CN107815251A - A kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris - Google Patents
A kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris Download PDFInfo
- Publication number
- CN107815251A CN107815251A CN201711225414.4A CN201711225414A CN107815251A CN 107815251 A CN107815251 A CN 107815251A CN 201711225414 A CN201711225414 A CN 201711225414A CN 107815251 A CN107815251 A CN 107815251A
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- CN
- China
- Prior art keywords
- parts
- wax
- statue
- preventing
- verdigris
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
Abstract
It is described to protect wax by weight the present invention relates to a kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris, including:30 60 parts of 50 80 parts of palm wax and silicone oil;Palm wax includes:50 80 parts of 20 40 parts of fatty acid ester, 6 20 parts of hydroxy fatty acid, 30 50 parts of p Methoxycinnamates and p hydroxy cinnamates acid diesters.The present invention includes wax by coating one layer on the surface of the copper sculpture processed, water in copper sculpture and air, oxygen can be isolated, copper sculpture and water, oxygen for a long time exposed to air and in the rain etc. will not be made to chemically react, generate verdigris, improve the aesthetics of copper sculpture.
Description
Technical field
The present invention relates to statue technical field, more particularly to a kind of protection wax and its system for preventing statue in bronze generation verdigris
Standby technique.
Background technology
Either copper sculpture or forge copper sculpture, as long as copper sculpture puts long meeting " getting rusty " in atmosphere.Sky of the copper in humidity
The cupric oxide of black can be oxidized in gas, the cupric oxide on cast copper surface continues to act on the carbon dioxide in air, generation one
Layer verdigris.In addition, copper can also have an effect with the hydrogen sulfide in air, the copper sulfide of black is generated.Verdigris is basic copper carbonate,
Chemical formula is Cu2 (OH) 2CO3, also known as malachite, is a kind of rare mineral jewel.The verdigris Cheng Cui of copper sculpture Surface Creation
Green, influence the attractive in appearance of copper sculpture.Therefore, it is badly in need of a kind of method for preventing from generating verdigris from source in industry.
The content of the invention
In order to overcome the verdigris of copper sculpture Surface Creation existing for prior art to influence the attractive in appearance of copper sculpture into emerald green
Deficiency, the invention provides a kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:Palm wax 50-80 parts and silicone oil 30-60
Part;The palm wax includes:Fatty acid ester 20-40 parts, hydroxy fatty acid 6-20 parts, p- Methoxycinnamate 30-50 parts
With p- hydroxy cinnamate acid diesters 50-80 parts.
Preferably, by weight, including:40-50 parts of palm wax 60-70 parts and silicone oil;The palm wax includes:Fat
Fat acid esters 25-35 parts, hydroxy fatty acid 10-18 parts, p- Methoxycinnamate 36-45 parts and p- hydroxy cinnamate acid diesters
60-70 parts.
Preferably, by weight, including:45 parts of 65 parts of palm wax and silicone oil;The palm wax includes:Fatty acid ester 30
Part, 15 parts of hydroxy fatty acid, 40 parts of p- Methoxycinnamates and 65 parts of p- hydroxy cinnamates acid diesters.
Preferably, by weight, in addition to:Antistatic additive 0.6-6 parts.
Preferably, the antistatic additive is interior mixed type antistatic additive.
Preferably, the silicone oil is methyl-silicone oil.
Preferably, the silicone oil is modified silicon oil.
A kind of preparation technology for protecting wax for preventing statue in bronze generation verdigris, including:The material of above-mentioned formula ratio is placed
In in the material-compound tank with chuck and agitator;The material is stirred, and leads to steam heating in chuck, raises temperature of charge
To the first temperature;After the material all dissolving, cooling water is led in chuck;Treat that the temperature of charge in material-compound tank drops to
It is after two temperature, the material stirring in material-compound tank is uniform;Material in material-compound tank is sent and is sent to bottle placer, is irrigated and wraps
Dress, obtains finished product protection wax.
Preferably, first temperature is 100 degree.
Preferably, the second temperature is 25 degree.
