CN107828338A - A kind of paint drier and preparation method thereof - Google Patents
A kind of paint drier and preparation method thereof Download PDFInfo
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- CN107828338A CN107828338A CN201711305430.4A CN201711305430A CN107828338A CN 107828338 A CN107828338 A CN 107828338A CN 201711305430 A CN201711305430 A CN 201711305430A CN 107828338 A CN107828338 A CN 107828338A
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- parts
- gasoline
- fatty alcohol
- chain fatty
- octoate
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- 239000003973 paint Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- -1 metals ethylhexanoate salt Chemical class 0.000 claims abstract description 35
- 239000004793 Polystyrene Substances 0.000 claims abstract description 18
- 229920002223 polystyrene Polymers 0.000 claims abstract description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
- 239000002253 acid Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 16
- 239000006184 cosolvent Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 16
- 239000011667 zinc carbonate Substances 0.000 claims description 16
- 235000004416 zinc carbonate Nutrition 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000011656 manganese carbonate Substances 0.000 claims description 14
- 235000006748 manganese carbonate Nutrition 0.000 claims description 14
- 229940093474 manganese carbonate Drugs 0.000 claims description 14
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims description 14
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 9
- 239000013049 sediment Substances 0.000 claims description 8
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000012452 mother liquor Substances 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 235000019439 ethyl acetate Nutrition 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052748 manganese Inorganic materials 0.000 abstract description 11
- 239000011572 manganese Substances 0.000 abstract description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011701 zinc Substances 0.000 abstract description 5
- 229910052725 zinc Inorganic materials 0.000 abstract description 5
- ADJMNWKZSCQHPS-UHFFFAOYSA-L zinc;6-methylheptanoate Chemical compound [Zn+2].CC(C)CCCCC([O-])=O.CC(C)CCCCC([O-])=O ADJMNWKZSCQHPS-UHFFFAOYSA-L 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 238000004581 coalescence Methods 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 238000000227 grinding Methods 0.000 abstract description 2
- 238000003801 milling Methods 0.000 abstract description 2
- 230000003389 potentiating effect Effects 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 238000009736 wetting Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 4
- 239000011133 lead Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- SDPBZSAJSUJVAT-UHFFFAOYSA-N carbonic acid;manganese Chemical compound [Mn].OC(O)=O SDPBZSAJSUJVAT-UHFFFAOYSA-N 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of paint drier and preparation method thereof is provided in the embodiment of the present invention, it is cumbersome to solve the problems, such as to prepare in the prior art.Two kinds of active ingredients of manganese iso-octoate and zinc Isoocatanoate can be made simultaneously for this method, belong to based on various metals ethylhexanoate salt and compound efficient, the nontoxic drier for having efficient accelerator to make its Synergistic.Wherein, manganese iso-octoate can effectively facilitate bottom film forming in paint as dry ingredients are sponsored；Zinc Isoocatanoate can aid in manganese iso-octoate, contribute to film to deploy, and film is thoroughly dried, so as to have preferable hardness, meanwhile, zinc is also a kind of potent wetting dispersing agent, is added in the grinding stage, can effectively reduce milling time.In addition, the polyoxyethylene polystyrene copolymer and long-chain fatty alcohol aryl ether of the application addition, have the function that to strengthen manganese iso-octoate filming performance, further improve the coalescence performance of manganese iso-octoate.
Description
Technical field
Disclosure paint technology field, more particularly to a kind of paint drier and preparation method thereof.
Background technology
Drier is a kind of conventional oil paint additive, the oxidation polymerization of drying oil and oil based coating is can speed up, to dryness
Oxygen uptake, the polymerization of oil film play a part of similar catalyst.
The huge number of drier, many metal salts are used as drier, such as：Cobalt, manganese, lead, iron, copper, nickel, zinc, calcium
It is different with the salt of aluminium etc., the drying ability of various metallic salts.Cobalt salt is the very strong drier of activity, is that a kind of oxidized form is urged
Dry agent, because oxidation is since coating surface, thus cobalt salt can be dried coating surface to accelerate, and it is dry to be that a kind of surface is urged
Agent, it is other to also have promotion paint film bottom dry and increase the lead drier of adhesive force；Manganese of the performance between said two devices is urged
Dry agent and zinc, calcicoater as drier activator.
But the drier such as traditional cobalt, lead, manganese, zinc, calcium, it need to be allocated when in use according to different proportion, formality is numerous and diverse
And addition is big；In addition, cobalt, lead are poisonous carcinogenic substances, requirement more and more higher of the current coatings industry for environment protection health is nontoxic
Drier is undoubtedly development trend.
