CN107815251B - Protective wax for preventing copper statue from generating verdigris and preparation process thereof - Google Patents
Protective wax for preventing copper statue from generating verdigris and preparation process thereof Download PDFInfo
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- CN107815251B CN107815251B CN201711225414.4A CN201711225414A CN107815251B CN 107815251 B CN107815251 B CN 107815251B CN 201711225414 A CN201711225414 A CN 201711225414A CN 107815251 B CN107815251 B CN 107815251B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
Abstract
The invention relates to a protective wax for preventing copper statues from generating verdigris and a preparation process thereof, wherein the protective wax comprises the following components in parts by weight: 50-80 parts of palm wax and 30-60 parts of silicone oil; the palm wax comprises: 20-40 parts of fatty acid ester, 6-20 parts of hydroxy fatty acid ester, 30-50 parts of p-methoxy cinnamate and 50-80 parts of p-hydroxy cinnamic diester. According to the invention, the surface of the processed copper sculpture is coated with the layer containing wax, so that the copper sculpture can be isolated from water and oxygen in the air, the copper sculpture exposed in the air and rain for a long time can not be subjected to chemical reaction with water, oxygen and the like to generate verdigris, and the attractiveness of the copper sculpture is improved.
Description
Technical Field
The invention relates to the technical field of statues, in particular to a protective wax for preventing copper statues from generating verdigris and a preparation process thereof.
Background
Whether the copper sculpture or the forged copper sculpture can rust as long as the copper sculpture is placed in the air for a long time. The copper is oxidized into black copper oxide in the humid air, and the copper oxide on the surface of the cast copper continuously reacts with carbon dioxide in the air to generate a layer of verdigris. In addition, copper also reacts with hydrogen sulfide in the air to form black copper sulfide. Verdigris is basic copper carbonate with a chemical formula of Cu2(OH)2CO3, also known as malachite, and is a precious mineral gem. Verdigris generated on the surface of the copper sculpture is emerald green, and the attractiveness of the copper sculpture is affected. Therefore, there is a need in the industry for a method of preventing the formation of verdigris from a source.
Disclosure of Invention
In order to overcome the defects that the copper sculpture surface generates verdigris and the appearance of the copper sculpture is affected in the prior art, the invention provides the protective wax for preventing the copper sculpture from generating the verdigris and the preparation process thereof.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 50-80 parts of palm wax and 30-60 parts of silicone oil; the palm wax comprises: 20-40 parts of fatty acid ester, 6-20 parts of hydroxy fatty acid ester, 30-50 parts of p-methoxy cinnamate and 50-80 parts of p-hydroxy cinnamic diester.
Preferably, the composition comprises the following components in parts by weight: 60-70 parts of palm wax and 40-50 parts of silicone oil; the palm wax comprises: 25-35 parts of fatty acid ester, 10-18 parts of hydroxy fatty acid ester, 36-45 parts of p-methoxy cinnamate and 60-70 parts of p-hydroxy cinnamic diester.
Preferably, the composition comprises the following components in parts by weight: 65 parts of palm wax and 45 parts of silicone oil; the palm wax comprises: 30 parts of fatty acid ester, 15 parts of hydroxy fatty acid ester, 40 parts of p-methoxy cinnamate and 65 parts of p-hydroxy cinnamic diester.
Preferably, the composition further comprises the following components in parts by weight: 0.6-6 parts of antistatic agent.
Preferably, the antistatic agent is an internal mixing type antistatic agent.
Preferably, the silicone oil is methyl silicone oil.
Preferably, the silicone oil is a modified silicone oil.
A preparation process of protective wax for preventing copper statues from generating verdigris comprises the following steps: placing the materials with the formula amount in a batching tank with a jacket and a stirrer; stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to a first temperature; after the materials are completely dissolved, cooling water is introduced into the jacket; after the temperature of the materials in the batching tank is reduced to a second temperature, uniformly stirring the materials in the batching tank; and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
Preferably, the first temperature is 100 degrees.
Preferably, the second temperature is 25 degrees.