The beneficial effects of the invention are as follows:The present invention includes wax by coating one layer on the surface of the copper sculpture processed, can
So that the water in copper sculpture and air, oxygen to be isolated, copper sculpture and water, oxygen for a long time exposed to air and in the rain will not be made
Deng chemically reacting, verdigris is generated, improves the aesthetics of copper sculpture.Moreover, after testing, the adhesive of the protection wax and according to
Attached property is strong, difficult for drop-off.
Embodiment
Embodiment 1
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:50 parts of palm wax, 0.6 part of antistatic additive and
30 parts of silicone oil;The palm wax includes:20 parts of fatty acid ester, 6 parts of hydroxy fatty acid, 30 parts of p- Methoxycinnamates and p-
50 parts of hydroxy cinnamate acid diesters.
Wherein, the antistatic additive is interior mixed type antistatic additive.The silicone oil is methyl-silicone oil.
The preparation technology for protecting wax for preventing statue in bronze generation verdigris is as follows:
The material of above-mentioned formula ratio is positioned in the material-compound tank with chuck and agitator;
The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to 100 degree;
After the material all dissolving, cooling water is led in chuck;
It is after the temperature of charge in material-compound tank drops to 25 degree, the material stirring in material-compound tank is uniform;
Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
The application method of the protection wax for preventing statue in bronze generation verdigris of the present embodiment is as follows:
The copper sculpture processed is polished;
The above-mentioned protection wax uniformly copper sculpture surface of smearing after a polish is picked with sponge;
Wait 1 minute, the copper sculpture surface after polishing is wiped with the sponge for speckling with above-mentioned protection wax;
Until the statue in bronze is in bright shape.
Embodiment 2
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:80 parts of palm wax, 6 parts of antistatic additive and silicon
60 parts of oil;The palm wax includes:40 parts of fatty acid ester, 20 parts of hydroxy fatty acid, 50 parts of p- Methoxycinnamates and p-
80 parts of hydroxy cinnamate acid diesters.
Wherein, the antistatic additive is interior mixed type antistatic additive.The silicone oil is methyl-silicone oil.
The preparation technology for protecting wax for preventing statue in bronze generation verdigris is as follows:
The material of above-mentioned formula ratio is positioned in the material-compound tank with chuck and agitator;
The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to 100 degree;
After the material all dissolving, cooling water is led in chuck;
It is after the temperature of charge in material-compound tank drops to 25 degree, the material stirring in material-compound tank is uniform;
Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
The application method of the protection wax for preventing statue in bronze generation verdigris of the present embodiment is as follows:
The copper sculpture processed is polished;
The above-mentioned protection wax uniformly copper sculpture surface of smearing after a polish is picked with sponge;
Wait 5 minutes, the copper sculpture surface after polishing is wiped with the sponge for speckling with above-mentioned protection wax;
Until the statue in bronze is in bright shape.
Embodiment 3
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:60 parts of palm wax, 4 parts of antistatic additive and silicon
40 parts of oil;The palm wax includes:25 parts of fatty acid ester, 10 parts of hydroxy fatty acid, 36 parts of p- Methoxycinnamates and p-
60 parts of hydroxy cinnamate acid diesters.
Wherein, the antistatic additive is interior mixed type antistatic additive.The silicone oil is modified silicon oil.
The preparation technology for protecting wax for preventing statue in bronze generation verdigris is as follows:
The material of above-mentioned formula ratio is positioned in the material-compound tank with chuck and agitator;
The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to 100 degree;
After the material all dissolving, cooling water is led in chuck;
It is after the temperature of charge in material-compound tank drops to 25 degree, the material stirring in material-compound tank is uniform;
Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
The application method of the protection wax for preventing statue in bronze generation verdigris of the present embodiment is as follows:
The copper sculpture processed is polished;
The above-mentioned protection wax uniformly copper sculpture surface of smearing after a polish is picked with sponge;
Wait 3 minutes, the copper sculpture surface after polishing is wiped with the sponge for speckling with above-mentioned protection wax;
Until the statue in bronze is in bright shape.
Embodiment 4
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:70 parts of palm wax, 4 parts of antistatic additive and silicon
50 parts of oil;The palm wax includes:35 parts of fatty acid ester, 18 parts of hydroxy fatty acid, 45 parts of p- Methoxycinnamates and p-
70 parts of hydroxy cinnamate acid diesters.
