CN107837787A - 一种活性炭脱硫剂及其制备方法 - Google Patents

一种活性炭脱硫剂及其制备方法 Download PDF

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CN107837787A
CN107837787A CN201711190387.1A CN201711190387A CN107837787A CN 107837787 A CN107837787 A CN 107837787A CN 201711190387 A CN201711190387 A CN 201711190387A CN 107837787 A CN107837787 A CN 107837787A
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王云荣
关剑轩
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Guilin Yanshan District Youth Activity Center
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Abstract

本发明涉及一种活性炭脱硫剂及其制备方法。所述活性炭脱硫剂,包括以下重量份组分:活性炭20‑40份,氧化锌20‑50份,硬脂酸钙5‑7份,沸石粉5‑15份,木质素磺酸钙5‑15份,碳酸氢钠15‑30份,陶瓷纤维棉为10‑35份。本发明将氧化锌、石灰石等添加到活性炭中,增强了脱硫效率和活性炭的强度,不易崩解,结实耐用;本发明添加陶瓷纤维棉,具有比表面积高的特点,有利于活性组分物质的附着和分散,增加活性组分与废气的接触几率;本发明采用特殊工艺将活性炭硅藻土混合体制成颗粒,添加粘性物质,使得活性炭不易崩解,结实耐用,本发明生产成本低,脱硫除尘效果好,适合工业干法脱硫,汽车尾气脱硫,日常空气净化等。

Description

一种活性炭脱硫剂及其制备方法
技术领域
本发明属于新能源及环保节能技术领域,尤其涉及一种活性炭脱硫剂及其制备方法。
背景技术
目前空气中的污染物主要是工业燃料燃烧产生的气体、汽车尾气、生产中产生的有毒有害气体。随着人们生活水平的提高,对空气的清新程度有了新的认知,对空气净化能力有了更高的要求。高比表面积活性炭具有多孔结构,能吸附各种有机物和无机物,具有吸附容量大、吸附速度快的特点,是一种优质的高效吸附剂,广泛用于食品工业、化学工业和环境保护等各个领域。在脱硫的众多方法中,有一种方法是活性炭吸附法,虽然活性炭能够吸附多种酸性气体,但是活性炭脱硫的效率较低。
发明内容
鉴于现有技术所存在的问题,本发明的目的在于提供一种脱硫效率更高的活性炭脱硫剂。
本发明解决上述技术问题的技术方案如下:一种活性炭脱硫剂,包括以下重量份组分:活性炭20-40份,5-15份,氧化锌20-50份,硬脂酸钙5-7份,沸石粉5-15份,活性碳5-15份,碳酸氢钠15-30份,陶瓷纤维棉为10-35份
在上述技术方案的基础上,本发明还可以做如下改进。
进一步地,所述活性炭脱硫剂包括以下重量份组分:20份活性炭,20份氧化锌,5份硬脂酸钙,5份沸石粉,5份活性碳,15份碳酸氢钠,10份陶瓷纤维棉。
进一步地,所述活性炭脱硫剂包括以下重量份组分:40份活性炭,50份氧化锌,7份硬脂酸钙,15份沸石粉,15份活性碳30份碳酸氢钠,35份陶瓷纤维棉。
进一步地,所述活性炭脱硫剂包括以下重量份组分:30份活性炭,30份氧化锌,6份硬脂酸钙,8份沸石粉,10份活性碳,20份碳酸氢钠,20份陶瓷纤维棉。
本发明还提供了一种活性炭脱硫剂的制备方法,包括以下步骤:按重量份配比称取以下组分:活性炭,氧化锌,,硬脂酸钙,沸石粉,活性碳,将上述组分在100-120℃下进行干燥处理,粉碎并混合均匀。
具体实施方式
以下对本发明的原理和特征进行描述,所举实例只用于解释本发明,并非用于限定本发明的范围。
本发明提供了一种活性炭脱硫剂,包括以下重量份组分:活性炭20-40份,氧化锌20-50份,硬脂酸钙5-7份,沸石粉5-15份,活性碳5-15份,碳酸氢钠15-30份,陶瓷纤维棉为10-35份。
本发明将氧化锌、石灰石等添加到活性炭中,增强了脱硫效率和活性炭的强度,不易崩解,结实耐用;本发明添加陶瓷纤维棉,具有比表面积高的特点,有利于活性组分物质的附着和分散,增加活性组分与废气的接触几率;本发明采用特殊工艺将活性炭硅藻土混合体制成颗粒,添加粘性物质,使得活性炭不易崩解,结实耐用,本发明生产成本低,脱硫除尘效果好,适合工业干法脱硫,汽车尾气脱硫,日常空气净化等。
下面通过具体的实施例来进行介绍。
实施例1
按重量份称取以下组分::活性炭20份,氧化锌20份,硬脂酸钙5份,沸石粉5份,木质素磺酸钙5份,碳酸氢钠15份,陶瓷纤维棉为10份,将上述组分混合并在100℃-120℃条件下干燥1-1.5小时,然后放入400℃-500℃的炭化炉中炭化2-3小时,取出后粉碎混合均匀
实施例2
按重量份称取以下组分:4活性炭40份,氧化锌50份,硬脂酸钙7份,沸石粉15份,木质素磺酸钙15份,碳酸氢钠30份,陶瓷纤维棉为35份,将上述组分混合并在100℃-120℃条件下干燥1-1.5小时,然后放入400℃-500℃的炭化炉中炭化2-3小时,取出后粉碎混合均匀。
实施例3
按重量份称取以下组分活性炭30份,氧化锌40份,硬脂酸钙6份,沸石粉8份,木质素磺酸钙9份,碳酸氢钠20份,陶瓷纤维棉为18份,将上述组分混合并在100℃-120℃条件下干燥1-1.5小时,然后放入400℃-500℃的炭化炉中炭化2-3小时,取出后粉碎混合均匀。
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要为准。