The invention has the beneficial effects that: according to the invention, the surface of the processed copper sculpture is coated with the layer containing wax, so that the copper sculpture can be isolated from water and oxygen in the air, the copper sculpture exposed in the air and rain for a long time can not be subjected to chemical reaction with water, oxygen and the like to generate verdigris, and the attractiveness of the copper sculpture is improved. Moreover, through detection, the protective wax has strong adhesion and adherence and is not easy to fall off.
Detailed Description
Example 1
A protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 50 parts of palm wax, 0.6 part of antistatic agent and 30 parts of silicone oil; the palm wax comprises: 20 parts of fatty acid ester, 6 parts of hydroxy fatty acid ester, 30 parts of p-methoxy cinnamate and 50 parts of p-hydroxy cinnamic diester.
Wherein the antistatic agent is an internal mixing type antistatic agent. The silicone oil is methyl silicone oil.
The preparation process of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
placing the materials with the formula amount in a batching tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to 100 ℃;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to 25 ℃, uniformly stirring the materials in the batching tank;
and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
The application method of the protective wax for preventing the copper statues from generating the verdigris is as follows:
polishing the processed copper sculpture;
dipping the protective wax by sponge and uniformly coating the protective wax on the surface of the polished copper sculpture;
after waiting for 1 minute, wiping the polished surface of the copper sculpture by using sponge stained with the protective wax;
until the bronze statue is bright.
Example 2
A protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 80 parts of palm wax, 6 parts of antistatic agent and 60 parts of silicone oil; the palm wax comprises: 40 parts of fatty acid ester, 20 parts of hydroxy fatty acid ester, 50 parts of p-methoxy cinnamate and 80 parts of p-hydroxy cinnamic diester.
Wherein the antistatic agent is an internal mixing type antistatic agent. The silicone oil is methyl silicone oil.
The preparation process of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
placing the materials with the formula amount in a batching tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to 100 ℃;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to 25 ℃, uniformly stirring the materials in the batching tank;
and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
The application method of the protective wax for preventing the copper statues from generating the verdigris is as follows:
polishing the processed copper sculpture;
dipping the protective wax by sponge and uniformly coating the protective wax on the surface of the polished copper sculpture;
waiting for 5 minutes, wiping the polished surface of the copper sculpture by using sponge stained with the protective wax;
until the bronze statue is bright.
Example 3
A protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 60 parts of palm wax, 4 parts of antistatic agent and 40 parts of silicone oil; the palm wax comprises: 25 parts of fatty acid ester, 10 parts of hydroxy fatty acid ester, 36 parts of p-methoxy cinnamate and 60 parts of p-hydroxy cinnamic diester.
Wherein the antistatic agent is an internal mixing type antistatic agent. The silicone oil is modified silicone oil.
The preparation process of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
placing the materials with the formula amount in a batching tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to 100 ℃;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to 25 ℃, uniformly stirring the materials in the batching tank;
and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
The application method of the protective wax for preventing the copper statues from generating the verdigris is as follows:
polishing the processed copper sculpture;
dipping the protective wax by sponge and uniformly coating the protective wax on the surface of the polished copper sculpture;
waiting for 3 minutes, wiping the polished surface of the copper sculpture by using sponge stained with the protective wax;
until the bronze statue is bright.
Example 4
A protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 70 parts of palm wax, 4 parts of antistatic agent and 50 parts of silicone oil; the palm wax comprises: 35 parts of fatty acid ester, 18 parts of hydroxy fatty acid ester, 45 parts of p-methoxy cinnamate and 70 parts of p-hydroxy cinnamic diester.
Wherein the antistatic agent is an internal mixing type antistatic agent. The silicone oil is modified silicone oil.
The preparation process of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
placing the materials with the formula amount in a batching tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to 100 ℃;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to 25 ℃, uniformly stirring the materials in the batching tank;
and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
The application method of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
polishing the processed copper sculpture;
dipping the protective wax by sponge and uniformly coating the protective wax on the surface of the polished copper sculpture;
waiting for 3 minutes, wiping the polished surface of the copper sculpture by using sponge stained with the protective wax;
until the bronze statue is bright.
