CN109706725A - A kind of anti-corrosion cloth dye formulation - Google Patents

A kind of anti-corrosion cloth dye formulation Download PDF

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Publication number
CN109706725A
CN109706725A CN201811540156.3A CN201811540156A CN109706725A CN 109706725 A CN109706725 A CN 109706725A CN 201811540156 A CN201811540156 A CN 201811540156A CN 109706725 A CN109706725 A CN 109706725A
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China
Prior art keywords
dye formulation
agent
cloth
formulation according
corrosion
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CN201811540156.3A
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Chinese (zh)
Inventor
郑玉峰
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Tongxiang Sheng Li Textile Co Ltd
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Tongxiang Sheng Li Textile Co Ltd
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Priority to CN201811540156.3A priority Critical patent/CN109706725A/en
Publication of CN109706725A publication Critical patent/CN109706725A/en
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Abstract

The invention discloses a kind of anti-corrosion cloth dye formulations, including following constituent and its mass fraction are as follows: calcium carbonate 6-12%, ethyl alcohol 4-9%, polyamide 20-35%, Sodium Polyacrylate 1-5%, deionized water 8-21%, defoaming agent 1-2%, dye leveller 4-8%, pigment 15-25%, glacial acetic acid 1-2%, thickener 1-3%, emulsifier 1-4%, paraffin 3-5%, aluminium powder 5-9%, filler 4-8%, antibacterial agent 1-2%, soda acid agent 2-4%, antioxidant 2-4% and anionic antistatic agents 0.5-1.5%, steps are as follows for the mixed method of the dye formulation: step 1: calcium carbonate 6-12% being added in Xiang Hengwen agitator tank, ethyl alcohol 4-9%, polyamide 20-35%, polyacrylic acid Sodium 1-5% and deionized water 8-21%, controlled at 45-75 degrees Celsius.The addition that the present invention passes through antioxidant, oxidation resistant effect is reached, has avoided the situation of cloth aging easy to oxidize when permanent, to solve the problems, such as that traditional cloth dyestuff does not have corrosion resistance, and then the service life of cloth is extended, it is suitble to promote the use of.

