CN105273590A - Environment-friendly coating for indoor decoration - Google Patents
Environment-friendly coating for indoor decoration Download PDFInfo
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- CN105273590A CN105273590A CN201510669557.9A CN201510669557A CN105273590A CN 105273590 A CN105273590 A CN 105273590A CN 201510669557 A CN201510669557 A CN 201510669557A CN 105273590 A CN105273590 A CN 105273590A
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Abstract
The invention discloses environment-friendly coating for indoor decoration. The environment-friendly coating comprises substances in parts by mass as follows: 40-50 parts of film forming matrixes, 7-12 parts of ash calcium powder, 7-12 parts of mica powder, 10-15 parts of talc powder, 8-12 parts of calcium carbonate powder, 3-5 parts of sodium carboxymethyl cellulose, 4-8 parts of a wetting agent, 3-5 parts of a defoaming agent, 4-6 parts of a polyacrylamide solution, 7-12 parts of a thickening agent, 10-15 parts of a negative ion powder, 3-5 parts of color paste, 4-6 parts of tungsten trioxide and 55-75 parts of water. According to the coating, the volatilization of formaldehyde can be reduced, formaldehyde can be almost completely volatilized in 10-15 days under the ventilated condition, the content of formaldehyde indoors after complete volatilization is lower than 0.09 milligrams each square meter and meets the national standard, besides, the surface of the coating is smooth after the coating is dried, and the color of the coating is good and more brighter.
Description
Technical field
The present invention relates to a kind of environmental protection coating material of interior decoration.
Background technology
Containing objectionable impuritiess such as formaldehyde in the finishing paint of many indoor, formaldehyde is wherein carcinogenic and causes deformed material.Formaldehyde is generally acknowledged allergen, and being also one of potential strong mutagen, is also cause one of leukemic Hazard Factor of child.According to domestic medical journal and pertinent literature report, indoor formaldehyde can be summarized as hormesis, toxic action and carcinogenesis to the harm of HUMAN HEALTH.
All can contain formaldehyde in the coating such as the woodenware in family room, plank, furniture, wall, but more frighteningly, the release period of formaldehyde is generally three to ten five years, causes formaldehyde to be slowly released contaminate environment in air.Therefore, how to improve the effect of the anti-formaldehyde of indoor paint, and improve that it is long-lasting, be coating industry common concern, need one of problem of solving.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental protection coating material of interior decoration, this coating can reduce the volatile quantity of formaldehyde, when keeping ventilating, formaldehyde content volatilized completely in 10-15 days, after volatilization completely, indoor formaldehyde content is lower than 0.09 milligram every square metre, meets national standard, and dried lacquer painting is comparatively smooth simultaneously, glossiness is better, and color and luster is comparatively beautiful.
For solving the problem, the present invention adopts following technical scheme:
An environmental protection coating material for interior decoration, comprises the material composition of following mass fraction:
Film forming binder 40-50 part
Sierozem power 7-12 part
Mica powder 7-12 part
Talcum powder 10-15 part
Paris white 8-12 part
Carboxymethylcellulose sodium solution 3-5 part
Wetting agent 4-8 part
Defoamer 3-5 part
Polyacrylamide solution 4-6 part
Thickening material 7-12 part
Negative ion powder 10-15 part
Mill base 3-5 part
Tungstic oxide 4-6 part
Water 55-75 part.
Preferably, described film forming binder is one or more the mixture in aqueous alkide resin, waterborne polyurethane resin, waterborne styrene-acrylic emulsion.
Water-borne acrylic resin comprises Emulsion acrylic resin, aqueous acrylic resin dispersion (also known as water-dilutable vinylformic acid) and acrylic resin aqueous solution.Emulsion to be mainly emulsified in water under water-based free radical initiator causes synthesis by oiliness vinyl monomer, and resin water dispersion is then by free radical solution polymerization or technique synthesis that progressively solution polymerization etc. is different.
The vegetables oil of water-based oil alkyd resin can be selected Oleum Cocois, slight sesame oil etc., also can obtain by lauric acid and some saturated fatty acids and middle low-carbon (LC) synthetic fatty acid.Short oil-ity alcohol acid resin oil content is 30% ~ 40%, makes through above-mentioned oil or lipid acid, using fragrance through class as solvent.Water-based medium oil alkyd mainly adopts Viscotrol C to synthesize, and polarity is large, with aromatic hydrocarbon as solvent.Water-based oil alkyd resin is often applied to celluloid lacquer, amino resin coatings etc.
