CN107904943A - 一种针织布超疏水改性的方法 - Google Patents

一种针织布超疏水改性的方法 Download PDF

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CN107904943A
CN107904943A CN201711229066.8A CN201711229066A CN107904943A CN 107904943 A CN107904943 A CN 107904943A CN 201711229066 A CN201711229066 A CN 201711229066A CN 107904943 A CN107904943 A CN 107904943A
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looped
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胡晓荣
俞娟
胡瑜
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Wuxi Haoyu Energy Saving Environmental Protection Equipment Co Ltd
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Abstract

一种针织布超疏水改性的方法，属于纺织技术领域。包括以下步骤：取水、氢氧化钠和十六烷基苯磺酸钠混匀后加热，然后将针织布浸入加热后的混合液中，取出后用清水冲洗干净；将处理后的针织布加入放有聚苯乙烯、聚偏二氟乙烯、甲基三甲氧基硅烷、乙醇和氨水的容器中，升温并搅拌反应；将碳纳米管、纳米氧化锌、玉米淀粉和水混合后磁力搅拌升温；取出针织布，放入保温后的混合物中浸泡；将处理后的针织布取出后室温晾干，然后放入烘箱中烘干，最终得到超疏水改性后的针织布。本发明所述方法是一种清洁、环保、低耗和低成本的新工艺方法。改性后的针织布具备优异的超疏水性能，其水接触角可达168°。