Description

A kind of anti-corrosion cloth dye formulation
Technical field
The present invention relates to technical field of dye, specially a kind of anti-corrosion cloth dye formulation.
Background technique
Dyestuff, which refers to, can make other substances obtain distinct and securely color a kind of organic compound, due to what is used now Pigment be all it is artificial synthesized, so also referred to as synthetic dyestuffs.Dyestuff and pigment are typically all itself to have color, and can be with molecule State or dispersity make other substances obtain distinct and secured color compound.
It selects the various fibers of dyestuff due to nature difference according to fibre property, just needs to select phase when being dyed The dyestuff of adaptation.Such as when cotton fiber dyeing, due on its molecular structure containing there are many hydrophilic hydroxyls, it is easy to moisture absorption swollen Change, can with reactive group chemically reactive, and it is more alkaline-resisting, thus may be selected directly, reduction, vulcanization, the dye such as ice dye and activity Material dyeing.Terylene hydrophobicity is strong, not alkaline-resisting under high temperature, should not select the above dyestuff under normal circumstances, and should select disperse dyes It is dyed.It selects dyestuff since pollutant purposes is different according to pollutant purposes, therefore the fastness of dyeing product is required also not Together.The cloth for being used for example as curtain is seldom washed, but will often by solar radiation, therefore when dyeing, should select light fastness compared with High dyestuff.The light coloured fabrics dyeing worn as underwear and summer, due to often to wash, solarization, so should select washable, resistance to It shines, the higher dyestuff of color fastness to perspiration.Select dyestuff when selecting dyestuff according to cost of dye, it not only will be from coloured light and fastness Think, while to consider dyestuff and adjuvant used cost, the source of goods etc..Such as the higher dyestuff of price, should consider as far as possible with can contaminate Other dyestuffs for obtaining effect same are next alternative, to reduce production cost.The selection of dyestuff selects dye when needing colorant match when colorant match Material is it should be noted that the performances such as their ingredient, solubility, color fastness, dye-uptake.Since the dyeability of all kinds of dyestuffs is different, Dyeing effect often is influenced because of the difference of temperature, solubility, dye-uptake etc. in dyeing.When therefore carrying out colorant match, it is necessary to Dyestuff similar in performance is selected, and more more close better, the control of process conditions, the stabilization of dyeing quality can be conducive in this way. Select dyestuff due to dyeing machinery difference according to dyeing machinery performance, the property and requirement to dyestuff is not also identical.If be used for Dye gigging should select direct higher dyestuff;For pad dyeing, then direct lower dyestuff should be selected, before otherwise will generating The undesirable product such as shallow, uneven shade after depth.
Traditional cloth dyestuff does not have corrosion resistant function, is used for a long time or easily corrodes under corrosive environment Damage, service life is extremely short, while color fastness is also poor, the serious curtailment service life of cloth.
Summary of the invention
The purpose of the present invention is to provide a kind of anti-corrosion cloth dye formulations, to solve to propose in above-mentioned background technique The problem of.
To achieve the above object, the invention provides the following technical scheme: a kind of anti-corrosion cloth dye formulation, including such as Lower constituent and its mass fraction are as follows: calcium carbonate 6-12%, ethyl alcohol 4-9%, polyamide 20-35%, Sodium Polyacrylate 1- 5%, deionized water 8-21%, defoaming agent 1-2%, dye leveller 4-8%, pigment 15-25%, glacial acetic acid 1-2%, thickener 1-3%, emulsification Agent 1-4%, paraffin 3-5%, aluminium powder 5-9%, filler 4-8%, antibacterial agent 1-2%, soda acid agent 2-4%, antioxidant 2-4% and yin from Sub- antistatic agent 0.5-1.5%;
Steps are as follows for the mixed method of the dye formulation:
Step 1: calcium carbonate 6-12%, ethyl alcohol 4-9%, polyamide 20-35%, Sodium Polyacrylate are added in Xiang Hengwen agitator tank 1-5% and deionized water 8-21%, controlled at 45-75 degrees Celsius, control speed of agitator be 1200-1800r/min, stirring 0.5-1h;
Step 2: defoaming agent 1-2%, dye leveller 4-8%, pigment 15-25%, glacial acetic acid 1-2%, thickening are added in Xiang Hengwen agitator tank Agent 1-3%, emulsifier 1-4% and paraffin 3-5%, controlled at 60-80 degrees Celsius, control speed of agitator is 1000-1500r/ Min stirs 1-1.5h;
Step 3: aluminium powder 5-9%, filler 4-8%, antibacterial agent 1-2%, antioxidant 2-4% and yin are added in Xiang Hengwen agitator tank Ionic antistatic agent 0.5-1.5%, controlled at 45-60 degrees Celsius, control speed of agitator is 1300-1800r/min, stirring 0.5-1.5h;
Step 4: being slowly added to soda acid agent 2-4% in Xiang Hengwen agitator tank, controlled at 50-65 degrees Celsius, control stirring turns Speed is 300-800r/min, stirs 0.5-1h, adjusts PH to 6.5-7.5.
Preferably, the diameter of the aluminium powder is 1-10 microns.
Preferably, the thickener is one of casein, guar gum and chitosan.
Preferably, the antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate and lithium carbonate.
Preferably, the soda acid agent is using one of sodium hydroxide, potassium hydroxide and saleratus.
Preferably, the emulsifier is butyl acrylate, methyl methacrylate, lauryl sodium sulfate and poly alkyl alcohol One of oxyethylene group ether.
Preferably, the filler is anhydrous sodium sulphate.
Preferably, the dye leveller is paregal O.
Preferably, the antioxidant is one of titanium dioxide, carbon black and silica flour.
Preferably, the defoaming agent is emulsification silicon.
Compared with prior art, beneficial effects of the present invention are as follows:
1, the present invention has reached oxidation resistant effect, it is easy to oxidize when permanent to avoid cloth by the addition of antioxidant The situation of aging to solve the problems, such as that traditional cloth dyestuff does not have corrosion resistance, and then extends the use of cloth Service life is suitble to promote the use of.
2, the present invention can be greatly improved the antistatic property of cloth, in turn by the addition of anionic antistatic agents So that the cloth is used in some particular surroundings, substantially increases the applicability of the cloth.
