium chloride | 1.5 | 1 | 2 |
| Chitosan | 0.1 | 0.5 | 0.05 |
| Sodium citrate | 0.05 | 0.01 | 0.1 |
| Decoyl hydroximic acid | 1 | 2 | 0.5 |
| Deionized water | To 100 | To 100 | To 100 |
(2) form a film spray composite Recipe
1) weigh chitosan according to formulation ratio to be added in deionized water, be warming up to 75-80 DEG C, with 500-600r/
Min, stirs 20-30min, until chitosan is completely dissolved；
2) 45-50 DEG C is cooled to, with 200-300r/min, sequentially adds calcium chloride, sodium citrate, decoyl hydroximic acid, directly
To whole dissolvings, stop stirring and be cooled to room temperature.
3rd, effect is evaluated and tested
3.1 oil-controls are evaluated and tested
(1) test philosophy
The effect of carrying out oil-Absorbing Sheets using effect using the skin oil and fat tester Sebumeter SM815 of German CK is commented
It is fixed.Using universally acknowledged SEBUMETER methods, it is be based on photometer principle for oil content test, a kind of 0.1mm thickness it is special
After delustring adhesive tape absorbs the grease on human skin, a kind of translucent adhesive tape will be become, its light transmission capacity will become
Change, the grease of absorption is more, and light transmission capacity will be bigger, can thus measure the content of skin oil and fat.Biggest advantage is
Test probe is small, easy to use, can test any position of skin.This is a kind of indirect measurement of grease glandular secretion thing
Method, as a result can be used for distinguishing different skin types, make to understand exactly the grease as caused by inside and outside reason and become
Change is possibly realized.
(2) test method
21 test objects of this time test selection, 3 one group of people are divided into 7 groups, and it is 3cm* to draw 3 sizes in forehead respectively
3cm regions, for blank sample (not wipe samples), control sample, (1 mud mask composition of embodiment is washed, without spray respectively
Mist) and patent sample (1 mud mask of embodiment+film forming spraying) carry out skin oil and fat content evaluation and test, each control sample takes three people to put down
Mean value computation fat content increment percentage carries out related judge.
1) selection test object skin health, age 18-30 Sui, after tested object know, agreement, study subject face cleaning
After 15 minutes, its forehead fat content is measured as initial value.
2) sample is not smeared in subject's forehead clear area, control sample area, patent sample area weigh 0.5ml Essences with 3cm*
After 3cm non-woven membranes cloth infiltration cover skin 20min, non-woven fabrics is removed, waits for quietly 10 minutes, carries out oil for three regions respectively
Fat assay, per 30min, test once, persistently evaluates and tests 2h；
3) test environment：T=25 DEG C of test environment temperature, humidity H=50；
4) testing time：Face cleaning is carried out before testing, is tested initial fat content within 15 minutes, is tested 30min respectively,
60min, 90min, 120min test grease content data；
5) test position：Forehead marks blank, control sample, the test zone of patent sample.
3.2 moisturizings are evaluated and tested
(1) test equipment
German CK companies Multi-functional skin tester, model C UTOMETER DUAL MPA 580, this patent select skin
Moisture test probe and moisture of skin scatter and disappear TEWL test probes.
(2) test method
1) skin moisture content MMV test methods
Test philosophy：
For the method using the moisture of capacitance method test human body keratoderma, its principle is based on water and other things
The difference in dielectric constant of matter is notable, different according to moisture content of skin, measures the capacitance difference of skin, its observed parameter can represent
Skin moisture value.
