CN105400286B - A kind of environment-friendly type water base ink compositions - Google Patents
A kind of environment-friendly type water base ink compositions Download PDFInfo
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- CN105400286B CN105400286B CN201510919094.7A CN201510919094A CN105400286B CN 105400286 B CN105400286 B CN 105400286B CN 201510919094 A CN201510919094 A CN 201510919094A CN 105400286 B CN105400286 B CN 105400286B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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Abstract
A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：3~5 parts of tannic acid, 4~8 parts of gallic acid, 8~14 parts of ferrous sulfate, 2~5 parts of colorant, 2~4 parts of sulfonic acid type water-based polyurethane, 8~15 parts of modifying agent, 0.5~1 part of anion surfactant, 0.5~1 part of mould inhibitor, 3~6 parts of dispersant, 50~80 parts of water.The composition for ink of the present invention adopts water as solvent, it is to avoid organic solvent produces harm to the health and natural environment of user；The raw material of the present invention uses the material of asepsis environment-protecting, without heavy metal；Rationally, the feel with good fluency and lubrication when gained ink is used to write, paper of not spreading and sinking in, ink does not flocculate, dried the formula of the present invention, and nib is not dry and hard, non-leakage, is a kind of good composition for ink of combination property.
Description
Technical field
The present invention relates to a kind of writing ink, and in particular to a kind of environment-friendly type water base ink compositions.
Background technology
With the development of the active and economy and trade of culture, the demand of various water-color paintbrush class products is growing at top speed year by year.According to endless
Full statistics, current China's water-color paintbrush product annual production oneself far surpass 10,000,000,000.Many water-color paintbrush inks are used based on organic solvent at present
Material, accounts for the 70~80% of drop mass, organic solvent typically has part benzene class, ethers, methanol based on alcohol, esters, also, very
To being acetone.These organic solvents are volatile when using and assembling to produce waste, not only pollutes environment, and people can be good for
Health produces harm.The solvent-based inks of some different colours are detected through researcher, wherein heavy metals exceeding standard, book is found
Have benzene solvent residual on paper product after writing, and also other heavy metal elements, such as mercury, arsenic, lead, press against, selenium, barium.These are residual
Influence can be produced to the health of human body especially children by staying, and abandon the destruction that natural environment is will also result in into environment.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of environment-friendly type water base ink compositions, gained composition for ink
Writing quality is excellent, and with the good feature of environmental protection.
The present invention solve the technical scheme that uses of above-mentioned technical problem for：A kind of environment-friendly type water base ink compositions, by with
Lower raw material composition：Tannic acid, gallic acid, ferrous sulfate, colorant, sulfonic acid type water-based polyurethane, modifying agent, anionic surface are lived
Property agent, mould inhibitor, dispersant and water, the mass parts ratio of the raw material is：3~5 parts of tannic acid, 4~8 parts of gallic acid, sulfuric acid
Ferrous 8~14 parts, 2~5 parts of colorant, 2~4 parts of sulfonic acid type water-based polyurethane, 8~15 parts of modifying agent, anion surfactant
0.5~1 part, 0.5~1 part of mould inhibitor, 3~6 parts of dispersant, 50~80 parts of water；
Described environment-friendly type water base ink compositions adjust pH2.0~4.0 using sulfuric acid.
Further, the modifying agent is one kind in glycerine, polysorbate or its combination, and the modifying agent is used to keep
Ink moistens on nib, not dry and hard；Its osmosis can be such that handwriting is dried immediately on paper, prevent from smearing, prevent ink
Water is spread and sunk in paper.
Further, the anion surfactant is nekal, and the anion surfactant can
Ink surface tension is reduced, writing smoothly property and lubrication feel is improved；Its hydrophilic group one end tends to inside polar solvent ink, hates
Water base one end is gathered in ink surface, and a kind of effect of sealing of surface is played in aligning for formation rule, prevents that ink oxidation is heavy
Form sediment, strengthen the stability of ink.
Further, the colorant is Acid Ink Blue G or acid black ATT.
Further, the mould inhibitor is salicylic acid, calcium propionate or its combination.
Further, the dispersant is naphthalenesulfonate formaldehyde condensation compound, for reducing the association between particulate or droplet
Effect, prevents flocculation.
The sulfonic acid type water-based polyurethane is anion-type water-thinned polyurethane, is favorably improved ink submissive in writing
Property, ink seepage in pen container when preventing from writing.
The environment-friendly type water base ink compositions be used as ink preparation method be：By the mass parts than tannic acid,
After gallic acid, ferrous sulfate and water are well mixed, pH2.0~4.0 are adjusted using sulfuric acid, sulfonic acid type water is stirring evenly and then adding into
Property polyurethane, colorant, modifying agent, anion surfactant, mould inhibitor and dispersant, stir, sulphur are then used again
Acid for adjusting pH to 2.0~4.0, both composition for ink of the invention.