Example 5
A protective wax for preventing copper figurines from generating verdigris comprises the following components in parts by weight: 65 parts of palm wax, 4 parts of antistatic agent and 45 parts of silicone oil; the palm wax comprises: 30 parts of fatty acid ester, 15 parts of hydroxy fatty acid ester, 40 parts of p-methoxy cinnamate and 65 parts of p-hydroxy cinnamic diester.
Wherein the antistatic agent is an internal mixing type antistatic agent. The silicone oil is modified silicone oil.
The preparation process of the protective wax for preventing the copper statue from generating the verdigris comprises the following steps:
placing the materials with the formula amount in a batching tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to 100 ℃;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to 25 ℃, uniformly stirring the materials in the batching tank;
and (5) sending the materials in the batching tank out to a filling machine, and filling and packaging to obtain the finished product protective wax.
The application method of the protective wax for preventing the copper statues from generating the verdigris is as follows:
polishing the processed copper sculpture;
dipping the protective wax by sponge and uniformly coating the protective wax on the surface of the polished copper sculpture;
waiting for 3 minutes, wiping the polished surface of the copper sculpture by using sponge stained with the protective wax;
until the bronze statue is bright.
Test data
The method comprises the steps of setting a test group 1, a test group 2, a test group 3, a test group 4, a test group 5 and a control group, wherein the test group 1 is to coat the protective wax of the embodiment 1 on the surface of the copper sculpture, the test group 2 is to coat the protective wax of the embodiment 2 on the surface of the copper sculpture, the test group 3 is to coat the protective wax of the embodiment 3 on the surface of the copper sculpture, the test group 4 is to coat the protective wax of the embodiment 4 on the surface of the copper sculpture, the test group 5 is to coat the protective wax of the embodiment 5 on the surface of the copper sculpture, the control group is to coat nothing on the surface of the copper sculpture, all the test groups are uniformly exposed in the air, and the copper sculpture surface of each group is observed to generate the verdigris every three months and 2 years.
After the experimental group 1 is placed for 18 months, a little of verdigris spots appear on the surface of the copper sculpture, a little of verdigris appears after 21 months, a little of verdigris appears after 24 months, and the verdigris on the copper sculpture is basically negligible.
The experimental group 2 showed a few of verdigris spots after being placed for 21 months, and showed a few of verdigris after 24 months, and the verdigris on the copper sculpture was basically negligible.
The experimental group 3 showed a few of verdigris spots after being placed for 21 months, and showed a few of verdigris after 24 months, and the verdigris on the copper sculpture was basically negligible.
Little mottle of verdigris appeared after 24 months of storage in experimental group 4, and the verdigris on the copper sculpture was essentially negligible.
The experimental group 5 showed no appearance of verdigris on the surface of the copper sculpture after 24 months of standing.
After the control group is placed for 6 months, a few of verdigris spots appear on the surface of the copper sculpture, a small amount of verdigris appears after 9 months, more parts of the copper sculpture have large areas after 12 months, and the area of the verdigris on the surface of the copper sculpture reaches 2% after 15 months. The area of the verdigris on the surface of the copper sculpture reaches 5 percent after 24 months.
In addition, after the protective wax for preventing the copper sculpture from generating the verdigris is coated by the method, the protective wax is still coated on the surface of the copper sculpture in an intact state after 2 years of detection, which shows that the protective wax has good adhesion and adherence. The detection method comprises the following steps:
and (3) after the coated protective wax is dried, scraping the protective wax on the surface of the copper sculpture with a certain area by using a knife, and measuring the weight of the scraped protective wax. After 2 years, the same area of the protective wax on the surface of the copper sculpture was scratched in the same manner, and the weight of the protective wax scratched off at this time was measured. The weight of the protective wax scraped off immediately after coating was compared with the weight of the protective wax scraped off after a lapse of 2 years, and it was found that the weights of both were the same.
In conclusion, the protective wax is coated on the surface of the copper sculpture, so that the copper sculpture and water and oxygen in the air can be well prevented from generating chemical reaction to generate verdigris, and the protective wax has good adhesion and adherence and is not easy to fall off.
In light of the foregoing description of the preferred embodiment of the present invention, many modifications and variations will be apparent to those skilled in the art without departing from the spirit and scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.
