CN108641596A - A kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box - Google Patents
A kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box Download PDFInfo
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- CN108641596A CN108641596A CN201810516725.4A CN201810516725A CN108641596A CN 108641596 A CN108641596 A CN 108641596A CN 201810516725 A CN201810516725 A CN 201810516725A CN 108641596 A CN108641596 A CN 108641596A
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- repellent paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to waterproof material technical fields, and in particular to a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box.The water-repellent paint includes following components：60 70 parts of emulsified wax, 15 20 parts of acrylic acid ester emulsion, 16 19 parts of dimethicone, 35 parts of modified starch, 8 13 parts of wear resistant filler, 47 parts of fire retardant, 36 parts of isobutyl palmitate, 14 parts of coalescents, 0.5 1.8 parts of levelling agent.Wherein, modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification；Wear resistant filler is nano-titanium dioxide；Fire retardant is the mixture of aluminium hydroxide, aluminium oxide and antimony oxide, and coalescents are alcohol ester 12, and levelling agent is organosilicon levelling agent or acrylic compounds levelling agent；The coating has good sealing water resistance, and has the characteristics that strong adhesive force, and good weatherability, flushing resistance is strong, and the interior painting suitable for advertising lamp box is protected.
Description
Technical field
The present invention relates to waterproof material technical fields, and in particular to a kind of resistance to flushing waterproof for being applied in advertising lamp box applies
Material.
Background technology
Advertising lamp box is a kind of device for advertising, and businessman is general to be mounted on outdoor flow of the people by advertising lamp box
The purpose solicited trade is played in big region.Advertising lamp box is generally by frame, the covering or decorative panel structure that are mounted on frame
At, inside setting headlamp, the night display effect for promoting lamp box.Wherein, the covering of common advertising lamp box outer layer is adopted
It is PVC material and the compound fabric of bonded scrim material, ad content is printed on outside by way of spray printing.This material
Water resistance it is preferable, but in the junction of lamp box structure, can still there is small-sized gap, rainwater enters from these gaps
To inside lamp box, internal metal framework and cable can be damaged, it is therefore desirable to being one kind having good waterproof effect,
And the coating with good wash-resistant property carries out protective treatment.
Invention content
For problems of the prior art, the present invention provides a kind of resistance to flushing waterproofs for being applied in advertising lamp box
Coating, which has good sealing water resistance, and has the characteristics that strong adhesive force, good weatherability, flushing resistance
By force, the interior painting for being suitable for advertising lamp box is protected.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of water-repellent paint of resistance to flushing for applying in advertising lamp box, according to mass fraction, the water-repellent paint include with
Lower component：60-70 parts of emulsified wax, 15-20 parts of acrylic acid ester emulsion, 16-19 parts of dimethicone, 3-5 parts of modified starch are resistance to
Grind 8-13 parts of filler, 4-7 parts of fire retardant, 3-6 parts of isobutyl palmitate, 1-4 parts of coalescents, 0.5-1.8 parts of levelling agent.
Preferably, according to mass fraction, water-repellent paint includes following components：65 parts of emulsified wax, acrylic acid ester emulsion
18 parts, 17 parts of dimethicone, 4 parts of modified starch, 10 parts of wear resistant filler, 6 parts of fire retardant, 4 parts of isobutyl palmitate, film forming helps
2 parts of agent, 0.9 part of levelling agent.
Preferably, modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification.
In the present invention, the preparation method of modified starch is as follows：
By mass fraction, 3 parts of epoxychloropropane and 4 sodium chloroacetates are added in 15 ethanol solutions, is uniformly mixed, must mix
Solution；10 parts of starch are added in mixed solution, is uniformly mixed, obtains mixed material, mixed material is heated to 45 DEG C, to heating
Sodium hydroxide solution is added in mixed material afterwards, adjusts the pH value of reactant to 5.6-5.8,0.3 part is added into reactant
Sulfuric acid Asia sodium, catalysis reaction 3-5h, by reaction product gelatinization it is dry after, obtain required modified starch.
In the present invention, the preparation method of emulsified wax includes the following steps：According to mass fraction, 85 parts of paraffin are added anti-
It answers and is heated to 70-80 DEG C of thawing in kettle, 4 parts of absolute ethyl alcohols, 1.5 parts of butyl titanates, 13 parts of breasts are then added into reaction kettle
Agent and 1 part of polysorbate are mixed evenly, and obtain the emulsified wax.
