CN107868590A - A kind of phthalic resin coating preparation method of surfacing - Google Patents
A kind of phthalic resin coating preparation method of surfacing Download PDFInfo
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- CN107868590A CN107868590A CN201711039761.8A CN201711039761A CN107868590A CN 107868590 A CN107868590 A CN 107868590A CN 201711039761 A CN201711039761 A CN 201711039761A CN 107868590 A CN107868590 A CN 107868590A
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- resin
- surfacing
- powder
- phthalic
- resin coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of phthalic resin coating preparation method of surfacing, comprise the following steps：Polyvinyl alcohol, bamboo charcoal powder are stirred, add silane coupler grinding, agarose is added and is ultrasonically treated to obtain first material；Aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, first material, water are mixed, ultrasonic disperse obtains second material；Phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, ethylene glycol, waterborne polyurethane resin, polyamide polyamine epichlorhydrin resin, OPE are stirred, add second material, polypropylene glycerol aether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, preservative continue stirring obtain the phthalic resin coating of surfacing.The inventive method is simple, and gained coating is good to substrate adhesion and film compactness, is less prone to obscission, and wet-heat resisting, temperature variation resistant are functional.
Description
Technical field
The present invention relates to the phthalic resin coating preparation method of technical field of coatings, more particularly to a kind of surfacing.
Background technology
In modern house fitment process, inevitably touch substantial amounts of coating, especially manufacturer in order that
Furniture is attractive in appearance, and substantial amounts of coating can be coated with furniture surface.With the gradual lifting of living standard, the environmental consciousness of people and
Health perception is more and more stronger, and more requirements are proposed to coating used in furniture surface, except stay in grade, attractive coat with
Outside, volatilizing, be green etc. also just like free from extraneous odour, without poisonous and harmful substance requires.
Organic volatile is largely used in antique traditional furniture coating, to environment and user to causing great wound
Evil.The coating of development environment friendly, reduce influences of the coating VOC to environment and user has turned into major coating material production, has answered
With the important topic of enterprise and scientific research institutions.It is the water paint of film forming matter because with excellent weatherability, resistance to using alkyd resin
Oiliness and higher hardness turn into most often applied aqueous coating system, but aqueous alkide resin has lacking for bad dispersibility
Point, smear surface and male and fomale(M＆F) be present, surface is unsightly, it would be highly desirable to solves.
The content of the invention
Based on technical problem existing for background technology, prepared by the phthalic resin coating that the present invention proposes a kind of surfacing
Method, method is simple, is easy to practical operation, and gained coating is good to substrate adhesion and film compactness, is less prone to and comes off now
As, and wet-heat resisting, temperature variation resistant are functional, even if under the adverse circumstances of pole, will not also produce spot, nigrescence, obscission.
A kind of phthalic resin coating preparation method of surfacing proposed by the present invention, comprises the following steps：
S1, polyvinyl alcohol, bamboo charcoal powder stirred, add silane coupler grinding, added agarose and be ultrasonically treated to obtain the
One material；
S2, aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, first material, water mixed
Close, ultrasonic disperse obtains second material；
S3, by phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, ethylene glycol, water
Property polyurethane resin, polyamide polyamine epichlorhydrin resin, OPE stir, add second material, poly-
Oxypropylene glycerin ether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, preservative continue stirring and obtain the alkyd tree of surfacing
Grease coating material.
Preferably, in S1, polyvinyl alcohol, bamboo charcoal powder, silane coupler, the weight ratio of agarose are 50-60：8-16：2-
4：6-12.
Preferably, in S1, polyvinyl alcohol, bamboo charcoal powder are stirred into 40-80min, whipping temp is 80-90 DEG C, adds silane
Coupling agent grinds 20-40min, grinding pressure 4-6kPa, adds agarose and is ultrasonically treated 40-60min, ultrasonic power 400-
550W, obtain first material.
Preferably, in S2, aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, the first thing
Material, the weight ratio of water are 12-16：8-12：4-8：6-12：8-16：4-8：60-120.
Preferably, in S2, by aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, the first thing
Material, water mixing, ultrasonic disperse 30-50min, ultrasonic power 700-850W, obtain second material.
Preferably, in S3, phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, second
Glycol, waterborne polyurethane resin, polyamide polyamine epichlorhydrin resin, OPE, second material, polyoxypropylene are sweet
Oily ether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, the weight ratio of preservative are 60-80：20-26：10-20：6-10：4-8：
4-10：6-12：20-30：2-4：2-4：1.5-2.5：3-5：3-5.