3, the present invention can be improved the antibacterial effect of the cloth by the addition of antibacterial agent, can be avoided cloth growth On the one hand germ avoids the situation that germ causes people to infect, on the other hand avoid germ secretion corrosive substance and cause cloth The situation for expecting damage, to improve the safety of the cloth and extend the service life of the cloth.
Specific embodiment
Below in conjunction with the embodiment in the present invention, technical solution in the embodiment of the present invention is carried out clearly and completely Description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on this hair Embodiment in bright, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment one:
A kind of anti-corrosion cloth dye formulation, including following constituent and its mass fraction are as follows: calcium carbonate 8%, ethyl alcohol 5%, Polyamide 23%, Sodium Polyacrylate 3%, deionized water 14%, emulsification silicon 1.3%, paregal O 5%, pigment 18%, glacial acetic acid 1.3%, casein 2%, methyl methacrylate 2.4%, paraffin 3.8%, aluminium powder 6%, anhydrous sodium sulphate 5%, zinc oxide 1.2%, titanium dioxide 2.3%, anionic antistatic agents 0.8% and saleratus 1.2%;
Steps are as follows for the mixed method of above-mentioned mass fraction ratio dye formulation:
Step 1: in Xiang Hengwen agitator tank be added calcium carbonate 8%, ethyl alcohol 5%, polyamide 23%, Sodium Polyacrylate 3% and go from Sub- water 14%, controlled at 60 degrees Celsius, control speed of agitator is 1400r/min, stirs 0.8h;
Step 2: emulsification silicon 1.3%, paregal O 5%, pigment 18%, glacial acetic acid 1.3%, casein are added in Xiang Hengwen agitator tank 2%, methyl methacrylate 2.4% and paraffin 3.8%, controlled at 75 degrees Celsius, control speed of agitator is 1400r/min, is stirred Mix 1.2h;
Step 3: it is anti-that aluminium powder 6%, anhydrous sodium sulphate 5%, zinc oxide 1.2%, titanium dioxide 2.3% and anion are added in Xiang Hengwen agitator tank Electrostatic agent 0.8%, controlled at 50 degrees Celsius, control speed of agitator is 1500r/min, stirs 0.9h;
Step 4: being slowly added to saleratus 1.2% in Xiang Hengwen agitator tank, controlled at 55 degrees Celsius, controls speed of agitator For 500r/min, 0.6h is stirred, adjusts PH to 7.0.
Embodiment two: the difference of the present embodiment and above-described embodiment is:
A kind of anti-corrosion cloth dye formulation, including following constituent and its mass fraction are as follows: calcium carbonate 9%, ethyl alcohol 4%, Polyamide 26%, Sodium Polyacrylate 2%, deionized water 13%, emulsification silicon 1.5%, paregal O 6%, pigment 19%, glacial acetic acid 1%, Guar gum 2.2%, butyl acrylate 2.4%, paraffin 3.8%, aluminium powder 7%, anhydrous sodium sulphate 5%, copper oxide 1.5%, titanium dioxide 2.5%, yin from Sub- antistatic agent 0.9% and saleratus 1.5%;
Steps are as follows for the mixed method of above-mentioned mass fraction dye formulation:
Step 1: in Xiang Hengwen agitator tank be added calcium carbonate 9%, ethyl alcohol 4%, polyamide 26%, Sodium Polyacrylate 2% and go from Sub- water 13%, controlled at 55 degrees Celsius, control speed of agitator is 1400r/min, stirs 0.8h;
Step 2: emulsification silicon 1.5%, paregal O 6%, pigment 19%, glacial acetic acid 1%, guar gum are added in Xiang Hengwen agitator tank 2.2%, butyl acrylate 2.4% and paraffin 3.8%, controlled at 70 degrees Celsius, control speed of agitator is 1500r/min, stirring 1.5h;
Step 3: it is anti-that aluminium powder 7%, anhydrous sodium sulphate 5%, copper oxide 1.5%, titanium dioxide 2.5% and anion are added in Xiang Hengwen agitator tank Electrostatic agent 0.9%, controlled at 60 degrees Celsius, control speed of agitator is 1300r/min, stirs 0.9h;
Step 4: being slowly added to saleratus 1.5% in Xiang Hengwen agitator tank, controlled at 50 degrees Celsius, controls speed of agitator For 550r/min, 0.7h is stirred, adjusts PH to 7.0.
Embodiment three: the difference of the present embodiment and above-described embodiment is:
A kind of anti-corrosion cloth dye formulation, including following constituent and its mass fraction are as follows: calcium carbonate 7%, ethyl alcohol 5%, Polyamide 20%, Sodium Polyacrylate 5%, deionized water 15%, emulsification silicon 1.5%, paregal O 5.2%, pigment 17%, glacial acetic acid 1.8%, chitosan 2.1%, lauryl sodium sulfate 2.1%, paraffin 3.5%, aluminium powder 8%, anhydrous sodium sulphate 4%, ammonium dihydrogen phosphate 1.4%, titanium White powder 2.5%, anionic antistatic agents 1% and saleratus 1.5%;
Steps are as follows for the mixed method of above-mentioned mass fraction ratio dye formulation:
Step 1: in Xiang Hengwen agitator tank be added calcium carbonate 7%, ethyl alcohol 5%, polyamide 20%, Sodium Polyacrylate 5% and go from Sub- water 15%, controlled at 70 degrees Celsius, control speed of agitator is 1300r/min, stirs 1.3h;
Step 2: emulsification silicon 1.5%, paregal O 5.2%, pigment 17%, glacial acetic acid 1.8%, chitosan are added in Xiang Hengwen agitator tank 2.1%, lauryl sodium sulfate 2.1% and paraffin 3.5%, controlled at 70 degrees Celsius, control speed of agitator is 1550r/min, Stir 1.5h;
Step 3: in Xiang Hengwen agitator tank be added aluminium powder 8%, anhydrous sodium sulphate 4%, ammonium dihydrogen phosphate 1.4%, titanium dioxide 2.5% and yin from Sub- 1 % of antistatic agent, controlled at 55 degrees Celsius, control speed of agitator is 1600r/min, stirs 0.7h;
Step 4: being slowly added to saleratus 1.5% in Xiang Hengwen agitator tank, controlled at 45 degrees Celsius, controls speed of agitator For 600r/min, 0.5h is stirred, adjusts PH to 7.0.
In summary: the anti-corrosion cloth dye formulation has reached oxidation resistant effect by the addition of antioxidant Fruit, avoids the situation of cloth aging easy to oxidize when permanent, thus solve traditional cloth dyestuff do not have it is corrosion-resistant Property the problem of, and then extend the service life of cloth, be suitble to promote the use of, can by the addition of anionic antistatic agents The antistatic property of cloth is substantially increased, and then the cloth is enable to use in some particular surroundings, substantially increases the cloth The applicability of material can be improved the antibacterial effect of the cloth by the addition of antibacterial agent, can be avoided cloth and breeds germ, On the one hand the situation that germ causes people to infect is avoided, germ secretion corrosive substance is on the other hand avoided and cloth is caused to damage Situation, to improve the safety of the cloth and extend the service life of the cloth.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (10)