Claims (5)

1.一种活性炭脱硫剂,其特征在于,包括以下重量份组分:活性炭20-40份,氧化锌20-50份,硬脂酸钙5-7份,沸石粉5-15份,木质素磺酸钙5-15份,碳酸氢钠15-30份,陶瓷纤维棉为10-35份。
2.根据权利要求1所述一种活性炭脱硫剂,其特征在于,包括以下重量份组分:活性炭20份,氧化锌20份,硬脂酸钙5份,沸石粉5份,木质素磺酸钙5份,碳酸氢钠15份,陶瓷纤维棉为10份。
3.根据权利要求1所述一种活性炭脱硫剂,其特征在于,包括以下重量份组分:活性炭40份,氧化锌50份,硬脂酸钙7份,沸石粉15份,木质素磺酸钙15份,碳酸氢钠30份,陶瓷纤维棉为35份。
4.根据权利要求1所述一种活性炭脱硫剂,其特征在于,包括以下重量份组分:活性炭30份,氧化锌40份,硬脂酸钙6份,沸石粉8份,木质素磺酸钙9份,碳酸氢钠20份,陶瓷纤维棉为18份。
5.一种如权利要求1至4任一项所述活性炭脱硫剂的制备方法,其特征在于,包括以下步骤:按重量份配比称取以下组分:活性炭,氧化锌,硬脂酸钙,沸石粉,木质素磺酸钙,碳酸氢钠,陶瓷纤维棉为,将上述组分混合并在100℃-120℃条件下干燥1-1.5小时,然后放入400℃-500℃的炭化炉中炭化2-3小时,取出后粉碎混合均匀。
CN201711190387.1A 2017-11-24 2017-11-24 一种活性炭脱硫剂及其制备方法 Withdrawn CN107837787A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113996176A (zh) * 2021-11-15 2022-02-01 江西省杰夫环保科技有限公司 一种高效加热炉烟气脱硫剂及其制备方法和应用
CN116897802A (zh) * 2023-08-21 2023-10-20 江苏叁山环境科学技术研究有限公司 一种用陶瓷纤维棉和园林废弃物的发酵物育苗的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104437366A (zh) * 2014-11-13 2015-03-25 安徽凤凰滤清器股份有限公司 一种不易崩解的混合活性炭脱硫剂及其制备方法
CN104475015A (zh) * 2014-10-20 2015-04-01 安徽省宿州市龙华机械制造有限公司 一种添加陶瓷纤维棉的活性炭硅藻土脱硫剂及其制备方法
CN105597701A (zh) * 2016-03-17 2016-05-25 杭州富阳高博信息技术服务有限公司 一种用于处理锅炉烟气的吸附剂

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104475015A (zh) * 2014-10-20 2015-04-01 安徽省宿州市龙华机械制造有限公司 一种添加陶瓷纤维棉的活性炭硅藻土脱硫剂及其制备方法
CN104437366A (zh) * 2014-11-13 2015-03-25 安徽凤凰滤清器股份有限公司 一种不易崩解的混合活性炭脱硫剂及其制备方法
CN105597701A (zh) * 2016-03-17 2016-05-25 杭州富阳高博信息技术服务有限公司 一种用于处理锅炉烟气的吸附剂

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113996176A (zh) * 2021-11-15 2022-02-01 江西省杰夫环保科技有限公司 一种高效加热炉烟气脱硫剂及其制备方法和应用
CN116897802A (zh) * 2023-08-21 2023-10-20 江苏叁山环境科学技术研究有限公司 一种用陶瓷纤维棉和园林废弃物的发酵物育苗的制备方法

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Application publication date: 20180327