CN107892842A - Application of the humate in Writing-painting breast ink - Google Patents
Application of the humate in Writing-painting breast ink Download PDFInfo
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- CN107892842A CN107892842A CN201711241808.9A CN201711241808A CN107892842A CN 107892842 A CN107892842 A CN 107892842A CN 201711241808 A CN201711241808 A CN 201711241808A CN 107892842 A CN107892842 A CN 107892842A
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- humate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of application of humate in Writing-painting breast ink：Raw material is made using humate and prepares newborn ink, and newborn ink is used for writing and/or painting field.Specifically comprise the following steps：Humate is mixed with water, is heated to boiling rolling afterwards；Poured into slowly in humate solution after ferrous sulfate is mixed with water, being sufficiently stirred makes iron ion emulsification complexing, obtains humate biochemistry liquid；Sanding and polishing in special mixer is put into after being cooled to, obtains newborn ink.Breast provided by the invention it is blackish green it is environmentally friendly, it is nontoxic it is odorless, do not sprinkle do not leak, write smoothly, quick-drying is glossy, and avoid the addition of the component such as colouring agent, preservative and spices in traditional prepared Chinese ink；In addition, the breast ink of the present invention also have the advantages that it is economical and practical, be easy to carry, be easy to use, clear water need to be only dripped in print cartridge mix well just can write, paint, and then has significantly saved the time, has had broad application prospects.
Description
Technical field
The present invention relates to stationery technical field, and in particular to a kind of humate answering in Writing-painting breast ink
With.
Background technology
It is well known that ink is as one of study " four is precious ", it is writing, the pigment of drawing.Chinese ink is successive dynasties people culture
The necessity of life, in the writing brush, ink stick, ink slab and paper, ink is not only indispensable content, and is a kind of composite technology artistic products.It is right
The development of China's cultural undertakings has played impetus, and has won very high evaluation in the world.Therefore, ink turns into the Chinese people
One of symbol of race's time-honoured.
In ancient times, people are using being more china ink stick, and also known as Chinese ink, such ink needs are ground in inkstone.It makes ink
Technique generally includes to refine cigarette and expect, makes, dries, paints in gold, and china ink stick always enjoys scholar, calligraphy, families of painting to like,
And collected.With the progress in epoch, it is less and less to write the people of calligraphy with china ink stick now, more using prepared Chinese ink.At present, I
The big prepared Chinese ink brand of state five includes：Beijing one obtains pavilion prepared Chinese ink, Shanghai Cao Su work(boards Huizhou inkstick, Li Ting Gui boards Huizhou inkstick, Hu Kaiwen board Huizhou inkstick
And the good Huizhou inkstick in Jixi.However, there is following defect in above-mentioned representational prepared Chinese ink：Blent using animal gelatine and with carbon ink
Form；Wherein, carbon ink is expensive, and animal gelatine is oxidizable smelly, harmful.
Based on this, to overcome the shortcomings of traditional prepared Chinese ink, invention it is a kind of it is economical and practical, environmentally friendly, make it is simple, nontoxic it is odorless,
It is significant that leak-free novel ink is not sprinkled.
The content of the invention
For in the prior art the defects of, the present invention is intended to provide a kind of humate Writing-painting breast ink in should
With.Breast provided by the invention it is blackish green it is environmentally friendly, it is nontoxic it is odorless, do not sprinkle do not leak, write smoothly, quick-drying is glossy, and avoid biography
The addition of the component such as colouring agent, preservative and spices in system prepared Chinese ink；Meanwhile breast ink of the invention also have it is economical and practical, just
In carry, it is easy to use the advantages that, clear water need to only drip in print cartridge mix well just can write, paint, and then notable when having saved
Between, have broad application prospects.In addition, countries in the world are provided with many Confucius institutes number, students are all liked using writing brush, ink
Water is painted, and breast ink provided by the invention is deep to be welcome by students in middle and primary schools' welcome and calligraphy fan, and travelling products can be used as to contribute
Widow's mite.
The present invention provides a kind of application of humate in Writing-painting breast ink, is made using humate biochemistry liquid former
Material, it is used for through breast ink is prepared, and by newborn ink in writing and/or painting field.
Preferably, the raw material components of humate biochemistry liquid include humate and ferrous sulfate；And humate and sulphur
Sour ferrous weight ratio is 10：3.
Preferably, the preparation method of humate biochemistry liquid comprises the following steps：S101：By humate and water according to
(2~3)：10 weight obtains humate dilution, dilution is heated into boiling rolling afterwards than mixing；S102：Will
Ferrous sulfate is with water according to 1：5 weight obtains copperas solution than being well mixed；Copperas solution is added afterwards
In the product that S101 is obtained, stir, until emulsification generation humate biochemistry liquid.