Wherein, the antistatic additive is interior mixed type antistatic additive.The silicone oil is modified silicon oil.
The preparation technology for protecting wax for preventing statue in bronze generation verdigris is as follows:
The material of above-mentioned formula ratio is positioned in the material-compound tank with chuck and agitator;
The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to 100 degree;
After the material all dissolving, cooling water is led in chuck;
It is after the temperature of charge in material-compound tank drops to 25 degree, the material stirring in material-compound tank is uniform;
Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
The application method of the protection wax for preventing statue in bronze generation verdigris of this programme is as follows:
The copper sculpture processed is polished;
The above-mentioned protection wax uniformly copper sculpture surface of smearing after a polish is picked with sponge;
Wait 3 minutes, the copper sculpture surface after polishing is wiped with the sponge for speckling with above-mentioned protection wax;
Until the statue in bronze is in bright shape.
Embodiment 5
A kind of protection wax for preventing statue in bronze generation verdigris, by weight, including:65 parts of palm wax, 4 parts of antistatic additive and silicon
45 parts of oil;The palm wax includes:30 parts of fatty acid ester, 15 parts of hydroxy fatty acid, 40 parts of p- Methoxycinnamates and p-
65 parts of hydroxy cinnamate acid diesters.
Wherein, the antistatic additive is interior mixed type antistatic additive.The silicone oil is modified silicon oil.
The preparation technology for protecting wax for preventing statue in bronze generation verdigris is as follows:
The material of above-mentioned formula ratio is positioned in the material-compound tank with chuck and agitator;
The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to 100 degree;
After the material all dissolving, cooling water is led in chuck;
It is after the temperature of charge in material-compound tank drops to 25 degree, the material stirring in material-compound tank is uniform;
Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
The application method of the protection wax for preventing statue in bronze generation verdigris of the present embodiment is as follows:
The copper sculpture processed is polished;
The above-mentioned protection wax uniformly copper sculpture surface of smearing after a polish is picked with sponge;
Wait 3 minutes, the copper sculpture surface after polishing is wiped with the sponge for speckling with above-mentioned protection wax;
Until the statue in bronze is in bright shape.
Test data
Test group 1, test group 2, experimental group 3, test group 4, experimental group 5 and control group are set, and test group 1 is by embodiment 1
Protection wax is coated in copper sculpture surface, and test group 2 is that the protection wax of embodiment 2 is coated in into copper sculpture surface, and test group 3 is will
The protection wax of embodiment 3 is coated in copper sculpture surface, and test group 4 is that the protection wax of embodiment 4 is coated in into copper sculpture surface, is tried
It is that the protection wax of embodiment 5 be coated in into copper sculpture surface to test group 5, control group be it is uncoated anything on copper sculpture surface,
By the unified exposure of each experimental group in atmosphere, every three months, duration 2 years, the feelings of each group copper sculpture Surface Creation verdigris are observed
Condition.
For experimental group 1 after placing 18 months, there is a little verdigris spot in copper sculpture surface, occurs a small amount of copper after 21 months
It is green, occur a small amount of verdigris after 24 months, the verdigris on copper sculpture can be neglected substantially.
There is a little verdigris spot after placing 21 months in experimental group 2, occurs a small amount of verdigris after 24 months, on copper sculpture
Verdigris can be neglected substantially.
There is a little verdigris spot after placing 21 months in experimental group 3, occurs a small amount of verdigris after 24 months, on copper sculpture
Verdigris can be neglected substantially.
There is a little verdigris spot after placing 24 months in experimental group 4, and the verdigris on copper sculpture can be neglected substantially.
There is not verdigris in copper sculpture surface after placing 24 months in experimental group 5.
For control group after placing 6 months, there is a little verdigris spot in copper sculpture surface, occurs a small amount of verdigris after 9 months, and 12
There is the larger verdigris of area in many places after individual month, and the verdigris area on copper sculpture surface is up to 2% after 15 months.Copper sculpture after 24 months
The verdigris area on surface is up to 5%.