Waterborne polyurethane resin is a kind of superfine aliphatic polyurethane dispersion liquid.Be mainly used in promoting the adherence of covering with paint, lacquer, colour wash, etc., there is ultra-fine causing and the film extended, excellent winter hardiness, but excessively can not fill grain.Be designed for base material following layer especially.
Preferably, the material composition of following mass fraction is comprised: film forming binder 40-50 part, sierozem power 7-12 part, mica powder 7-12 part, talcum powder 10-15 part, Paris white 8-12 part, carboxymethylcellulose sodium solution 3-5 part, wetting agent 4-8 part, defoamer 3-5 part, polyacrylamide solution 4-6 part, thickening material 7-12 part, negative ion powder 10-15 part, mill base 3-5 part, water 55-75 part.
Preferably, the particle diameter of described sierozem power is 200-235 micron.
Sierozem power: because sierozem power can give coating excellent properties at a lower cost, thus in recent years people according to the new demand of national standard, sierozem power is applied in synthetic resin emulsion coating, enable coating meet the requirement of GB/T9756-2001 and GB18582-2001 at a lower cost, and the feels of the condition in container of coating, levelling property and film etc. are all good.Thus, under new requirement, sierozem power still has using value.But what sierozem power class application of paints film when old coating film turned yellow is still within the bounds of possibility, so also should not exaggerate the effect of sierozem power, and low and middle-grade interior wall coating can only be used for.
Preferably, the particle diameter of described mica powder is 70-80 micron.
Mica powder: a kind of non-metallic minerals, containing Multiple components, wherein mainly contains SiO2, content generally at about 49%, Al2O3 content about 30%.Mica powder has good elasticity, toughness.The characteristic such as insulativity, high temperature resistant, acid and alkali-resistance, corrosion-resistant, strong adhesion is a kind of excellent additive.It is widely used in the industries such as electrical equipment, welding electrode, rubber, plastics, papermaking, paint, coating, pigment, pottery, makeup, building material, and purposes is extremely extensive.Along with the development of science and technology, people open up the Application Areas made new advances.
Preferably, described talcous particle diameter is 150-165 micron.
Talcum powder: talcum matter is soft, its Mohs' hardness coefficient is 1 ~ 1.5, and have sliding sense, { 001} cleavage is extremely complete, very easily split into thin slice, natural repose angle little (35 ° ~ 40 °), built on the sand, country rock is the magnesite of silication and talcum, magnesite rock, lean ore or dolomitic marble in pole, except minority moderately stable, generally all built on the sand, joint, cranny development, the impact of physico-mechanical properties on production practice of ore and country rock is very large.
Preferably, the particle diameter of described Paris white is 90-115 micron.
Paris white: 1. proterties: fine white crystalline powder, odorless, tasteless, can absorb foul smell.2. relative density (g/cm3, 25/4 DEG C): 2.6-2.7(2.710-2.930, water-ground limestone) 3. relative steam density (g/cm3, air=1): 2.5 ~ 2.74. fusing point (oC): 1339 DEG C of 825-896.6(decompose, light calcium carbonate) 5. boiling point (oC, normal pressure): do not determine 6. boiling point (oC, 5.2kPa): do not determine 7. specific refractory poweres: 1.498. flash-point (oF): 1389. specific rotatory powers (o): do not determine 10. spontaneous ignition temperatures or ignition temperature (oC): do not determine 11. vapour pressure (kPa, 25oC): do not determine 12. saturation vapour pressure (kPa, 60oC): do not determine 13. combustions heat (KJ/mol): do not determine 14. critical temperatures (oC): do not determine 15. emergent pressures (KPa): the logarithmic value not determining 16. profits (octanol/water) partition ratio: do not determine 17. upper explosive limit (%, V/V): do not determine 18. Lower Explosive Limit (%, V/V): do not determine 19. solvabilities: dissolve in acetic acid, the diluted acids such as hydrochloric acid, be insoluble in dilute sulphuric acid, water-soluble and ethanol hardly.20. specific heat capacities (J/(kg DEG C)): 0.836 ~ 0.8951(0 ~ 100 DEG C) 21. thermal linear expansion coefficients (DEG C): 11.7 × 10-6(15 ~ 100 DEG C).
Preferably, described wetting agent is one or more the mixture in ethanol, propylene glycol, dimethyl sulfoxide (DMSO).
Preferably, described defoamer is that the mixture of oxyethane and propylene oxide carries out addition polymerization and makes.
Preferably, described thickening material is Polyacrylate thickeners.
The invention has the beneficial effects as follows: this coating can reduce the volatile quantity of formaldehyde, when keeping ventilating, formaldehyde content volatilized completely in 10-15 days, after volatilization completely, indoor formaldehyde content is lower than 0.09 milligram every square metre, meet national standard, dried lacquer painting is comparatively smooth simultaneously, and glossiness is better, and color and luster is comparatively beautiful.