Claims (6)
1. A protective wax for preventing copper statues from generating verdigris, which is characterized by comprising the following components in parts by weight: 50-80 parts of palm wax and 30-60 parts of silicone oil;
the palm wax comprises: 20-40 parts of fatty acid ester, 6-20 parts of hydroxy fatty acid ester, 30-50 parts of p-methoxy cinnamate and 50-80 parts of p-hydroxy cinnamic diester;
further comprising: 0.6-6 parts of antistatic agent; the antistatic agent is an internal mixing type antistatic agent.
2. The protective wax for preventing the generation of verdigris from bronze statues according to claim 1, comprising, by weight: 60-70 parts of palm wax and 40-50 parts of silicone oil;
the palm wax comprises: 25-35 parts of fatty acid ester, 10-18 parts of hydroxy fatty acid ester, 36-45 parts of p-methoxy cinnamate and 60-70 parts of p-hydroxy cinnamic diester.
3. The protective wax for preventing the generation of verdigris from bronze statues according to claim 1, comprising, by weight: 65 parts of palm wax and 45 parts of silicone oil;
the palm wax comprises: 30 parts of fatty acid ester, 15 parts of hydroxy fatty acid ester, 40 parts of p-methoxy cinnamate and 65 parts of p-hydroxy cinnamic diester.
4. The protective wax for preventing the formation of verdigris from cuprammrons according to claim 1, wherein the silicone oil is methyl silicone oil.
5. The protective wax for preventing cuprammrons from generating verdigris according to claim 1, wherein the silicone oil is a modified silicone oil.
6. A preparation process of protective wax for preventing copper statues from generating verdigris is characterized by comprising the following steps:
placing the material of any one of claims 1-5 in a dispensing tank with a jacket and a stirrer;
stirring the materials, and introducing steam into a jacket for heating to raise the temperature of the materials to a first temperature;
after the materials are completely dissolved, cooling water is introduced into the jacket;
after the temperature of the materials in the batching tank is reduced to a second temperature, uniformly stirring the materials in the batching tank;
sending out the materials in the batching tank to a filling machine, and filling and packaging to obtain finished product protective wax;
the first temperature is 100 ℃;
the second temperature is 25 degrees.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711225414.4A CN107815251B (en) | 2017-11-29 | 2017-11-29 | Protective wax for preventing copper statue from generating verdigris and preparation process thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711225414.4A CN107815251B (en) | 2017-11-29 | 2017-11-29 | Protective wax for preventing copper statue from generating verdigris and preparation process thereof |
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| CN107815251A CN107815251A (en) | 2018-03-20 |
| CN107815251B true CN107815251B (en) | 2020-06-05 |
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| CN111376635A (en) * | 2018-12-27 | 2020-07-07 | 杭州朱炳仁文化艺术有限公司 | Purple gold copper carving process |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278894A (en) * | 2008-05-23 | 2008-10-08 | 海南京润珍珠生物技术股份有限公司 | Sun cream containing liposome component of hydrolyzed pearl solution |
| CN101760139A (en) * | 2009-12-24 | 2010-06-30 | 珠海市虹彩精细化工有限公司 | Furniture glossing care aerosol wax with antimicrobial function and preparation method thereof |
| CN103361195A (en) * | 2013-08-03 | 2013-10-23 | 山东丽波日化股份有限公司 | Cleaning-waxing-integrated washing agent for automobile and preparation method thereof |
| CN103666279A (en) * | 2012-09-24 | 2014-03-26 | 天津博克尼科技发展有限公司 | Anti-static vehicle paint surface body polishing emulsion wax |
