CN107946433A - A kind of white light LEDs - Google Patents

A kind of white light LEDs Download PDF

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Publication number
CN107946433A
CN107946433A CN201711101524.XA CN201711101524A CN107946433A CN 107946433 A CN107946433 A CN 107946433A CN 201711101524 A CN201711101524 A CN 201711101524A CN 107946433 A CN107946433 A CN 107946433A
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CN
China
Prior art keywords
quantum dot
lens
white light
light leds
dot film
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Pending
Application number
CN201711101524.XA
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Chinese (zh)
Inventor
张家雨
杨鸿宇
陈章扬
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Southeast University
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Southeast University
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Application filed by Southeast University filed Critical Southeast University
Priority to CN201711101524.XA priority Critical patent/CN107946433A/en
Publication of CN107946433A publication Critical patent/CN107946433A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/501Wavelength conversion elements characterised by the materials, e.g. binder
    • H01L33/502Wavelength conversion materials
    • H01L33/504Elements with two or more wavelength conversion materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/58Optical field-shaping elements

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Led Device Packages (AREA)

Abstract

The present invention provides a kind of white light LEDs, the white light LEDs include base, the blue chip being arranged on the base, cover on the first lens on the blue chip, the second lens on the base and at least two layers of quantum dot film between first lens and second lens, wherein, the quantum dot film includes red quantum dot film and green quantum dot film.The white light LEDs of the present invention increase the light emitting angle of LED component, improve quantum dot influence of lifetime because heated;White light LED color temperature uniformity is improved, improves color saturation, realizes the wide display effect of colour gamut;The quantity of the quanta point material used in white light LEDs can be effectively reduced, is effectively improved energy consumption, realizes straight-down negative quantum dot LED component to ultra-thin development;It is effectively improved quantum dot and shows cost.

