CN107813566A - A kind of antistatic latex mattress and preparation method thereof - Google Patents

A kind of antistatic latex mattress and preparation method thereof Download PDF

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Publication number
CN107813566A
CN107813566A CN201711164308.XA CN201711164308A CN107813566A CN 107813566 A CN107813566 A CN 107813566A CN 201711164308 A CN201711164308 A CN 201711164308A CN 107813566 A CN107813566 A CN 107813566A
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China
Prior art keywords
parts
antistatic
latex mattress
latex
weight
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CN201711164308.XA
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Chinese (zh)
Inventor
戴爱春
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Ningbo Endi Sanitary Ware Co Ltd
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Ningbo Endi Sanitary Ware Co Ltd
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Priority to CN201711164308.XA priority Critical patent/CN107813566A/en
Publication of CN107813566A publication Critical patent/CN107813566A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/002—Methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00—Characterised by the use of natural rubber
    • C08J2307/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2421/00—Characterised by the use of unspecified rubbers
    • C08J2421/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of antistatic latex mattress, the surface of the latex mattress is compounded with antistatic fibre layer by adhesive, the latex mattress includes 50 60 parts of natural emulsion by weight, 40 50 parts of artificial latex, 5 10 parts of Chinese medicine additive, 15 parts of accelerator, 15 parts of vulcanizing agent, 12 parts of foaming agent, 12 parts of antioxidant, the antistatic fibre layer is formed by the braiding of antistatic fibre silk, antistatic additive in the antistatic fibre silk includes 20 30 parts of silver oxide by weight, 10 15 parts of graphene, 20 25 parts of organosilicon, dodecyl dimethyl season 10 15 parts of second inner salt, 15 parts of bentonite, 15 parts of rare earth.A kind of antistatic latex mattress that the present invention obtains, it by adhesive on the surface of latex mattress by being compounded with antistatic fibre layer, so that the antistatic latex mattress not only has the original fine air permeability of latex, resilience, but also there is antistatic behaviour and wearability caused by antistatic fibre layer so that usage time is longer.

