CN107892842B - Application of humate in writing and drawing emulsion ink - Google Patents
Application of humate in writing and drawing emulsion ink Download PDFInfo
- Publication number
- CN107892842B CN107892842B CN201711241808.9A CN201711241808A CN107892842B CN 107892842 B CN107892842 B CN 107892842B CN 201711241808 A CN201711241808 A CN 201711241808A CN 107892842 B CN107892842 B CN 107892842B
- Authority
- CN
- China
- Prior art keywords
- humate
- ink
- writing
- emulsion ink
- ferrous sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to an application of humate in writing and painting emulsion ink, which comprises the following steps: the emulsion ink is prepared by adopting humate as a raw material and is used in the field of writing and/or drawing. The method specifically comprises the following steps: mixing humate with water, and then heating until boiling and rolling; mixing ferrous sulfate with water, slowly pouring into humate solution, and fully stirring to emulsify and complex iron ions to obtain humate biochemical solution; and cooling, and then putting the cooled mixture into a special stirrer for grinding and polishing to obtain the emulsion ink. The emulsion ink provided by the invention is green and environment-friendly, nontoxic, odorless, free from splashing and leaking, fluent in writing, quick-drying and glossy, and avoids the addition of components such as a colorant, a preservative, a spice and the like in the traditional Chinese ink; in addition, the emulsion ink disclosed by the invention has the advantages of economy, convenience in carrying and use and the like, can be used for writing and drawing only by uniformly dripping clear water in the ink box, further obviously saves time, and has a wide application prospect.
Description
Technical Field
The invention relates to the technical field of stationery, in particular to application of humate in writing and drawing emulsion ink.
Background
As one of the four treasures of the study, ink is known as a pigment for writing and drawing. The Chinese ink is a necessity of people's cultural life in all ages, and in the four treasures of the study, the ink is not only an indispensable content, but also a comprehensive industrial art. It has a promoting effect on the development of the cultural cause of China and has gained high evaluation internationally. Therefore, ink becomes one of the symbols of ancient civilizations of the chinese nation.
In ancient times, people used more ink sticks, also called Chinese ink, which needed to be ground in inkstones. The ink making process usually includes refining tobacco, mixing materials, making, drying in the sun, tracing gold and the like, and the ink stick is always popular with the cultural relics, calligraphy and painting artists and is collected. With the progress of times, people writing calligraphy with ink sticks are fewer and more, and ink is used. At present, five Chinese ink brands comprise: beijing Yidelge ink, Shanghai Cao Gong brand ink, Liyangtian brand ink, Hukai Wen brand ink and Kuaixi Liang ink. However, the above representative inks all suffer from the following drawbacks: blending animal bone glue and carbon ink; wherein, the carbon ink is expensive, and the animal bone glue is easy to oxidize and stink and is harmful to human body.
Based on the above, in order to overcome the defects of the traditional ink, the invention of the novel ink which is economical, practical, environment-friendly, simple to manufacture, nontoxic, odorless and non-spill has important significance.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the application of humate in writing and drawing emulsion ink. The emulsion ink provided by the invention is green and environment-friendly, nontoxic, odorless, free from splashing and leaking, fluent in writing, quick-drying and glossy, and avoids the addition of components such as a colorant, a preservative, a spice and the like in the traditional Chinese ink; meanwhile, the emulsion ink disclosed by the invention has the advantages of economy, convenience in carrying and use and the like, can be used for writing and drawing only by uniformly dripping clear water in the ink box, further obviously saves time, and has a wide application prospect. In addition, a plurality of Confucius colleges are arranged in various countries in the world, students like to draw with writing brushes and ink, the emulsion ink provided by the invention is popular among primary and secondary school students and calligraphy lovers, and can contribute to a thin force for a travel product to one way.
The invention provides an application of humate in writing and drawing emulsion, which adopts humate biochemical liquid as a raw material to prepare the emulsion, and the emulsion is used in the writing and/or drawing field.