Preferably, in S3, by phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate,
Ethylene glycol, waterborne polyurethane resin, polyamide polyamine epichlorhydrin resin, OPE stir, whipping temp
For 85-95 DEG C, add second material, polypropylene glycerol aether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, preservative after
Continuous stirring 30-50min, mixing speed 1600-1900r/min, whipping temp is 45-55 DEG C, obtains the alkyd of surfacing
Cold coating.
In S1 of the present invention, compounded using polyvinyl alcohol, bamboo charcoal powder, bond strength is high in the presence of silane coupler, heat
Stablize, and absorption property is excellent, and further first material is obtained in Surface coating agarose after grinding, and it is micro- to form agarose
Ball, not only particle diameter is small, and dispersive property is excellent；Hydroxyl crosslinking in the epoxy radicals and alkyd resin of phenol-modified alkyd resin
Afterwards, it is more easy to disperse with acrylic acid modified alkyd resin, makes the present invention good to substrate adhesion and film compactness, further coordinate
Second material acts on, and can effectively promote dispersed between phenol-modified alkyd resin, acrylic acid modified alkyd resin and second material
It is good, after cured, network-like macromolecular is formed, film compactness, adhesion performance further enhance, and film, which is less prone to, to come off
Phenomenon；And second material and diethylene glycol dimethyl ether acetate, ethylene glycol, waterborne polyurethane resin, polyamide polyamine epoxy chloropropionate
After alkane resin, OPE compounding, make coating wet-heat resisting, temperature variation resistant obtained by the present invention, even if under the adverse circumstances of pole, also not
Spot, nigrescence, obscission can be produced, and preparation method is simple, is easy to practical operation.
Gained paint film of the invention soaks 100h in room temperature water, and paint film does not occur the phenomenon turned white, bubble, come off；Through second
Alcohol/acetone wipes 400 times, and paint film does not occur turning white, faded, loss of gloss phenomenon；By coating application obtained by the present invention in furniture surface,
Film surface is smooth, without obvious coarse grain, lubricates good leveling property, has good bonding force, bright-coloured with outward appearance, glossiness becomes clear, nothing
Peculiar smell, and it is skin friendly, and the feature of environmental protection is strong；Through spontaneously drying, drying time is short, no more than 8h, and meanwhile it is easily stored, under high temperature
It is unlikely to deteriorate, effective storage period is more than 180 days.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of phthalic resin coating preparation method of surfacing, comprises the following steps：
S1,50kg polyvinyl alcohol, 16kg bamboo charcoal powders are stirred to 40min, whipping temp is 90 DEG C, and it is silane coupled to add 2kg
40min, grinding pressure 4kPa are ground in agent, are added 12kg agaroses and are ultrasonically treated 40min, ultrasonic power 550W, obtain the
One material；
S2, by 12kg aerosils, 12kg wollastonites in powder, 4kg vermiculite powers, 12kg nanomete talc powders, 8kg acetic acid second
Ester, 8kg first materials, the mixing of 60kg water, ultrasonic disperse 50min, ultrasonic power 700W, obtain second material；
S3, by 80kg phenol-modified alkyd resins, 20kg acrylic acid modified alkyd resins, 20kg diethylene glycol dimethyl ether acetic acid
Ester, 6kg ethylene glycol, 8kg waterborne polyurethane resins, 4kg polyamide polyamine epichlorhydrins resin, 12kg OPEs stir
Mix uniformly, whipping temp is 85 DEG C, adds 30kg second materials, 2kg polypropylene glycerol aethers, 4kg hydroxy silicon oils, 1.5kg
Sldium lauryl sulfate, 5kg wetting agents, 3kg preservatives continue to stir 50min, mixing speed 1600r/min, and whipping temp is
55 DEG C, obtain the phthalic resin coating of surfacing.
Embodiment 2
A kind of phthalic resin coating preparation method of surfacing, comprises the following steps：
S1,60kg polyvinyl alcohol, 8kg bamboo charcoal powders are stirred to 80min, whipping temp is 80 DEG C, adds 4kg silane couplers
20min, grinding pressure 6kPa are ground, 6kg agaroses is added and is ultrasonically treated 60min, ultrasonic power 400W, obtain the first thing
Material；
S2, by 16kg aerosils, 8kg wollastonites in powder, 8kg vermiculite powers, 6kg nanomete talc powders, 16kg acetic acid second
Ester, 4kg first materials, the mixing of 120kg water, ultrasonic disperse 30min, ultrasonic power 850W, obtain second material；
S3, by 60kg phenol-modified alkyd resins, 26kg acrylic acid modified alkyd resins, 10kg diethylene glycol dimethyl ether acetic acid
Ester, 10kg ethylene glycol, 4kg waterborne polyurethane resins, 10kg polyamide polyamine epichlorhydrins resin, 6kg OPEs
Stir, whipping temp be 95 DEG C, add 20kg second materials, 4kg polypropylene glycerol aethers, 2kg hydroxy silicon oils,
2.5kg sldium lauryl sulfates, 3kg wetting agents, 5kg preservatives continue to stir 30min, mixing speed 1900r/min, stirring temperature
Spend for 45 DEG C, obtain the phthalic resin coating of surfacing.
