CN107936853A - A kind of high-performance environment protection type adhesive - Google Patents
A kind of high-performance environment protection type adhesive Download PDFInfo
- Publication number
- CN107936853A CN107936853A CN201711084763.9A CN201711084763A CN107936853A CN 107936853 A CN107936853 A CN 107936853A CN 201711084763 A CN201711084763 A CN 201711084763A CN 107936853 A CN107936853 A CN 107936853A
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- CN
- China
- Prior art keywords
- protection type
- environment protection
- type adhesive
- performance environment
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of high-performance environment protection type adhesive, includes the component of following percentage by weight：Polyisoprene 0~20%, polyvinyl alcohol 0~15%, polyacrylamide 1~30%, methyl hydroxyethylcellulose 0.5~10%, antioxidant N dibutylamino dithiocarbonic acids zinc 0.1~10%, titanium dioxide 0~10%, antimony oxide 0~5%, fire retardant 0~15%, plasticizer 0~25%, surplus are solvent, a kind of high-performance environment protection type adhesive provided by the invention, aqueous solution is made into by the way that the claddings such as leather leftover pieces are extracted gelatin, after rising temperature for dissolving, carry out cross-linking reaction with epoxides and form；A kind of high-performance environment protection type adhesive provided herein has the advantages that ecological, pollution-free, glueability is good, it is the inaccessiable excellent properties of traditional small molecule adhesive institute, and environment will not be polluted in the production and use process, there is great economy and social value.
Description
Technical field
The present invention relates to field of adhesive technology, and in particular to a kind of high-performance environment protection type adhesive.
Background technology
Gluing is an essential link in leatherware production, and the leather adhesive used at present is mostly with petrochemical industry
Product chemically reacts the synthetic adhesive being prepared through a variety of.Project is for conventional leather synthetic adhesive asking not environmentally
Topic, by analyzing the fundamental characteristics of leather synthetic adhesive, using improved from leather adhesive raw material, the side of finished product process modification
Method, works out the efficient leather adhesive of ecological environment-friendly type for meeting product requirement, and forms corresponding patented technology, is developed
The efficient leather adhesive of ecological environment-friendly type there is good plybonding effect, can preferably improve the product matter of leatherware goods
Amount.Gluing is an essential link in leather production, it can assign leather products good fixed effect, mould U.S.
Beautiful appearance, meets different demands of the consumer to leather products, assigns leather products fashion breath, improves the attached of leather products
It is value added.Most of leather adhesive largely used at present is using petrochemicals as raw material, is prepared through a variety of chemical reactions
The synthetic adhesive formed.Synthetic adhesive is gluing good, and performance is stablized, but can produce a variety of nuisances in process of production
Matter, can both pollute environment in process of production, can also removing residue formaldehyde, volatile organic gases etc. are poisonous has in adhesive products
Evil material, damages human body, therefore, a kind of ecological environment-friendly type leather adhesive is developed, so as to which leather system is better achieved
The gluing functional meaning of product is great.
The content of the invention
The technical problems to be solved by the invention are in view of the above shortcomings of the prior art and provide a kind of easy to use, dye
Good, the environmentally protective high-performance environment protection type adhesive of color effect.
The present invention is that technical solution is used by solving the above problems：
The present invention provides a kind of high-performance environment protection type adhesive, includes the component of following percentage by weight：
Polyisoprene 0~20%,
Polyvinyl alcohol 0~15%,
Polyacrylamide 1~30%,
Methyl hydroxyethylcellulose 0.5~10%,
Antioxidant N- dibutylamino dithiocarbonic acids zinc 0.1~10%,
Titanium dioxide 0~10%,
Antimony oxide 0~5%,
Fire retardant 0~15%,
Plasticizer 0~25%,
Surplus is solvent.
Further, the solvent for ethanol or ethylene glycol one or both of mixing.
Further, the toughener that percentage by weight is 0~25% is further included.
Further, the sodium hydroxide that percentage by weight is 0~2% is further included.
Further, butyl acrylate, Isooctyl acrylate monomer, acrylic acid -2- that percentage by weight is 0~25% are further included
One or more of combinations in ethylhexyl.
The beneficial effects of the present invention are：
A kind of high-performance environment protection type adhesive provided by the invention, is matched somebody with somebody by the way that the claddings such as leather leftover pieces are extracted gelatin
Into aqueous solution, after rising temperature for dissolving, carry out cross-linking reaction with epoxides and form；A kind of high-performance environment protection type provided herein
Adhesive has the advantages that ecological, pollution-free, glueability is good, is the inaccessiable superiority of traditional small molecule adhesive institute
Can, and environment will not be polluted in the production and use process, there is great economy and social value.
Embodiment
Embodiments of the present invention are illustrated with reference to specific, only for reference and explanation uses, and does not form special to the present invention
The limitation of sharp protection domain.
Embodiment 1
The present embodiment provides a kind of high-performance environment protection type adhesive, include the component of following percentage by weight：
Polyisoprene 5%,
Polyvinyl alcohol 5%,
Polyacrylamide 5%,
Methyl hydroxyethylcellulose 1%,
Antioxidant N- dibutylamino dithiocarbonic acids zinc 5%,
Titanium dioxide 2%,
Antimony oxide 2%,
Fire retardant 1%,
Plasticizer 5%,
Surplus is solvent.
In the present embodiment, the solvent is ethanol 2.
In the present embodiment, the toughener that percentage by weight is 5% is further included.
In the present embodiment, the sodium hydroxide that percentage by weight is 1% is further included.
In the present embodiment, butyl acrylate, Isooctyl acrylate monomer, acrylic acid -2- that percentage by weight is 12% are further included
The composition of ethylhexyl.