Preferably, the raw material components of the humate biochemical liquid comprise humate and ferrous sulfate; and the weight ratio of the humate to the ferrous sulfate is 10: 3.
preferably, the preparation method of the humate biochemical liquid comprises the following steps: s101: mixing humate and water according to the ratio of (2-3): 10 to obtain humate diluent, and then heating the diluent to boil and roll; s102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and then adding the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring until the product is emulsified to generate the humate biochemical liquid.
Preferably, the preparation method of the emulsion ink comprises the following steps: and cooling the humate biochemical liquid, and then putting the cooled humate biochemical liquid into a stirrer for grinding and polishing to obtain the emulsion ink.
Preferably, in S101, the heating temperature is 100 ℃ to 120 ℃.
Preferably, the humate is sodium humate and/or potassium humate.
Preferably, the preparation method of the sodium humate and/or the potassium humate comprises the following steps: peat or lignite or weathered coal is taken as a raw material, alkali is added, and the weight percentage of the raw material is as follows: alkali: the water is 100: (8.5-9.5): (400-500), pouring the materials into a reaction kettle with a stirrer, heating to 70-130 ℃ until the pH value of the reaction extract is 9-11, precipitating to obtain sodium/potassium humate colloidal liquid, and drying to prepare powdery or granular sodium/potassium humate; wherein, the content of humic acid is more than 50 percent, and the content of water-insoluble substances is less than 15 percent.
Compared with the prior art, the technical scheme of the invention has the following advantages:
(1) the applicant has found through a great deal of research that: the emulsion ink provided by the invention is green and environment-friendly, nontoxic, odorless, free from splashing and leaking, fluent in writing, quick-drying and glossy, and avoids the addition of components such as a colorant, a preservative, a spice and the like in the traditional Chinese ink; in addition, the emulsion ink disclosed by the invention has the advantages of economy, convenience in carrying and use and the like, can be used for writing and drawing only by uniformly dripping clear water in the ink box, further obviously saves time, and has a wide application prospect.
(2) Sodium/potassium humate, the physical properties of which are: has colloid property and large internal surface area, is similar to loose sponge, has strong adsorption capacity, and is nontoxic and odorless. The sodium humate/potassium is black brown and powdery, has a pH value of 9-11, can be used for curing paper cellulose impregnation, and does not cause ink marks; furthermore, the chemical properties are: the structure is complex, macromolecule containing multiple functional groups, the solution is alkalescent, harmful gases in indoor air such as cigarette burning and the like can be prevented, treated and removed, and the environment is more environment-friendly and cleaner when writing and drawing.
(3) As is known, a plurality of Confucius colleges are arranged in various countries in the world, students like to draw with writing brushes and ink, the emulsion ink provided by the invention is popular among primary and secondary school students and calligraphy lovers, and can contribute to a thin force as a travel product.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
Hereinafter, embodiments of the present invention will be described in detail. The following examples are only for illustrating the technical solutions of the present invention more clearly, and therefore are only examples, and the protection scope of the present invention is not limited thereby.
The invention provides an application of humate in writing and drawing emulsion, which adopts humate biochemical liquid as a raw material to prepare the emulsion, and the emulsion is used in the writing and/or drawing field. Wherein, the raw material components of the humate biochemical liquid comprise humate and ferrous sulfate; and the weight ratio of the humate to the ferrous sulfate is 10: 3.
the preparation method of the emulsion ink provided by the invention comprises the following steps:
s101: mixing humate and water according to the ratio of (2-3): 10 to obtain humate diluent, heating the diluent to 100-120 ℃ in a reaction kettle or an iron pot, and boiling and rolling the diluent in the pot. Wherein, the humate is sodium humate and/or potassium humate.
S102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and slowly pouring the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring to emulsify and complex iron ions, wherein the color of the ink is bright and outstanding, so that the humate biochemical liquid is obtained.
S103: cooling the humate biochemical liquid, and putting the cooled humate biochemical liquid into a special stirrer for grinding and polishing to obtain glossy emulsion ink. Then scooping the emulsion ink into a special box according to a certain weight ratio, and labeling to obtain the emulsion ink product.