Description

A kind of white light LEDs
Technical field
The invention belongs to technical field of LED illumination, a kind of particularly white light LEDs for display backlight.
Background technology
LED (light emitting diode) is that one kind is based on semiconductor light emitting made of P-N junction electroluminescent principle Device, has the advantages that light efficiency is high, service life is long, pollution-free, small, it has also become green lighting technique of future generation.With Breakthrough using nitride as the third generation semiconductor material technology of representative, the semiconductor based on high power high brightness led Lighting Industry is rapidly growing in the whole world, just as semi-conductor photoelectronic industry new growth engines, and in traditional lighting field A revolution is triggered.LED gradually substitutes conventional light source, applied to every field, including back light unit, street lamp, car light etc..
The commercialization white light LEDs of mainstream currently on the market, be using coat on blue-light LED chip it is yellow, green, red a kind of or A variety of fluorescent powders are realized.Existing fluorescent powder paint-on technique includes dotting glue method, shape-preserving coating method, away from cladding process, dispensing Method is simple, of low cost thus be used widely due to its technique.Fluorescent powder conversion hysteria white light LEDs have technique simply into Ripe, the features such as cost is relatively low, be the major product in current illumination market, but fluorescent conversion type white light LEDs still suffer from The problem of many and challenge.
Quanta point material is the semiconductor crystal of nanoscale, has the spies such as Wavelength tunable, quantum yield height, excitation purity height Point, has become important nano luminescent material, is hopeful to change the limitation of conventional fluorescent powder material selection, improves existing white light The luminescent properties of LED.In recent years, nano-luminescent material receives significant attention, and gets the nod and answer in display lighting area With.Utilization of the quantum dot in display backlight illumination at present, mainly using two ways, one kind is to be placed in quantum dot solution In container, quantum dot is then illuminated into white light using side entering type LED light bar, in this way, quantum dot usage amount is very Greatly, but quantum dot price is high, substantially increases manufacture cost, is unfavorable for marketing.Another way is to be prepared into Quantum dot film.However, being primarily present, color saturation is low, the colour temperature uniformity is not high, luminous efficiency is low, fluorescent powder fever is serious The problems such as, it is difficult to display backlight lighting area.
In order to solve the problems, such as the cost of quantum dot backlight and excitation purity, and the development of quantum dot back lighting is promoted, It is necessary to provide a kind of new white light LEDs.
The content of the invention
In order to increase the light emitting angle of LED light, the color temperature uniformity of white light is improved, and solves quantum dot back lighting The problem of cost and color saturation, realize downward back optical illumination ultrathin, described the present invention provides a kind of white light LEDs White light LEDs include base, the blue chip being arranged on the base, cover on the first lens on the blue chip, installation The second lens on the base and at least two layers of quantum dot film between first lens and second lens, Wherein, the quantum dot film includes red quantum dot film and green quantum dot film.
As an improvement first lens are lens of ball crown type, and first lens include hemispherical The inner surface and the outer surface.
As an improvement second lens are free-form surface lens, and second lens are including hemispheric The outer surface of inner surface and free form surface.
As an improvement the inner surface and the outer surface of first lens and second lens is centrosymmetric, And symmetry axis overlaps.
As an improvement second lens are arranged on the top of first lens, and first lens and There are gap, the gap it is about 0.5-1mm between second lens.
As an improvement the red quantum dot film includes red quantum dot, the red quantum dot is CdSe@CdS Colloidal Quantum Dots.
As an improvement the size of the red quantum dot is in the range of 10nm-20nm, the red quantum dot Launch wavelength is less than 40nm in 600-640nm and halfwidth.
As an improvement the green quantum dot film includes green quantum dot, the green quantum dot is CdZnSeS ZnS Colloidal Quantum Dots.
As an improvement the size of the green quantum dot is in the range of 10nm-20nm, the green quantum dot Launch wavelength 520-540nm and halfwidth is less than 30nm.
As an improvement the light emitting angle of the white light LEDs is in the range of 140-150 °.
The beneficial effects of the invention are as follows:
The white light LEDs of the present invention increase the light emitting angle of LED component, improve quantum dot because heated and lifetime Influence;White light LED color temperature uniformity is improved, improves color saturation, realizes the wide display effect of colour gamut;Can be effective Reduce the quantity of quanta point material used in white light LEDs, be effectively improved energy consumption, realize straight-down negative quantum dot LED component to Ultra-thin development;It is effectively improved quantum dot and shows cost.
Brief description of the drawings
Fig. 1 is the diagrammatic cross-section of the white light LEDs of the present invention.
Fig. 2 is the schematic diagram of the first lens of the present invention.
Fig. 3 is the schematic diagram of the second lens of the present invention.
Fig. 4 is blue chip distribution curve flux and passes through the distribution curve flux after two lens.
Fig. 5 is the spectrogram of the white light LEDs of the present invention.
Fig. 6 is the white light LEDs angle colour temperature figure of the present invention.
Fig. 7 is the chromaticity coordinates of white light LEDs and the schematic diagram of colour triangle of the present invention.
Embodiment
The embodiment of the present invention is described in further detail below in conjunction with Fig. 1 to Fig. 7.
Embodiment 1
As shown in Figure 1 to Figure 3, a kind of backlight module for straight-down negative LED of present invention offer can simultaneously improve color and satisfy With the white light LEDs of degree, which includes base 7, the blue chip 5 being arranged on base, positioned at the two sides edge of base Point stent 6, cover on the first lens 1 on blue chip 5, the second lens 2 on base 7 and in the first lens 1 And the second quantum dot film between lens 2.
