CN103694869A - Temperature-resistant wear-resistant alkyd resin paint for copper sculpture - Google Patents
Temperature-resistant wear-resistant alkyd resin paint for copper sculpture Download PDFInfo
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- CN103694869A CN103694869A CN201310671982.2A CN201310671982A CN103694869A CN 103694869 A CN103694869 A CN 103694869A CN 201310671982 A CN201310671982 A CN 201310671982A CN 103694869 A CN103694869 A CN 103694869A
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Abstract
The invention relates to paint and in particular relates to temperature-resistant wear-resistant alkyd resin paint for a copper sculpture. The paint is prepared from the following raw materials in parts by weight: 30-34 parts of long oil length alkyd resin, 2-3 parts of p-aminophenol, 5-8 parts of methyl parahydroxybenzoats, 2-3 parts of isoporopyl myristate, 20-25 parts of aromatic polyurethane acrylate, 1-2 parts of acetylsalicylic acid, 1-2 parts of N-hydroxymethyl acrylamide, 2-3 parts of polyethylene glycol, 3-4 parts of KH-560 silane coupling agent, 4-5 parts of molybdenum disulfide, 5-8 parts of paraffin, 10-12 parts of acrylic acid-2-propylparaben, 2-3 parts of isopropyl oleic acid acyloxy(dioctyl phosphate acyloxy) titanate, 1-2 parts of methyl tin mercaptide, 5-6 parts of aids, 10-12 parts of dimethylbenzene and 10-12 parts of butyl acetate. The paint film has the advantages of high metal adhesive force, brightness, fullness, high lubricating property, high wear resistance, high temperature change resistance, high environment corrosion ageing resistance and relatively simple production process and is widely applied for protecting copper sculpture artware in various environments.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to heat-resistant, wear-resistant Synolac paint and preparation technology thereof for a kind of copper sculpture.
Background technology
Copper sculpture is a class artwork common in daily life, there is higher artistic value and enjoying value, yet, copper sculpture artwork is due to itself material character and the feature of putting environment, easily there is the problems such as oxidation corrosion, affect attractive in appearance and work-ing life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and copper sculpture is had to certain requirement with paint, such as sticking power, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, make the paint that is applicable to different use occasions, increase its artistic value.
Summary of the invention
The object of the invention is to, heat-resistant, wear-resistant Synolac paint for a kind of copper sculpture is provided, to protect sculpture, to achieve these goals, the technical solution used in the present invention is as follows:
Heat-resistant, wear-resistant Synolac paint for a kind of copper sculpture, it is characterized in that, material of the present invention is made by the raw material of following weight part: long oil alkyd 30-34, p-aminophenol 2-3, methyl p-hydroxybenzoate 5-8, nutmeg isopropyl propionate 2-3, aromatic urethane acrylic acid ester 20-25, acetylsalicylic acid 1-2, N hydroxymethyl acrylamide 1-2, polyoxyethylene glycol 2-3, KH-560 silane coupling agent 3-4, molybdenumdisulphide 4-5, paraffin 5-8, 2-hydroxypropyl acrylate 10-12, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 2-3, Methyl stannum mercaptide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.
Described auxiliary agent is made by the raw material of following weight part: clay 10-14, Nanoscale Iron slag powders 1-2, captax 3-4, phenyl triethoxysilane 2-3, Sodium orthomolybdate 1-2, magnetite 2-3, Sodium Benzoate 1-2, tributyl citrate 35-40, Tenox PG 2-3, coix seed oil 3-4, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into clay, magnetite in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
Heat-resistant, wear-resistant Synolac paint for described a kind of copper sculpture, its preparation technology is:
(1) methyl p-hydroxybenzoate, acetylsalicylic acid, polyoxyethylene glycol, molybdenumdisulphide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds nutmeg isopropyl propionate, 2-hydroxypropyl acrylate, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Compared with prior art, copper sculpture provided by the invention is painted possesses following advantage: the strong adhesion of paint film and metal, and light is full, oilness is good, wear-resistant, temperature-change resistance, environmental corrosion resisting is aging, and production technique is relatively simple, can be widely used in all kinds of copper carving handicraft articles of protection.
Embodiment
Embodiment
The present embodiment paint is made by following weight part raw material: long oil alkyd 34, p-aminophenol 3, methyl p-hydroxybenzoate 8, nutmeg isopropyl propionate 3, aromatic urethane acrylic acid ester 25, acetylsalicylic acid 2, N hydroxymethyl acrylamide 2, polyoxyethylene glycol 3, KH-560 silane coupling agent 4, molybdenumdisulphide 5, paraffin 8, 2-hydroxypropyl acrylate 12, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 3, Methyl stannum mercaptide 2, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.