Embodiment
Below the preferred embodiments of the present invention are described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
An environmental protection coating material for interior decoration, comprises the material composition of following mass fraction:
Film forming binder 40-50 part
Sierozem power 7-12 part
Mica powder 7-12 part
Talcum powder 10-15 part
Paris white 8-12 part
Carboxymethylcellulose sodium solution 3-5 part
Wetting agent 4-8 part
Defoamer 3-5 part
Polyacrylamide solution 4-6 part
Thickening material 7-12 part
Negative ion powder 10-15 part
Mill base 3-5 part
Tungstic oxide 4-6 part
Water 55-75 part.
Preferably, described film forming binder is one or more the mixture in aqueous alkide resin, waterborne polyurethane resin, waterborne styrene-acrylic emulsion.
Water-borne acrylic resin comprises Emulsion acrylic resin, aqueous acrylic resin dispersion (also known as water-dilutable vinylformic acid) and acrylic resin aqueous solution.Emulsion to be mainly emulsified in water under water-based free radical initiator causes synthesis by oiliness vinyl monomer, and resin water dispersion is then by free radical solution polymerization or technique synthesis that progressively solution polymerization etc. is different.
The vegetables oil of water-based oil alkyd resin can be selected Oleum Cocois, slight sesame oil etc., also can obtain by lauric acid and some saturated fatty acids and middle low-carbon (LC) synthetic fatty acid.Short oil-ity alcohol acid resin oil content is 30% ~ 40%, makes through above-mentioned oil or lipid acid, using fragrance through class as solvent.Water-based medium oil alkyd mainly adopts Viscotrol C to synthesize, and polarity is large, with aromatic hydrocarbon as solvent.Water-based oil alkyd resin is often applied to celluloid lacquer, amino resin coatings etc.
Waterborne polyurethane resin is a kind of superfine aliphatic polyurethane dispersion liquid.Be mainly used in promoting the adherence of covering with paint, lacquer, colour wash, etc., there is ultra-fine causing and the film extended, excellent winter hardiness, but excessively can not fill grain.Be designed for base material following layer especially.
Preferably, the material composition of following mass fraction is comprised: film forming binder 40-50 part, sierozem power 7-12 part, mica powder 7-12 part, talcum powder 10-15 part, Paris white 8-12 part, carboxymethylcellulose sodium solution 3-5 part, wetting agent 4-8 part, defoamer 3-5 part, polyacrylamide solution 4-6 part, thickening material 7-12 part, negative ion powder 10-15 part, mill base 3-5 part, water 55-75 part.
Preferably, the particle diameter of described sierozem power is 200-235 micron.
Sierozem power: because sierozem power can give coating excellent properties at a lower cost, thus in recent years people according to the new demand of national standard, sierozem power is applied in synthetic resin emulsion coating, enable coating meet the requirement of GB/T9756-2001 and GB18582-2001 at a lower cost, and the feels of the condition in container of coating, levelling property and film etc. are all good.Thus, under new requirement, sierozem power still has using value.But what sierozem power class application of paints film when old coating film turned yellow is still within the bounds of possibility, so also should not exaggerate the effect of sierozem power, and low and middle-grade interior wall coating can only be used for.
Preferably, the particle diameter of described mica powder is 70-80 micron.
Mica powder: a kind of non-metallic minerals, containing Multiple components, wherein mainly contains SiO2, content generally at about 49%, Al2O3 content about 30%.Mica powder has good elasticity, toughness.The characteristic such as insulativity, high temperature resistant, acid and alkali-resistance, corrosion-resistant, strong adhesion is a kind of excellent additive.It is widely used in the industries such as electrical equipment, welding electrode, rubber, plastics, papermaking, paint, coating, pigment, pottery, makeup, building material, and purposes is extremely extensive.Along with the development of science and technology, people open up the Application Areas made new advances.
Preferably, described talcous particle diameter is 150-165 micron.
Talcum powder: talcum matter is soft, its Mohs' hardness coefficient is 1 ~ 1.5, and have sliding sense, { 001} cleavage is extremely complete, very easily split into thin slice, natural repose angle little (35 ° ~ 40 °), built on the sand, country rock is the magnesite of silication and talcum, magnesite rock, lean ore or dolomitic marble in pole, except minority moderately stable, generally all built on the sand, joint, cranny development, the impact of physico-mechanical properties on production practice of ore and country rock is very large.
Preferably, the particle diameter of described Paris white is 90-115 micron.