Tannic acid reacts in ink with ferrous sulfate in acid condition, generates that colourless tannic acid is ferrous to be simultaneously dissolved in water, with
The tannic acid high ferro of black is gradually oxidized to after air contact；Gallic acid and ferrous salt action in acid condition, connect with air
Touch and generate water insoluble black gallic acid high ferro after gradually aoxidizing, water-fast, the sun-proof strong degree of ink writing can be improved, with
Black or blue colorant, which coexist, can strengthen the durability of ink writing, be suitable for the field high to document writing life requirement
Close；Both gallic acid and tannic acid can also play mutual solubilization.
Compared with prior art, the advantage that the present invention possesses：The composition for ink of the present invention adopts water as solvent, it is to avoid
Organic solvent produces harm to the health and natural environment of user；The raw material of the present invention uses the material of asepsis environment-protecting, is free of
Heavy metal；Rationally, the feel with good fluency and lubrication, does not spread and sink in the formula of the present invention when gained ink is used to write
Paper, ink does not flocculate, dried, and nib is not dry and hard, non-leakage, is a kind of good composition for ink of combination property.
Embodiment
With reference to specific embodiment, the present invention is described further.
Embodiment 1：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：4 parts of tannic acid, do not have
6 parts of gallate-based, 12 parts of ferrous sulfate, 3 parts of colorant, 3 parts of sulfonic acid type water-based polyurethane, 12 parts of modifying agent, anion surface active
1 part of agent, 0.5 part of mould inhibitor, 5 parts of dispersant, 65 parts of water；Described environment-friendly type water base ink compositions are adjusted using sulfuric acid
pH3.0。
Further, the modifying agent is glycerine and polysorbate, and the modifying agent is used to keep ink wet on nib
Profit, it is not dry and hard；Its osmosis can be such that handwriting is dried immediately on paper, prevent from smearing, and prevent that ink from spreading and sinking in paper.
Further, the anion surfactant is nekal, and the anion surfactant can
Ink surface tension is reduced, writing smoothly property and lubrication feel is improved；Its hydrophilic group one end tends to inside polar solvent ink, hates
Water base one end is gathered in ink surface, and a kind of effect of sealing of surface is played in aligning for formation rule, prevents that ink oxidation is heavy
Form sediment, strengthen the stability of ink.
Further, the colorant is Acid Ink Blue G.
Further, the mould inhibitor is the mixture of salicylic acid and calcium propionate.
Further, the dispersant is naphthalenesulfonate formaldehyde condensation compound, for reducing the association between particulate or droplet
Effect, prevents flocculation.
The sulfonic acid type water-based polyurethane is anion-type water-thinned polyurethane, is favorably improved ink submissive in writing
Property, ink seepage in pen container when preventing from writing.
Embodiment 2：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：3 parts of tannic acid, do not have
4 parts of gallate-based, 8 parts of ferrous sulfate, 2 parts of colorant, 2 parts of sulfonic acid type water-based polyurethane, 8 parts of modifying agent, anion surfactant
0.5 part, 0.5 part of mould inhibitor, 3 parts of dispersant, 50 parts of water；Described environment-friendly type water base ink compositions are adjusted using sulfuric acid
pH2.0。
Further, the modifying agent is glycerine, and the anion surfactant is nekal, the color
Expect for acid black ATT, the mould inhibitor is salicylic acid, the dispersant is naphthalenesulfonate formaldehyde condensation compound.
Embodiment 3：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：5 parts of tannic acid, do not have
8 parts of gallate-based, 14 parts of ferrous sulfate, 5 parts of colorant, 4 parts of sulfonic acid type water-based polyurethane, 15 parts of modifying agent, anion surface active
1 part of agent, 1 part of mould inhibitor, 6 parts of dispersant, 80 parts of water；Described environment-friendly type water base ink compositions adjust pH4.0 using sulfuric acid.
Further, the modifying agent is polysorbate, and the anion surfactant is nekal, institute
Colorant is stated for Acid Ink Blue G, the mould inhibitor is the mixture of salicylic acid and calcium propionate, the dispersant is naphthalene sulfonate first
Aldehyde condensate.
Embodiment 4：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：3 parts of tannic acid, do not have
8 parts of gallate-based, 8 parts of ferrous sulfate, 5 parts of colorant, 2 parts of sulfonic acid type water-based polyurethane, 10 parts of modifying agent, anion surfactant
1 part, 0.5 part of mould inhibitor, 6 parts of dispersant, 80 parts of water；Described environment-friendly type water base ink compositions adjust pH3.0 using sulfuric acid.
Further, the modifying agent is glycerine, the mixture of polysorbate, and the anion surfactant is two fourths
Base sodium naphthalene sulfonate, the colorant is acid black ATT, and the mould inhibitor is calcium propionate, and the dispersant contracts for naphthalene sulphonate formaldehyde
Compound.