Description

A kind of antistatic latex mattress and preparation method thereof
Technical field
The present invention relates to latex mattress, particularly a kind of antistatic latex mattress and preparation method thereof.
Background technology
At present, common mattress, pillow are made of generic latex more, therefore its gas permeability and elasticity are all poor, therefore Long-term use of easy moldy metamorphism.Part producer uses high polymer material as pillow, although the high polymer material has uniformly Gap structure, but gapping interval is big, and air permeable effect is bad, and peculiar smell generation is had after long-time use.Simultaneously because people Raising for quality of living, therefore more requirements, such as antistatic behaviour are also further provided for latex mattress.
The content of the invention
It is a primary object of the present invention to provide a kind of antistatic latex mattress so that latex mattress not only good permeability, cost It is low, but also there is anlistatig performance.
To achieve the above objectives, the technical solution adopted by the present invention is：A kind of antistatic latex mattress, the table of the latex mattress Face is compounded with antistatic fibre layer by adhesive, and the latex mattress includes natural emulsion 50-60 parts, artificial latex by weight 40-50 parts, Chinese medicine additive 5-10 parts, accelerator 1-5 parts, vulcanizing agent 1-5 parts, foaming agent 1-2 parts, antioxidant 1-2 parts, institute State antistatic fibre layer to be formed by the braiding of antistatic fibre silk, the antistatic fibre silk includes polyamide fibre 70-80 parts by weight, washs Synthetic fibre 20-30 parts, viscose rayon 10-15 parts, fluorocarbons 5-10 parts, antistatic additive 1-5 parts, wherein antistatic additive include by weight Silver oxide 20-30 parts, graphene 10-15 parts, organosilicon 20-25 parts, dodecyl dimethyl season second inner salt 10-15 parts, swelling Native 1-5 parts, rare earth 1-5 parts.
It is 50 parts of polyvinyl acetate that described adhesive includes by weight, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and 10 parts of aminoacrylic acid.
The Chinese medicine additive includes 2 parts of Radix Codonopsis by weight, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, 10 parts of the Radix Astragali, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood.
A kind of preparation method of antistatic latex mattress, comprises the following steps：
The first step：Antistatic additive is prepared, by silver oxide 20-30 parts, graphene 10-15 parts, bentonite 1-5 parts and rare earth 1- 5 parts, it is put into is heated into reacting furnace by weight, heating-up temperature is 300-350 DEG C, room temperature is cooled to after melting, so After be ground into particle, be subsequently placed into organosilicon 20-25 parts, dodecyl dimethyl season second inner salt 10-15 parts, stir and produce Antistatic additive；
Second step：Antistatic fibre layer is prepared, by polyamide fibre 70-80 parts, terylene 20-30 parts, viscose rayon 10-15 parts, fluorine Change carbon 5-10 parts, antistatic additive 1-5 parts, which are put into reactor, carries out frit reaction, reacts 2h at being 220-240 DEG C in temperature, Reaction is passed through in screw extruder after terminating and extrudes and be granulated, and obtains antistatic fibre screw grain；Then by antistatic fibre silk Master batch is sent into melt spinning machine hopper, is sprayed by spinning head, is wound in tube filler, obtained by coiler device after crosswind cools down To antistatic fibre silk, antistatic fibre layer is obtained finally by braiding；
3rd step, prepares adhesive, by 50 parts of polyvinyl acetate, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and amino 10 parts of acrylic acid is well mixed, while adding waterside to stir, stops adding water when viscosity reaches 2000CP, then proceedes to stir 30min After obtain adhesive；
4th step, latex mattress is prepared, first by 2 parts of Radix Codonopsis, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, the Radix Astragali 10 parts, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood weighed, then ground Into particle, Chinese medicine additive is obtained, then toward sequentially adding natural emulsion 50-60 parts in mixer, artificial latex's 40-50 parts, Chinese medicine additive 5-10 parts, accelerator 1-5 parts, vulcanizing agent 1-5 parts, foaming agent 1-2 parts, antioxidant 1-2 parts are stirred mixed Close, latex material is made, the wherein rotating speed of mixer is 1200 turns/min, mixing time 20min, then by foaming, note Modeling, boiling, cooling obtain latex mattress, and finally antistatic fibre layer is resisted on the surface of latex mattress is compound by adhesive Electrostatic latex mattress.
The latex mattress with the addition of Chinese medicine additive in natural emulsion and artificial latex, so as to increase healthcare function.
Polyamide fibre, terylene and three kinds of fiber collective effects of viscose rayon in the antistatic fibre silk, have given play to respective Elastic good, the intensity height of feature, wherein polyamide fibre, wearability height, terylene have extremely excellent setting performance；Spun polyester thread or fabric Generated after setting it is flat very, fluffy form or rivel etc., in use through repeatedly washing, remain to prolonged constant；Viscose glue is fine The hygroscopicity of dimension meets the physiological requirement of human body skin, has smooth nice and cool, ventilative, antistatic, antiultraviolet, lucuriant in design, The features such as dyefastness is preferable.Other fluorocarbons English improves the filametntary intensity so that obtained antistatic fibre layer Intensity is higher.
Silver oxide in the antistatic additive is inorganic antistatic agent, and graphene can then improve the antistatic energy of silver oxide Power；Organosilicon and dodecyl dimethyl season second inner salt are organic antistatic agentses, and bentonite and rare earth are then as inorganic matter with having Bridge joint effect between machine thing so that inorganic antistatic agent and organic antistatic agentses can play synergy with collective effect.
Be aqueous binder in described adhesive, wherein polyvinyl acetate and aminoacrylic acid as stickies main body, Polypropylene is then used to improve adhesion strength, and polyvinyl alcohol is used to improve the various tables formed between phase in emulsion as emulsifying agent Face tension force, it is allowed to be formed the material of uniform and stable dispersion or emulsion.
