CN107881803A - A kind of processing method of hydrophobic antibacterial multi-functional coatings cloth - Google Patents

A kind of processing method of hydrophobic antibacterial multi-functional coatings cloth Download PDF

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Publication number
CN107881803A
CN107881803A CN201711288578.1A CN201711288578A CN107881803A CN 107881803 A CN107881803 A CN 107881803A CN 201711288578 A CN201711288578 A CN 201711288578A CN 107881803 A CN107881803 A CN 107881803A
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hydrophobic
coating
cloth
functional coatings
fungistatic
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张进
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Individual
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
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    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D06M13/156—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring containing halogen atoms
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
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    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
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    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
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    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
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Abstract

The present invention relates to a kind of processing method of hydrophobic antibacterial multi-functional coatings cloth.A kind of processing method of described hydrophobic antibacterial multi-functional coatings cloth, comprises the following steps：a）Stirred 12~24 hours after the raw material of fungistatic coating is mixed, produce fungistatic coating slurries, be evenly applied to warp knitting cloth surface, dried, fungistatic coating is formed on warp knitting cloth surface；b）Stirred 1~3 hour at 50~80 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed and obtain hydrophobic coating slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, obtains the warp knitting cloth with hydrophobic coating；c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method hydrophobic antibacterial multi-functional coatings cloth is made.

Description

A kind of processing method of hydrophobic antibacterial multi-functional coatings cloth
Technical field
The present invention relates to a kind of coating cloth, more particularly, to a kind of processing method of hydrophobic antibacterial multi-functional coatings cloth.
Background technology
Coating cloth is mainly to be coated with one layer of material with specific function using special process on the basis of cloth so that Cloth adds specific function, and coating cloth is widely used in the numerous areas such as tent, clothes, case and bag, national defence, transport.Coating cloth Using or storage in inevitably contact the environment of high humidity, now, waterproof and biocidal property are particularly important.
Generally, the method for waterproof material coating can be used to realize waterproof, the method by adding antibacterial material Realize preferable fungistatic effect.But in the prior art simultaneously realize that the coating cloth of waterproof and fungistatic effect is considerably less, waterproof and The addition of antibacterial material often causes the flexibility of coating cloth and mechanical property to be deteriorated, and influences the normal use of coating cloth, moreover, The adhesion-tight degree of in general waterproof and antibacterial material in base fabric is limited, it is impossible to long-term use of.In addition, waterproof material and antibacterial How material realizes uniformly coating and a great problem.
The content of the invention
To solve the above problems, the present invention, which provides one kind, has hydrophobic function, there is anti-light corrosive nature, hydrophobic well The processing method of antibacterial multi-functional coatings cloth.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of processing method of described hydrophobic antibacterial multi-functional coatings cloth, comprises the following steps：
a）Will fungistatic coating raw material mix after stir 12~24 hours, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；Fungistatic coating is made by the raw material of following parts by weight：Bamboo fibre 15~20 parts, 0.5~2 part of horseradish extract, 0.5~2 part of Semen Benincasae extract, 20~35 parts of polyvinylidene emulsions, third 35~45 parts of the compound emulsion of olefin(e) acid ester copolymer and paraffin；
b）Stirred 1~3 hour at 50~80 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed To hydrophobic coating slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, had There is the warp knitting cloth of hydrophobic coating；Hydrophobic coating is made by the raw material of following parts by weight：100 parts of PVC paste resin, environment-friendly plasticizer 50 ~80 parts, 2~5 parts of stabilizer, 0~60 part of filler, 0~20 part of fire retardant, 0~5 part of mould inhibitor, 0~5 part of antioxidant, glue 0~10 part of mixture, 0~70 part of hydrophobic nanofiber but is not zero；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.
Preferably, the thickness of the hydrophobic coating and fungistatic coating is respectively 0.1~1mm, it is hydrophobic after electrostatic spinning to receive The density of rice fiber is 250~400/mm2。
Further to be preferably, both weight ratios are 1 in the compound emulsion of acrylate copolymer and paraffin：1.