Embodiment 5：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：4 parts of tannic acid, do not have
5 parts of gallate-based, 9 parts of ferrous sulfate, 4 parts of colorant, 4 parts of sulfonic acid type water-based polyurethane, 13 parts of modifying agent, anion surfactant
0.7 part, 0.8 part of mould inhibitor, 4 parts of dispersant, 58 parts of water；Described environment-friendly type water base ink compositions are adjusted using sulfuric acid
pH2.5。
Further, the modifying agent is glycerine, and the anion surfactant is nekal, the color
Expect for acid black ATT, the mould inhibitor is salicylic acid, the mixture of calcium propionate, the dispersant is naphthalene sulphonate formaldehyde condensation
Thing.
Embodiment 6：A kind of environment-friendly type water base ink compositions, including following mass parts than raw material：4 parts of tannic acid, do not have
8 parts of gallate-based, 11 parts of ferrous sulfate, 3 parts of colorant, 3 parts of sulfonic acid type water-based polyurethane, 9 parts of modifying agent, anion surfactant
0.8 part, 0.5 part of mould inhibitor, 5 parts of dispersant, 70 parts of water；Described environment-friendly type water base ink compositions are adjusted using sulfuric acid
pH2.0。
Further, the modifying agent is glycerine, and the anion surfactant is nekal, the color
Expect for acid black ATT, the mould inhibitor is salicylic acid, the dispersant is naphthalenesulfonate formaldehyde condensation compound.
Take composition for ink obtained by 1-6 of the embodiment of the present invention using QB/T1745-93 standard carry out ink it is water-fast,
Sun-proof aptitude test, as a result shows that the writing stitching after experiment process is clear, the requirement of professional standard is fully achieved；And
Feel with good fluency and lubrication during writing, paper of not spreading and sinking in, ink does not flocculate, dried, and nib is not dry and hard, non-leakage,
For a kind of good composition for ink of combination property.
Claims (1)
1. a kind of environment-friendly type water base ink compositions, it is characterised in that be made up of following raw material：Tannic acid, gallic acid, sulfuric acid
Ferrous iron, colorant, sulfonic acid type water-based polyurethane, modifying agent, anion surfactant, mould inhibitor, dispersant and water, the raw material
Mass parts ratio be：3~5 parts of tannic acid, 4~8 parts of gallic acid, 8~14 parts of ferrous sulfate, 2~5 parts of colorant, sulfonic acid type water
2~4 parts of polyurethane of property, 8~15 parts of modifying agent, 0.5~1 part of anion surfactant, 0.5~1 part of mould inhibitor, dispersant 3
~6 parts, 50~80 parts of water；
Described environment-friendly type water base ink compositions adjust pH2.0~4.0 using sulfuric acid；
The modifying agent is one kind in glycerine, polysorbate or its combination；
The anion surfactant is nekal；
The colorant is Acid Ink Blue G or acid black ATT；
The mould inhibitor is salicylic acid, calcium propionate or its combination；
The dispersant is naphthalenesulfonate formaldehyde condensation compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510919094.7A CN105400286B (en) | 2015-12-11 | 2015-12-11 | A kind of environment-friendly type water base ink compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510919094.7A CN105400286B (en) | 2015-12-11 | 2015-12-11 | A kind of environment-friendly type water base ink compositions |
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| Publication Number | Publication Date |
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| CN105400286A CN105400286A (en) | 2016-03-16 |
| CN105400286B true CN105400286B (en) | 2017-10-31 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108129910A (en) * | 2017-12-23 | 2018-06-08 | 洛阳名力科技开发有限公司 | Weak solvent ink |
| CN108841242A (en) * | 2018-07-18 | 2018-11-20 | 太仓市顺昌锻造有限公司 | A kind of antirust fungicidal ink |
| CN109735169A (en) * | 2019-03-12 | 2019-05-10 | 云南师范大学 | A kind of aqueous invisible ink of catalytic type and preparation method thereof |
| CN112251070A (en) * | 2020-10-22 | 2021-01-22 | 梁贻波 | Environment-friendly water-based ink and preparation method thereof |
| CN114196253A (en) * | 2021-12-28 | 2022-03-18 | 威海长青海洋科技股份有限公司 | Water-soluble high-temperature-resistant ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130627A (en) * | 2014-07-23 | 2014-11-05 | 王勇 | Stable discoloration ink |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130627A (en) * | 2014-07-23 | 2014-11-05 | 王勇 | Stable discoloration ink |
Non-Patent Citations (2)
| Title |
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| 墨水成分研究;豆丁网;《http://www.docin.com/p-1248984289.html》;20150807;第1-9页 * |
| 文化用品与化学;百度文库;《https://wenku.baidu.com/view/deeb3ece84254b35effd3401.html》;20130814;第2-4页 * |
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