CN107805152A - A kind of preparation method and product of mangrove special liquid compoiste fertilizer - Google Patents
A kind of preparation method and product of mangrove special liquid compoiste fertilizer Download PDFInfo
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- CN107805152A CN107805152A CN201711344415.0A CN201711344415A CN107805152A CN 107805152 A CN107805152 A CN 107805152A CN 201711344415 A CN201711344415 A CN 201711344415A CN 107805152 A CN107805152 A CN 107805152A
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- Prior art keywords
- liquid
- chelating
- potassium
- mangrove
- preparation
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/02—Fertilisers containing other nitrates containing sodium or potassium nitrate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of preparation method and product of mangrove special liquid compoiste fertilizer.The preparation method of the composite fertilizer, comprises the following steps：1) take potassium nitrate and amino acid to be dissolved in the water, chelating >=48h is vibrated under the conditions of≤60 DEG C, obtain chelating liquid；Wherein, the amount ratio of potassium nitrate, amino acid and water is：30‑50g：300‑600g：3‑4L；2) alkyl benzene sulphonate potassium and alcohol waste mash are added into chelating liquid, chelating >=24h is stirred under the conditions of≤60 DEG C, that is, obtains mangrove special liquid compoiste fertilizer；Wherein, the addition of alkyl benzene sulphonate potassium adds 1 3g by every liter of chelating liquid and calculated, and the volume ratio for chelating liquid and alcohol waste mash is 1：0.8‑1.2.Inorganic states potassium and nitrogen more than 90% are converted into organic potassium and the nitrogen such as potassio methionine and potassio cystine in the product as made from the method for the invention, can effectively improve mangrove to potassium, the absorption rate of nitrogen.
Description
Technical field
The present invention relates to a kind of organic fertilizer, and in particular to a kind of preparation method of mangrove special liquid compoiste fertilizer
And product.
Background technology
The fertilizer that tradition is applied to mangrove is mainly inorganic fertilizer and foliar fertilizer.For inorganic fertilizer, due to mangrove
Growth conditions is poor, slower to the absorption rate of inorganic fertilizer, easily occurs not having enough time also absorbing the feelings taken away by seawater
Condition, and then cause fertilizer supply insufficient, slow-growing, survival rate is relatively low.For foliar fertilizer, foliar fertilizer is in application pair
Plant has burn seedlings risk in itself；On the other hand, blade face needs repeatedly to spray, and not only workload is big but also cost of labor is high.
During alcohol is produced as fermenting raw materials using molasses, alcohol waste mash will be produced.Due to alcohol waste mash
COD, BOD it is very high, pH value is relatively low, but also contains the composition such as substantial amounts of organic matter and nitrogen, potassium, if not being acted upon, directly
Discharge, will cause environment pollution, can also cause the waste of the manure resources such as useful nitrogen, potassium.
Have not yet to see mangrove made from alcohol waste mash and potassium nitrate, amino acid progress chelatropic reaction is special
The relevant report of liquid organic composite fertilizer.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of mangrove special liquid compoiste fertilizer and
Product.Inorganic states potassium and nitrogen more than 90% are converted into potassio methionine and potassio cystine etc. in product obtained by this method
Organic potassium and nitrogen, mangrove can be effectively improved to potassium, the absorption rate of nitrogen.
The preparation method of mangrove special liquid compoiste fertilizer of the present invention, comprises the following steps：
1) take potassium nitrate and amino acid to be dissolved in the water, chelating >=48h is vibrated under the conditions of≤60 DEG C, obtain chelating liquid；
Wherein, the amount ratio of potassium nitrate, amino acid and water is：30-50g：300-600g：3-4L；
2) alkyl benzene sulphonate potassium and alcohol waste mash are added into chelating liquid, chelating >=24h are stirred under the conditions of≤60 DEG C,
Obtain mangrove special liquid compoiste fertilizer；Wherein, the addition of alkyl benzene sulphonate potassium adds 1-3g by every liter of chelating liquid
Calculate, the volume ratio for chelating liquid and alcohol waste mash is 1：0.8-1.2.
In the step 1) of above-mentioned preparation method, the amount ratio of the potassium nitrate, amino acid and water is preferably：40g：400-
500g：3-4L.Potassium nitrate and amino acid are first preferably subjected to chelatropic reaction again with water wiring solution-forming respectively, specifically, can incite somebody to action
Potassium nitrate is made into the 30-50g/L aqueous solution, the aqueous solution by amino acid ligand into 300-600g/L, is then mixed further according to ratio
After carry out vibration chelatropic reaction.
In the step 1) of above-mentioned preparation method, described amino acid is the agricultural use that can be bought directly from the market
Composite aminophenol powder, the amino acid original powder produced such as Jinan great plan Chemical Co., Ltd., the limited public affairs of Xuzhou green source agricultural science and technology
Take charge of the agricultural amino acid original powder of production, agricultural amino acid powder that Shandong Yang Dao bio tech ltd produces etc..