Described auxiliary agent is made by the raw material of following weight part: clay 14, Nanoscale Iron slag powders 2, captax 4, phenyl triethoxysilane 3, Sodium orthomolybdate 2, magnetite 3, Sodium Benzoate 2, tributyl citrate 40, Tenox PG 3, coix seed oil 4, vanadium diboride 2, l-Epicatechol 3; Preparation method sends into clay, magnetite in calcining furnace and at 720-740 ℃, calcines 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.
Heat-resistant, wear-resistant Synolac paint for described a kind of copper sculpture, its preparation technology is:
(1) methyl p-hydroxybenzoate, acetylsalicylic acid, polyoxyethylene glycol, molybdenumdisulphide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;
(2) material of step (1) is cooled to 70-85 ℃, adds nutmeg isopropyl propionate, 2-hydroxypropyl acrylate, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 50 μ m slurries, obtains.
The performance test results of the present invention's paint is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a copper sculpture paints with heat-resistant, wear-resistant Synolac, it is characterized in that, this paint is made by the raw material of following weight part: long oil alkyd 30-34, p-aminophenol 2-3, methyl p-hydroxybenzoate 5-8, nutmeg isopropyl propionate 2-3, aromatic urethane acrylic acid ester 20-25, acetylsalicylic acid 1-2, N hydroxymethyl acrylamide 1-2, polyoxyethylene glycol 2-3, KH-560 silane coupling agent 3-4, molybdenumdisulphide 4-5, paraffin 5-8, 2-hydroxypropyl acrylate 10-12, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester 2-3, Methyl stannum mercaptide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,
Described auxiliary agent is made by the raw material of following weight part: clay 10-14, Nanoscale Iron slag powders 1-2, captax 3-4, phenyl triethoxysilane 2-3, Sodium orthomolybdate 1-2, magnetite 2-3, Sodium Benzoate 1-2, tributyl citrate 35-40, Tenox PG 2-3, coix seed oil 3-4, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into clay, magnetite in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
2. a kind of copper sculpture as claimed in claim 1 paints with heat-resistant, wear-resistant Synolac, and its manufacture craft is:
(1) methyl p-hydroxybenzoate, acetylsalicylic acid, polyoxyethylene glycol, molybdenumdisulphide, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds nutmeg isopropyl propionate, 2-hydroxypropyl acrylate, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanic acid ester, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671982.2A CN103694869B (en) | 2013-12-07 | 2013-12-07 | Heat-resistant, wear-resistant alkyd resins paint for a kind of copper sculpture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671982.2A CN103694869B (en) | 2013-12-07 | 2013-12-07 | Heat-resistant, wear-resistant alkyd resins paint for a kind of copper sculpture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103694869A true CN103694869A (en) | 2014-04-02 |
| CN103694869B CN103694869B (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310671982.2A Active CN103694869B (en) | 2013-12-07 | 2013-12-07 | Heat-resistant, wear-resistant alkyd resins paint for a kind of copper sculpture |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085163A (en) * | 2016-08-05 | 2016-11-09 | 吴静 | The preparation method of alkyd resin wood lacquer |
| CN107815251A (en) * | 2017-11-29 | 2018-03-20 | 广东鎏明雕塑有限公司 | A kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63256664A (en) * | 1987-04-15 | 1988-10-24 | Mitsubishi Oil Co Ltd | Alkyd resin paint composition |
| CN102702874A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anticorrosive coating |
-
2013
- 2013-12-07 CN CN201310671982.2A patent/CN103694869B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63256664A (en) * | 1987-04-15 | 1988-10-24 | Mitsubishi Oil Co Ltd | Alkyd resin paint composition |
| CN102702874A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Anticorrosive coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085163A (en) * | 2016-08-05 | 2016-11-09 | 吴静 | The preparation method of alkyd resin wood lacquer |
| CN107815251A (en) * | 2017-11-29 | 2018-03-20 | 广东鎏明雕塑有限公司 | A kind of protection wax and its preparation technology for preventing statue in bronze generation verdigris |
| CN107815251B (en) * | 2017-11-29 | 2020-06-05 | 广东鎏明文化艺术有限公司 | Protective wax for preventing copper statue from generating verdigris and preparation process thereof |
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| Publication number | Publication date |
|---|---|
| CN103694869B (en) | 2016-05-04 |
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Denomination of invention: Temperature-resistant wear-resistant alkyd resin paint for copper sculpture Effective date of registration: 20161209 Granted publication date: 20160504 Pledgee: Tongling Jinyu SME Credit Guarantee Center Pledgor: TONGLING XINJIUDING COPPER CULTURE INDUSTRY CO., LTD. Registration number: 2016340000105 |
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