CN102942412A - Macroelement soluble fertilizer and preparation method thereof - Google Patents
Macroelement soluble fertilizer and preparation method thereof Download PDFInfo
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- CN102942412A CN102942412A CN2012104233054A CN201210423305A CN102942412A CN 102942412 A CN102942412 A CN 102942412A CN 2012104233054 A CN2012104233054 A CN 2012104233054A CN 201210423305 A CN201210423305 A CN 201210423305A CN 102942412 A CN102942412 A CN 102942412A
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011573 trace mineral Substances 0.000 claims abstract description 19
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 19
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 150000001413 amino acids Chemical class 0.000 claims abstract description 12
- 210000003746 feather Anatomy 0.000 claims abstract description 11
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 10
- 239000004202 carbamide Substances 0.000 claims abstract description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 9
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 9
- 241001671204 Stemona Species 0.000 claims abstract description 9
- 229910052796 boron Inorganic materials 0.000 claims abstract description 9
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 9
- 235000005221 swamp mahogany Nutrition 0.000 claims abstract description 9
- 239000011592 zinc chloride Substances 0.000 claims abstract description 9
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 6
- 238000000855 fermentation Methods 0.000 claims description 12
- 230000004151 fermentation Effects 0.000 claims description 12
- 230000004048 modification Effects 0.000 claims description 11
- 238000012986 modification Methods 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 244000239645 swamp mahogany Species 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 3
- 239000011609 ammonium molybdate Substances 0.000 claims description 3
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 239000002728 pyrethroid Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000009637 wintergreen oil Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 235000015097 nutrients Nutrition 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005903 acid hydrolysis reaction Methods 0.000 abstract description 3
- 238000002425 crystallisation Methods 0.000 abstract description 3
- 230000008025 crystallization Effects 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 244000103090 Eucalyptus robusta Species 0.000 abstract 1
- 240000000111 Saccharum officinarum Species 0.000 abstract 1
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract 1
- 230000009920 chelation Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000010803 wood ash Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 6
- 239000013522 chelant Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a macroelement soluble fertilizer and a preparation method thereof. The macroelement soluble fertilizer disclosed herein comprises 50-60 weight parts of dipotassium hydrogen phosphate, 5-7 weight parts of phosphoric acid, 33-38 weight parts of urea, 0.8-1.2 weight parts of zinc chloride, 2-4 weight parts of instant boron, 2-3 weight parts of disodium ethylene diamine tetraacetate, 1-2 weight parts of animal hair and feather, 8-12 weight parts of ammonium nitrate, 2-4 weight parts of stemona powder, 3-5 weight parts of vinasse, 5-7 weight parts of eucalyptus robusta leaf, 7-9 weight parts of sugarcane leaf, 2-5 weight parts of modified wood ash, 4-6 weight parts of trace element fertilizer, and 60-70 weight parts of water. According to the invention, amino acid is generated by acid hydrolysis and the like, then chelation is carried out on medium and trace elements, and the chelated structure is added to carboxymethyl cellulose, thus effective utilization of the medium and trace elements is benefited, and ineffective release of the medium and trace elements is benefited is reduced; the content of the nutrients included in the fertilizer is high, the production process is simple, the processes of evaporation, crystallization and drying are reduced, the produced dipotassium hydrogen phosphate solution can be directly used for preparing the liquid soluble fertilizer, the ph is 6.0-8.0, and there is no corrosion to pouring pipelines and nozzles.
Description
Technical field
The invention belongs to the water-soluble fertilizer production field, be specifically related to a kind of macroelement water-soluble fertilizer and preparation method thereof.
Background technology
The macroelement water-soluble fertilizer can utilize the raw materials such as dipotassium hydrogen phosphate, phosphoric acid, urea, ammonium nitrate, trace element fertilizer, forms through adding the auxiliary agent science bedding-ins such as sequestrant, solubilizing agent, treating compound.Current China uses the Freshwater resources in the world 6% to account for the arable land in the world 9%, produces the agricultural-food that account for the world 26%, has supported the total population amount in the world 21%, has been to have created miracle.But look forward to the future, because the huge and increase of the scarcity in China's fresh water and arable land, the size of population is rapid, solve China people's problem concerning life, pressure is still very large, and situation allows of no optimist, and must find one to make the fast way of volume increase of agricultural-food.