1. a kind of anti-corrosion cloth dye formulation, it is characterised in that: including following constituent and its mass fraction are as follows: carbonic acid Calcium 6-12%, ethyl alcohol 4-9%, polyamide 20-35%, Sodium Polyacrylate 1-5%, deionized water 8-21%, defoaming agent 1-2%, Stain 4-8%, pigment 15-25%, glacial acetic acid 1-2%, thickener 1-3%, emulsifier 1-4%, paraffin 3-5%, aluminium powder 5-9%, filler 4-8%, antibacterial agent 1-2%, soda acid agent 2-4%, antioxidant 2-4% and anionic antistatic agents 0.5-1.5%;
Steps are as follows for the mixed method of the dye formulation:
Step 1: calcium carbonate 6-12%, ethyl alcohol 4-9%, polyamide 20-35%, Sodium Polyacrylate are added in Xiang Hengwen agitator tank 1-5% and deionized water 8-21%, controlled at 45-75 degrees Celsius, control speed of agitator be 1200-1800r/min, stirring 0.5-1h;
Step 2: defoaming agent 1-2%, dye leveller 4-8%, pigment 15-25%, glacial acetic acid 1-2%, thickening are added in Xiang Hengwen agitator tank Agent 1-3%, emulsifier 1-4% and paraffin 3-5%, controlled at 60-80 degrees Celsius, control speed of agitator is 1000-1500r/ Min stirs 1-1.5h;
Step 3: aluminium powder 5-9%, filler 4-8%, antibacterial agent 1-2%, antioxidant 2-4% and yin are added in Xiang Hengwen agitator tank Ionic antistatic agent 0.5-1.5%, controlled at 45-60 degrees Celsius, control speed of agitator is 1300-1800r/min, stirring 0.5-1.5h;
Step 4: being slowly added to soda acid agent 2-4% in Xiang Hengwen agitator tank, controlled at 50-65 degrees Celsius, control stirring turns Speed is 300-800r/min, stirs 0.5-1h, adjusts PH to 6.5-7.5.
2. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the diameter of the aluminium powder is 1-10 microns.
3. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the thickener is cheese One of element, guar gum and chitosan.
4. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the antibacterial agent is oxidation One of zinc, copper oxide, ammonium dihydrogen phosphate and lithium carbonate.
5. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the soda acid agent uses hydrogen One of sodium oxide molybdena, potassium hydroxide and saleratus.
6. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the emulsifier is propylene One of acid butyl ester, methyl methacrylate, lauryl sodium sulfate and fatty alcohol polyoxyethylene ether.
7. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the filler is that member is bright Powder.
8. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the dye leveller is average Add O.
9. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the antioxidant is titanium One of white powder, carbon black and silica flour.
10. a kind of anti-corrosion cloth dye formulation according to claim 1, it is characterised in that: the defoaming agent is cream SiClx.
CN201811540156.3A 2018-12-17 2018-12-17 A kind of anti-corrosion cloth dye formulation Pending CN109706725A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111691206A (en) * 2020-06-30 2020-09-22 东莞职业技术学院 Cloth dye with good antibacterial effect
CN113417152A (en) * 2021-06-30 2021-09-21 嘉兴市腾旺染整有限公司 Dyeing and finishing formula and stirring equipment
CN114891364A (en) * 2021-06-18 2022-08-12 东阳市神农纺织品有限公司 Organic plant dye and preparation method and application thereof