In the step 1) of above-mentioned preparation method, chelatropic reaction is preferably carried out under the conditions of 35-45 DEG C, and the time is preferably
72-80h；The frequency of concussion is preferably 60-120 pendulum/min.
In the step 2) of above-mentioned preparation method, preferably chelatropic reaction is carried out under the conditions of 25-35 DEG C, time 48-60h；
The speed of stirring is preferably 20-40r/min.
In the step 2) of above-mentioned preparation method, the addition of alkyl benzene sulphonate potassium is preferably added based on 2g by every liter of chelating liquid
Calculate, the volume ratio for chelating liquid and alcohol waste mash is preferably 1：1.
Present invention additionally comprises the mangrove special liquid compoiste fertilizer being prepared by the above method.
Compared with prior art, the method have the characteristics that：
The 1st, potassium nitrate and amino acid are entered under certain temperature to Mobile state concussion chelating in water, then add adhesive with
Alcohol waste mash containing compound bacteria, a variety of nutriments enters Mobile state chelating again, further promotes potassium and nitrogen to organic
Conversion, the stable absorption of mangrove during being advantageous to subsequent applications.
2nd, the compoiste fertilizer obtained by the method for the invention is different from common fermentation mixed liquor (common fermentation mixed liquor
In potassium be substantially inorganic states potassium ion), but a kind of chelating liquid, inorganic potassium therein have been largely converted into potassio egg ammonia
Acid and organic potassium and the nitrogen such as potassio cystine, specifically, the inorganic states potassium and nitrogen of the inside is by double chelatings, wherein more than 90%
Organic potassium and the nitrogen such as potassio methionine and potassio cystine are had been converted into, eliminates murder by poisoning risk；On the other hand also save significantly
The about usage amount of potassium nitrate raw material, can save more than 60%.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, to more fully understand present disclosure, but
The present invention is not limited to following examples.
The alcohol waste mash being related in following embodiment obtains from Nanning Hong Xu trade Co., Ltds, and pH value is
8-9；The amino acid being related to is the amino acid original powder of Jinan great plan Chemical Co., Ltd. production, containing 18 kinds of Free amino acids,
Wherein 9 kinds of essential amino acid, content about 25%, various total amino acid contents about 45.1%；The organic nothing also needed containing crop
Machine nitrogen 18.2%, phosphorus 0.5% or so, potassium 2.2%-4%.
Embodiment 1
1) weigh potassium nitrate to be dissolved in deionized water, be made into 40g/L potassium nitrate solution；Amino acid is taken to be dissolved in deionization
In water, 200g/L Freamine Ⅲ is made into；
2) 3L potassium nitrate solutions and 7L Freamine Ⅲs are taken, mix, shaken under the conditions of 45 DEG C (frequency be 100 pendulum
Secondary/min) chelating 72h, obtain chelating liquid；
3) chelated to gained and alkyl benzene sulphonate potassium and alcohol waste mash are added in liquid, wherein, the addition of alkyl benzene sulphonate potassium
Amount adds 2g by every liter of chelating liquid and calculated, and the volume ratio for chelating liquid and alcohol waste mash is 1：1；Gained mixed liquor is in 35 DEG C of conditions
Lower stirring (speed of stirring is 40r/min) chelating 48h, that is, obtain mangrove special liquid compoiste fertilizer.
It is soluble effective in the liquid mangrove special organic composite fertilizer being prepared by the present embodiment method by detection
Potassium and nitrogen content are 0.51%.
5 samples are prepared respectively according to the present embodiment method, and the step 2) in Sample Preparation Procedure for the first time tie by chelating
Second of chelating of beam and step 3) is respectively adopted chromatographic fractionation system, atomic fluorescence spectrophotometer and Potassium forms after terminating and located in advance
Reason device is combined into HPLC-HG-AFS combined systems and is measured, and after chelating terminates for the first time, chelate has 5 samples in liquid
Machine potassium content accounts for potassium total amount and is followed successively by 60.1%, 62.2%, 65.2%, 62.1%, 63.5% respectively, average out to 62.6%；The
After secondary chelating terminates, chelate organic potassium content in liquid account for respectively total potassium content be followed successively by 89.7%, 92.6%, 93.2%,
97.9%th, 96.8%, average out to 94.04%.As can be seen here, after second chelates, conversion ratio improves 50.2% (with first
Compared after secondary chelating), it is more beneficial for mangrove absorption.