In a further embodiment of the present invention, the method for preparing sodium humate and/or potassium humate comprises the steps of: peat or lignite or weathered coal is taken as a raw material, alkali is added, and the weight percentage of the raw material is as follows: alkali: the water is 100: (8.5-9.5): (400-500), pouring the materials into a reaction kettle with a stirrer, heating to 70-130 ℃ until the pH value of the reaction extract is 9-11, precipitating to obtain sodium/potassium humate colloidal liquid, and drying to prepare powdery or granular sodium/potassium humate; wherein, the content of humic acid is more than 50 percent, and the content of water-insoluble substances is less than 15 percent.
The following description is made with reference to specific embodiments:
example one
The invention provides an application of humate in writing and drawing emulsion ink, and a preparation method of the emulsion ink comprises the following steps:
s100: taking peat as a raw material, adding alkali, and mixing the raw materials according to the weight ratio of coal: alkali: the water is 100: 8.5: taking materials according to the weight ratio of 500, pouring the materials into a reaction kettle with a stirrer, heating to 130 ℃ until the pH value of a reaction extract is 11, precipitating to obtain sodium humate/potassium colloidal liquid, and drying to prepare powdery or granular sodium humate/potassium humate; wherein, the content of humic acid is 55 percent, and the content of water-insoluble substances is 13 percent.
S101: mixing sodium humate/potassium with water according to the ratio of 3: 10 to obtain humate diluent, heating the diluent to 120 ℃ in a reaction kettle or an iron pot, and boiling and rolling the diluent in the pot.
S102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and slowly pouring the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring to emulsify and complex iron ions, wherein the color of the ink is bright and outstanding, so that the humate biochemical liquid is obtained.
S103: cooling the humate biochemical liquid, and putting the cooled humate biochemical liquid into a special stirrer for grinding and polishing to obtain the emulsion ink.
Example two
The invention provides an application of humate in writing and drawing emulsion ink, and a preparation method of the emulsion ink comprises the following steps:
s100: lignite is taken as a raw material, then alkali is added, and the weight ratio of lignite is as follows: alkali: the water is 100: 9.5: taking materials according to the weight ratio of 400, pouring the materials into a reaction kettle with a stirrer, heating the materials to 70 until the pH value of a reaction extract is 9, precipitating the reaction extract to obtain sodium humate/potassium colloidal liquid, and then drying the colloidal liquid to prepare powdery or granular sodium humate/potassium humate; wherein, the content of humic acid is 58 percent, and the content of water-insoluble substances is 10 percent.
S101: mixing sodium humate/potassium with water according to the ratio of 2: 10 to obtain humate diluent, heating the diluent to 100 ℃ in a reaction kettle or an iron pot, and boiling and rolling the diluent in the pot.
S102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and slowly pouring the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring to emulsify and complex iron ions, wherein the color of the ink is bright and outstanding, so that the humate biochemical liquid is obtained.
S103: cooling the humate biochemical liquid, and putting the cooled humate biochemical liquid into a special stirrer for grinding and polishing to obtain the emulsion ink.
EXAMPLE III
The invention provides an application of humate in writing and drawing emulsion ink, and a preparation method of the emulsion ink comprises the following steps:
s100: weathered coal is used as a raw material, and then alkali is added, wherein the weight ratio of coal: alkali: the water is 100: 9: taking materials according to the weight ratio of 450, pouring the materials into a reaction kettle with a stirrer, heating to 100 ℃ until the pH value of a reaction extract is 10, precipitating to obtain sodium humate/potassium colloidal liquid, and drying to prepare powdery or granular sodium humate/potassium humate; wherein, the content of humic acid is 60 percent, and the content of water-insoluble substances is 13 percent.
S101: mixing sodium humate/potassium humate and water according to the ratio of 2.5: 10 to obtain humate diluent, heating the diluent to 110 ℃ in a reaction kettle or an iron pot, and boiling and rolling the diluent in the pot.