Preferably, wear resistant filler is nano-titanium dioxide.
Preferably, fire retardant is the mixture of aluminium hydroxide, aluminium oxide and antimony oxide, the quality of three in mixture
Score ratio is 3:2:4；The material mesh number of fire retardant is 500-550 mesh.
Preferably, coalescents are alcohol ester 12, and levelling agent is organosilicon levelling agent or acrylic compounds levelling agent.
The preparation method of water-repellent paint provided by the invention is as follows：Emulsified wax is heated to 80-90 DEG C in Scattered Kettle,
After thinking that addition acrylic acid ester emulsion, dimethicone stir in Scattered Kettle after thawing, by modified starch and palmitic acid
Different monooctyl ester is added, and continues stirring and insulation reaction 15-20min, then by wear resistant filler, fire retardant, coalescents and levelling agent
It is added, with the rotating speed decentralized processing 30-35min of 600-650r/min, then cools to room temperature, pack to obtain required waterproof
Coating.
The present invention has following advantageous effect：
Dimethyl is added using emulsified wax and acrylic acid ester emulsion as coating matrix in the type water-repellent paint in aggregate material
Silicone oil improves the combination between emulsified wax and acrylate solution, so that the chemical stability higher of material,
The use of modified starch is to enhance the adhesive force of coating, the effect of wear resistant filler is to improve to improve the viscosity of coating
The resistance to flushing performance and wear-resisting property of coating.The type coating not only has preferable waterproof sealing effect, and can be with gold
Belonging to the fabrics such as frame, PVC material and grid cloth has good combination effect, the strong adhesive force of coating not easily to fall off.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of water-repellent paint of resistance to flushing for applying in advertising lamp box, according to mass fraction, the water-repellent paint include with
Lower component：60 parts of emulsified wax, 15 parts of acrylic acid ester emulsion, 16 parts of dimethicone, 3 parts of modified starch, 8 parts of wear resistant filler,
4 parts of fire retardant, 3 parts of isobutyl palmitate, 1 part of coalescents, 0.5 part of levelling agent.
Modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification.It is modified in the present embodiment
The preparation method of starch is as follows：
By mass fraction, 3 parts of epoxychloropropane and 4 sodium chloroacetates are added in 15 ethanol solutions, is uniformly mixed, must mix
Solution；10 parts of starch are added in mixed solution, is uniformly mixed, obtains mixed material, mixed material is heated to 45 DEG C, to heating
Sodium hydroxide solution is added in mixed material afterwards, adjusts the pH value of reactant to 5.6,0.3 part of sulphur is added into reactant
Acid Asia sodium, catalysis reaction 3h obtain required modified starch after reaction product gelatinization drying.
In the present embodiment, the preparation method of emulsified wax includes the following steps：According to mass fraction, 85 parts of paraffin are added
It is heated to 70 DEG C of thawings in reaction kettle, 4 parts of absolute ethyl alcohols, 1.5 parts of butyl titanates, 13 parts of emulsifications are then added into reaction kettle
Agent and 1 part of polysorbate are mixed evenly, and obtain the emulsified wax.
Wherein, wear resistant filler is nano-titanium dioxide.
Fire retardant is the mixture of aluminium hydroxide, aluminium oxide and antimony oxide, the mass fraction ratio of three in mixture
It is 3:2:4；The material mesh number of fire retardant is 500 mesh.
Coalescents are alcohol ester 12, and levelling agent is organosilicon levelling agent.
The preparation method of water-repellent paint provided in this embodiment is as follows：Emulsified wax is heated to 80 DEG C in Scattered Kettle,
After thinking that addition acrylic acid ester emulsion, dimethicone stir in Scattered Kettle after thawing, by modified starch and palmitic acid
Different monooctyl ester is added, and continues stirring and insulation reaction 15min, then adds wear resistant filler, fire retardant, coalescents and levelling agent
Enter, with the rotating speed decentralized processing 30min of 600r/min, then cools to room temperature, pack to obtain required water-repellent paint.
Embodiment 2
A kind of water-repellent paint of resistance to flushing for applying in advertising lamp box, according to mass fraction, the water-repellent paint include with
Lower component：70 parts of emulsified wax, 20 parts of acrylic acid ester emulsion, 19 parts of dimethicone, 5 parts of modified starch, 13 parts of wear resistant filler,
7 parts of fire retardant, 6 parts of isobutyl palmitate, 4 parts of coalescents, 1.8 parts of levelling agent.
Modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification.It is modified in the present embodiment
The preparation method of starch is as follows：
By mass fraction, 3 parts of epoxychloropropane and 4 sodium chloroacetates are added in 15 ethanol solutions, is uniformly mixed, must mix
Solution；10 parts of starch are added in mixed solution, is uniformly mixed, obtains mixed material, mixed material is heated to 45 DEG C, to heating
Sodium hydroxide solution is added in mixed material afterwards, adjusts the pH value of reactant to 5.8,0.3 part of sulphur is added into reactant
Acid Asia sodium, catalysis reaction 5h obtain required modified starch after reaction product gelatinization drying.
In the present embodiment, the preparation method of emulsified wax includes the following steps：According to mass fraction, 85 parts of paraffin are added
It is heated to 80 DEG C of thawings in reaction kettle, 4 parts of absolute ethyl alcohols, 1.5 parts of butyl titanates, 13 parts of emulsifications are then added into reaction kettle
Agent and 1 part of polysorbate are mixed evenly, and obtain the emulsified wax.
Wherein, wear resistant filler is nano-titanium dioxide.
Fire retardant is the mixture of aluminium hydroxide, aluminium oxide and antimony oxide, the mass fraction ratio of three in mixture
It is 3:2:4；The material mesh number of fire retardant is 550 mesh.
Coalescents are alcohol ester 12, and levelling agent is acrylic compounds levelling agent.
The preparation method of water-repellent paint provided in this embodiment is as follows：Emulsified wax is heated to 90 DEG C in Scattered Kettle,
After thinking that addition acrylic acid ester emulsion, dimethicone stir in Scattered Kettle after thawing, by modified starch and palmitic acid
Different monooctyl ester is added, and continues stirring and insulation reaction 20min, then adds wear resistant filler, fire retardant, coalescents and levelling agent
Enter, with the rotating speed decentralized processing 30-35min of 650r/min, then cools to room temperature, pack to obtain required water-repellent paint.
Embodiment 3
A kind of water-repellent paint of resistance to flushing for applying in advertising lamp box, according to mass fraction, the water-repellent paint include with
Lower component：65 parts of emulsified wax, 18 parts of acrylic acid ester emulsion, 17 parts of dimethicone, 4 parts of modified starch, 10 parts of wear resistant filler,
5 parts of fire retardant, 5 parts of isobutyl palmitate, 2 parts of coalescents, 0.9 part of levelling agent.
Modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification.It is modified in the present embodiment
The preparation method of starch is as follows：
By mass fraction, 3 parts of epoxychloropropane and 4 sodium chloroacetates are added in 15 ethanol solutions, is uniformly mixed, must mix
Solution；10 parts of starch are added in mixed solution, is uniformly mixed, obtains mixed material, mixed material is heated to 45 DEG C, to heating
Sodium hydroxide solution is added in mixed material afterwards, adjusts the pH value of reactant to 5.7,0.3 part of sulphur is added into reactant
Acid Asia sodium, catalysis reaction 4h obtain required modified starch after reaction product gelatinization drying.
In the present embodiment, the preparation method of emulsified wax includes the following steps：According to mass fraction, 85 parts of paraffin are added
It is heated to 75 DEG C of thawings in reaction kettle, 4 parts of absolute ethyl alcohols, 1.5 parts of butyl titanates, 13 parts of emulsifications are then added into reaction kettle
Agent and 1 part of polysorbate are mixed evenly, and obtain the emulsified wax.
Wherein, wear resistant filler is nano-titanium dioxide.
Fire retardant is the mixture of aluminium hydroxide, aluminium oxide and antimony oxide, the mass fraction ratio of three in mixture
It is 3:2:4；The material mesh number of fire retardant is 500-550 mesh.
Coalescents are alcohol ester 12, and levelling agent is organosilicon levelling agent.
The preparation method of water-repellent paint provided in this embodiment is as follows：Emulsified wax is heated to 85 DEG C in Scattered Kettle,
After thinking that addition acrylic acid ester emulsion, dimethicone stir in Scattered Kettle after thawing, by modified starch and palmitic acid
Different monooctyl ester is added, and continues stirring and insulation reaction 17min, then adds wear resistant filler, fire retardant, coalescents and levelling agent
Enter, with the rotating speed decentralized processing 33min of 630r/min, then cools to room temperature, pack to obtain required water-repellent paint.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (9)
1. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box, it is characterised in that：According to mass fraction, the waterproof applies
Material includes following components：60-70 parts of emulsified wax, 15-20 parts of acrylic acid ester emulsion, 16-19 parts of dimethicone are modified to form sediment
3-5 parts of powder, 8-13 parts of wear resistant filler, 4-7 parts of fire retardant, 3-6 parts of isobutyl palmitate, 1-4 parts of coalescents, levelling agent 0.5-
1.8 part.
2. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：According to
Mass fraction, the water-repellent paint include following components：65 parts of emulsified wax, 18 parts of acrylic acid ester emulsion, dimethicone
17 parts, 4 parts of modified starch, 10 parts of wear resistant filler, 6 parts of fire retardant, 4 parts of isobutyl palmitate, 2 parts of coalescents, levelling agent 0.9
Part.
3. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：It is described
Modified starch is the thickening starch by epoxychloropropane and sodium chloroacetate modification.
4. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 3, it is characterised in that：It is described
The preparation method of modified starch is as follows：
By mass fraction, 3 parts of epoxychloropropane and 4 sodium chloroacetates are added in 15 ethanol solutions, is uniformly mixed, must mix molten
Liquid；10 parts of starch are added in mixed solution, is uniformly mixed, obtains mixed material, mixed material is heated to 45 DEG C, to after heating
Mixed material in sodium hydroxide solution is added, adjust the pH value of reactant to 5.6-5.8,0.3 part be added into reactant
Sulfuric acid Asia sodium, catalysis reaction 3-5h obtain required modified starch after reaction product gelatinization drying.
5. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：It is described
The preparation method of emulsified wax includes the following steps：According to mass fraction, 85 parts of paraffin are added in reaction kettle and are heated to 70-80
DEG C melt, 4 parts of absolute ethyl alcohols, 1.5 parts of butyl titanates, 13 parts of emulsifiers and 1 part of polysorbate are then added into reaction kettle
It is mixed evenly, obtains the emulsified wax.
6. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：It is described
Wear resistant filler is nano-titanium dioxide.
7. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：Institute
Fire retardant is stated as aluminium hydroxide, the mixture of aluminium oxide and antimony oxide, the mass fraction ratio of three is 3 in mixture:2:
4；The material mesh number of fire retardant is 500-550 mesh.
8. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：It is described
Coalescents are alcohol ester 12, and levelling agent is organosilicon levelling agent or acrylic compounds levelling agent.
9. a kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box according to claim 1, it is characterised in that：Institute
The preparation method for stating water-repellent paint is as follows：Emulsified wax is heated to 80-90 DEG C in Scattered Kettle, thinks to add in Scattered Kettle after thawing
Enter acrylic acid ester emulsion, after dimethicone stirs, modified starch and isobutyl palmitate are added, continue to stir
And insulation reaction 15-20min, then wear resistant filler, fire retardant, coalescents and levelling agent are added, with 600-650r/min
Rotating speed decentralized processing 30-35min, then cool to room temperature, pack to obtain required water-repellent paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810516725.4A CN108641596A (en) | 2018-05-25 | 2018-05-25 | A kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810516725.4A CN108641596A (en) | 2018-05-25 | 2018-05-25 | A kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box |
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| CN108641596A true CN108641596A (en) | 2018-10-12 |
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| CN201810516725.4A Pending CN108641596A (en) | 2018-05-25 | 2018-05-25 | A kind of water-repellent paint of resistance to flushing for being applied in advertising lamp box |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112549226A (en) * | 2020-11-28 | 2021-03-26 | 无锡市森泰木制品有限公司 | Waterproof wood processing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1690083A (en) * | 2004-04-23 | 2005-11-02 | 郝庆阳 | Composite modified starch and its preparing method |
| CN107011743A (en) * | 2017-03-30 | 2017-08-04 | 天长市天达纸箱纸品厂 | A kind of preparation method of corrugated board water-repellent paint |
-
2018
- 2018-05-25 CN CN201810516725.4A patent/CN108641596A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1690083A (en) * | 2004-04-23 | 2005-11-02 | 郝庆阳 | Composite modified starch and its preparing method |
| CN107011743A (en) * | 2017-03-30 | 2017-08-04 | 天长市天达纸箱纸品厂 | A kind of preparation method of corrugated board water-repellent paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112549226A (en) * | 2020-11-28 | 2021-03-26 | 无锡市森泰木制品有限公司 | Waterproof wood processing method |
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