Experimental condition and volunteer require
Test environment conditions：Test environment temperature is 22 ± 1 DEG C, and humidity is 50 ± 5%, and carries out dynamic in real time and examine
Survey；
Volunteer requires：Effective volunteer at least 30 people, the age, (gestation or the newborn phase women in Pu removed between 16-65 Sui
Outside)：The basic value of forearm test zone capacitance method moisture of skin measure meaning is between 15-100：Without serious systemic disease, nothing
Immune deficiency or autoimmune disease person；No active anaphylactic disease person；Previously to skin-care cosmetics without severe allergy history
Person；Hormone medicine and immunodepressant person are not used in nearly one month：To participate in other clinical test persons；Use according to regulations
Test medicine and all information；All volunteers should fill in informed consent form before test；
Prepare before test：
Any product (cosmetics or topical drug) cannot be used within 2-3 days before recipient site.Before experiment, subject needs same
Surveyed in meaning cleaning both hands forearm, with dry face tissue wiped clean.Surveyed after cleaning in subject's both hands forearm and carry out measured zone
Mark.At least 30min that sits quietly in standard room should met before official testing, it is impossible to drink water, forearm exposure, puts in test mode
Put, keep loosening.
Testing procedure：
Mark 3*3cm on the inside of left and right arm in experiment2Test area, same arm can mark multiple regions, interregional
Every 1cm.Patent sample (1 mud mask composition of embodiment+film forming spray composite) and control sample (1 mud mask group of embodiment
Compound washing wipes) it is randomly dispersed in left and right arm.Tested region and check plot are carried out using capacitance method skin analyzer
The measurement in domain.Each region is according to parallel determination 15 times.The blank value of each test zone is first measured, then by 1.0 ± 0.1mg samples
Product/cm2Dosage, experiment is spread evenly across in trial zone using latex finger cot.Smearing measures 30min, 60min respectively,
The moisture content of skin (during verification by this time measure) of 90min, tested region and control zone, the test of same volunteer by
Same survey crew completes.
Test data：
Design empirically measures the MMV values of each period respectively.
2) percutaneous moisture loss TEWL test methods
Test philosophy：
The measuring principle of the test apparatus derives from FICK Fick'ss law of diffusion：Dm/dt=D.A.dp/dx.Pass through two groups
Temperature-humidity sensor measures the water vapor pressure ladder that nearly epidermis (about in 1cm) is formed by cuticula moisture loss in different bright spots
Degree, directly measures the amount of moisture percutaneously distributed.TEWL values are an important symbols of skin barrier quality, and the TEWL values of skin are got over
It is low, illustrate that the barrier function of skin is better, on the contrary it is poorer.
Experimental condition and volunteer require
Test environment conditions：Test environment temperature is 22 ± 1 DEG C, and humidity is 50 ± 5%, and carries out dynamic in real time and examine
Survey；
Volunteer requires：Effective volunteer at least 30 people, the age, (gestation or the newborn phase women in Pu removed between 16-65 Sui
Outside)：The basic value of forearm test zone capacitance method moisture of skin measure meaning is between 15-100：Without serious systemic disease, nothing
Immune deficiency or autoimmune disease person；No active anaphylactic disease person；Previously to skin-care cosmetics without severe allergy history
Person；Hormone medicine and immunodepressant person are not used in nearly one month：To participate in other clinical test persons；Use according to regulations
Test medicine and all information；All volunteers should fill in informed consent form before test；
Prepare before test：
Any product (cosmetics or topical drug) cannot be used within 2-3 days before recipient site.Before experiment, subject needs same
Surveyed in meaning cleaning both hands forearm, with dry face tissue wiped clean.Surveyed after cleaning in subject's both hands forearm and carry out measured zone
Mark.At least 30min that sits quietly in standard room should met before official testing, it is impossible to drink water, forearm exposure, puts in test mode
Put, keep loosening.
Testing procedure：
Mark 3*3cm on the inside of left and right arm in experiment2Test area, same arm can mark multiple regions, interregional
Every 1cm.Patent sample (1 mud mask composition of embodiment+film forming spray composite) and control sample (1 mud mask group of embodiment
Compound washing wipes) it is randomly dispersed in left and right arm.Tested region and check plot are carried out using capacitance method skin analyzer
The measurement in domain.Each region is according to parallel determination 15 times.The blank value of each test zone is first measured, then by 1.0 ± 0.1mg samples
Product/cm2Dosage, experiment is spread evenly across in trial zone using latex finger cot.Smearing measures 30min, 60min respectively,
The moisture of skin of 90min, tested region and control zone scatters and disappears TEWL (during verification by this time measure), same volunteer's
Test is completed by same survey crew.Test data
Empirically design the TEWL values for measuring day part respectively.
4th, effect evaluation result
4.1 fat content
O%=(O1-O2)/O1*100%
O1- uses preceding skin oil and fat content；
O2- uses rear skin oil and fat content；
O%- fat contents reduce percentage；
As shown in Figure 1：The mud mask that embodiment 1 is prepared using rectorite powder, sodium alginate, using chitosan, chlorination
The tearing mud mask that calcium is formed for spraying prepared by primary raw material, due to sodium alginate, chitosan, calcium chloride form densification
Mud mask, having significantly reduces fat secretion, and 30min fat contents suppress fat secretion after being reduced to 78.38%, 120min
Up to 47.61%.
4.2 moisture
W%=(W2-W1)/W1*100%
W1- uses preceding skin moisture content；
W2- uses rear skin moisture content；
W%- uses front and rear skin moisture content increase percentage.
As shown in Figure 2：The mud mask that embodiment 1 is prepared using rectorite powder, sodium alginate, using chitosan, chlorination
The tearing mud mask that calcium is formed for spraying prepared by primary raw material, due to sodium alginate, chitosan, calcium chloride form densification
Mud mask, has effects that to be obviously improved skin moisture content, control sample lifting moisture is 18.83%, patent sample
Moisture is lifted up to 35%.
4.3 moisture loss
T%=(T2-T1)/T1*100%
T1- uses preceding skin surface moisture loss value；
T2- uses rear skin surface moisture loss value；
T%- is scattered and disappeared using front and rear moisture of skin increases percentage.
As shown in Figure 3：The mud mask that embodiment 1 is prepared using rectorite mud, sodium alginate, using chitosan, chlorine
Change the tearing mud mask that calcium is formed for spraying prepared by primary raw material, due to sodium alginate, chitosan, calcium chloride form densification
Mud mask, have effects that relative reduction moisture of skin scatters and disappears, so as to prove that tear-pull mud face is gently peeled off, Bu Huizao
Into skin barrier injury.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, its description is more specific and detailed, but simultaneously
Cannot therefore it be construed as limiting the scope of the patent.It should be pointed out that come for those of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (9)
1. a kind of rectorite tears mud mask, it is characterised in that including mud mask composition and film forming spray composite；
The mud mask composition includes the component of following mass percent：Rectorite powder 30-40%, sodium alginate 1-
2.6%, auxiliary material 10-20%, adds water to 100%；
The film forming spray composite includes the component of aqueous solvent and following mass percent：Calcium chloride 1-2%, chitosan
0.01-0.5%, sodium citrate 0.01-0.1%.
2. rectorite according to claim 1 tears mud mask, it is characterised in that the particle diameter of the rectorite powder is 1-
10μm。
3. rectorite according to claim 1 tears mud mask, it is characterised in that the molecular weight of chitosan is 8000-
12000KD。
4. mud mask is torn according to claim 1-3 any one of them rectorite, it is characterised in that the auxiliary material, which is selected from, to be protected
One or more in humectant, thickener, film forming agent or preservative.
5. rectorite according to claim 4 tears mud mask, it is characterised in that the auxiliary material includes glycerine, the third two
Alcohol, butanediol, beta glucan, xanthans, Sepic 350, niacinamide, decoyl glycine, arginine, titanium dioxide, Fourstamen Stephania Root
Extracting solution, allantoin and decoyl hydroximic acid.
6. rectorite according to claim 5 tears mud mask, it is characterised in that the mud mask composition includes
The component of following mass percent：Rectorite powder 30-40%, sodium alginate 1-2.6%, glycerine 1-3%, propane diols 0.5-2%,
Butanediol 2-4%, beta glucan 0.1-1%, xanthans 0.1-0.5%, Sepic 350 1-3%, niacinamide 1-3%, decoyl
Glycine 0.1-1%, arginine 0.1-1%, titanium dioxide 1-2%, Fourstamen Stephania Root extracting solution 0.1-1%, allantoin 0.1-
0.5%, decoyl hydroximic acid 0.5-2%, adds water to 100%.