S102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and slowly pouring the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring to emulsify and complex iron ions, wherein the color of the ink is bright and outstanding, so that the humate biochemical liquid is obtained.
S103: cooling the humate biochemical liquid, and putting the cooled humate biochemical liquid into a special stirrer for grinding and polishing to obtain the emulsion ink.
Example four
The invention provides an application of humate in writing and drawing emulsion ink, and a preparation method of the emulsion ink comprises the following steps:
s101: commercially available potassium humate was mixed with water in a ratio of 2.5: 10 to obtain humate diluent, heating the diluent to 110 ℃ in a reaction kettle or an iron pot, and boiling and rolling the diluent in the pot.
S102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and slowly pouring the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring to emulsify and complex iron ions, wherein the color of the ink is bright and outstanding, so that the humate biochemical liquid is obtained.
S103: cooling the humate biochemical liquid, and putting the cooled humate biochemical liquid into a special stirrer for grinding and polishing to obtain the emulsion ink.
The emulsion ink prepared by the embodiments of the invention is detected according to the light industry standard QB/T2860-2007 of the people's republic of China, and the physical and chemical indexes of the ink products are shown in the specific data in tables 1 and 2.
TABLE 1 list of physicochemical Properties of emulsion inks of the examples I
TABLE 2 list of physicochemical Properties of emulsion inks of the examples II
Of course, other kinds and ratios of the raw material components, conditions and parameters in the production process, and the like are also possible except for those exemplified in each example.
The emulsion ink provided by the invention is green and environment-friendly, nontoxic, odorless, free from splashing and leaking, fluent in writing, quick-drying and glossy, and avoids the addition of components such as a colorant, a preservative, a spice and the like in the traditional Chinese ink; in addition, the emulsion ink disclosed by the invention has the advantages of economy, convenience in carrying and use and the like, can be used for writing and drawing only by uniformly dripping clear water in the ink box, further obviously saves time, and has a wide application prospect.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.
Claims (5)
1. The application of humate in writing and drawing emulsion ink is characterized in that:
adopting humate biochemical liquid as a raw material, preparing to obtain the emulsion ink, and applying the emulsion ink to the field of writing and/or drawing;
the raw material components of the humate biochemical liquid comprise humate and ferrous sulfate; and the weight ratio of the humate to the ferrous sulfate is 10: 3;
the preparation method of the humate biochemical liquid comprises the following steps:
s101: mixing humate and water according to the ratio of (2-3): 10 to obtain humate diluent, and then heating the diluent to boil and roll;
s102: mixing ferrous sulfate and water according to the weight ratio of 1: 5 to obtain ferrous sulfate solution; and then adding the ferrous sulfate solution into the product obtained in the step S101, and fully and uniformly stirring until the product is emulsified to generate the humate biochemical liquid.
2. The use of humate in writing and drawing inks according to claim 1, wherein the preparation method of the ink comprises the steps of:
and cooling the humate biochemical liquid, and then putting the cooled humate biochemical liquid into a stirrer for grinding and polishing to obtain the emulsion ink.
3. Use of a humate according to claim 1 in a writing and painting ink, characterized in that:
in S101, the heating temperature is 100-120 ℃.
4. Use of a humate according to any one of claims 1 to 3 in a writing and painting ink, wherein:
the humate is sodium humate and/or potassium humate.