The content of the invention
A kind of paint drier and preparation method thereof is provided in the embodiment of the present invention, it is numerous to solve to prepare in the prior art
The problem of trivial.
The invention provides a kind of paint drier, include the raw material of following parts by weight：Isooctyl acid, sodium hydroxide, carbonic acid
Manganese, zinc carbonate, ethyl acetate, cosolvent, 120# gasoline, polyoxyethylene-polystyrene copolymer, long-chain fatty alcohol aryl ether,
Deionized water.
Preferably, including：Isooctyl acid 20-30 parts, sodium hydroxide 5-15 parts, manganese carbonate 4-10 parts, zinc carbonate 1-3 parts, second
Acetoacetic ester 5-10 parts, cosolvent 1-6 parts, 120# gasoline 3-8 parts, deionized water 100-150 parts, polyoxyethylene-polystyrene are common
Polymers 1-3 parts, long-chain fatty alcohol aryl ether 1-5 parts.
Preferably, including：20 parts of isooctyl acid, 10 parts of sodium hydroxide, 5 parts of manganese carbonate, 3 parts of zinc carbonate, 10 parts of ethyl acetate,
3 parts of cosolvent, 3 parts of 120# gasoline, 150 parts of deionized water, polyoxyethylene -3 parts of polystyrene copolymer, long-chain fatty alcohol aryl
5 parts of ether.
Present invention also offers a kind of preparation method of paint drier, comprise the following steps：
Step 1：The isooctyl acid that acid number is 230-235 is put into reactor, deionized water is added, hydroxide is added under stirring
Sodium and ethyl acetate, 90 DEG C are heated to after mixing mixing, and adjust pH to 8-9；
Step 2：Manganese carbonate and cosolvent are slowly added under stirring, constant temperature cools down after stirring 30 minutes, standby；
Step 3：Zinc carbonate, polyoxyethylene-polystyrene copolymer, long-chain fatty alcohol aryl ether and 120# gasoline are mixed
Close, the product obtained in step 2 is slowly added under stirring, discards lower floor's mother liquor and middle level emulsion, sediment is made；
Step 4：Sediment made from step 3 is cleaned repeatedly, is then refluxed for dehydration 6 hours, then be warming up to 130 DEG C and slough
After industrial naptha, minor amount of water is further sloughed under vacuo and obtains finished product.
Preferably, the parts by weight of each raw material are in the preparation method：20 parts of isooctyl acid, 10 parts of sodium hydroxide, carbonic acid
5 parts of manganese, 3 parts of zinc carbonate, 10 parts of ethyl acetate, 3 parts of cosolvent, 3 parts of 120# gasoline, 150 parts of deionized water, polyoxyethylene-poly-
Third 3 parts of ethylene copolymer.
Preferably, in the step 2 and the step 3, mixing speed is not less than 7000 revs/min.
The application's has the beneficial effect that：
A kind of paint drier and preparation method thereof is provided in the embodiment of the present invention.Paint drier includes：Isooctyl acid,
Sodium hydroxide, manganese carbonate, zinc carbonate, ethyl acetate, cosolvent, 120# gasoline, polyoxyethylene-polystyrene copolymer, long-chain
Fatty alcohol aryl ether, deionized water.Preparation method comprises the following steps：Step 1：The isooctyl acid that acid number is 230-235 is put into
Reactor, deionized water is added, stir lower addition sodium hydroxide and ethyl acetate, be heated to 90 DEG C after mixing mixing, and adjust
PH to 8-9；Step 2：Manganese carbonate and cosolvent are slowly added under stirring, constant temperature cools down after stirring 30 minutes, standby；Step 3：Will
Zinc carbonate, polyoxyethylene-polystyrene copolymer and the mixing of 120# gasoline, are slowly added to obtain in step 2 under stirring
Product, discard lower floor's mother liquor and middle level emulsion, be made sediment；Step 4：Sediment made from step 3 is cleaned repeatedly,
Be then refluxed for dehydration 6 hours, then be warming up to 130 DEG C slough industrial naptha after, further slough minor amount of water under vacuo and obtain finished product.