Paris white: 1. proterties: fine white crystalline powder, odorless, tasteless, can absorb foul smell.2. relative density (g/cm3, 25/4 DEG C): 2.6-2.7(2.710-2.930, water-ground limestone) 3. relative steam density (g/cm3, air=1): 2.5 ~ 2.74. fusing point (oC): 1339 DEG C of 825-896.6(decompose, light calcium carbonate) 5. boiling point (oC, normal pressure): do not determine 6. boiling point (oC, 5.2kPa): do not determine 7. specific refractory poweres: 1.498. flash-point (oF): 1389. specific rotatory powers (o): do not determine 10. spontaneous ignition temperatures or ignition temperature (oC): do not determine 11. vapour pressure (kPa, 25oC): do not determine 12. saturation vapour pressure (kPa, 60oC): do not determine 13. combustions heat (KJ/mol): do not determine 14. critical temperatures (oC): do not determine 15. emergent pressures (KPa): the logarithmic value not determining 16. profits (octanol/water) partition ratio: do not determine 17. upper explosive limit (%, V/V): do not determine 18. Lower Explosive Limit (%, V/V): do not determine 19. solvabilities: dissolve in acetic acid, the diluted acids such as hydrochloric acid, be insoluble in dilute sulphuric acid, water-soluble and ethanol hardly.20. specific heat capacities (J/(kg DEG C)): 0.836 ~ 0.8951(0 ~ 100 DEG C) 21. thermal linear expansion coefficients (DEG C): 11.7 × 10-6(15 ~ 100 DEG C).
Preferably, described wetting agent is one or more the mixture in ethanol, propylene glycol, dimethyl sulfoxide (DMSO).
Preferably, described defoamer is that the mixture of oxyethane and propylene oxide carries out addition polymerization and makes.
Preferably, described thickening material is Polyacrylate thickeners.
The invention has the beneficial effects as follows: this coating can reduce the volatile quantity of formaldehyde, when keeping ventilating, formaldehyde content volatilized completely in 10-15 days, after volatilization completely, indoor formaldehyde content is lower than 0.09 milligram every square metre, meet national standard, dried lacquer painting is comparatively smooth simultaneously, and glossiness is better, and color and luster is comparatively beautiful.
Embodiment 1
Comprise the material of following mass fraction: film forming binder 50 parts, sierozem power 7 parts, mica powder 7 parts, talcum powder 10 parts, Paris white 8 parts, carboxymethylcellulose sodium solution 3 parts, wetting agent 8 parts, defoamer 3-5 part, polyacrylamide solution 6 parts, thickening material 7 parts, negative ion powder 15 parts, mill base 5 parts, tungstic oxide 6 parts, 75 parts, water, by above each component by agitator, after uniform stirring 30min, namely obtain the environmental protection coating material of interior decoration of the present invention.
After tested, after paint brush Figure 10 days, indoor formaldehyde content is 0.08 milligram every cubic metre, meets national standard.
Embodiment 2
Comprise the material of following mass fraction: film forming binder 50 parts, sierozem power 12 parts, mica powder 12 parts, talcum powder 15 parts, Paris white 8 parts, carboxymethylcellulose sodium solution 5 parts, wetting agent 8 parts, defoamer 3 parts, polyacrylamide solution 6 parts, thickening material 12 parts, negative ion powder 15 parts, mill base 3 parts, tungstic oxide 4 parts, 75 parts, water, by above each component by agitator, after uniform stirring 45min, namely obtain the environmental protection coating material of interior decoration of the present invention.
After tested, after paint brush Figure 10 days, indoor formaldehyde content is 0.09 milligram every cubic metre, meets national standard.
Embodiment 3
Comprise the material of following mass fraction: film forming binder 40 parts, sierozem power 7 parts, mica powder 7 parts, talcum powder 10 parts, Paris white 8 parts, carboxymethylcellulose sodium solution 5 parts, wetting agent 4 parts, defoamer 3 parts, polyacrylamide solution 6 parts, thickening material 7 parts, negative ion powder 10 parts, mill base 5 parts, tungstic oxide 4 parts, 55 parts, water, by above each component by agitator, after uniform stirring 45min, namely obtain the environmental protection coating material of interior decoration of the present invention.
After tested, after paint brush Figure 10 days, indoor formaldehyde content is 0.07 milligram every cubic metre, meets national standard.