Preferably, the preparation method of breast ink comprises the following steps：Humate biochemistry liquid is cooled down, is placed in stirring afterwards
Sanding and polishing in machine, obtain newborn ink.
Preferably, in S101, heating-up temperature is 100 DEG C~120 DEG C.
Preferably, humate selects sodium humate and/or potassium humate.
Preferably, the preparation method of sodium humate and/or potassium humate comprises the following steps：With mud coal or lignite or wind
Change coal is raw material, then adds alkali, by coal：Alkali：Water is 100：(8.5~9.5)：The part by weight feeding of (400~500), pours into band
In the reactor of agitator, 70~130 DEG C are heated to, until the pH value of reaction extract is 9~11, precipitation obtains humic acid
Sodium/potassium colloidal fluid, after through drying powdered or granular sodium humate/potassium is made；Wherein, humic acid content is more than
50%, the content of water-insoluble is less than 15%.
The above-mentioned technical proposal of the present invention has the following advantages that compared with prior art：
(1) applicant has found by numerous studies：Breast provided by the invention it is blackish green it is environmentally friendly, it is nontoxic it is odorless, do not sprinkle not
Leak, write smoothly, quick-drying is glossy, and avoid the addition of the component such as colouring agent, preservative and spices in traditional prepared Chinese ink；
In addition, the present invention breast ink also have the advantages that it is economical and practical, be easy to carry, be easy to use, only need to be dripped in print cartridge clear water adjust
It is even just to write, paint, and then the time significantly has been saved, have broad application prospects.
(2) sodium humate/potassium, its physical property are：It is similar loose with colloidal nature and very big internal surface area
Sponge, adsorption capacity is very strong, nontoxic odorless.Sodium humate/potassium profile is dark brown, powdered, and pH value is between 9~11,
Solidification, not deinking mark can be impregnated to paper fiber element；In addition, its chemical property is：It is complicated, contain a variety of officials
The macromolecular that can be rolled into a ball, solution show alkalescent, the pernicious gas such as cigarette combustion etc. in room air can be prevented and treated and remove, in book
Make environment more environmentally friendly cleaning while writing drawing.
(3) it is well known that countries in the world are provided with many Confucius institutes number, students are all liked using writing brush, and ink is painted,
Breast ink provided by the invention is deep to be welcome and calligraphy fan welcomes by students in middle and primary schools, and can be used as travelling products contribution meagre strength it
Power.
The additional aspect and advantage of the present invention will be set forth in part in the description, partly will from the following description
Become obvious, or recognized by the practice of the present invention.
Embodiment
The embodiment of technical solution of the present invention will be described in detail below.Following examples are only used for more clear
The explanation technical scheme of Chu, therefore be only used as example, and can not be limited the scope of the invention with this.
The present invention provides a kind of application of humate in Writing-painting breast ink, is made using humate biochemistry liquid former
Material, it is used for through breast ink is prepared, and by newborn ink in writing and/or painting field.Wherein, the raw material of humate biochemistry liquid
Component includes humate and ferrous sulfate；And the weight of humate and ferrous sulfate ratio is 10：3.
The preparation method of breast ink provided by the invention comprises the following steps：
S101：By humate and water according to (2~3)：10 weight obtains humate dilution, by this than mixing
Dilution is heated to 100 DEG C~120 DEG C in reactor or iron pan, and dilution seethes with excitement rolling in pot.Wherein, humate
From sodium humate and/or potassium humate.
S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by sulphur
Sour ferrous iron solution is poured into the product that S101 is obtained slowly, is stirred, and makes iron ion emulsification complexing, and mass colour is distinct to dash forward
Go out, obtain humate biochemistry liquid.
S103：Humate biochemistry liquid is cooled down, sanding and polishing in special mixer is put into, obtains more glossiness breast
Ink.Newborn ink is scooped into special box by certain weight ratio afterwards, labelled, as newborn graphite product.
In the further embodiment of the present invention, the preparation method of sodium humate and/or potassium humate includes following step
Suddenly：Using mud coal or lignite or weathered coal as raw material, then add alkali, by coal：Alkali：Water is 100：(8.5~9.5)：(400~500)
Part by weight feeding, pour into the reactor of belt stirrer, be heated to 70~130 DEG C, until the pH value of reaction extract is 9
~11, precipitation obtain sodium humate/potassium colloidal fluid, after through drying powdered or granular sodium humate/potassium is made；Its
In, humic acid content is more than 50%, and the content of water-insoluble is less than 15%.