Two kinds of active ingredients of manganese iso-octoate and zinc Isoocatanoate can be made simultaneously for this method, belong to various metals ethylhexanoate salt
Based on and compound have efficient, the nontoxic drier that efficient accelerator makes its Synergistic.Wherein, manganese iso-octoate is used as to sponsor and done into
Point, bottom film forming in paint can be effectively facilitated；Zinc Isoocatanoate can aid in manganese iso-octoate, contribute to film to deploy, and make film
Thoroughly dry, so as to have preferable hardness, meanwhile, zinc is also a kind of potent wetting dispersing agent, is added in the grinding stage, can
Effectively reduce milling time.In addition, polyoxyethylene-polystyrene the copolymer and long-chain fatty alcohol aryl ether of the application addition,
Have the function that to strengthen manganese iso-octoate filming performance, further improve the coalescence performance of manganese iso-octoate.Add polyoxyethylene-poly- third
Ethylene copolymer and the sample of long-chain fatty alcohol aryl ether are relatively not added with polyoxyethylene-polystyrene copolymer and long-chain fatty alcohol
The sample of aryl ether, it can at least improve the drying time of paint 20%.
Brief description of the drawings
Accompanying drawing herein is merged in specification and forms the part of this specification, shows the implementation for meeting the present invention
Example, and for explaining principle of the invention together with specification.
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the required accompanying drawing used in technology description to be briefly described, it should be apparent that, for those of ordinary skill in the art
Speech, without having to pay creative labor, other accompanying drawings can also be obtained according to these accompanying drawings.
Accompanying drawing 1 is a kind of schematic flow sheet for paint drier preparation method that the application provides.
Embodiment
In order that those skilled in the art more fully understand the technical scheme in the present invention, below in conjunction with of the invention real
The accompanying drawing in example is applied, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
The every other embodiment that technical staff is obtained under the premise of creative work is not made, should all belong to protection of the present invention
Scope.
Embodiment 1
The present embodiment provides a kind of paint drier, includes the raw material of following parts by weight：20 parts of isooctyl acid, sodium hydroxide 5
Part, 4 parts of manganese carbonate, 1 part of zinc carbonate, 5 parts of ethyl acetate, 1 part of cosolvent, 3 parts of 120# gasoline, 100 parts of deionized water, polyoxy second
Alkene-polystyrene copolymer 1 part, 1 part of long-chain fatty alcohol aryl ether.
Embodiment 2
The present embodiment provides a kind of paint drier, includes the raw material of following parts by weight：20 parts of isooctyl acid, sodium hydroxide 10
Part, 5 parts of manganese carbonate, 3 parts of zinc carbonate, 10 parts of ethyl acetate, 3 parts of cosolvent, 3 parts of 120# gasoline, 150 parts of deionized water, polyoxy
Ethene -3 parts of polystyrene copolymer, 5 parts of long-chain fatty alcohol aryl ether.
Embodiment 3
The present embodiment provides a kind of paint drier, includes the raw material of following parts by weight：30 parts of isooctyl acid, sodium hydroxide 15
Part, 10 parts of manganese carbonate, 2 parts of zinc carbonate, 8 parts of ethyl acetate, 6 parts of cosolvent, 8 parts of 120# gasoline, 120 parts of deionized water, polyoxy
Ethene -2 parts of polystyrene copolymer, 2 parts of long-chain fatty alcohol aryl ether.
Embodiment 4
The present embodiment provides a kind of preparation method of paint drier, and this method comprises the following steps：
Step S01：The isooctyl acid that acid number is 230-235 is put into reactor, deionized water is added, hydrogen-oxygen is added under stirring
Change sodium and ethyl acetate, be heated to 90 DEG C after mixing mixing, and adjust pH to 8-9；
Step S02：Manganese carbonate and cosolvent are slowly added under stirring, constant temperature cools down after stirring 30 minutes, standby；
Step S03：Zinc carbonate, polyoxyethylene-polystyrene copolymer, long-chain fatty alcohol aryl ether and 120# gasoline are mixed
Close, the product obtained in step 2 is slowly added under stirring, discards lower floor's mother liquor and middle level emulsion, sediment is made；
Step S04：Sediment made from step 3 is cleaned repeatedly, is then refluxed for dehydration 6 hours, then is warming up to 130 DEG C and takes off
After removing industrial naptha, minor amount of water is further sloughed under vacuo and obtains finished product.
Claims (6)
1. a kind of paint drier, it is characterised in that include the raw material of following parts by weight：Isooctyl acid, sodium hydroxide, manganese carbonate,
Zinc carbonate, ethyl acetate, cosolvent, 120# gasoline, polyoxyethylene-polystyrene copolymer, long-chain fatty alcohol aryl ether, go from
Sub- water.