Embodiment 3
A kind of phthalic resin coating preparation method of surfacing, comprises the following steps：
S1,58kg polyvinyl alcohol, 10kg bamboo charcoal powders are stirred to 70min, whipping temp is 82 DEG C, and it is even to add 3.5kg silane
Join agent grinding 25min, grinding pressure 5.5kPa, add 8kg agaroses and be ultrasonically treated 55min, ultrasonic power 450W, obtain
First material；
S2, by 15kg aerosils, 9kg wollastonites in powder, 7kg vermiculite powers, 8kg nanomete talc powders, 14kg acetic acid second
Ester, 5kg first materials, the mixing of 100kg water, ultrasonic disperse 35min, ultrasonic power 800W, obtain second material；
S3, by 65kg phenol-modified alkyd resins, 24kg acrylic acid modified alkyd resins, 12kg diethylene glycol dimethyl ether acetic acid
Ester, 9kg ethylene glycol, 5kg waterborne polyurethane resins, 8kg polyamide polyamine epichlorhydrins resin, 8kg OPEs stir
Mix uniformly, whipping temp be 92 DEG C, add 22kg second materials, 3.5kg polypropylene glycerol aethers, 2.5kg hydroxy silicon oils,
2.2kg sldium lauryl sulfates, 3.5kg wetting agents, 4.5kg preservatives continue to stir 35min, mixing speed 1800r/min, stir
Temperature is mixed as 48 DEG C, obtains the phthalic resin coating of surfacing.
Embodiment 4
A kind of phthalic resin coating preparation method of surfacing, comprises the following steps：
S1,52kg polyvinyl alcohol, 14kg bamboo charcoal powders are stirred to 50min, whipping temp is 88 DEG C, and it is even to add 2.5kg silane
Join agent grinding 35min, grinding pressure 4.5kPa, add 10kg agaroses and be ultrasonically treated 45min, ultrasonic power 500W, obtain
To first material；
S2, by 13kg aerosils, 11kg wollastonites in powder, 5kg vermiculite powers, 10kg nanomete talc powders, 10kg acetic acid
Ethyl ester, 7kg first materials, the mixing of 80kg water, ultrasonic disperse 45min, ultrasonic power 750W, obtain second material；
S3, by 75kg phenol-modified alkyd resins, 22kg acrylic acid modified alkyd resins, 18kg diethylene glycol dimethyl ether acetic acid
Ester, 7kg ethylene glycol, 7kg waterborne polyurethane resins, 6kg polyamide polyamine epichlorhydrins resin, 10kg OPEs stir
Mix uniformly, whipping temp be 88 DEG C, add 28kg second materials, 2.5kg polypropylene glycerol aethers, 3.5kg hydroxy silicon oils,
1.8kg sldium lauryl sulfates, 4.5kg wetting agents, 3.5kg preservatives continue to stir 45min, mixing speed 1700r/min, stir
Temperature is mixed as 52 DEG C, obtains the phthalic resin coating of surfacing.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. the phthalic resin coating preparation method of a kind of surfacing, it is characterised in that comprise the following steps：
S1, by polyvinyl alcohol, bamboo charcoal powder stir, add silane coupler grinding, add agarose be ultrasonically treated to obtain the first thing
Material；
S2, by aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, first material, water mix, surpass
Sound is scattered to obtain second material；
S3, by phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, ethylene glycol, water-based poly-
Urethane resin, polyamide polyamine epichlorhydrin resin, OPE stir, and add second material, polyoxy third
Alkene glycerin ether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, preservative continue stirring and obtain the alkyd resin painting of surfacing
Material.
2. the phthalic resin coating preparation method of surfacing according to claim 1, it is characterised in that in S1, polyethylene
Alcohol, bamboo charcoal powder, silane coupler, the weight ratio of agarose are 50-60：8-16：2-4：6-12.