Illustrated with reference to embodiment：
Embodiment one
A kind of application of the humate of present invention offer in Writing-painting breast ink, the preparation method of breast ink is including following
Step：
S100：Using mud coal as raw material, then add alkali, by coal：Alkali：Water is 100：8.5：500 part by weight feeding, is poured into
In the reactor of belt stirrer, 130 DEG C are heated to, until the pH value of reaction extract is 11, precipitation obtains sodium humate/potassium
Colloidal fluid, after through drying powdered or granular sodium humate/potassium is made；Wherein, humic acid content is 55%, and water is not
The content of molten thing is 13%.
S101：By sodium humate/potassium and water according to 3：10 weight ratio mixing, obtains humate dilution, and this is dilute
Release liquid and be heated to 120 DEG C in reactor or iron pan, dilution seethes with excitement rolling in pot.
S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by sulphur
Sour ferrous iron solution is poured into the product that S101 is obtained slowly, is stirred, and makes iron ion emulsification complexing, and mass colour is distinct to dash forward
Go out, obtain humate biochemistry liquid.
S103：Humate biochemistry liquid is cooled down, is put into sanding and polishing in special mixer, obtains newborn ink.
Embodiment two
A kind of application of the humate of present invention offer in Writing-painting breast ink, the preparation method of breast ink is including following
Step：
S100：Using lignite as raw material, then add alkali, by coal：Alkali：Water is 100：9.5：400 part by weight feeding, is poured into
In the reactor of belt stirrer, 70 are heated to, until the pH value of reaction extract is 9, it is gluey that precipitation obtains sodium humate/potassium
Liquid, after through drying powdered or granular sodium humate/potassium is made；Wherein, humic acid content is 58%, water-insoluble
Content be 10%.
S101：By sodium humate/potassium and water according to 2：10 weight ratio mixing, obtains humate dilution, and this is dilute
Release liquid and be heated to 100 DEG C in reactor or iron pan, dilution seethes with excitement rolling in pot.
S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by sulphur
Sour ferrous iron solution is poured into the product that S101 is obtained slowly, is stirred, and makes iron ion emulsification complexing, and mass colour is distinct to dash forward
Go out, obtain humate biochemistry liquid.
S103：Humate biochemistry liquid is cooled down, is put into sanding and polishing in special mixer, obtains newborn ink.
Embodiment three
A kind of application of the humate of present invention offer in Writing-painting breast ink, the preparation method of breast ink is including following
Step：
S100：Using weathered coal as raw material, then add alkali, by coal：Alkali：Water is 100：9：450 part by weight feeding, is poured into
In the reactor of belt stirrer, 100 DEG C are heated to, until the pH value of reaction extract is 10, precipitation obtains sodium humate/potassium
Colloidal fluid, after through drying powdered or granular sodium humate/potassium is made；Wherein, humic acid content is 60%, and water is not
The content of molten thing is 13%.
S101：By sodium humate/potassium and water according to 2.5：10 weight obtains humate dilution, by this than mixing
Dilution is heated to 110 DEG C in reactor or iron pan, and dilution seethes with excitement rolling in pot.
S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by sulphur
Sour ferrous iron solution is poured into the product that S101 is obtained slowly, is stirred, and makes iron ion emulsification complexing, and mass colour is distinct to dash forward
Go out, obtain humate biochemistry liquid.
S103：Humate biochemistry liquid is cooled down, is put into sanding and polishing in special mixer, obtains newborn ink.
Example IV
A kind of application of the humate of present invention offer in Writing-painting breast ink, the preparation method of breast ink is including following
Step：
S101：By commercially available humic acid potassium and water according to 2.5：10 weight ratio mixing, obtains humate dilution, will
The dilution is heated to 110 DEG C in reactor or iron pan, and dilution seethes with excitement rolling in pot.
S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by sulphur
Sour ferrous iron solution is poured into the product that S101 is obtained slowly, is stirred, and makes iron ion emulsification complexing, and mass colour is distinct to dash forward
Go out, obtain humate biochemistry liquid.
S103：Humate biochemistry liquid is cooled down, is put into sanding and polishing in special mixer, obtains newborn ink.
The breast ink being prepared for various embodiments of the present invention, by People's Republic of China (PRC) light industry standard QB/
T2860-2007, the physical and chemical index of prepared Chinese ink product are detected, and specific data are as shown in Table 1 and Table 2.
The physical and chemical performance list one of 1 each embodiment of table breast ink
The physical and chemical performance list two of 2 each embodiment of table breast ink
Certainly, except the situation that each embodiment is enumerated, the bar in the species and ratio of other raw material components, preparation process
Part and parameter etc. are also possible.