2. paint drier according to claim 1, it is characterised in that include the raw material of following parts by weight：Isooctyl acid 20-
30 parts, sodium hydroxide 5-15 parts, manganese carbonate 4-10 parts, zinc carbonate 1-3 parts, ethyl acetate 5-10 parts, cosolvent 1-6 parts, 120#
Gasoline 3-8 parts, polyoxyethylene--3 parts of polystyrene copolymer 1, long-chain fatty alcohol aryl ether 1-5 parts, deionized water 100-150
Part.
3. paint drier according to claim 1, it is characterised in that include the raw material of following parts by weight：Isooctyl acid 20
Part, 10 parts of sodium hydroxide, 5 parts of manganese carbonate, 3 parts of zinc carbonate, 10 parts of ethyl acetate, 3 parts of cosolvent, 3 parts of 120# gasoline, polyoxy second
Alkene -3 parts of polystyrene copolymer, 5 parts of long-chain fatty alcohol aryl ether, 150 parts of deionized water.
4. a kind of preparation method of paint drier, it is characterised in that comprise the following steps：
Step 1：The isooctyl acid that acid number is 230-235 is put into reactor, adds deionized water, stir it is lower add sodium hydroxide and
Ethyl acetate, 90 DEG C are heated to after mixing mixing, and adjust pH to 8-9；
Step 2：Manganese carbonate and cosolvent are slowly added under stirring, constant temperature cools down after stirring 30 minutes, standby；
Step 3：Zinc carbonate, polyoxyethylene-polystyrene copolymer, long-chain fatty alcohol aryl ether and 120# gasoline are mixed,
The product obtained in step 2 is slowly added under stirring, discards lower floor's mother liquor and middle level emulsion, sediment is made；
Step 4：Sediment made from step 3 is cleaned repeatedly, is then refluxed for dehydration 6 hours, then be warming up to 130 DEG C and slough solvent
After gasoline, minor amount of water is further sloughed under vacuo and obtains finished product.
5. the preparation method of paint drier according to claim 4, it is characterised in that each raw material in the preparation method
Parts by weight be：20 parts of isooctyl acid, 10 parts of sodium hydroxide, 5 parts of manganese carbonate, 3 parts of zinc carbonate, 10 parts of ethyl acetate, cosolvent 3
Part, 3 parts of 120# gasoline, 150 parts of deionized water, polyoxyethylene -3 parts of polystyrene copolymer, 5 parts of long-chain fatty alcohol aryl ether.
6. the preparation method of paint drier according to claim 4, it is characterised in that the step 2 and the step 3
In, mixing speed is not less than 7000 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711305430.4A CN107828338A (en) | 2017-12-11 | 2017-12-11 | A kind of paint drier and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711305430.4A CN107828338A (en) | 2017-12-11 | 2017-12-11 | A kind of paint drier and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107828338A true CN107828338A (en) | 2018-03-23 |
Family
ID=61642613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711305430.4A Pending CN107828338A (en) | 2017-12-11 | 2017-12-11 | A kind of paint drier and preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108794324A (en) * | 2018-07-23 | 2018-11-13 | 上海华谊（集团）公司 | The preparation method of zinc Isoocatanoate |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1908100A (en) * | 2006-08-11 | 2007-02-07 | 盖州市油漆化工厂 | Organosilicon alcohol acid ready mixed paint coating composition and method of making the same |
| CN101096570A (en) * | 2007-06-22 | 2008-01-02 | 闫里选 | Preparation method of water-based polyurethane drier |
-
2017
- 2017-12-11 CN CN201711305430.4A patent/CN107828338A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1908100A (en) * | 2006-08-11 | 2007-02-07 | 盖州市油漆化工厂 | Organosilicon alcohol acid ready mixed paint coating composition and method of making the same |
| CN101096570A (en) * | 2007-06-22 | 2008-01-02 | 闫里选 | Preparation method of water-based polyurethane drier |
Non-Patent Citations (1)
| Title |
|---|
| 俞志明: "《中国化工商品大全》", 31 January 1996, 中国物资出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108794324A (en) * | 2018-07-23 | 2018-11-13 | 上海华谊（集团）公司 | The preparation method of zinc Isoocatanoate |
| CN108794324B (en) * | 2018-07-23 | 2021-06-29 | 上海华谊（集团）公司 | Preparation method of zinc isooctanoate |
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