A kind of antistatic latex mattress that the present invention obtains and preparation method thereof, it on the surface of latex mattress by passing through bonding Agent is compounded with antistatic fibre layer, so that the antistatic latex mattress not only has the original fine air permeability of latex, resilience Property, but also there is antistatic behaviour and wearability caused by antistatic fibre layer so that usage time is longer, and human body is good for Kang Gengwei is beneficial.
Embodiment
Describe to be used to disclose the present invention below so that those skilled in the art can realize the present invention.It is excellent in describing below Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious modifications.
Embodiment 1：
A kind of antistatic latex mattress that the present embodiment provides, the surface of the latex mattress are compounded with antistatic by adhesive Fibrous layer, the latex mattress include 50 parts of natural emulsion, 40 parts of artificial latex, 5 parts of Chinese medicine additive, accelerator 1 by weight Part, 1 part of vulcanizing agent, 1 part of foaming agent, 1 part of antioxidant, the antistatic fibre layer are formed by the braiding of antistatic fibre silk, should Antistatic fibre silk includes 70 parts of polyamide fibre by weight, 20 parts of terylene, 10 parts of viscose rayon, 5 parts of fluorocarbons, 1 part of antistatic additive, Wherein antistatic additive includes 20 parts of silver oxide by weight, 10 parts of graphene, 20 parts of organosilicon, in dodecyl dimethyl Ji Yi 10 parts of salt, 1 part of bentonite, 1 part of rare earth.
It is 50 parts of polyvinyl acetate that described adhesive includes by weight, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and 10 parts of aminoacrylic acid.
The Chinese medicine additive includes 2 parts of Radix Codonopsis by weight, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, 10 parts of the Radix Astragali, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood.
A kind of preparation method of antistatic latex mattress, comprises the following steps：
The first step：Antistatic additive is prepared, by 20 parts of silver oxide, 10 parts of graphene, 1 part of 1 part of bentonite and rare earth, by weight Heated than being put into reacting furnace, heating-up temperature is 300-350 DEG C, and room temperature is cooled to after melting, and is then ground to Grain, is subsequently placed into 20 parts of organosilicon, dodecyl dimethyl season 10 parts of second inner salt, stir and produce antistatic additive；
Second step：Antistatic fibre layer is prepared, 70 parts of polyamide fibre, 10 parts of viscose rayon, 5 parts of fluorocarbons, resists 20 parts of terylene 1 part of electrostatic agent, which is put into reactor, carries out frit reaction, reacts 2h at being 220-240 DEG C in temperature, reaction is passed through after terminating Extrude and be granulated in screw extruder, obtain antistatic fibre screw grain；Then antistatic fibre screw grain is sent into melting to spin In silk machine hopper, sprayed by spinning head, be wound to after crosswind cools down by coiler device in tube filler, obtain antistatic fibre Silk, antistatic fibre layer is obtained finally by braiding；
3rd step, prepares adhesive, by 50 parts of polyvinyl acetate, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and amino 10 parts of acrylic acid is well mixed, while adding waterside to stir, stops adding water when viscosity reaches 2000CP, then proceedes to stir 30min After obtain adhesive；
4th step, latex mattress is prepared, first by 2 parts of Radix Codonopsis, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, the Radix Astragali 10 parts, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood weighed, then ground Into particle, Chinese medicine additive is obtained, then toward 50 parts of natural emulsion is sequentially added in mixer, 40 parts of artificial latex, Chinese medicine adds Adding 5 parts of agent, 1 part of accelerator, 1 part of vulcanizing agent, 1 part of foaming agent, 1 part of antioxidant is stirred mixing, latex material is made, its The rotating speed of middle mixer is 1200 turns/min, mixing time 20min, then obtains breast by foaming, injection, boiling, cooling Rubber cushion, finally antistatic fibre layer obtains antistatic latex mattress on the surface of latex mattress is compound by adhesive.
Latex mattress made from the present embodiment is subjected to antistatic property test, surface resistivity is 107-109Between.
Embodiment 2：
A kind of antistatic latex mattress that the present embodiment provides and preparation method thereof substantially same as Example 1, its difference Be the latex mattress includes 60 parts of natural emulsion by weight, 50 parts of artificial latex, 10 parts of Chinese medicine additive, 5 parts of accelerator, 5 parts of vulcanizing agent, 2 parts of foaming agent, 2 parts of antioxidant.
Latex mattress made from the present embodiment is subjected to antistatic property test, surface resistivity is 107-109Between.
Embodiment 3：
A kind of antistatic latex mattress that the present embodiment provides and preparation method thereof substantially same as Example 1, its difference It is, the antistatic fibre silk includes 80 parts of polyamide fibre by weight, 30 parts of terylene, 15 parts of viscose rayon, 10 parts of fluorocarbons, resists 5 parts of electrostatic agent.
Latex mattress made from the present embodiment is subjected to antistatic property test, surface resistivity is 107-109Between.
Embodiment 4：
A kind of antistatic latex mattress that the present embodiment provides and preparation method thereof substantially same as Example 1, its difference It is that the antistatic additive includes 30 parts of silver oxide, 15 parts of graphene, 25 parts of organosilicon, dodecyl dimethyl season by weight 15 parts of second inner salt, 5 parts of bentonite, 5 parts of rare earth.
Latex mattress made from the present embodiment is subjected to antistatic property test, surface resistivity is 107-109Between.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is the present invention Principle, various changes and modifications of the present invention are possible without departing from the spirit and scope of the present invention, these change and Improvement is both fallen within the range of claimed invention.The protection domain of application claims by appended claims and its Equivalent defines.