Breast provided by the invention it is blackish green it is environmentally friendly, it is nontoxic it is odorless, do not sprinkle do not leak, write smoothly, quick-drying is glossy, and keep away
The addition of the component such as colouring agent, preservative and spices in traditional prepared Chinese ink is exempted from；In addition, the breast ink of the present invention also has economy
Material benefit, the advantages that being easy to carry, be easy to use, clear water need to only drip in print cartridge mix well just can write, paint, and then notable section
About the time, have broad application prospects.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or the spy for combining the embodiment or example description
Point is contained at least one embodiment or example of the present invention.In this manual, to the schematic representation of above-mentioned term not
Identical embodiment or example must be directed to.Moreover, specific features, structure, material or the feature of description can be with office
Combined in an appropriate manner in one or more embodiments or example.In addition, in the case of not conflicting, this area
Technical staff can be carried out the different embodiments or example and the feature of different embodiments or example described in this specification
With reference to and combination.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example
Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned
Embodiment is changed, changed, replacing and modification.
Claims (7)
- A kind of 1. application of humate in Writing-painting breast ink, it is characterised in that：Raw material is made using humate biochemistry liquid, is used for writing and/or painting field through breast ink is prepared, and by the breast ink In.
- 2. application of the humate according to claim 1 in Writing-painting breast ink, it is characterised in that：The raw material components of the humate biochemistry liquid include humate and ferrous sulfate；And the humate and the sulphur Sour ferrous weight ratio is 10：3.
- 3. application of the humate according to claim 2 in Writing-painting breast ink, it is characterised in that the humic acid The preparation method of salt biochemistry liquid comprises the following steps：S101：By humate and water according to (2~3)：10 weight obtains humate dilution, afterwards by institute than mixing State dilution and be heated to boiling rolling；S102：By ferrous sulfate and water according to 1：5 weight obtains copperas solution than being well mixed；Afterwards by the sulphur Sour ferrous iron solution is added in the product that the S101 is obtained, and is stirred, until emulsification generation humate biochemistry liquid.
- 4. application of the humate according to claim 3 in Writing-painting breast ink, it is characterised in that the breast ink Preparation method comprises the following steps：The humate biochemistry liquid is cooled down, is placed in sanding and polishing in mixer afterwards, obtains newborn ink.
- 5. application of the humate according to claim 3 in Writing-painting breast ink, it is characterised in that：In the S101, the heating-up temperature is 100 DEG C~120 DEG C.
- 6. application of the humate in Writing-painting breast ink according to any one of claim 2~5, it is characterised in that：The humate selects sodium humate and/or potassium humate.
- 7. application of the humate according to claim 6 in Writing-painting breast ink, it is characterised in that：The preparation method of the sodium humate and/or potassium humate comprises the following steps：Using mud coal or lignite or weathered coal as raw material, then add alkali, by coal：Alkali：Water is 100：(8.5~9.5)：(400~500) Part by weight feeding, pour into the reactor of belt stirrer, be heated to 70~130 DEG C, until the pH value of reaction extract for 9~ 11, precipitation obtain sodium humate/potassium colloidal fluid, after through drying powdered or granular sodium humate/potassium is made；Wherein, Humic acid content is more than 50%, and the content of water-insoluble is less than 15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711241808.9A CN107892842B (en) | 2017-11-30 | 2017-11-30 | Application of humate in writing and drawing emulsion ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711241808.9A CN107892842B (en) | 2017-11-30 | 2017-11-30 | Application of humate in writing and drawing emulsion ink |
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| CN107892842A true CN107892842A (en) | 2018-04-10 |
| CN107892842B CN107892842B (en) | 2020-09-04 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112523A (en) * | 1997-04-30 | 1999-01-19 | Pentel Kk | Ink jet ink |
| CN1562448A (en) * | 2004-03-23 | 2005-01-12 | 文正贵 | Biochemical liquid of humate in application for purifying air indoors |
| CN101370883A (en) * | 2006-09-15 | 2009-02-18 | 株式会社理光 | Recording ink, inkjet recording method and inkjet recording apparatus |
| CN103468060A (en) * | 2013-09-24 | 2013-12-25 | 昆明理工大学 | Humate-containing ink and preparation method thereof |
-
2017
- 2017-11-30 CN CN201711241808.9A patent/CN107892842B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112523A (en) * | 1997-04-30 | 1999-01-19 | Pentel Kk | Ink jet ink |
| CN1562448A (en) * | 2004-03-23 | 2005-01-12 | 文正贵 | Biochemical liquid of humate in application for purifying air indoors |
| CN101370883A (en) * | 2006-09-15 | 2009-02-18 | 株式会社理光 | Recording ink, inkjet recording method and inkjet recording apparatus |
| CN103468060A (en) * | 2013-09-24 | 2013-12-25 | 昆明理工大学 | Humate-containing ink and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN107892842B (en) | 2020-09-04 |
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