7. mud mask is torn according to claim 1-3 any one of them rectorite, it is characterised in that the film forming spraying group
Compound further includes preservative.
8. rectorite according to claim 7 tears mud mask, it is characterised in that the film forming spray composite includes
The component of aqueous solvent and following mass percent：Calcium chloride 1-2%, chitosan 0.01-0.5%, sodium citrate 0.01-
0.1% and decoyl hydroximic acid 0.5-2%.
9. rectorite according to claim 1 tears mud mask, it is characterised in that
The mud mask composition includes the component of following mass percent：Rectorite powder 35%, sodium alginate 1.5% are sweet
Oil 2%, propane diols 1%, butanediol 3%, beta glucan 0.5%, xanthans 0.2%, Sepic350 2%, niacinamide 2% are pungent
Acyl glycine 0.5%, arginine 0.5%, titanium dioxide 1.5%, Fourstamen Stephania Root extracting solution 0.5%, allantoin 0.2%, decoyl hydroxyl
Oxime acid 1%, adds water to 100%；
The film forming spray composite includes the component of aqueous solvent and following mass percent：Calcium chloride 1.5%, chitosan
0.1%, sodium citrate 0.05% and decoyl hydroximic acid 1%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711436906.8A CN107951732B (en) | 2017-12-26 | 2017-12-26 | Rectorite tearing slurry mask |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711436906.8A CN107951732B (en) | 2017-12-26 | 2017-12-26 | Rectorite tearing slurry mask |
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| CN107951732B CN107951732B (en) | 2020-10-30 |
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| CN201711436906.8A Active CN107951732B (en) | 2017-12-26 | 2017-12-26 | Rectorite tearing slurry mask |
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| CN109260032A (en) * | 2018-09-18 | 2019-01-25 | 广州达人研选生物科技有限公司 | A kind of combined type easily tears mud film and its application method |
| CN110075005A (en) * | 2019-06-12 | 2019-08-02 | 广州相宜化妆品有限公司 | Facial mask preformed objects and preparation method thereof and facial mask and facial mask application method |
| CN110721140A (en) * | 2019-11-29 | 2020-01-24 | 海南女人春天美容有限公司 | Uterus warming care membrane powder and preparation method thereof |
| CN113057915A (en) * | 2021-04-13 | 2021-07-02 | 东晟源研究院(广州)有限公司 | Alga mask for improving skin |
| CN113164344A (en) * | 2018-11-29 | 2021-07-23 | 联合利华知识产权控股有限公司 | Clay mask composition and method of use thereof |
| CN113194921A (en) * | 2018-12-29 | 2021-07-30 | 莱雅公司 | Set for caring skin |
| CN115444782A (en) * | 2022-09-08 | 2022-12-09 | 浙江科技学院 | Rapid film-forming liquid smearing mask, preparation method and use method |
| CN115607481A (en) * | 2022-10-13 | 2023-01-17 | 绍兴市柯桥区东纺纺织产业创新研究院 | Spray type mask and preparation method thereof |
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| CN109260032A (en) * | 2018-09-18 | 2019-01-25 | 广州达人研选生物科技有限公司 | A kind of combined type easily tears mud film and its application method |
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| CN110721140A (en) * | 2019-11-29 | 2020-01-24 | 海南女人春天美容有限公司 | Uterus warming care membrane powder and preparation method thereof |
| CN113057915A (en) * | 2021-04-13 | 2021-07-02 | 东晟源研究院(广州)有限公司 | Alga mask for improving skin |
| CN115444782A (en) * | 2022-09-08 | 2022-12-09 | 浙江科技学院 | Rapid film-forming liquid smearing mask, preparation method and use method |
| CN115607481A (en) * | 2022-10-13 | 2023-01-17 | 绍兴市柯桥区东纺纺织产业创新研究院 | Spray type mask and preparation method thereof |
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| CN107951732B (en) | 2020-10-30 |
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