Embodiment 4
Comprise the material of following mass fraction: film forming binder 50 parts, sierozem power 12 parts, mica powder 10 parts, talcum powder 15 parts, Paris white 10 parts, carboxymethylcellulose sodium solution 4 parts, wetting agent 6 parts, defoamer 3 parts, polyacrylamide solution 4 parts, thickening material 12 parts, negative ion powder 12 parts, mill base 4 parts, tungstic oxide 6 parts, 65 parts, water, by above each component by agitator, after uniform stirring 45min, namely obtain the environmental protection coating material of interior decoration of the present invention.
After tested, after paint brush Figure 10 days, indoor formaldehyde content is 0.08 milligram every cubic metre, meets national standard.
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (10)
1. an environmental protection coating material for interior decoration, is characterized in that: the material composition comprising following mass fraction:
Film forming binder 40-50 part
Sierozem power 7-12 part
Mica powder 7-12 part
Talcum powder 10-15 part
Paris white 8-12 part
Carboxymethylcellulose sodium solution 3-5 part
Wetting agent 4-8 part
Defoamer 3-5 part
Polyacrylamide solution 4-6 part
Thickening material 7-12 part
Negative ion powder 10-15 part
Mill base 3-5 part
Tungstic oxide 4-6 part
Water 55-75 part.
2. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: described film forming binder is one or more the mixture in aqueous alkide resin, waterborne polyurethane resin, waterborne styrene-acrylic emulsion.
3. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: the material composition comprising following mass fraction: film forming binder 40-50 part, sierozem power 7-12 part, mica powder 7-12 part, talcum powder 10-15 part, Paris white 8-12 part, carboxymethylcellulose sodium solution 3-5 part, wetting agent 4-8 part, defoamer 3-5 part, polyacrylamide solution 4-6 part, thickening material 7-12 part, negative ion powder 10-15 part, mill base 3-5 part, water 55-75 part.
4. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: the particle diameter of described sierozem power is 200-235 micron.
5. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: the particle diameter of described mica powder is 70-80 micron.
6. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: described talcous particle diameter is 150-165 micron.
7. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: the particle diameter of described Paris white is 90-115 micron.
8. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: described wetting agent is the one in ethanol, propylene glycol, dimethyl sulfoxide (DMSO).
9. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: described defoamer is that the mixture of oxyethane and propylene oxide carries out addition polymerization and makes.
10. the environmental protection coating material of interior decoration according to claim 1, is characterized in that: described thickening material is Polyacrylate thickeners.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510669557.9A CN105273590A (en) | 2015-10-16 | 2015-10-16 | Environment-friendly coating for indoor decoration |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510669557.9A CN105273590A (en) | 2015-10-16 | 2015-10-16 | Environment-friendly coating for indoor decoration |
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| CN105273590A true CN105273590A (en) | 2016-01-27 |
Family
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| CN201510669557.9A Pending CN105273590A (en) | 2015-10-16 | 2015-10-16 | Environment-friendly coating for indoor decoration |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106833314A (en) * | 2017-01-10 | 2017-06-13 | 河北晨阳工贸集团有限公司 | Water alcohol acid interior wall sealing wax and preparation method thereof |
| CN107868590A (en) * | 2017-10-30 | 2018-04-03 | 合肥林邦门业有限公司 | A kind of phthalic resin coating preparation method of surfacing |
| CN108384353A (en) * | 2018-03-27 | 2018-08-10 | 占军 | Environmental protection coating material for building |
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| CN102925018A (en) * | 2012-11-30 | 2013-02-13 | 刘凯 | Indoor decoration coating |
| CN103468074A (en) * | 2013-09-03 | 2013-12-25 | 吴江市冰心文教用品有限公司 | Photochromic paint |
| CN104263093A (en) * | 2014-08-28 | 2015-01-07 | 黄艳 | Energy-saving environment-friendly interior decoration paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| WO2009155115A2 (en) * | 2008-05-30 | 2009-12-23 | Reactive Surfaces, Ltd. | Coatings and surface treatments having active enzymes and peptides |
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| CN106833314A (en) * | 2017-01-10 | 2017-06-13 | 河北晨阳工贸集团有限公司 | Water alcohol acid interior wall sealing wax and preparation method thereof |
| CN106833314B (en) * | 2017-01-10 | 2020-05-22 | 河北晨阳工贸集团有限公司 | Water-based alkyd interior wall water paint and preparation method thereof |
| CN107868590A (en) * | 2017-10-30 | 2018-04-03 | 合肥林邦门业有限公司 | A kind of phthalic resin coating preparation method of surfacing |
| CN108384353A (en) * | 2018-03-27 | 2018-08-10 | 占军 | Environmental protection coating material for building |
| CN108384353B (en) * | 2018-03-27 | 2020-04-28 | 山西玉壁建筑装饰工程股份有限公司 | Environment-friendly coating for buildings |
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