Titanium dioxide is a kind of UV resistant agent with excellent results, while titanium dioxide also has good self-cleaning Effect；Titanium dioxide-coated is being played into uvioresistant in multi-functional coatings cloth surface, is preventing to play while photoetch Self-cleaning net effect, organic matter of cleaning multi-functional coatings cloth surface attachment etc. has dysgenic to the multi-functional coatings cloth life-span Dust etc., the titanium dioxide used in addition are not traditional powdered titanium dioxide, but use titanium dioxide micro-nano fiber, this Sample can play a part of increasing titanium dioxide specific surface area, while multi-functional coatings cloth surface is furnished with micro-nano fiber and can played Hydrophobic effect, so it is also prevented from erosion of the rainy day rainwater to multi-functional coatings cloth.
Preferably, described environment-friendly plasticizer for synthesis vegetable esters, butyl epoxy stearate, octyl epoxy stearate or One or more in dioctyl phthalate, described stabilizer are calcium stearate, zinc stearate or zinc ricinate, institute The mould inhibitor stated is phenol, pentachlorophenol or tributyl tin, and described antioxidant is butylated hydroxy anisole, butylated hydroxy-a Benzene or propylgallate, described fire retardant are magnesium hydroxide, aluminium hydroxide or tricresyl phosphate.
Preferably, hydrophobic nanofiber is 0.1~3mm of length, the titania fiber that 0.1~1 μm of diameter.
Preferably, titania fiber is made by following steps：Titanium source is mixed with water, and is heated to 60~80 DEG C, Fully filtered after reaction and be cleaned and dried sediment, dried sediment is uniformly mixed with fused salt afterwards, then heated to 500~600 DEG C are calcined 0.5~1 hour, are warming up to 800~850 DEG C afterwards and are calcined 4~10 hours, are cooled to clear with water after room temperature Wash and dry；Wherein, the mass ratio of titanium source and fused salt is 1：10~12, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, Wherein the molar percentage of lithium carbonate is 35~65%.
Titanium dioxide micro-nano fiber is prepared using molten-salt growth method, has processing step simple, is meeting the premise of product requirement Under, simplify process, and raw material prepared by molten-salt growth method be easy to get, endanger it is small, using lithium carbonate and potassium carbonate as fused salt because The liquid phase region of lithium carbonate potassium carbonate fused salt mixt is wider, and liquid phase region is 500~900 DEG C, at 800 DEG C above is the mobility of fused salt It is higher, the fused salt of liquid phase is just presented compared to 700 DEG C or so, the mobility of lithium carbonate potassium carbonate fused salt is higher, can be with more efficient Promotion raw material reaction and produce fiber；First time insulation in calcination process is in order that zinc source（Zinc acetate or citric acid During zinc）Titanium dioxide is resolved into, second insulation is in order that titania growth is into threadiness.Preferably, titanium source is four Titanium chloride.
Therefore, the invention has the advantages that：
（1）With excellent hydrophobic performance, it can prevent from adhering to more ponding on multi-functional coatings cloth after rain, influence stability, It is suitable as the use of canopy cloth；
（2）With good anti-light corrosive nature, substantial amounts of visible ray can be reflected, shielding can also be played to ultraviolet and is made With, be also applied for high temperature and the environment such as be exposed to the sun under；
（3）Preparation method simple and fast, effect is good, is prepared using existing equipment, and industry alteration difficulty is small；
（4）Bacteriostasis property is excellent, using Natural anti-mildew bacteriostatic agent, by suitable compatibility, makes product not easy to change mouldy, does not allow Easy breed bacteria, antiageing effect are good.
Embodiment
Technical scheme is further described with reference to embodiment.
Horseradish extract, purchased from Xi'an Sai Ao Bioisystech Co., Ltd；
Semen Benincasae extract, Shaanxi Bo Lin Bioisystech Co., Ltd；
Vegetable esters are synthesized, purchased from Guangzhou Fu Fei Chemical Co., Ltd.s；
Bamboo fibre, select bamboo fibre raw material of the length range for 5-25mm.
Embodiment 1
A kind of hydrophobic antibacterial multi-functional coatings cloth, the multi-functional coatings cloth include warp knitting cloth, coated on warp knitting cloth from bottom to top The fungistatic coating on surface and coated on the hydrophobic coating on fungistatic coating；
Wherein, fungistatic coating is made by following raw material：The kg of bamboo fibre 20, the kg of horseradish extract 2, the kg of Semen Benincasae extract 2, The compound emulsion of the kg of polyvinylidene emulsions 20, acrylate copolymer and paraffin（Weight is than 1：1）35kg,
Hydrophobic coating is made by following raw material：The kg of PVC paste resin 100, synthesis vegetable esters are with dioctyl phthalate with weight Than 1:The kg of composition 50, the kg of calcium stearate 2, the kg of hydrophobic nanofiber 40 of 1 mixing；Hydrophobic nanofiber is that length is 1mm Left and right, the titania fiber that 0.1 μm or so of diameter；
Titania fiber is made by following steps：Titanium tetrachloride is mixed with water, and is heated to 60 DEG C, is fully filtered after reaction And sediment is cleaned and dried, dried sediment is uniformly mixed with fused salt afterwards, it is small to then heat to 500 DEG C of calcinings 0.5 When, 800 DEG C are warming up to afterwards and is calcined 4 hours, are cooled to after room temperature and are cleaned and dried with water；The mass ratio of titanium tetrachloride and fused salt For 1：10, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, and wherein the molar percentage of lithium carbonate is 35%.
The processing method of above-mentioned hydrophobic antibacterial multi-functional coatings cloth, is comprised the concrete steps that：
a）Will fungistatic coating raw material mix after stir 24 hours or so, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；
b）Stirred 2 hours at 60 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed and obtain hydrophobic painting Layer slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, obtains that there is hydrophobic painting The warp knitting cloth of layer；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.The thickness of fungistatic coating is about 0.8mm, and the thickness of hydrophobic coating is about 1mm, dewatering nano after electrostatic spinning The density of fiber is 250/mm2。
Embodiment 2
A kind of hydrophobic antibacterial multi-functional coatings cloth, the multi-functional coatings cloth include warp knitting cloth, coated on warp knitting cloth from bottom to top The fungistatic coating on surface and coated on the hydrophobic coating on fungistatic coating；
Wherein, fungistatic coating is made by following raw material：The kg of bamboo fibre 16, the kg of horseradish extract 2, the kg of Semen Benincasae extract 2, The compound emulsion of the kg of polyvinylidene emulsions 20, acrylate copolymer and paraffin（Weight is than 1：1）35kg,
Hydrophobic coating is made by following raw material：PVC paste resin 100kg, butyl epoxy stearate 50kg, calcium stearate 2kg, is filled out Expect 15kg, magnesium hydroxide 3kg, phenol 1kg, butylated hydroxy anisole 1kg, adhesive 2kg, hydrophobic nanofiber 40kg；It is hydrophobic Nanofiber is length 0.5mm, the titania fiber that 0.1 μm of diameter；
Titania fiber is made by following steps：Titanium tetrachloride is mixed with water, and is heated to 60 DEG C, is fully filtered after reaction And sediment is cleaned and dried, dried sediment is uniformly mixed with fused salt afterwards, it is small to then heat to 500 DEG C of calcinings 0.5 When, 800 DEG C are warming up to afterwards and is calcined 4 hours, are cooled to after room temperature and are cleaned and dried with water；The mass ratio of titanium tetrachloride and fused salt For 1：10, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, and wherein the molar percentage of lithium carbonate is 40%.
The processing method of above-mentioned hydrophobic antibacterial multi-functional coatings cloth, is comprised the concrete steps that：
a）Will fungistatic coating raw material mix after stir 24 hours or so, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；
b）Stirred 1 hour at 55 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed and obtain hydrophobic painting Layer slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, obtains that there is hydrophobic painting The warp knitting cloth of layer；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.The thickness of fungistatic coating is about 1mm, and the thickness of hydrophobic coating is about 0.5mm, dewatering nano after electrostatic spinning The density of fiber is 250/mm2。
Embodiment 3
A kind of hydrophobic antibacterial multi-functional coatings cloth, the multi-functional coatings cloth include warp knitting cloth, coated on warp knitting cloth from bottom to top The fungistatic coating on surface and coated on the hydrophobic coating on fungistatic coating；
Wherein, fungistatic coating is made by following raw material：Bamboo fibre 15 kg, horseradish extract 0.8kg, Semen Benincasae extract 1kg, The compound emulsion of the kg of polyvinylidene emulsions 35, acrylate copolymer and paraffin（Weight is than 1：1）40kg,
Hydrophobic coating is made by following raw material：PVC paste resin 100kg, octyl epoxy stearate 65kg, zinc stearate 4kg, is filled out Expect 30kg, aluminium hydroxide 10kg, pentachlorophenol 3kg, dibutyl hydroxy toluene 2kg, adhesive 5kg, hydrophobic nanofiber 55kg；Dredge Water nanofiber is length 0.5mm, the titania fiber that 0.5 μm of diameter；
Titania fiber is made by following steps：Titanium tetrachloride is mixed with water, and is heated to 70 DEG C, is fully filtered after reaction And sediment is cleaned and dried, dried sediment is uniformly mixed with fused salt afterwards, 550 DEG C is then heated to and calcines 1 hour, 850 DEG C are warming up to afterwards to calcine 7 hours, are cooled to after room temperature and are cleaned and dried with water；The mass ratio of titanium tetrachloride and fused salt is 1：11, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, and wherein the molar percentage of lithium carbonate is 50%.
The processing method of above-mentioned hydrophobic antibacterial multi-functional coatings cloth, is comprised the concrete steps that：
a）Will fungistatic coating raw material mix after stir 24 hours or so, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；
b）Stirred 1 hour at 65 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed and obtain hydrophobic painting Layer slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, obtains that there is hydrophobic painting The warp knitting cloth of layer；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.The thickness of fungistatic coating is about 0.5mm, and the thickness of hydrophobic coating is about 0.5mm, hydrophobic after electrostatic spinning to receive The density of rice fiber is 350/mm2。
Embodiment 4
A kind of hydrophobic antibacterial multi-functional coatings cloth, the multi-functional coatings cloth include warp knitting cloth, coated on warp knitting cloth from bottom to top The fungistatic coating on surface and coated on the hydrophobic coating on fungistatic coating；
Wherein, fungistatic coating is made by following raw material：Bamboo fibre 18kg, horseradish extract 1kg, the kg of Semen Benincasae extract 1, gather The compound emulsion of the kg of vinylidene chloride emulsion 30, acrylate copolymer and paraffin（Weight is than 1：1）35kg,
Hydrophobic coating is made by following raw material：PVC paste resin 100kg, epoxy tetrahydro-2-ethylhexyl phthalate 80kg, castor-oil plant Zinc oleate 5kg, filler 60kg, tricresyl phosphate 20kg, tributyl tin 5kg, propylgallate 5kg, adhesive 10kg, dredge Water nanofiber 70kg；Hydrophobic nanofiber is length 0.3mm, the titania fiber that 1 μm of diameter；
Titania fiber is made by following steps：Titanium tetrachloride is mixed with water, and is heated to 80 DEG C, is fully filtered after reaction And sediment is cleaned and dried, dried sediment is uniformly mixed with fused salt afterwards, 600 DEG C is then heated to and calcines 1 hour, 850 DEG C are warming up to afterwards to calcine 10 hours, are cooled to after room temperature and are cleaned and dried with water；The mass ratio of titanium tetrachloride and fused salt is 1：12, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, and wherein the molar percentage of lithium carbonate is 65%.
The processing method of above-mentioned hydrophobic antibacterial multi-functional coatings cloth, is comprised the concrete steps that：
a）Will fungistatic coating raw material mix after stir 24 hours or so, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；
b）Stirred 1 hour at 65 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed and obtain hydrophobic painting Layer slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, obtains that there is hydrophobic painting The warp knitting cloth of layer；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.The thickness of fungistatic coating is about 0.3mm, and the thickness of hydrophobic coating is about 0.2mm, hydrophobic after electrostatic spinning to receive The density of rice fiber is 400/mm2。
Comparative example 1：
A kind of coating cloth, is not provided with fungistatic coating, and remaining is the same as embodiment 1.
Comparative example 2：
A kind of coating cloth, is not provided with hydrophobic coating, and remaining is the same as embodiment 1.
Comparative example 3：
A kind of coating cloth, horseradish extract and Semen Benincasae extract is not contained in fungistatic coating, remaining is the same as embodiment 1.
Test example
First, fungistatic effect is tested：
1st, test strain：Select representative strain, staphylococcus aureus, candida albicanses, Pseudomonas aeruginosa and more Killing property Pasteurella, it is market purchase.
2nd, bacterium culture medium：Nutrient agar and nutrient broth medium.
3rd, specific test procedure：
（1）The preparation of bacterium solution：Above-mentioned four kinds of strains are inoculated on four agar mediums respectively, it is small that 36 are cultivated at 37 DEG C When, picking colonies typical is inoculated in four fresh nutrient broth mediums respectively from above-mentioned agar medium respectively, together At a temperature of, cultivate 24 hours, it is standby.
（2）Strain dispenses and mark：By step（1）Through the sterile nutrient broth of the foster 24 hours strain of nutrition broth cultivation 50 times are diluted respectively, and every kind of strain is sub-packed in 7 culture dishes.
（3）Sterilization：By the rain cover cloth of embodiment 1~4 and comparative example 1~4, any interception 1cm × 1cm, immerses respectively Step（2）Culture dish in.
5th, result of the test：
Observe four groups of strains and measure strain revolution mark, record observation result, be specifically shown in Table 1.
The bacterium colony revolution mark result of table 1.
Staphylococcus aureus Candida albicanses Pseudomonas aeruginosa Pasteurella multocida
Embodiment 1 0.5% 0.8% 0.8% 0.3%
Embodiment 2 0.4% 0.5% 0.6% 0.5%
Embodiment 3 0.3% 0.8% 0.7% 0.5%
Embodiment 4 0.5% 0.6% 0.5% 0.3%
Comparative example 1 42% 36% 58% 40%
Comparative example 2 3.0% 4.2% 4.8% 2.6%
Comparative example 3 10.1% 13.5% 6.7% 14.2%
Conclusion as can be drawn from Table 1, fungistatic coating and hydrophobic coating after special compounding, make the present invention product have it is more preferable Bacteriostasis property.
2nd, water resistance is tested：
Water resistance test is carried out according to GB/T14577-1993 method, is shone with reference and is commented according to the range estimation of following 5 grades of standards Determine the water proofing property of sample, 5 grades optimal, and 1 grade worst：
5 grades, droplet quickly drips；
4 grades, form large water drop；
3 grades, aliquot is stained with the globule；
It is 2 grades, partially wetted；
1 grade, whole surface wetting.
After tested, the water resistance of embodiment 1-4 rain cover cloth is 5 grades, and comparative example 1 and 3 is 5 grades, and comparative example 2 is 3 Level.
3rd, permanence operation：
30 DEG C of temperature, under the conditions of humidity 65%RH, after 2 years, the multi-functional coatings cloth of embodiment 1~4 does not occur coating Situation about coming off, remain to adhere to well, there is longer service life.

Claims (7)

1. a kind of processing method of hydrophobic antibacterial multi-functional coatings cloth, it is characterised in that comprise the following steps：
a）Will fungistatic coating raw material mix after stir 12~24 hours, produce fungistatic coating slurries, be evenly applied to through Cloth surface is compiled, drying, fungistatic coating is formed on warp knitting cloth surface；Fungistatic coating is made by the raw material of following parts by weight：Bamboo fibre 15~20 parts, 0.5~2 part of horseradish extract, 0.5~2 part of Semen Benincasae extract, 20~35 parts of polyvinylidene emulsions, third 35~45 parts of the compound emulsion of olefin(e) acid ester copolymer and paraffin；
b）Stirred 1~3 hour at 50~80 DEG C after the raw material made in hydrophobic coating in addition to hydrophobic nanofiber is mixed To hydrophobic coating slurry；Hydrophobic coating slurry after stirring is coated uniformly on the fungistatic coating that step a obtains, had There is the warp knitting cloth of hydrophobic coating；Hydrophobic coating is made by the raw material of following parts by weight：100 parts of PVC paste resin, environment-friendly plasticizer 50 ~80 parts, 2~5 parts of stabilizer, 0~60 part of filler, 0~20 part of fire retardant, 0~5 part of mould inhibitor, 0~5 part of antioxidant, glue 0~10 part of mixture, 0~70 part of hydrophobic nanofiber but is not zero；
c）Hydrophobic nanofiber is planted in the hydrophobic coating surface that step b obtains with electrostatic spinning method and is made hydrophobic antibacterial more Functional coating cloth.
A kind of 2. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 1, it is characterised in that：It is described The thickness of hydrophobic coating and fungistatic coating is respectively 0.1~3mm, and the density of hydrophobic nanofiber is 250~400 after electrostatic spinning Root/mm2。
A kind of 3. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 1, it is characterised in that：It is described Environment-friendly plasticizer in synthesis vegetable esters, butyl epoxy stearate, octyl epoxy stearate or dioctyl phthalate One or more, described stabilizer are calcium stearate, zinc stearate or zinc ricinate, and described mould inhibitor is phenol, five Chlorophenol or tributyl tin, described antioxidant are butylated hydroxy anisole, dibutyl hydroxy toluene or propylgallate, institute The fire retardant stated is magnesium hydroxide, aluminium hydroxide or tricresyl phosphate.
A kind of 4. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 1, it is characterised in that：It is hydrophobic Nanofiber is 0.1~1mm of length, the titania fiber that 0.1~1 μm of diameter.
A kind of 5. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 4, it is characterised in that：It is described Titania fiber be made by following steps：Titanium source is mixed with water, and is heated to 60~80 DEG C, is fully filtered simultaneously after reaction Sediment is cleaned and dried, afterwards uniformly mixes dried sediment with fused salt, then heats to 500~600 DEG C of calcinings 0.5 ~1 hour, 800~850 DEG C were warming up to afterwards and is calcined 4~10 hours, cleans and dries after being cooled to room temperature；
Wherein, the mass ratio of titanium source and fused salt is 1：10~12, fused salt is the mixed inorganic of potassium carbonate and lithium carbonate, wherein carbon The molar percentage of sour lithium is 35~65%.
A kind of 6. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 5, it is characterised in that：It is described Titanium source be titanium tetrachloride.
A kind of 7. processing method of hydrophobic antibacterial multi-functional coatings cloth according to claim 1, it is characterised in that：It is described Environment-friendly plasticizer for synthesis vegetable esters and dioctyl phthalate with weight than 1:The composition of 1 mixing.
CN201711288578.1A 2016-08-05 2016-08-05 A kind of processing method of hydrophobic antibacterial multi-functional coatings cloth Pending CN107881803A (en)

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Application publication date: 20180406