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CN107722715A (en) * 2017-09-27 2018-02-23 安徽金星包装有限公司 A kind of packages printing dyestuff
CN107778917A (en) * 2016-08-30 2018-03-09 江苏吉华化工有限公司 A kind of disperse dye composition
CN107793789A (en) * 2016-08-30 2018-03-13 江苏吉华化工有限公司 A kind of aroma type disperse dyes
CN108441118A (en) * 2018-03-22 2018-08-24 徐州巨龙新材料科技有限公司 A kind of high calcium chemistry painting industry

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
CN106479361A (en) * 2015-08-26 2017-03-08 盐城市瓯华化学工业有限公司 A kind of chemistry painting industry
CN106634286A (en) * 2015-10-30 2017-05-10 什邡市美的家木业有限责任公司 Antibacterial furniture paint
CN105544207A (en) * 2016-01-12 2016-05-04 中山市绿浪助剂有限公司 Water-based textile dyeing antibacterial auxiliary
CN107778917A (en) * 2016-08-30 2018-03-09 江苏吉华化工有限公司 A kind of disperse dye composition
CN107793789A (en) * 2016-08-30 2018-03-13 江苏吉华化工有限公司 A kind of aroma type disperse dyes
CN106978736A (en) * 2017-05-09 2017-07-25 南通薇星纺织科技有限公司 A kind of dye formulation not easy to fade
CN107722715A (en) * 2017-09-27 2018-02-23 安徽金星包装有限公司 A kind of packages printing dyestuff
CN108441118A (en) * 2018-03-22 2018-08-24 徐州巨龙新材料科技有限公司 A kind of high calcium chemistry painting industry

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111691206A (en) * 2020-06-30 2020-09-22 东莞职业技术学院 Cloth dye with good antibacterial effect
CN114891364A (en) * 2021-06-18 2022-08-12 东阳市神农纺织品有限公司 Organic plant dye and preparation method and application thereof
CN113417152A (en) * 2021-06-30 2021-09-21 嘉兴市腾旺染整有限公司 Dyeing and finishing formula and stirring equipment

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Application publication date: 20190503