Claims (4)

  1. A kind of 1. antistatic latex mattress, it is characterised in that：The surface of the latex mattress is compounded with antistatic fibre by adhesive Layer, the latex mattress include natural emulsion 50-60 parts, artificial latex's 40-50 parts, Chinese medicine additive 5-10 parts, promoted by weight Enter agent 1-5 parts, vulcanizing agent 1-5 parts, foaming agent 1-2 parts, antioxidant 1-2 parts, the antistatic fibre layer is by antistatic fibre Silk braiding forms, and the antistatic fibre silk includes polyamide fibre 70-80 parts by weight, terylene 20-30 parts, viscose rayon 10-15 parts, Fluorocarbons 5-10 parts, wherein antistatic additive 1-5 parts, antistatic additive include silver oxide 20-30 parts, graphene 10-15 by weight Part, organosilicon 20-25 parts, dodecyl dimethyl season second inner salt 10-15 parts, bentonite 1-5 parts, rare earth 1-5 parts.
  2. 2. antistatic latex mattress according to claim 1, it is characterised in that：It is poly-vinegar that described adhesive includes by weight 10 parts of 50 parts of vinyl acetate, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and aminoacrylic acid.
  3. 3. antistatic latex mattress according to claim 1, it is characterised in that：The Chinese medicine additive includes party by weight 2 parts of ginseng, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, 10 parts of the Radix Astragali, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood.
  4. 4. the preparation method of a kind of antistatic latex mattress as described in claim 1-3, it is characterised in that comprise the following steps：
    The first step：Antistatic additive is prepared, by silver oxide 20-30 parts, graphene 10-15 parts, bentonite 1-5 parts and rare earth 1-5 parts, It is put into and is heated into reacting furnace by weight, heating-up temperature is 300-350 DEG C, and room temperature, Ran Houyan are cooled to after melting Wear into particle, be subsequently placed into organosilicon 20-25 parts, dodecyl dimethyl season second inner salt 10-15 parts, stirring, it is anti-quiet to produce Electric agent；
    Second step：Antistatic fibre layer is prepared, by polyamide fibre 70-80 parts, terylene 20-30 parts, viscose rayon 10-15 parts, fluorocarbons 5-10 parts, antistatic additive 1-5 parts, which are put into reactor, carries out frit reaction, reacts 2h at being 220-240 DEG C in temperature, reacts It is passed through after end in screw extruder and extrudes and be granulated, obtains antistatic fibre screw grain；Then by antistatic fibre screw grain It is sent into melt spinning machine hopper, is sprayed by spinning head, be wound in tube filler, resisted by coiler device after crosswind cools down Electrostatic fibre silk, antistatic fibre layer is obtained finally by braiding；
    3rd step, prepares adhesive, by 50 parts of polyvinyl acetate, 20 parts of polypropylene, 10 parts of polyvinyl alcohol and amino propylene Sour 10 parts well mixed, while adding waterside to stir, stops adding water when viscosity reaches 2000CP, then proceedes to obtain after stirring 30min To adhesive；
    4th step, latex mattress is prepared, first by 2 parts of Radix Codonopsis, 2 parts of ganoderma lucidum, 8 parts of chrysanthemum, 10 parts of Jasmine, 8 parts of aloe, the Radix Astragali 10 Part, 10 parts of matrimony vine, 10 parts of lily, 10 parts of peppermint, 5 parts of ginkgo leaf, 15 parts of green tea, 10 parts of wormwood are weighed, are then ground to Particle, Chinese medicine additive is obtained, then toward sequentially adding natural emulsion 50-60 parts in mixer, artificial latex's 40-50 parts, in Medicine additive 5-10 parts, accelerator 1-5 parts, vulcanizing agent 1-5 parts, foaming agent 1-2 parts, antioxidant 1-2 parts are stirred mixing, Be made latex material, the wherein rotating speed of mixer is 1200 turns/min, mixing time 20min, then by foaming, injection, Boiling, cooling obtain latex mattress, finally on the surface of latex mattress is compound by adhesive antistatic fibre layer obtain it is anti-quiet Electric latex mattress.
CN201711164308.XA 2017-11-10 2017-11-10 A kind of antistatic latex mattress and preparation method thereof Pending CN107813566A (en)

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CN109330272A (en) * 2018-12-12 2019-02-15 菩艾堂（湖北）蕲艾科技有限公司 A kind of Chinese mugwort latex bed mattress and its manufacturing method
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CN110558796B (en) * 2019-09-23 2020-10-30 江苏金世缘乳胶制品股份有限公司 Anti-static natural latex pillow
CN110840154A (en) * 2019-11-29 2020-02-28 江苏爱德福乳胶制品有限公司 Artemisia argyi microcapsule fragrance type latex mattress, foaming liquid and foaming layer preparation method
CN118063865A (en) * 2024-02-18 2024-05-24 江苏爱德福乳胶制品有限公司 Antistatic latex mattress and preparation method thereof

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Application publication date: 20180320