Specifically, white light LEDs include the first lens 1, are arranged on the second lens 2 of the top of the first lens 1, wherein, the One lens 1 are lens of ball crown type, and the first lens 1 have hemispheric the inner surface and the outer surface;Second lens 2 are freely bent Face lens, the second lens 2 have the outer surface of hemispheric inner surface and free form surface, if the bottom surface of the second lens 2 is equipped with Recessed bag is done, recessed bag is located at the peripheral part of bottom, and recess is for pyramid-shaped or other shapes and with optically focused and guide-lighting effect;The The inner surface and the outer surface of one lens and the second lens is centrosymmetric, and symmetry axis overlaps;First lens 1 and second There is the gap of about 0.5-1mm between lens 2, which is mixed light space, in the gap applied in two coats quantum dot film, tool Body includes green quantum dot film 3 and red quantum dot film 4;Include the air gap between quantum dot film and blue chip 5;Lens Material is, for example, polymethyl methacrylate (PMMA) or polystyrene (PC) etc., and light transmittance is high, compared to devices such as reflectors Part light absorbs are small, light efficiency higher.The light emitting angle of the white light LEDs of said structure is in the range of 140-150 °.Due to green Quantum dot can only absorb blue light without absorbing feux rouges, thus, it is possible to reduce because of situations such as color temperature shift caused by reabsorption. Since, there are distance, institute produces quantum dot because blue chip 5 generates heat so as to reducing between quantum dot film and blue chip 5 Influence.In the present embodiment, red quantum dot is CdSe CdS (core shell) Colloidal Quantum Dots, and green quantum dot is CdZnSeS@ZnS (core@shells) Colloidal Quantum Dots, but not limited to this, quantum dot can also be the semiconductor of II-VI elements composition Compound such as CdSe, CdTe, MgS, MgSe, MgTe, CaS, CaSe, CaTe, SrS, SrSe, SrTe, BaS, BaSe, BaTe, One or more combinations of ZnS, ZnSe, ZnTe and CdS or or iii-v element composition semiconducting compound such as One or more combinations of GaN, GaP, GaAs, InN, InP and InAs, or the semiconductor transformation being made of II-VI group element Several mixing in the semiconducting compound of compound and iii-v element composition.
A curves in Fig. 4 are the distribution curve flux of the blue chip of the present invention, which is lambertian.Pass through one After secondary lens and secondary lens, shaping is carried out to the distribution curve flux of blue chip 5, the b in the distribution curve flux such as Fig. 4 after shaping is bent It is side light-emitting mode shown in line, light emitting angle is 140 °, and the distribution curve flux after shaping can be formed in close luminous flat The hot spot of uniform-illumination, it is thus possible to reduce the thickness of down straight aphototropism mode set.
Specifically, 5 launch wavelength of blue chip is less than the blue light of 25nm in 440nm to 460nm and halfwidth FWHM.Green And the size of red quantum dot, between 10nm-20nm, the launch wavelength 520-540nm and halfwidth FWHM of green quantum dot are small In 30nm, the launch wavelength of red quantum dot is less than 40m in 600-640nm and halfwidth FWHM.The blue light that blue chip 5 is launched Fall in the absorption band of quantum dot, quantum dot film inspires green light or feux rouges after absorbing blue light, then and through quantum dot film Blue light carry out being mixed to form quantum spot white light in mixed light space, the NTSC color gamut for realizing white light LEDs is at least 110%, Colour temperature greatly improves color temperature uniformity between 5000-6000, so as to fulfill the display effect that color saturation is high, colour gamut is wide Fruit, the spectrum of quantum spot white light LED are as shown in Figure 5.Because the luminosity of quantum dot also has much relations, temperature with its temperature It is likely to result in ligand when rising to come off and cause the increase of quantum dot surface defect, therefore, it may occur that phenomena such as photobleaching.Adopt With the method remotely coated, on the one hand quantum dot can be made to have a certain distance relative to blue chip 5, will not be because of blue light core 5 operation of piece generates heat and causes the change of quantum dot property;On the other hand, quantum dot can also be increased by the second lens Heat dissipation, soon can distribute heat when heated.In addition, the size of quantum dot is smaller, its size is much smaller than visible ray Wavelength, because without causing scattering, its light-emitting mode shines for isotropism, can be considered that what an isotropism shone shines Face.In the present embodiment, the light that quantum dot film is sent can be reflected back by the light of some after lens due to being totally reflected In mirror, the wide majority of this part can be reflected by the tapered recess of the second lens and pass through lens outgoing.Using this second Lens can make distribution curve flux of the light that quantum dot is sent in space match with blue chip 5 by the distribution curve flux after lens, Distribution of the colour temperature in space also can be very uniformly specific as shown in Figure 6.
In addition, the spectrum by calculating blue chip, green quantum dot film 3 and red quantum dot film 4, in the CIE colour spaces Middle calculating chromaticity coordinates and colour triangle are as shown in Figure 7.The halfwidth FWHM of quantum dot is relatively narrow, similar to monochromatic light, by mixed Color saturation higher after light, colour temperature is relatively low, therefore the white light LEDs of the present invention are more suitable for display field.
Compared with prior art, white light LEDs of the invention increase the light emitting angle of LED component, improve quantum dot because It is heated and the influence of lifetime;White light LED color temperature uniformity is improved, improves color saturation, it is wide to realize colour gamut Display effect;The quantity of the quanta point material used in white light LEDs can be effectively reduced, is effectively improved energy consumption, under realizing directly Formula quantum dot LED component is to ultra-thin development;It is effectively improved quantum dot and shows cost.
The white light LEDs of the present invention are used for down straight aphototropism mode set, which provides the white-light illuminating back of the body for display device Light, wherein display device are, for example, liquid crystal display device, Electronic Paper, mobile phone, tablet computer, television set, display, notebook electricity Any product or component with display function such as brain, Digital Frame, navigator.
Above embodiment and embodiment are that the specific of white light LEDs proposed by the present invention is supported, it is impossible to are limited with this Determine protection scope of the present invention, every according to technological thought proposed by the present invention, that is done on the basis of the technical program is any Equivalent variations or equivalent change, still fall within the scope of technical solution of the present invention protection.

