CN106187598A - Silico-calcium capsule fertilizer and preparation method thereof - Google Patents

Silico-calcium capsule fertilizer and preparation method thereof Download PDF

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Publication number
CN106187598A
CN106187598A CN201610549019.0A CN201610549019A CN106187598A CN 106187598 A CN106187598 A CN 106187598A CN 201610549019 A CN201610549019 A CN 201610549019A CN 106187598 A CN106187598 A CN 106187598A
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China
Prior art keywords
parts
fertilizer
agricultural
silico
calcium capsule
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CN201610549019.0A
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Chinese (zh)
Inventor
李振轩
祝小娟
肖小樊
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HENAN JINDIBAO ECOLOGICAL FERTILIZER INDUSTRY Co Ltd
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HENAN JINDIBAO ECOLOGICAL FERTILIZER INDUSTRY Co Ltd
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Priority to CN201610549019.0A priority Critical patent/CN106187598A/en
Publication of CN106187598A publication Critical patent/CN106187598A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B5/00Thomas phosphate; Other slag phosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to agriculture field, be silico-calcium capsule fertilizer being suitable for modern agriculture and preparation method thereof.According to parts by weight, silico-calcium capsule fertilizer, includes that following components forms: mine tailings, ammonium sulfate, agricultural magnesium sulfate, agricultural zinc sulfate, agricultural ferrous sulfate, agricultural Borax, silicon dioxide, soluble starch, trace element, bentonite, hydrophilic high molecular material, surface active agent, citric acid powder, aminoacid, Cortex Meliae, Fructus Quisqualis, Galla Chinensis, Radix Ilicis Pubescentis, Fructus Sapindi Mukouossi episperm, Rhizoma Atractylodis, cellulase.The present invention is practical, can effectively solve the problem such as pest and disease damage, nutrient substance low, the salt-affected soil of utilization rate unbalanced, fertilizer.