Macroelement water-soluble fertilizer is through water dissolution or dilution, is used for the liquid or solid fertilizer that the purposes such as root is dipped in fertigation, leaf dressing, soilless culture, seed soaking.This fertilizer solubility is good, and nutrient is comprehensive, and Crop is fast, and produce effects is rapid; Plant recovery of nutrient is high, can reach 50%--70%; Prescription can be adjusted the nutrient proportioning by the needs of crop flexibly; Solubleness is high, impurity is few, not the shower nozzle of clogging drip irrigation or sprinkling irrigation; The Macroelement water-soluble fertilizer consumption is few, and utilization ratio is high, without unnecessary fertilizer pollution soil.Farm crop use Macroelement water-soluble fertilizer significantly to increase output, improve quality of agricultural product.In addition, using this fertilizer to also have a large advantage, is exactly water saving.Therefore, Macroelement water-soluble fertilizer has accounted for more than 60% of whole fertilizer in developed country, has also caused the very big concern of China's agricultural fertilizer circle now, also will be at the propagation and employment of China's rapid large-area.It not only will be in the plantation of the facility in the whole nation overall application, also will extensively be promoted the vast arid area in the Huaihe River of China, to the north of the Qinling Mountains.
Summary of the invention
The object of the present invention is to provide a kind of macroelement water-soluble fertilizer and preparation method thereof, the present invention adopts the generation amino acid such as acid hydrolysis feather, then centering, trace element carry out chelating, carboxymethyl cellulose has increased its chelate structure, in being conducive to, trace element effectively utilizes, in having reduced, the invalid release of trace element; It is very high that water-soluble fertilizer of the present invention contains nutrient, and production art is simple, reduced evaporation, crystallization and stoving process, and the dipotassium hydrogen phosphate solution of producing can directly be used for preparing this liquid water-soluble fertilizer, and ph is 6.0～8.0, do not corrode pipeline and the shower nozzle of pouring.
The present invention adopts following technical scheme to achieve these goals:
A kind of macroelement water-soluble fertilizer is characterized in that the weight part of its constitutive material is: dipotassium hydrogen phosphate 50-60, phosphoric acid 5-7, urea 33-38, zinc chloride 0.8-1.2, instant boron 2-4, disodium ethylene diamine tetraacetate 2-3, animal hair, feather 1-2, ammonium nitrate 8-12, Stemona Root 2-4, vinasse 3-5, Swamp Mahogany Leaf 5-7, Caulis Sacchari sinensis leaf 7-9, modification trees ash 2-5, trace element fertilizer 4-6 and water 60-70.
Described macroelement water-soluble fertilizer is characterized in that the weight part of its constitutive material is: dipotassium hydrogen phosphate 55, phosphoric acid 6, urea 35, zinc chloride 1, instant boron 3, disodium ethylene diamine tetraacetate 2.5, animal hair, feather 1, ammonium nitrate 10, Stemona Root 3, vinasse 4, Swamp Mahogany Leaf 6, Caulis Sacchari sinensis leaf 8, modification trees ash 3.5, trace element fertilizer 5 and water 65.
The preparation method of described macroelement water-soluble fertilizer is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, first animal hair, feather etc. are added 25-35% sulfuric acid 60-80 ℃ of lower hydrolysis 8-10 hour, generate amino acid, then add the lime neutralization, per 15 weight parts hydrolysis liquid adds 3-4 weight part carboxymethyl cellulose, add again phosphoric acid, urea, trace element fertilizer, ammonium nitrate dissolving, generate little, the middle fertilizer liquid of chelating amino acids;
(2) little, the middle fertilizer liquid of chelating amino acids and dipotassium hydrogen phosphate, the disodium ethylene diamine tetraacetate that step (1) are generated mix, then add water dissolution, behind dissolve complete, add zinc chloride, instant boron, Stemona Root, vinasse, Swamp Mahogany Leaf, Caulis Sacchari sinensis leaf and modification trees ash, stir, add the fertilizer starter and carry out just fermentation, fermented 13-15 days, leavening temperature is controlled at 50-55 ℃, regulate water content 40-45%, potential of hydrogen 5.0-6.0;
(3) fermented product after the just fermentation of step (2) is mixed, carry out Secondary Fermentation, fermented 7-9 days, leavening temperature is controlled at 60-70 ℃; Dry after the fermentation, granulation obtains finished product.
Described macroelement water-soluble fertilizer, it is characterized in that: described modification trees ash preparation method adds the trees ash in (0.8～1.2) g/L potassium permanganate solution, the 8-10% sodium hydroxide solution to soak, remove impurity, then filtration washing is neutral, the polyvinyl alcohol that adds again 10-15% adds the 3-5% ammonium molybdate again and mixes in the lump, heats 60-70 ℃, kept 50-60 minute, and obtained in high speed dispersion 10-20 minute again.