Claims (10)

  1. A kind of 1. white light LEDs, it is characterised in that the white light LEDs include base, be arranged on the base blue chip, Cover on the first lens on the blue chip, the second lens on the base and in first lens and institute At least two layers of quantum dot film between the second lens is stated, wherein, the quantum dot film includes red quantum dot film and green quantum Point film.
  2. 2. white light LEDs according to claim 1, it is characterised in that first lens are lens of ball crown type, and First lens include hemispheric the inner surface and the outer surface.
  3. 3. white light LEDs according to claim 1, it is characterised in that second lens are free-form surface lens, and institute Stating the second lens includes the outer surface of hemispheric inner surface and free form surface.
  4. 4. white light LEDs according to claim 1, it is characterised in that the interior table of first lens and second lens Face and outer surface are centrosymmetric, and symmetry axis overlaps.
  5. 5. white light LEDs according to claim 1, it is characterised in that second lens are arranged on first lens Top, and be about 0.5-1mm there are gap, the gap between first lens and second lens.
  6. 6. white light LEDs according to claim 1, it is characterised in that the red quantum dot film includes red quantum dot, institute It is CdSe@CdS Colloidal Quantum Dots to state red quantum dot.
  7. 7. white light LEDs according to claim 6, it is characterised in that the size of the red quantum dot is 10nm-20nm's In the range of, the launch wavelength of the red quantum dot is less than 40nm in 600-640nm and halfwidth.
  8. 8. white light LEDs according to claim 1, it is characterised in that the green quantum dot film includes green quantum dot, institute It is CdZnSeS ZnS Colloidal Quantum Dots to state green quantum dot.
  9. 9. white light LEDs according to claim 8, it is characterised in that the size of the green quantum dot is 10nm-20nm's In the range of, the launch wavelength 520-540nm and halfwidth of the green quantum dot are less than 30nm.
  10. 10. white light LEDs according to claim 1, it is characterised in that the light emitting angle of the white light LEDs is at 140-150 ° In the range of.
CN201711101524.XA 2017-11-09 2017-11-09 A kind of white light LEDs Pending CN107946433A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110319368A (en) * 2019-08-19 2019-10-11 Tcl华瑞照明科技(惠州)有限公司 LED light bar and backlight module
CN110501842A (en) * 2018-05-18 2019-11-26 深圳Tcl新技术有限公司 A kind of backlight module and display device
CN112083520A (en) * 2020-09-26 2020-12-15 南通惟怡新材料科技有限公司 Quantum dot lens, backlight module, display device and quantum dot lens manufacturing method
CN114777078A (en) * 2022-04-19 2022-07-22 东莞雷笛克光学有限公司 LED quantum dot lens
CN116841083A (en) * 2023-07-06 2023-10-03 南通惟怡新材料科技有限公司 High-color-gamut quantum dot lens and backlight module manufacturing method

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Publication number Priority date Publication date Assignee Title
CN103542326A (en) * 2013-09-30 2014-01-29 易美芯光(北京)科技有限公司 Optical device capable of realizing high-color-gamut backlight
CN203784738U (en) * 2013-09-30 2014-08-20 易美芯光(北京)科技有限公司 Optical device capable of achieving high color gamut backlight
CN105856763A (en) * 2016-02-25 2016-08-17 北京北达聚邦科技有限公司 Quantum dot fluorescent film with double-monocolor-layer structure and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103542326A (en) * 2013-09-30 2014-01-29 易美芯光(北京)科技有限公司 Optical device capable of realizing high-color-gamut backlight
CN203784738U (en) * 2013-09-30 2014-08-20 易美芯光(北京)科技有限公司 Optical device capable of achieving high color gamut backlight
CN105856763A (en) * 2016-02-25 2016-08-17 北京北达聚邦科技有限公司 Quantum dot fluorescent film with double-monocolor-layer structure and manufacturing method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110501842A (en) * 2018-05-18 2019-11-26 深圳Tcl新技术有限公司 A kind of backlight module and display device
CN110319368A (en) * 2019-08-19 2019-10-11 Tcl华瑞照明科技(惠州)有限公司 LED light bar and backlight module
CN112083520A (en) * 2020-09-26 2020-12-15 南通惟怡新材料科技有限公司 Quantum dot lens, backlight module, display device and quantum dot lens manufacturing method
WO2022062938A1 (en) * 2020-09-26 2022-03-31 南通惟怡新材料科技有限公司 Quantum dot lens, backlight module, display device, and quantum dot lens manufacturing method
US11822098B2 (en) 2020-09-26 2023-11-21 Nantong Veeyee New Material Technology Co., Ltd Quantum dot lens, backlight module, display device and manufacturing method of quantum dot lens
CN114777078A (en) * 2022-04-19 2022-07-22 东莞雷笛克光学有限公司 LED quantum dot lens
CN114777078B (en) * 2022-04-19 2024-07-12 东莞雷笛克光学有限公司 LED quantum dot lens
CN116841083A (en) * 2023-07-06 2023-10-03 南通惟怡新材料科技有限公司 High-color-gamut quantum dot lens and backlight module manufacturing method

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Application publication date: 20180420