3. the phthalic resin coating preparation method of surfacing according to claim 1 or claim 2, it is characterised in that, will be poly- in S1
Vinyl alcohol, bamboo charcoal powder stirring 40-80min, whipping temp is 80-90 DEG C, adds silane coupler grinding 20-40min, grinding pressure
Power is 4-6kPa, adds agarose and is ultrasonically treated 40-60min, ultrasonic power 400-550W, obtains first material.
4. according to the phthalic resin coating preparation method of any one of the claim 1-3 surfacings, it is characterised in that S2
In, aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, first material, the weight of water ratio are 12-
16：8-12：4-8：6-12：8-16：4-8：60-120.
5. according to the phthalic resin coating preparation method of any one of the claim 1-4 surfacings, it is characterised in that S2
In, aerosil, wollastonite in powder, vermiculite power, nanomete talc powder, ethyl acetate, first material, water are mixed, ultrasound point
30-50min is dissipated, ultrasonic power 700-850W, obtains second material.
6. according to the phthalic resin coating preparation method of any one of the claim 1-5 surfacings, it is characterised in that S3
In, phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, ethylene glycol, aqueous polyurethane tree
Fat, polyamide polyamine epichlorhydrin resin, OPE, second material, polypropylene glycerol aether, hydroxy silicon oil, the moon
Lauryl sulfate, wetting agent, the weight ratio of preservative are 60-80：20-26：10-20：6-10：4-8：4-10：6-12：20-30：
2-4：2-4：1.5-2.5：3-5：3-5.
7. according to the phthalic resin coating preparation method of any one of the claim 1-6 surfacings, it is characterised in that S3
In, by phenol-modified alkyd resin, acrylic acid modified alkyd resin, diethylene glycol dimethyl ether acetate, ethylene glycol, aqueous polyurethane
Resin, polyamide polyamine epichlorhydrin resin, OPE stir, and whipping temp is 85-95 DEG C, add the
Two materials, polypropylene glycerol aether, hydroxy silicon oil, sldium lauryl sulfate, wetting agent, preservative continue to stir 30-50min, stir
It is 1600-1900r/min to mix speed, and whipping temp is 45-55 DEG C, obtains the phthalic resin coating of surfacing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711039761.8A CN107868590A (en) | 2017-10-30 | 2017-10-30 | A kind of phthalic resin coating preparation method of surfacing |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711039761.8A CN107868590A (en) | 2017-10-30 | 2017-10-30 | A kind of phthalic resin coating preparation method of surfacing |
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| CN107868590A true CN107868590A (en) | 2018-04-03 |
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| CN201711039761.8A Pending CN107868590A (en) | 2017-10-30 | 2017-10-30 | A kind of phthalic resin coating preparation method of surfacing |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109608662A (en) * | 2018-10-31 | 2019-04-12 | 安徽开林新材料股份有限公司 | A kind of alkyd paint for wood furniture polyethylene wax microballoon and its preparation |
| CN109810626A (en) * | 2018-12-29 | 2019-05-28 | 安徽鑫铂铝业股份有限公司 | A kind of high intensity corrosion resistant SUV offroad vehicle luggage carrier aluminum profile |
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| CN105038543A (en) * | 2015-08-05 | 2015-11-11 | 天长市开林化工有限公司 | Alkyd resin coating for industrial outer wall and preparation method thereof |
| CN105273590A (en) * | 2015-10-16 | 2016-01-27 | 广西巨邦科技有限公司 | Environment-friendly coating for indoor decoration |
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2017
- 2017-10-30 CN CN201711039761.8A patent/CN107868590A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038543A (en) * | 2015-08-05 | 2015-11-11 | 天长市开林化工有限公司 | Alkyd resin coating for industrial outer wall and preparation method thereof |
| CN105273590A (en) * | 2015-10-16 | 2016-01-27 | 广西巨邦科技有限公司 | Environment-friendly coating for indoor decoration |
Non-Patent Citations (1)
| Title |
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| 姚时俊: "《汽车美容与装饰》", 30 September 2001, 辽宁科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109608662A (en) * | 2018-10-31 | 2019-04-12 | 安徽开林新材料股份有限公司 | A kind of alkyd paint for wood furniture polyethylene wax microballoon and its preparation |
| CN109810626A (en) * | 2018-12-29 | 2019-05-28 | 安徽鑫铂铝业股份有限公司 | A kind of high intensity corrosion resistant SUV offroad vehicle luggage carrier aluminum profile |
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Application publication date: 20180403 |