Embodiment 2
1) weigh potassium nitrate to be dissolved in deionized water, be made into 30g/L potassium nitrate solution；Amino acid is taken to be dissolved in deionization
In water, 150g/L Freamine Ⅲ is made into；
2) potassium nitrate solution and Freamine Ⅲ are taken by 1：2 volume ratio mixing, is shaken (frequency under the conditions of 35 DEG C
For 120 pendulum/min) chelating 72h, obtain chelating liquid；
3) chelated to gained and alkyl benzene sulphonate potassium and alcohol waste mash are added in liquid, wherein, the addition of alkyl benzene sulphonate potassium
Amount adds 3g by every liter of chelating liquid and calculated, and the volume ratio for chelating liquid and alcohol waste mash is 1：0.8；Gained mixed liquor is in 25 DEG C of bars
(speed of stirring is 30r/min) chelating 48h is stirred under part, that is, obtains mangrove special liquid compoiste fertilizer.
It is soluble effective in the liquid mangrove special organic composite fertilizer being prepared by the present embodiment method by detection
Potassium and nitrogen content are 0.48%.
Chelating terminates the step 2) of the present embodiment for the first time and step 3) chelates after terminating and chromatogram point is respectively adopted for the second time
HPLC-HG-AFS combined systems are combined into from system, atomic fluorescence spectrophotometer and Potassium forms pretreatment unit to be measured,
Organic potassium content accounts for potassium total amount as 63.0% in chelating liquid after wherein chelating terminates for the first time；After second of chelating terminates, chela
Close organic potassium content in liquid and account for total potassium content as 93.3%.
Embodiment 3
1) weigh potassium nitrate to be dissolved in deionized water, be made into 50g/L potassium nitrate solution；Amino acid is taken to be dissolved in deionization
In water, 180g/L Freamine Ⅲ is made into；
2) potassium nitrate solution and Freamine Ⅲ are taken by 1：3 volume ratio mixing, is shaken (frequency under the conditions of 40 DEG C
For 60 pendulum/min) chelating 80h, obtain chelating liquid；
3) chelated to gained and alkyl benzene sulphonate potassium and alcohol waste mash are added in liquid, wherein, the addition of alkyl benzene sulphonate potassium
Amount adds 1g by every liter of chelating liquid and calculated, and the volume ratio for chelating liquid and alcohol waste mash is 1：1.2；Gained mixed liquor is in 30 DEG C of bars
(speed of stirring is 20r/min) chelating 60h is stirred under part, that is, obtains mangrove special liquid compoiste fertilizer.
It is soluble effective in the liquid mangrove special organic composite fertilizer being prepared by the present embodiment method by detection
Potassium and nitrogen content are 0.52%.
Chelating terminates the step 2) of the present embodiment for the first time and step 3) chelates after terminating and chromatogram point is respectively adopted for the second time
HPLC-HG-AFS combined systems are combined into from system, atomic fluorescence spectrophotometer and Potassium forms pretreatment unit to be measured,
Organic potassium content accounts for potassium total amount as 64.5% in chelating liquid after wherein chelating terminates for the first time；After second of chelating terminates, chela
Close organic potassium content in liquid and account for total potassium content as 95.5%.
Experimental example 1：Mangrove special liquid compoiste fertilizer is used for Aegiceras corniculatum and carries out spraying test
Will the mangrove special liquid compoiste fertilizer as made from the methods described of embodiment 1 in thatch tail sea National Urban Wetland Park in Zhejiang
The Aegiceras corniculatum of (Kangxu ridge piece) carries out spraying test, and on March 15th, 2016 and April 15, every mu uses the mangrove every time
500 milliliters of woods special liquid compoiste fertilizer carries out foliage-spray once after being diluted with water 100 times.And using the compound of in the market
(the broad spectrum type organic water-soluble fertilizer of Guangxi joint-stock company production, packing specification is * 50 bags of 10 milliliter/bag/box to fertilizer, is said by it
Product is diluted 1000 times and carries out foliage-spray 2 times by bright book requirement) as a comparison, same amount sprays on Aegiceras corniculatum.
Result of the test shows, using the Aegiceras corniculatum of mangrove special liquid compoiste fertilizer made from the embodiment of the present invention 1
Leaf color, growing way is all remarkably higher than control, and does not have burn seedlings phenomenon.
Experimental example 2：Mangrove special liquid compoiste fertilizer is applied to autumn eggplant spraying test
By the liquid mangrove special organic composite fertilizer of embodiment 1 thatch tail sea National Urban Wetland Park in Zhejiang (Kangxu ridge piece) autumn
Eggplant carries out spraying test, and on March 15th, 2016 and April 15, every mu uses liquid mangrove special organic composite fertilizer every time
500 milliliters, foliage-spray is carried out once after diluting 100 times.And using composite fertilizer's (Guangxi joint-stock company production of in the market
Broad spectrum type organic water-soluble fertilizer, packing specification is * 50 bags of 10 milliliter/bag/box, by its specification requirement by product dilute 1000
Foliage-spray is carried out again 2 times) as a comparison, same amount sprays on autumn eggplant.