Description

一种针织布超疏水改性的方法
技术领域
本发明属于纺织技术领域，具体涉及一种针织布超疏水改性的方法。
背景技术
超疏水织物是指织物与水的接触角大于150°的织物，因其具有防雪、防污染、抗氧化以及防止电流传导等性能逐渐受到人们的青睐。
织物拒水整理的历史悠久，常用的拒水剂主要为有机硅和含氟化合物。含氟拒水剂不仅具有良好的拒水、拒油性，而且可以使织物保持柔软的手感、透气性及保湿性。目前市场上的疏水整理剂大部分为全氟长碳链(‐CnF2n+1，n≥8)的丙烯酸类聚合物，特别是含全氟辛基磺酰化合物(PFOS)和全氟辛酸化合物(PFOA)，因其极低的表面自由能、优良的憎水憎油、透气性，以及耐洗、防污和易去污性能，而被广泛地应用于织物功能整理。随着相关研究的日益深入，人们逐渐认识到PFOA/PFOS难以降解、在应用过程中存在生物累积性和对环境危害等问题，因此该类含氟化合物被限用和禁用。尽管市场上存在非氟疏水整理剂，例如有机硅疏水整理剂和蜡乳疏水整理剂，但它们存在初始防水性不足，耐洗性差等缺点，限制了其广泛使用。
因此，研发一种环保型超疏水针织布具有很高的工业价值。
发明内容
解决的技术问题：针对上述技术问题，本发明提供一种针织布超疏水改性的方法，所述方法简单、原料易得，改性后的针织布具备优异的超疏水性能。
技术方案：一种针织布超疏水改性的方法，所述制备方法包括以下步骤：
步骤一.取100～120质量份水、7～12质量份氢氧化钠和0.5～1.2质量份十六烷基苯磺酸钠混匀后加热至80～90℃，然后将10～15质量份针织布浸入加热后的混合液中30～50min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有3～7质量份聚苯乙烯、1～2质量份聚偏二氟乙烯、10～13质量份甲基三甲氧基硅烷、20～25质量份乙醇和5～8质量份28wt.％氨水的容器中，升温至40～55℃后搅拌反应3～5h；
步骤三.将4～8质量份碳纳米管、5～7质量份纳米氧化锌、0.5～1.5质量份玉米淀粉和70～90质量份水磁力搅拌升温至90～100℃，保温15～30min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡120～150min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为100～110℃烘箱中烘10～15min，然后升温至120～130℃烘1～2min，最终得到超疏水改性后的针织布。
作为优选，所述步骤一中取110质量份水、9质量份氢氧化钠和0.8质量份十六烷基苯磺酸钠混匀后加热至85℃，然后将12质量份针织布浸入加热后的混合液中40min。
作为优选，所述步骤二中将步骤一处理后的针织布加入放有5质量份聚苯乙烯、1.5质量份聚偏二氟乙烯、12质量份甲基三甲氧基硅烷、23质量份乙醇和7质量份28wt.％氨水的容器中，升温至50℃后搅拌反应4h。
作为优选，所述步骤三中将6质量份碳纳米管、6质量份纳米氧化锌、1质量份玉米淀粉和80质量份水，磁力搅拌升温至95℃，保温20min。
作为优选，所述步骤四中将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡130min。
作为优选，所述步骤五中放入预热温度为105℃烘箱中烘10min，然后升温至125℃烘1min。
有益效果：本发明所述方法简便易行，易于实现工业化大规模生产。因表面碳纳米管网络的存在，其水接触角可达168°。采用的原料安全环保，对环境无污染。是一种清洁、环保、低耗和低成本的新工艺方法。
具体实施方式
实施例1
一种针织布超疏水改性的方法，所述制备方法包括以下步骤：
步骤一.取100质量份水、7质量份氢氧化钠和0.5质量份十六烷基苯磺酸钠混匀后加热至80℃，然后将10质量份针织布浸入加热后的混合液中30min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有3质量份聚苯乙烯、1质量份聚偏二氟乙烯、10质量份甲基三甲氧基硅烷、20质量份乙醇和5质量份28wt.％氨水的容器中，升温至40℃后搅拌反应3h；
步骤三.将4质量份碳纳米管、5质量份纳米氧化锌、0.5质量份玉米淀粉和70质量份水，磁力搅拌升温至90℃，保温15min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡120min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为100℃烘箱中烘10min，然后升温至120℃烘1min，最终得到超疏水改性后的针织布。
经检测，所得超疏水针织布的接触角为165°，滚动角5°。
实施例2
一种针织布超疏水改性的方法，所述制备方法包括以下步骤：
步骤一.取120质量份水、12质量份氢氧化钠和1.2质量份十六烷基苯磺酸钠混匀后加热至90℃，然后将15质量份针织布浸入加热后的混合液中50min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有7质量份聚苯乙烯、2质量份聚偏二氟乙烯、13质量份甲基三甲氧基硅烷、25质量份乙醇和8质量份28wt.％氨水的容器中，升温至55℃后搅拌反应5h；
步骤三.将8质量份碳纳米管、7质量份纳米氧化锌、1.5质量份玉米淀粉和90质量份水，磁力搅拌升温至100℃，保温30min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡150min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为110℃烘箱中烘15min，然后升温至130℃烘2min，最终得到超疏水改性后的针织布。
经检测，所得超疏水针织布的接触角为164°，滚动角4°。
实施例3
一种针织布超疏水改性的方法，所述制备方法包括以下步骤：
步骤一.取110质量份水、9质量份氢氧化钠和0.8质量份十六烷基苯磺酸钠混匀后加热至85℃，然后将12质量份针织布浸入加热后的混合液中40min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有5质量份聚苯乙烯、1.5质量份聚偏二氟乙烯、12质量份甲基三甲氧基硅烷、23质量份乙醇和7质量份28wt.％氨水的容器中，升温至50℃后搅拌反应4h；
步骤三.将6质量份碳纳米管、6质量份纳米氧化锌、1质量份玉米淀粉和80质量份水，磁力搅拌升温至95℃，保温20min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡130min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为105℃烘箱中烘10min，然后升温至125℃烘1min，最终得到超疏水改性后的针织布。
经检测，所得超疏水针织布的接触角为168°，滚动角5°。
对比例1
同实施例3，区别在于不添加纳米氧化锌和玉米淀粉，具体制备方法如下：
步骤一.取110质量份水、9质量份氢氧化钠和0.8质量份十六烷基苯磺酸钠混匀后加热至85℃，然后将12质量份针织布浸入加热后的混合液中40min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有5质量份聚苯乙烯、1.5质量份聚偏二氟乙烯、12质量份甲基三甲氧基硅烷、23质量份乙醇和7质量份28wt.％氨水的容器中，升温至50℃后搅拌反应4h；
步骤三.将6质量份碳纳米管和80质量份水，磁力搅拌升温至95℃，保温20min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡130min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为105℃烘箱中烘10min，然后升温至125℃烘1min，最终得到超疏水改性后的针织布。
经检测，所得超疏水针织布的接触角为150°，滚动角5°。