In addition, it is above-mentioned prevent statue in bronze generation verdigris protection wax after the above method coats, after 2 years, after testing, institute
Stating protection, wax is still intact be coated in copper sculpture surface, illustrate described to protect wax to have good adhesive and depend on
Property.Wherein detection method is as follows:
After coated protection wax is dried, the protection wax on the copper sculpture surface of certain area is scratched with knife, measures quilt
The weight of the protection wax to scratch.After 2 years, with same method scratch copper sculpture surface protection wax of the same area, survey
The weight for the protection wax that amount is now got off by scratch.Relatively the good weight by protection wax that scratch is got off of just coating with last 2 years
The weight of the protection wax to be got off afterwards by scratch, it is found that the two weight is the same.
To sum up, the surface of copper sculpture is coated in using the protection wax of this programme, can prevented very well in copper sculpture and air
Water, oxygen occur chemical reaction generation verdigris, and it is described protection wax there is good adhesive and dependency, it is difficult for drop-off.
It is complete by above-mentioned description, relevant staff using the above-mentioned desirable embodiment according to the present invention as enlightenment
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to determines its technical scope according to right.
Claims (10)
- A kind of 1. protection wax for preventing statue in bronze generation verdigris, it is characterised in that by weight, including:Palm wax 50-80 parts With 30-60 parts of silicone oil;The palm wax includes:Fatty acid ester 20-40 parts, hydroxy fatty acid 6-20 parts, p- Methoxycinnamate 30-50 parts With p- hydroxy cinnamate acid diesters 50-80 parts.
- 2. the protection wax according to claim 1 for preventing statue in bronze generation verdigris, it is characterised in that by weight, bag Include:40-50 parts of palm wax 60-70 parts and silicone oil;The palm wax includes:Fatty acid ester 25-35 parts, hydroxy fatty acid 10-18 parts, p- Methoxycinnamates 36-45 Part and p- hydroxy cinnamate acid diesters 60-70 parts.
- 3. the protection wax according to claim 1 for preventing statue in bronze generation verdigris, it is characterised in that by weight, bag Include:45 parts of 65 parts of palm wax and silicone oil;The palm wax includes:30 parts of fatty acid ester, 15 parts of hydroxy fatty acid, 40 parts of p- Methoxycinnamates and p- hydroxyls 65 parts of Chinese cassia tree acid diesters.
- 4. the protection wax according to claim 1 for preventing statue in bronze generation verdigris, it is characterised in that by weight, also Including:Antistatic additive 0.6-6 parts.
- 5. the protection wax according to claim 4 for preventing statue in bronze generation verdigris, it is characterised in that the antistatic additive is Interior mixed type antistatic additive.
- 6. the protection wax according to claim 1 for preventing statue in bronze generation verdigris, it is characterised in that the silicone oil is methyl Silicone oil.
- 7. the protection wax according to claim 1 for preventing statue in bronze generation verdigris, it is characterised in that the silicone oil is modification Silicone oil.
- A kind of 8. preparation technology for protecting wax for preventing statue in bronze generation verdigris, it is characterised in that including:The material of claim 1-7 any one formula ratios is positioned in the material-compound tank with chuck and agitator;The material is stirred, and leads to steam heating in chuck, temperature of charge is increased to the first temperature;After the material all dissolving, cooling water is led in chuck;It is after the temperature of charge in material-compound tank drops to second temperature, the material stirring in material-compound tank is uniform;Material in material-compound tank is sent and is sent to bottle placer, is irrigated and packs, obtains finished product protection wax.
- 9. the preparation technology according to claim 8 that protect wax for preventing statue in bronze generation verdigris, it is characterised in that described First temperature is 100 degree.
- 10. the preparation technology according to claim 9 that protect wax for preventing statue in bronze generation verdigris, the second temperature are 25 degree.
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CN201711225414.4A CN107815251B (en) | 2017-11-29 | 2017-11-29 | Protective wax for preventing copper statue from generating verdigris and preparation process thereof |
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CN201711225414.4A CN107815251B (en) | 2017-11-29 | 2017-11-29 | Protective wax for preventing copper statue from generating verdigris and preparation process thereof |
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CN107815251B CN107815251B (en) | 2020-06-05 |
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Cited By (1)
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CN111376635A (en) * | 2018-12-27 | 2020-07-07 | 杭州朱炳仁文化艺术有限公司 | Purple gold copper carving process |
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