Described macroelement water-soluble fertilizer is characterized in that: described granulation fertilizer is proceeded the following step:
(1), diatomite is put into 3 times of water gagings, add again nano-sized carbon, the 4-5% of the sodium laurylsulfate that is equivalent to diatomite weight 2-3%, 1-2% wintergreen oil, 3-5% aluminium hydroxide,, high speed 5200-6500 rev/min of stirring obtains dispersion pulp;
(2), dispersion pulp is sprayed at outside the described fertiliser granulates oven dry;
(3) the pyrethroid mixture of spraying again outside particle again, then oven dry can not sprayed yet.
Beneficial effect of the present invention:
The present invention adopts acid hydrolysis feather etc. to generate amino acid, and then centering, trace element carry out chelating, and carboxymethyl cellulose has increased its chelate structure, in being conducive to, trace element effectively utilizes, in having reduced, the invalid release of trace element; It is very high that water-soluble fertilizer of the present invention contains nutrient, and production art is simple, reduced evaporation, crystallization and stoving process, and the dipotassium hydrogen phosphate solution of producing can directly be used for preparing this liquid water-soluble fertilizer, and ph is 6.0～8.0, do not corrode pipeline and the shower nozzle of pouring.
Embodiment
Embodiment 1:
A kind of macroelement water-soluble fertilizer is characterized in that the weight part (kilogram) of its constitutive material is: dipotassium hydrogen phosphate 55, phosphoric acid 6, urea 35, zinc chloride 1, instant boron 3, disodium ethylene diamine tetraacetate 2.5, animal hair, feather 1, ammonium nitrate 10, Stemona Root 3, vinasse 4, Swamp Mahogany Leaf 6, Caulis Sacchari sinensis leaf 8, modification trees ash 3.5, trace element fertilizer 5 and water 65.
The preparation method is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, first animal hair, feather etc. being added the 3(kilogram) 25-35% sulfuric acid is 60-80 ℃ of lower hydrolysis 8-10 hour, generate amino acid, then add the lime neutralization, concern in proportion 15:3-4, per 15 weight parts hydrolysis liquid adds 3-4 weight part carboxymethyl cellulose, adds phosphoric acid, urea, trace element fertilizer, ammonium nitrate dissolving again, generates little, the middle fertilizer liquid of chelating amino acids;
(2) little, the middle fertilizer liquid of chelating amino acids and dipotassium hydrogen phosphate, the disodium ethylene diamine tetraacetate that step (1) are generated mix, then add water dissolution, behind dissolve complete, add zinc chloride, instant boron, Stemona Root, vinasse, Swamp Mahogany Leaf, Caulis Sacchari sinensis leaf and modification trees ash, stir, add the fertilizer starter and carry out just fermentation, fermented 13-15 days, leavening temperature is controlled at 50-55 ℃, regulate water content 40-45%, acidity-basicity ph value 5.0-6.0;
(3) fermented product after the just fermentation of step (2) is mixed, carry out Secondary Fermentation, fermented 7-9 days, leavening temperature is controlled at 60-70 ℃; Dry after the fermentation, granulation obtains finished product.
Modification trees ash preparation method adds the trees ash respectively in (0.8～1.2) g/L potassium permanganate solution, the 8-10% sodium hydroxide solution to soak 10-15 minute, remove impurity, then filtration washing is neutral, add again the polyvinyl alcohol that is equivalent to trees ash weight 10-15%, adding the 3-5% ammonium molybdate mixes in the lump again, heat 60-70 ℃, kept 50-60 minute, obtained in high speed dispersion 10-20 minute again.
The field experiment data of the macroelement water-soluble fertilizer that above-described embodiment makes:
On embodiment 1 granulation fertilizer basis, proceed the following step:
Described granulation fertilizer is proceeded the following step:
(1), diatomite is put into 3 times of water gagings, add again nano-sized carbon, the 4-5% of the sodium laurylsulfate that is equivalent to diatomite weight 2-3%, 1-2% wintergreen oil, 3-5% aluminium hydroxide,, high speed 5200-6500 rev/min of stirring obtains dispersion pulp;
(2), dispersion pulp is sprayed at outside the described fertiliser granulates oven dry;
(3) the pyrethroid mixture of spraying again outside particle again, then oven dry can not sprayed yet.
Above way can reduce rate of fertilizer 10-15%, and fertilizer efficiency is the same.
Claims (5)
1. a macroelement water-soluble fertilizer is characterized in that the weight part of its constitutive material is: dipotassium hydrogen phosphate 50-60, phosphoric acid 5-7, urea 33-38, zinc chloride 0.8-1.2, instant boron 2-4, disodium ethylene diamine tetraacetate 2-3, animal hair, feather 1-2, ammonium nitrate 8-12, Stemona Root 2-4, vinasse 3-5, Swamp Mahogany Leaf 5-7, Caulis Sacchari sinensis leaf 7-9, modification trees ash 2-5, trace element fertilizer 4-6 and water 60-70.