Claims (6)

1.一种针织布超疏水改性的方法，其特征在于，所述制备方法包括以下步骤：
步骤一.取100~120质量份水、7~12质量份氢氧化钠和0.5~1.2质量份十六烷基苯磺酸钠混匀后加热至80~90℃，然后将10~15质量份针织布浸入加热后的混合液中30~50min，取出后用清水冲洗干净；
步骤二.将步骤一处理后的针织布加入放有3~7质量份聚苯乙烯、1~2质量份聚偏二氟乙烯、 10~13质量份甲基三甲氧基硅烷、20~25质量份乙醇和5~8质量份28wt.%氨水的容器中，升温至40~55℃后搅拌反应3~5 h；
步骤三.将4~8质量份碳纳米管、5~7质量份纳米氧化锌、0.5~1.5质量份玉米淀粉和70~90质量份水磁力搅拌升温至90~100℃，保温15~30 min；
步骤四.将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡120~150min；
步骤五.将步骤四处理后的针织布取出后室温晾干，然后放入预热温度为100~110℃烘箱中烘10~15min，然后升温至120~130℃烘1~2min，最终得到超疏水改性后的针织布。
2.根据权利要求1所述的一种针织布超疏水改性的方法，其特征在于，所述步骤一中取110质量份水、9质量份氢氧化钠和0.8质量份十六烷基苯磺酸钠混匀后加热至85℃，然后将12质量份针织布浸入加热后的混合液中40 min。
3.根据权利要求1所述的一种针织布超疏水改性的方法，其特征在于，所述步骤二中将步骤一处理后的针织布加入放有5质量份聚苯乙烯、1.5质量份聚偏二氟乙烯、12质量份甲基三甲氧基硅烷、23质量份乙醇和7质量份28wt.%氨水的容器中，升温至50℃后搅拌反应4h。
4.根据权利要求1所述的一种针织布超疏水改性的方法，其特征在于，所述步骤三中将6质量份碳纳米管、6质量份纳米氧化锌、1质量份玉米淀粉和80质量份水，磁力搅拌升温至95℃，保温20 min。
5.根据权利要求1所述的一种针织布超疏水改性的方法，其特征在于，所述步骤四中将步骤二处理后的针织布取出放入步骤三保温后的混合物中浸泡130 min。
6.根据权利要求1所述的一种针织布超疏水改性的方法，其特征在于，所述步骤五中放入预热温度为105℃烘箱中烘10min，然后升温至125℃烘1min。
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Publication number Priority date Publication date Assignee Title
US6251989B1 (en) * 1998-05-26 2001-06-26 Degussa-Huels Aktiengesellschaft Oligomerized organopolysiloxane cocondensate, its production and its use for treatment of surfaces
CN103088629A (zh) * 2012-12-18 2013-05-08 华南理工大学 一种对pet织物表面进行超疏水改性的方法
CN104805680A (zh) * 2015-04-28 2015-07-29 武汉纺织大学 一种功能性织物的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6251989B1 (en) * 1998-05-26 2001-06-26 Degussa-Huels Aktiengesellschaft Oligomerized organopolysiloxane cocondensate, its production and its use for treatment of surfaces
CN103088629A (zh) * 2012-12-18 2013-05-08 华南理工大学 一种对pet织物表面进行超疏水改性的方法
CN104805680A (zh) * 2015-04-28 2015-07-29 武汉纺织大学 一种功能性织物的制备方法

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