Result of the test shows, using the autumn eggplant of mangrove special liquid compoiste fertilizer made from the embodiment of the present invention 1
Leaf color, growing way is all remarkably higher than control, and does not have burn seedlings phenomenon.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to is assert
The specific implementation of the present invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the present invention's
Protection domain.
Claims (9)
1. a kind of preparation method of mangrove special liquid compoiste fertilizer, comprises the following steps：
1) take potassium nitrate and amino acid to be dissolved in the water, chelating >=48h is vibrated under the conditions of≤60 DEG C, obtain chelating liquid；Wherein,
The amount ratio of potassium nitrate, amino acid and water is：30-50g：300-600g：3-4L；
2) alkyl benzene sulphonate potassium and alcohol waste mash are added into chelating liquid, chelating >=24h is stirred under the conditions of≤60 DEG C, is produced
To mangrove special liquid compoiste fertilizer；Wherein, the addition of alkyl benzene sulphonate potassium adds 1-3g by every liter of chelating liquid and calculated,
The volume ratio for chelating liquid and alcohol waste mash is 1：0.8-1.2.
2. preparation method according to claim 1, it is characterised in that：In step 1), the potassium nitrate, amino acid and water
Amount ratio is：40g：400-500g：3-4L.
3. preparation method according to claim 1, it is characterised in that：In step 1), chelatropic reaction is under the conditions of 35-45 DEG C
Carry out, time 72-80h.
4. preparation method according to claim 1, it is characterised in that：In step 2), chelatropic reaction is under the conditions of 25-35 DEG C
Carry out, time 48-60h.
5. preparation method according to claim 1, it is characterised in that：In step 2), the addition of alkyl benzene sulphonate potassium is pressed
Every liter of chelating liquid adds 2g and calculated.
6. preparation method according to claim 1, it is characterised in that：In step 2), the body of liquid and alcohol waste mash is chelated
Product is than being 1：1.
7. according to the preparation method any one of claim 1-6, it is characterised in that：In step 1), the frequency of concussion is
60-120 pendulum/min.
8. according to the preparation method any one of claim 1-6, it is characterised in that：In step 2), the speed of stirring is
20-40r/min。
9. the mangrove special liquid compoiste fertilizer that any one of claim 1-8 methods described is prepared.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711344415.0A CN107805152A (en) | 2017-12-14 | 2017-12-14 | A kind of preparation method and product of mangrove special liquid compoiste fertilizer |
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| CN201711344415.0A CN107805152A (en) | 2017-12-14 | 2017-12-14 | A kind of preparation method and product of mangrove special liquid compoiste fertilizer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650789A (en) * | 2022-10-11 | 2023-01-31 | 文山学院 | Foliar fertilizer special for panax notoginseng |
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| CN104926419A (en) * | 2015-07-02 | 2015-09-23 | 湖北新生源生物工程股份有限公司 | Preparation method of water-soluble powdery fertilizer containing amino acid |
| CN105399543A (en) * | 2015-12-25 | 2016-03-16 | 武汉皓达农业科技有限公司 | Liquid high-concentration water-soluble fertilizer containing organic matters and preparation method thereof |
| CN105777353A (en) * | 2016-03-17 | 2016-07-20 | 广州甘蔗糖业研究所 | Bioactive organic chelate liquid fertilizer and preparation method thereof |
| CN105924283A (en) * | 2016-04-29 | 2016-09-07 | 武汉皓达农业科技有限公司 | Preparation method for colorless organic water-soluble fertilizer |
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2017
- 2017-12-14 CN CN201711344415.0A patent/CN107805152A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104926419A (en) * | 2015-07-02 | 2015-09-23 | 湖北新生源生物工程股份有限公司 | Preparation method of water-soluble powdery fertilizer containing amino acid |
| CN105399543A (en) * | 2015-12-25 | 2016-03-16 | 武汉皓达农业科技有限公司 | Liquid high-concentration water-soluble fertilizer containing organic matters and preparation method thereof |
| CN105777353A (en) * | 2016-03-17 | 2016-07-20 | 广州甘蔗糖业研究所 | Bioactive organic chelate liquid fertilizer and preparation method thereof |
| CN105924283A (en) * | 2016-04-29 | 2016-09-07 | 武汉皓达农业科技有限公司 | Preparation method for colorless organic water-soluble fertilizer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650789A (en) * | 2022-10-11 | 2023-01-31 | 文山学院 | Foliar fertilizer special for panax notoginseng |
| CN115650789B (en) * | 2022-10-11 | 2023-10-27 | 文山学院 | Foliar fertilizer special for pseudo-ginseng |
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Application publication date: 20180316 |