| CN103694869A (en) * | 2013-12-07 | 2014-04-02 | 铜陵新九鼎铜文化产业有限公司 | Temperature-resistant wear-resistant alkyd resin paint for copper sculpture |
| CN104231942A (en) * | 2014-09-10 | 2014-12-24 | 南京信息工程大学 | Antistatic decontaminating car wax and preparation method of antistatic decontaminating car wax |
| CN104403560A (en) * | 2014-12-15 | 2015-03-11 | 3M中国有限公司 | Coating composition, coating as well as preparation method and application thereof |
| CN104710881A (en) * | 2015-02-13 | 2015-06-17 | 中山市优贝汽车用品科技有限公司 | Automobile glazing protection solid wax containing active ingredients and preparation method thereof |
| CN104745010A (en) * | 2015-03-10 | 2015-07-01 | 深圳市彩虹精细化工股份有限公司 | Water-in-oil type solid automobile glazing protective wax and preparation method thereof |
| CN106065284A (en) * | 2016-05-26 | 2016-11-02 | 合肥市田源精铸有限公司 | A kind of oil base automobile rust-proofing wax |
| CN106479701A (en) * | 2016-10-14 | 2017-03-08 | 珠海巴陆信息科技有限公司 | Waterless nano automobile clean care agent |
| CN106867414A (en) * | 2015-12-11 | 2017-06-20 | 张美玲 | A kind of UV resistance decontamination car wax |
| CN107129666A (en) * | 2017-05-24 | 2017-09-05 | 张敏 | A kind of handicraft carving material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101711636B1 (en) * | 2015-08-25 | 2017-03-02 | 주식회사 디와이엠 솔루션 | Room Temperature Cross linking Type, Halogen-free Flame Retardant Composition and manufacturing method thereof |
-
2017
- 2017-11-29 CN CN201711225414.4A patent/CN107815251B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278894A (en) * | 2008-05-23 | 2008-10-08 | 海南京润珍珠生物技术股份有限公司 | Sun cream containing liposome component of hydrolyzed pearl solution |
| CN101760139A (en) * | 2009-12-24 | 2010-06-30 | 珠海市虹彩精细化工有限公司 | Furniture glossing care aerosol wax with antimicrobial function and preparation method thereof |
| CN103666279A (en) * | 2012-09-24 | 2014-03-26 | 天津博克尼科技发展有限公司 | Anti-static vehicle paint surface body polishing emulsion wax |
| CN103361195A (en) * | 2013-08-03 | 2013-10-23 | 山东丽波日化股份有限公司 | Cleaning-waxing-integrated washing agent for automobile and preparation method thereof |
| CN103694869A (en) * | 2013-12-07 | 2014-04-02 | 铜陵新九鼎铜文化产业有限公司 | Temperature-resistant wear-resistant alkyd resin paint for copper sculpture |
| CN104231942A (en) * | 2014-09-10 | 2014-12-24 | 南京信息工程大学 | Antistatic decontaminating car wax and preparation method of antistatic decontaminating car wax |
| CN104403560A (en) * | 2014-12-15 | 2015-03-11 | 3M中国有限公司 | Coating composition, coating as well as preparation method and application thereof |
| CN104710881A (en) * | 2015-02-13 | 2015-06-17 | 中山市优贝汽车用品科技有限公司 | Automobile glazing protection solid wax containing active ingredients and preparation method thereof |
| CN104745010A (en) * | 2015-03-10 | 2015-07-01 | 深圳市彩虹精细化工股份有限公司 | Water-in-oil type solid automobile glazing protective wax and preparation method thereof |
| CN106867414A (en) * | 2015-12-11 | 2017-06-20 | 张美玲 | A kind of UV resistance decontamination car wax |
| CN106065284A (en) * | 2016-05-26 | 2016-11-02 | 合肥市田源精铸有限公司 | A kind of oil base automobile rust-proofing wax |
| CN106479701A (en) * | 2016-10-14 | 2017-03-08 | 珠海巴陆信息科技有限公司 | Waterless nano automobile clean care agent |
| CN107129666A (en) * | 2017-05-24 | 2017-09-05 | 张敏 | A kind of handicraft carving material |
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|---|---|
| CN107815251A (en) | 2018-03-20 |
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Address after: 510000 Jiangnan village, South Village, Panyu District, Guangzhou, Guangdong Applicant after: Guangdong gilming culture and Art Co., Ltd. Address before: 510000 Jiangnan village, South Village, Panyu District, Guangzhou, Guangdong Applicant before: Guangdong Liu Ming sculpture Co. Ltd. |
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