5. Use of a humate according to claim 4 in a writing and painting ink, wherein:
the preparation method of the sodium humate and/or the potassium humate comprises the following steps:
peat or lignite or weathered coal is taken as a raw material, alkali is added, and the weight percentage of the raw material is as follows: alkali: the water is 100: (8.5-9.5): (400-500), pouring the materials into a reaction kettle with a stirrer, heating to 70-130 ℃ until the pH value of the reaction extract is 9-11, precipitating to obtain sodium/potassium humate colloidal liquid, and drying to prepare powdery or granular sodium/potassium humate; wherein, the content of humic acid is more than 50 percent, and the content of water-insoluble substances is less than 15 percent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711241808.9A CN107892842B (en) | 2017-11-30 | 2017-11-30 | Application of humate in writing and drawing emulsion ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711241808.9A CN107892842B (en) | 2017-11-30 | 2017-11-30 | Application of humate in writing and drawing emulsion ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107892842A CN107892842A (en) | 2018-04-10 |
| CN107892842B true CN107892842B (en) | 2020-09-04 |
Family
ID=61806473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711241808.9A Active CN107892842B (en) | 2017-11-30 | 2017-11-30 | Application of humate in writing and drawing emulsion ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107892842B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112523A (en) * | 1997-04-30 | 1999-01-19 | Pentel Kk | Ink jet ink |
| CN1562448A (en) * | 2004-03-23 | 2005-01-12 | 文正贵 | Biochemical liquid of humate in application for purifying air indoors |
| CN101370883A (en) * | 2006-09-15 | 2009-02-18 | 株式会社理光 | Recording ink, inkjet recording method and inkjet recording apparatus |
| CN103468060A (en) * | 2013-09-24 | 2013-12-25 | 昆明理工大学 | Humate-containing ink and preparation method thereof |
-
2017
- 2017-11-30 CN CN201711241808.9A patent/CN107892842B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112523A (en) * | 1997-04-30 | 1999-01-19 | Pentel Kk | Ink jet ink |
| CN1562448A (en) * | 2004-03-23 | 2005-01-12 | 文正贵 | Biochemical liquid of humate in application for purifying air indoors |
| CN101370883A (en) * | 2006-09-15 | 2009-02-18 | 株式会社理光 | Recording ink, inkjet recording method and inkjet recording apparatus |
| CN103468060A (en) * | 2013-09-24 | 2013-12-25 | 昆明理工大学 | Humate-containing ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107892842A (en) | 2018-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103468060B (en) | Prepared Chinese ink containing humate and preparation method thereof | |
| CN102533003B (en) | Non-cracking ink | |
| CN107892842B (en) | Application of humate in writing and drawing emulsion ink | |
| CN103483909A (en) | Preparation method for water-based ink | |
| CN105907174A (en) | Environment-friendly erasable blackboard writing liquid and preparing method thereof | |
| CN102585594A (en) | Environment-friendly viscosity reducer | |
| CN105802337B (en) | Prepared Chinese ink based on synthesising macromolecule copolymer and preparation method thereof | |
| CN103694896A (en) | Air-drying colorful color-change raw lacquer coating and modulation method thereof | |
| CN1392203B (en) | Engraved intaglo printing pearlite ink and producing technology | |
| CN104312268A (en) | Environment-friendly printing ink with high adhesive force | |
| CN111117354A (en) | Water-based propylene marker ink and preparation method thereof | |
| CN110204793A (en) | One kind is from moisturizing procrypsis changeable colour plasticine and preparation method thereof | |
| CN103497583A (en) | Preparation method of rubber environment-friendly printing ink | |
| CN103483904B (en) | The titanium mountain valley with clumps of trees and bamboo blue plastics black printed ink manufacture method | |
| CN108441023B (en) | Writing brush writing method ink mark correction liquid and preparation method thereof | |
| CN102702862B (en) | Ink paste and preparation technology thereof | |
| CN103497570B (en) | Light planographic ink manufacture method | |
| CN103497572A (en) | Preparation method of benzidine yellow letter press ink | |
| PO et al. | N I. Erasable Ink Production for White Board Marker Using Locally Sourced Dye | |
| CN106433298A (en) | Binder and environment-friendly offset rotary ink containing same | |
| US328366A (en) | Chaeles walpuski | |
| CN109280421A (en) | A kind of writing brush ink with good stability | |
| CN112826753A (en) | Environment-friendly high-stability water-based frosted nail polish and preparation method thereof | |
| CN103497584A (en) | Environmentally-friendly printing ink for polyethylene film printing | |
| CN103497575A (en) | Preparation method of environment-friendly crimson ink for plastic printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |