CN107880699A - 一种抗菌型丙烯酸防腐磁漆 - Google Patents

一种抗菌型丙烯酸防腐磁漆 Download PDF

Info

Publication number
CN107880699A
CN107880699A CN201711296628.0A CN201711296628A CN107880699A CN 107880699 A CN107880699 A CN 107880699A CN 201711296628 A CN201711296628 A CN 201711296628A CN 107880699 A CN107880699 A CN 107880699A
Authority
CN
China
Prior art keywords
parts
acrylic acid
antimicrobial form
acid corrosive
form acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711296628.0A
Other languages
English (en)
Inventor
李继盛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711296628.0A priority Critical patent/CN107880699A/zh
Publication of CN107880699A publication Critical patent/CN107880699A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • C09D133/064Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23Magnetisable or magnetic paints or lacquers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种抗菌型丙烯酸防腐磁漆,属于涂料生产技术领域。本发明的抗菌型丙烯酸防腐磁漆,由以下原料组成:丙烯酸树脂、聚乙二醇、填料、成膜剂、流平剂、分散剂、增稠剂、润湿剂、颜料、纳米级二氧化钛粉末、去离子水。本发明的抗菌型丙烯酸防腐磁漆是经过制备丙烯酸树脂、配置、混匀等一系列步骤制成的。本发明所述的抗菌型丙烯酸防腐磁漆,原料来源广泛、配比科学,具有耐高温、抗摩擦力好、防腐、抗菌的优点。