Embodiment 2
The present embodiment provides a kind of high-performance environment protection type adhesive, include the component of following percentage by weight：
Polyisoprene 10%,
Polyvinyl alcohol 10%,
Polyacrylamide 10%,
Methyl hydroxyethylcellulose 1%,
Antioxidant N- dibutylamino dithiocarbonic acids zinc 5%,
Titanium dioxide 2%,
Antimony oxide 2%,
Fire retardant 1%,
Plasticizer 5%,
Surplus is solvent.
In the present embodiment, the solvent is ethanol 2.
In the present embodiment, the toughener that percentage by weight is 5% is further included.
In the present embodiment, the sodium hydroxide that percentage by weight is 1% is further included.
In the present embodiment, butyl acrylate, Isooctyl acrylate monomer, acrylic acid -2- that percentage by weight is 12% are further included
The composition of ethylhexyl.
Embodiment 3
The present embodiment provides a kind of high-performance environment protection type adhesive, include the component of following percentage by weight：
Polyisoprene 20%,
Polyvinyl alcohol 15%,
Polyacrylamide 15%,
Methyl hydroxyethylcellulose 10%,
Antioxidant N- dibutylamino dithiocarbonic acids zinc 5%,
Titanium dioxide 2%,
Antimony oxide 2%,
Fire retardant 1%,
Plasticizer 5%,
Surplus is solvent.
In the present embodiment, the solvent is ethanol 2.
In the present embodiment, the toughener that percentage by weight is 5% is further included.
In the present embodiment, the sodium hydroxide that percentage by weight is 1% is further included.
In the present embodiment, butyl acrylate, Isooctyl acrylate monomer, acrylic acid -2- that percentage by weight is 21% are further included
The composition of ethylhexyl, each component according to 1:1:1 ratio is matched.
Found by contrast：Formula in embodiment 3 shows splendid performance during performance test, therefore,
Embodiment 3 is preferable formula design, a kind of high-performance environment protection type adhesive provided by the invention, by by leather leftover pieces etc.
Cladding extracts gelatin and is made into aqueous solution, after rising temperature for dissolving, carries out cross-linking reaction with epoxides and forms；Provided herein
A kind of high-performance environment protection type adhesive has the advantages that ecological, pollution-free, glueability is good, is traditional small molecule adhesive institute
Inaccessiable excellent properties, and environment will not being polluted in the production and use process, have it is greatly economical and
Social value.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (5)
1. a kind of high-performance environment protection type adhesive, it is characterised in that include the component of following percentage by weight：
Polyisoprene 0~20%,
Polyvinyl alcohol 0~15%,
Polyacrylamide 1~30%,
Methyl hydroxyethylcellulose 0.5~10%,
Antioxidant N- dibutylamino dithiocarbonic acids zinc 0.1~10%,
Titanium dioxide 0~10%,
Antimony oxide 0~5%,
Fire retardant 0~15%,
Plasticizer 0~25%,
Surplus is solvent.
A kind of 2. high-performance environment protection type adhesive according to claim 1, it is characterised in that：The solvent is ethanol or second
Glycol one or both of mixing.
A kind of 3. high-performance environment protection type adhesive according to claim 1, it is characterised in that：Further including percentage by weight is
0~25% toughener.
A kind of 4. high-performance environment protection type adhesive according to claim 1, it is characterised in that：Further including percentage by weight is
0~2% sodium hydroxide.
A kind of 5. high-performance environment protection type adhesive according to claim 1, it is characterised in that：Further including percentage by weight is
One or more of combinations in 0~25% butyl acrylate, Isooctyl acrylate monomer, acrylic acid-2-ethyl caproite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084763.9A CN107936853A (en) | 2017-11-07 | 2017-11-07 | A kind of high-performance environment protection type adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711084763.9A CN107936853A (en) | 2017-11-07 | 2017-11-07 | A kind of high-performance environment protection type adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107936853A true CN107936853A (en) | 2018-04-20 |
Family
ID=61933412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711084763.9A Pending CN107936853A (en) | 2017-11-07 | 2017-11-07 | A kind of high-performance environment protection type adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107936853A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1205644A (en) * | 1995-12-22 | 1999-01-20 | 美国3M公司 | Pressure-sensitive adhesive suitable for skin and method of preparing |
| CN101445711A (en) * | 2008-12-23 | 2009-06-03 | 上海生大医保股份有限公司 | Water polyisoprene copolymer emulsion adhesive and preparation method and application thereof |
| CN106318252A (en) * | 2016-08-18 | 2017-01-11 | 宁波卓胜新材料有限公司 | Coextruded coating-type protection adhesive tape and preparation method thereof |
| CN107201198A (en) * | 2017-06-27 | 2017-09-26 | 阜南县力韦包装材料有限公司 | A kind of good heat resistant type transparent adhesive tape of adhesive property |
-
2017
- 2017-11-07 CN CN201711084763.9A patent/CN107936853A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1205644A (en) * | 1995-12-22 | 1999-01-20 | 美国3M公司 | Pressure-sensitive adhesive suitable for skin and method of preparing |
| CN101445711A (en) * | 2008-12-23 | 2009-06-03 | 上海生大医保股份有限公司 | Water polyisoprene copolymer emulsion adhesive and preparation method and application thereof |
| CN106318252A (en) * | 2016-08-18 | 2017-01-11 | 宁波卓胜新材料有限公司 | Coextruded coating-type protection adhesive tape and preparation method thereof |
| CN107201198A (en) * | 2017-06-27 | 2017-09-26 | 阜南县力韦包装材料有限公司 | A kind of good heat resistant type transparent adhesive tape of adhesive property |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180420 |
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| RJ01 | Rejection of invention patent application after publication |