2. macroelement water-soluble fertilizer according to claim 1 is characterized in that the weight part of its constitutive material is: dipotassium hydrogen phosphate 55, phosphoric acid 6, urea 35, zinc chloride 1, instant boron 3, disodium ethylene diamine tetraacetate 2.5, animal hair, feather 1, ammonium nitrate 10, Stemona Root 3, vinasse 4, Swamp Mahogany Leaf 6, Caulis Sacchari sinensis leaf 8, modification trees ash 3.5, trace element fertilizer 5 and water 65.
3. the preparation method of a macroelement water-soluble fertilizer as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, first animal hair, feather etc. are added 25-35% sulfuric acid 60-80 ℃ of lower hydrolysis 8-10 hour, generate amino acid, then add the lime neutralization, per 15 weight parts hydrolysis liquid adds 3-4 weight part carboxymethyl cellulose, add again phosphoric acid, urea, trace element fertilizer, ammonium nitrate dissolving, generate little, the middle fertilizer liquid of chelating amino acids;
(2) little, the middle fertilizer liquid of chelating amino acids and dipotassium hydrogen phosphate, the disodium ethylene diamine tetraacetate that step (1) are generated mix, then add water dissolution, behind dissolve complete, add zinc chloride, instant boron, Stemona Root, vinasse, Swamp Mahogany Leaf, Caulis Sacchari sinensis leaf and modification trees ash, stir, add the fertilizer starter and carry out just fermentation, fermented 13-15 days, leavening temperature is controlled at 50-55 ℃, regulate water content 40-45%, potential of hydrogen 5.0-6.0;
(3) fermented product after the just fermentation of step (2) is mixed, carry out Secondary Fermentation, fermented 7-9 days, leavening temperature is controlled at 60-70 ℃; Dry after the fermentation, granulation obtains finished product.
4. macroelement water-soluble fertilizer according to claim 1, it is characterized in that: described modification trees ash preparation method adds the trees ash in (0.8～1.2) g/L potassium permanganate solution, the 8-10% sodium hydroxide solution to soak, remove impurity, then filtration washing is neutral, the polyvinyl alcohol that adds again 10-15% adds the 3-5% ammonium molybdate again and mixes in the lump, heats 60-70 ℃, kept 50-60 minute, and obtained in high speed dispersion 10-20 minute again.
5. macroelement water-soluble fertilizer according to claim 1, it is characterized in that: described granulation fertilizer is proceeded the following step:
(1), diatomite is put into 3 times of water gagings, add again nano-sized carbon, the 4-5% of the sodium laurylsulfate that is equivalent to diatomite weight 2-3%, 1-2% wintergreen oil, 3-5% aluminium hydroxide,, high speed 5200-6500 rev/min of stirring obtains dispersion pulp;
(2), dispersion pulp is sprayed at outside the described fertiliser granulates oven dry;
(3) the pyrethroid mixture of spraying again outside particle again, then oven dry can not sprayed yet.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107826A (en) * | 1994-11-18 | 1995-09-06 | 钟福才 | Efficient fertilizer for spraying plant root and its processing method |
| HU215560B (en) * | 1991-06-07 | 1999-01-28 | AGROTERM Kft. | Process for the production of solid leaf-mould compositions with water solubility containing macro- and micro -nutritives and the leaf-mould compositions |
| CN101381251A (en) * | 2008-09-24 | 2009-03-11 | 广东省农业科学院土壤肥料研究所 | Ecological organic fertilizer and preparation method thereof |
| CN102584420A (en) * | 2011-12-01 | 2012-07-18 | 北京雷力农用化学有限公司 | Functional composite liquid fertilizer and preparation method thereof |
-
2012
- 2012-10-30 CN CN201210423305.4A patent/CN102942412B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU215560B (en) * | 1991-06-07 | 1999-01-28 | AGROTERM Kft. | Process for the production of solid leaf-mould compositions with water solubility containing macro- and micro -nutritives and the leaf-mould compositions |
| CN1107826A (en) * | 1994-11-18 | 1995-09-06 | 钟福才 | Efficient fertilizer for spraying plant root and its processing method |
| CN101381251A (en) * | 2008-09-24 | 2009-03-11 | 广东省农业科学院土壤肥料研究所 | Ecological organic fertilizer and preparation method thereof |
| CN102584420A (en) * | 2011-12-01 | 2012-07-18 | 北京雷力农用化学有限公司 | Functional composite liquid fertilizer and preparation method thereof |
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