Description

一种抗菌型丙烯酸防腐磁漆
技术领域
本发明属于涂料生产技术领域,具体涉及一种抗菌型丙烯酸防腐磁漆。
背景技术
丙烯酸漆具有极好的耐候性,很高的机械性能,是发展很快的一类涂料。丙烯酸漆可分为自干型丙烯酸漆(热塑型)和交联固化型丙烯酸漆(热固型),前者属于非转化型涂料,后者属于转化型涂料。自干型丙烯酸涂料主要用于建筑涂料、塑料涂料、电子涂料、道路划线涂料等,具有表干迅速、易于施工、保护和装饰作用明显的优点。缺点是固含量不容易太高,硬度、弹性不容易兼顾,一次施工不能得到很厚的涂膜,涂膜丰满性不够理想。交联固化型丙烯酸涂料主要有丙烯酸氨基漆、丙烯酸聚氨酯漆、丙烯酸醇酸漆、辐射固化丙烯酸涂料等品种。广泛用于汽车涂料、电器涂料、木器涂料、建筑涂料等方面。交联固化型丙烯酸涂料一般都具有很高的固含量,一次涂装可以得到很厚的涂膜,而且机械性能优良,可以制成高耐候性、高丰满度、高弹性、高硬度的涂料。缺点是双组分涂料,施工比较麻烦,许多品种还需要加热固化或辐射固化,对环境条件要求比较高,一般都需要较好的设备,较熟练的涂装技巧。
丙烯酸磁漆是由丙烯酸树脂、加入各种颜料及增塑剂经研磨后加入有机溶剂配制而成。主要应用于磁器、瓷砖表面防护。近年来,随着消费者要求的不断提升,丙烯酸磁漆由于其成本低、防护力好、持久性好等优点,广受消费者喜欢。丙烯酸磁漆的相关配方技术也在不断发展。
发明内容
本发明提供了一种抗菌型丙烯酸防腐磁漆,以解决丙烯酸磁漆持久性差、涂装后易产生细菌造成本体受到腐蚀的问题。
为解决以上技术问题,本发明采用以下技术方案:一种抗菌型丙烯酸防腐磁漆,由以下质量配比的原料制备:丙烯酸树脂33~48份、聚乙二醇9~16份、填料10~21份、成膜剂15~27份、流平剂3~11份、分散剂4~13份、增稠剂4~12份、润湿剂2.5~8.5份、颜料4~10份、纳米级二氧化钛粉末5~10份、去离子水45~60份。
优选地,所述的抗菌型丙烯酸防腐磁漆,原料中所述的填料为云母粉、重晶石、碳酸钙按质量比1:0.5:1混合。
优选地,所述的抗菌型丙烯酸防腐磁漆,原料中所述的增稠剂为HEC、PEO、HPAM中的一种。
所述丙烯酸树脂的制备方法是:将甲苯和甲基丙烯酸丁酯的混合溶液后加入到反应釜中,加热搅拌;待水温升至80℃后,将已经混合均匀的苯乙烯、甲基丙烯酸甲酯、丙烯酸、AIBN匀速滴入混合溶液,在80℃恒温下在2h内滴加完毕,继续反应4h,停止加热,即得。
更优选地,所述的抗菌型丙烯酸防腐磁漆的制备方法,包括以下步骤:将丙烯酸树脂加入反应釜中,再依次加入聚乙二醇、填料、成膜剂、流平剂、分散剂、增稠剂、润湿剂、颜料、纳米级二氧化钛粉末、去离子水,升温至温度为50~70℃,在转速为300~400RPM转速下充分搅拌2~3h;待步骤均匀混合物料冷却至室温后,过200~300目筛网。
如未做说明,本发明技术方案所述成膜剂、流平剂、分散剂、润湿剂、颜料均为本领域常规产品。
本发明具有以下有益效果:本发明所述的抗菌型丙烯酸防腐磁漆具有耐高温、抗摩擦力好、防腐、抗菌的优点,其原料来源广泛,制备过程简单,成本低廉,制备工艺简明,对反应设备的要求较低,易于实现规模化工业生产。
具体实施方式
下面通过更具体实施例对本发明进行说明。为便于更好地理解本发明,通过以下实例加以说明,这些实例属于本发明的保护范围,但不限制本发明的保护范围。
实施例1一种抗菌型丙烯酸防腐磁漆,由以下质量配比原料制备:丙烯酸树脂33份、聚乙二醇9份、填料(云母粉、重晶石、碳酸钙按质量比1:0.5:1混合)10份、成膜剂15份、流平剂3份、分散剂4份、增稠剂HEC 4份、润湿剂2.5份、颜料4份、纳米级二氧化钛粉末5份、去离子水45份;其制备方法如下:
S1:将甲苯和甲基丙烯酸丁酯的混合溶液后加入到反应釜中,加热搅拌;待水温升至80℃后,将已经混合均匀的苯乙烯、甲基丙烯酸甲酯、丙烯酸、AIBN匀速滴入混合溶液,在80℃恒温下在2h内滴加完毕,继续反应4h,停止加热即得丙烯酸树脂;
S2:将步骤S1制得的丙烯酸树脂加入反应釜中,再依次加入聚乙二醇、填料、成膜剂、流平剂、分散剂、HEC、润湿剂、颜料、纳米级二氧化钛粉末、去离子水,升温至温度为50℃,在转速为300RPM转速下充分搅拌3h;
S3:待步骤S2所制得的均匀混合物料冷却至室温后,过200~目筛网。
实施例2一种抗菌型丙烯酸防腐磁漆,由以下质量配比原料制备:丙烯酸树脂48份、聚乙二醇16份、填料(云母粉、重晶石、碳酸钙按质量比1:0.5:1混合)21份、成膜剂27份、流平剂11份、分散剂13份、增稠剂PEO 12份、润湿剂8.5份、颜料10份、纳米级二氧化钛粉末10份、去离子水60份;其制备方法如下:
S1:将甲苯和甲基丙烯酸丁酯的混合溶液后加入到反应釜中,加热搅拌;待水温升至80℃后,将已经混合均匀的苯乙烯、甲基丙烯酸甲酯、丙烯酸、AIBN匀速滴入混合溶液,在80℃恒温下在2h内滴加完毕,继续反应4h,停止加热即得丙烯酸树脂;
S2:将步骤S1制得的丙烯酸树脂加入反应釜中,再依次加入聚乙二醇、填料、成膜剂、流平剂、分散剂、PEO、润湿剂、颜料、纳米级二氧化钛粉末、去离子水,升温至温度为70℃,在转速为400RPM转速下充分搅拌2h;
S3:待步骤S2所制得的均匀混合物料冷却至室温后,过300目筛网。
实施例3 一种抗菌型丙烯酸防腐磁漆,由以下质量配比原料制备:丙烯酸树脂42份、聚乙二醇12份、填料(云母粉、重晶石、碳酸钙按质量比1:0.5:1混合)16份、成膜剂21份、流平剂8份、分散剂8份、增稠剂HPAM 8份、润湿剂6.5份、颜料7份、纳米级二氧化钛粉末8份、去离子水55份;其制备方法如下:
S1:将甲苯和甲基丙烯酸丁酯的混合溶液后加入到反应釜中,加热搅拌;待水温升至80℃后,将已经混合均匀的苯乙烯、甲基丙烯酸甲酯、丙烯酸、AIBN匀速滴入混合溶液,在80℃恒温下在2h内滴加完毕,继续反应4h,停止加热即得丙烯酸树脂;
S2:将步骤S1制得的丙烯酸树脂加入反应釜中,再依次加入聚乙二醇、填料、成膜剂、流平剂、分散剂、HPAM、润湿剂、颜料、纳米级二氧化钛粉末、去离子水,升温至温度为60℃,在转速为350RPM转速下充分搅拌2.5h;
S3:待步骤S2所制得的均匀混合物料冷却至室温后,过250目筛网。
以上内容不能认定本发明具体实施只局限于这些说明,对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思前提下,还可以做出若干简单推演或替换,都应当视为属于本发明由所提交的权利要求书确定的专利保护范围。

Claims (5)

1.一种抗菌型丙烯酸防腐磁漆,其特征在于,由以下质量配比的原料制备:丙烯酸树脂33~48份、聚乙二醇9~16份、填料10~21份、成膜剂15~27份、流平剂3~11份、分散剂4~13份、增稠剂4~12份、润湿剂2.5~8.5份、颜料4~10份、纳米级二氧化钛粉末5~10份、去离子水45~60份。
2.根据权利要求1所述的抗菌型丙烯酸防腐磁漆,其特征在于,原料中所述的填料为云母粉、重晶石、碳酸钙按质量比1:0.5:1混合。
3.根据权利要求1所述的抗菌型丙烯酸防腐磁漆,其特征在于,原料中所述的增稠剂为HEC、PEO、HPAM中的一种。
4.根据权利要求1所述的抗菌型丙烯酸防腐磁漆,其特征在于,所述丙烯酸树脂的制备方法是:将甲苯和甲基丙烯酸丁酯的混合溶液后加入到反应釜中,加热搅拌;待水温升至80℃后,将已经混合均匀的苯乙烯、甲基丙烯酸甲酯、丙烯酸、AIBN匀速滴入混合溶液,在80℃恒温下在2h内滴加完毕,继续反应4h,停止加热,即得。
5.根据权利要求1所述的抗菌型丙烯酸防腐磁漆,其特征在于,其制备方法是:将丙烯酸树脂加入反应釜中,再依次加入聚乙二醇、填料、成膜剂、流平剂、分散剂、增稠剂、润湿剂、颜料、纳米级二氧化钛粉末、去离子水,升温至温度为50~70℃,在转速为300~400RPM转速下充分搅拌2~3h;待步骤均匀混合物料冷却至室温后,过200~300目筛网。
CN201711296628.0A 2017-12-08 2017-12-08 一种抗菌型丙烯酸防腐磁漆 Withdrawn CN107880699A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711296628.0A CN107880699A (zh) 2017-12-08 2017-12-08 一种抗菌型丙烯酸防腐磁漆

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711296628.0A CN107880699A (zh) 2017-12-08 2017-12-08 一种抗菌型丙烯酸防腐磁漆

Publications (1)

Publication Number Publication Date
CN107880699A true CN107880699A (zh) 2018-04-06

Family

ID=61773273

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711296628.0A Withdrawn CN107880699A (zh) 2017-12-08 2017-12-08 一种抗菌型丙烯酸防腐磁漆

Country Status (1)

Country Link
CN (1) CN107880699A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111172742A (zh) * 2020-02-28 2020-05-19 山东锦程地毯有限公司 一种吸水防臭型地毯及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486861A (zh) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 一种环保抗菌型水性涂料及其制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486861A (zh) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 一种环保抗菌型水性涂料及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王锡娇: "《涂料与颜料标准应用手册(上册)》", 30 April 2005, 军事谊文出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111172742A (zh) * 2020-02-28 2020-05-19 山东锦程地毯有限公司 一种吸水防臭型地毯及其制备方法

Similar Documents

Publication Publication Date Title
CN105062335B (zh) 一种功能性环保涂料的制备方法
CN105273557A (zh) 一种水性木器漆及其制备方法
CN104312225B (zh) 一种高柔韧性、高光泽度无机涂料及制备方法
CN105368164A (zh) 植物生态内墙涂料及其制备方法
CN103113801A (zh) 一种多功能环保内墙漆
CN110093078B (zh) 混凝土外墙涂料
CN104497824A (zh) 聚脲地坪涂料及其制备、使用方法和聚脲树脂
CN103131318A (zh) 一种建筑板材用uv漆
CN107880698A (zh) 一种丙烯酸环保磁漆
CN105273581A (zh) 一种高红外快速固化卷钢用粉末涂料及其制备方法
CN107880699A (zh) 一种抗菌型丙烯酸防腐磁漆
CN101215442A (zh) 耐候型粉末涂料组合物
CN103468110B (zh) 一种防水涂料
CN104710917A (zh) 一种新型水性醇酸树脂涂料及其制备方法
CN107936729A (zh) 一种环保改性氟硅丙烯酸磁漆
CN107868528A (zh) 一种改性丙烯酸磁漆
CN109251644A (zh) 一种聚脲地坪涂料及其制备、使用方法和聚脲树脂
CN107964359A (zh) 一种涂料
CN107858053A (zh) 一种丙烯酸防腐磁漆
CN107057425A (zh) 一种建筑用防水防腐涂料及制备方法
CN105062336A (zh) 一种醇酸涂料的制备方法
CN101864235A (zh) 一种外墙涂料的制备方法
CN103497601A (zh) 一种新型的压缩涂料及其制备方法
CN112210258A (zh) 一种水性氟碳保温涂料
CN107163697A (zh) 一种建筑用防水防腐涂料及制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180406

WW01 Invention patent application withdrawn after publication