Description

Silico-calcium capsule fertilizer and preparation method thereof
Technical field
The invention belongs to Crop fertilizer field, the silico-calcium capsule fertilizer of a kind of applicable modern agriculture and Its preparation method.
Background technology
Existing complex fertilizer product formula is unreasonable, solely pursues high nitrogen or Gao Jia class compound fertilizer, and blindness is big, utilizes Rate is low, and have even causes quality of agricultural product low, endangers consumer health;Physical behavior is bad, and dust is many, not resistance to compression, knot Block, is not easy to store, transport and apply fertilizer.From the point of view of crops, its growth supplementing necessary not only for various elements, in addition it is also necessary to One suitable soil environment.And silico-calcium capsule fertilizer is exactly a kind of compound fertilizer rich in multielement, plant can be met Growth demand, each element is through miniaturization surface coating modification, it is to avoid deliquescence, caking, the generation of metathesis reaction after compounding, It is effectively prevented the fertilizer efficiency loss that after being dissolved in water, nutrient Ion leakage causes.Its aminoacid can reduce the pH value in salt-soda soil again can Supplement a large amount of organic for soil;Soluble starch, citric acid are not only the cross-linking agent forming cellulose gel, are also equipped with salt In stain soil, harmful ion possesses absorption, exchange and buffer capacity, it is achieved that the nutrient slow release in soil, the biggest Improve greatly utilization rate of fertilizer, reduce the fertilising secondary salt damage to soil.The Chinese medicine ingredients added in the present invention is multiple with other compositions Close, on the premise of increasing the soil organism, reduce the probability of plant infection pest and disease damage.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, it is provided that the production technology of silico-calcium capsule fertilizer.The present invention is practical, can Effectively solve that pest and disease damage, nutrient substance utilization rate unbalanced, fertilizer be low, salt-affected soil problem.
First technical problem to be solved by this invention there is provided a kind of silico-calcium capsule fertilizer fertilizer.
According to parts by weight, a kind of silico-calcium capsule fertilizer fertilizer, includes that following components forms: mine tailings 60~80 parts, sulphuric acid Ammonium 16~25 parts, agricultural magnesium sulfate 15~25 parts, agricultural zinc sulfate 1~2 parts, agricultural ferrous sulfate 1~2 parts, agricultural Borax 1~ 2 parts, silica 1~2 parts, soluble starch 3~10 parts, trace element 4~7 parts, bentonite 3~8 parts, hydrophilic macromolecule Material 15~25 parts, surface active agent 5~10 parts, citric acid powder 1~5 parts, aminoacid 5~20 parts, Melia azedarach L. Skin 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi episperm 5~15 parts, grey Art 10~15 parts, cellulase 1~2 parts.
Concrete, described mine tailings are the phosphorus emplaster during MAP produces.
Concrete, described surfactant is a kind of in sucrose ester, alkylsulfonate, amino acid salts or any several groups Close.
Concrete, it is characterised in that described hydrophilic high molecular material is in dimension element derivant, chitosan, sodium alginate A kind of or any several combination.
Concrete, it is characterised in that described trace element is copper amino acid chelate: chelating amino acids manganese: chelating amino acids Molybdenum is made according to the weight ratio of 1:0.3~0.5:1.
Second technical problem to be solved by this invention there is provided the preparation method of above-mentioned fertilizer.
Technical scheme: in order to solve above-mentioned technical problem, it is provided that the preparation method of silico-calcium capsule fertilizer, including following step Rapid:
A, by mine tailings 60~80 parts, ammonium sulfate 16~25 parts, bentonite 3~8 parts of mix homogeneously, be allowed to react certain time;
B, in the product of step A add agricultural magnesium sulfate 15~25 parts, agricultural zinc sulfate 1~2 parts, agricultural ferrous sulfate 1~2 Part, agricultural Borax 1~2 parts, continue reaction after mix homogeneously;
C, take outside Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi plant Skin 5~15 parts, Rhizoma Atractylodis 10~15 parts soak and add surface active agent 5~10 parts, titanium dioxide after pulverizing in water Silicon 1~2 parts, cellulase 1~2 parts carry out enzymolysis, control temperature, are filtrated to get herb liquid and are dried to powder and product in step B Uniformly mixing, dries and makes granule;
D, citric acid powder 1~5 parts being added water is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 4~7 parts are uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Particle surface sprays atomized water by particle surface moistening, adds aminoacid 5~20 parts, hydrophilic high molecular material 15~25 successively Part in sugar coating machine, making aminoacid be coated on the surface of granulated fertilizer, hydrophilic high molecular material is wrapped in granulated fertilizer outermost Layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment Powder 3~10 parts, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain silico-calcium capsule fertilizer after drying.
The invention provides silico-calcium capsule fertilizer, product is with mine tailings, Cortex Meliae, Fructus Quisqualis, Galla Chinensis, Radix Ilicis Pubescentis, nothing Suffer from sub-episperm, Rhizoma Atractylodis are raw material, are aided with surfactant, trace element, hydrophilic high molecular material etc., pass through coating technology Prepare.
For silico-calcium capsule fertilizer, the effective ingredient in its Chinese medicine can effective the sending out of bacteria growing inhibiting and pest and disease damage Raw;: the recycling of mine tailings;To increasing the soil organism, improve soil physico-chemical property and will get positive effect;Achieve foster Divide the slow release in soil, be on the one hand greatly improved utilization rate of fertilizer, reduce the secondary salt damage applied fertilizer to soil, the opposing party Face, can significantly improve soil fertility, free salinity superfluous in absorption salt-soda soil, improve the sustainable production capacity of soil;Two The absorption property that silicon oxide bentonite isoreactivity material is good can ensure the slow release of fertilizer;Hydrophilicity macromolecule material used by the present invention Material and soluble starch, nonhazardous and environmentally degradable, can form stable hydrogel after a large amount of water suction that is manured into soil, have relatively Good water holding capacity, can slow down the evaporation of soil moisture, slowly discharge the moisture stored so that it is fully be inhaled by crops Receive, promote crop growth, be effectively improved the utilization rate of water resource;Salinized soil is had non-by hydrophilic high molecular material and aminoacid The most significantly improved effect, aminoacid can not only supplement the organic matter lacked in salt-affected soil, moreover it is possible to reduces the pH of salt-affected soil Value, moreover it is possible to stimulating crop root growth, the lapping as fertilizer can make fertilizer slowly discharge in soil.This product has Preferably biocompatibility, biodegradability, belong to environmental friendly fertilizer, beneficially the sustainable development of resource.
Detailed description of the invention
The preparation of silico-calcium capsule fertilizer, comprises the following steps:
A, by mine tailings 70 parts, 20 parts of ammonium sulfate, 5 parts of mix homogeneously of bentonite, be allowed to react certain time;
B, in the product of step A add agricultural 20 parts of magnesium sulfate, agricultural 1 part of zinc sulfate, agricultural 1 part of ferrous sulfate, agricultural boron 1 part of sand, continues reaction after mix homogeneously;
C, take Cortex Meliae 40 parts, Fructus Quisqualis 10 parts, Galla Chinensis 5 parts, Radix Ilicis Pubescentis 10 parts, Fructus Sapindi Mukouossi episperm 5 parts, 10 parts of powder of Rhizoma Atractylodis Soak and add surface active agent 5 parts after broken in water, silicon dioxide 2 parts, cellulase 2 parts carry out enzymolysis, control Temperature processed, is filtrated to get herb liquid and is dried to powder and uniformly mixes with product in step B, dries and makes granule;
D, being added water by 3 parts of citric acid powder is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 3 parts is uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Atomized water is sprayed by particle surface moistening in grain surface, adds 8 parts of aminoacid, hydrophilic high molecular material 15 parts successively to sugar coating machine In, make aminoacid be coated on the surface of granulated fertilizer, hydrophilic high molecular material is wrapped in granulated fertilizer outermost layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment 10 parts of powder, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain silico-calcium capsule fertilizer after drying.
The silico-calcium capsule fertilizer that the present invention prepares understands after testing: application of the crops upgrading of the fertilizer of the present invention Effect of increasing production is the most obvious.The clad of this product can be degraded, and does not results in soil pollution, energy after a large amount of water suction that is manured into soil Form stable hydrogel, there is preferable water holding capacity, the evaporation of soil moisture can be slowed down, slowly discharge the water stored Point so that it is fully absorbed by crops, promote crop growth, be effectively improved the utilization rate of water resource;Silicon dioxide bentonite The absorption property that isoreactivity material is good can ensure the slow release of fertilizer;Salinized soil is had non-by hydrophilic high molecular material and aminoacid The most significantly improved effect, aminoacid can not only supplement the organic matter lacked in salt-affected soil, moreover it is possible to reduces the pH of salt-affected soil Value, moreover it is possible to stimulating crop root growth, the lapping as fertilizer can make fertilizer slowly discharge in soil.This product has Preferably biocompatibility, biodegradability, belong to environmental friendly fertilizer, beneficially the sustainable development of resource;The most real Show the nutrient slow release in soil, be on the one hand greatly improved utilization rate of fertilizer, reduce the fertilising secondary salt damage to soil, On the other hand, can significantly improve soil fertility, free salinity superfluous in absorption salt-soda soil, improve the sustainable production energy of soil Power;Each element is through miniaturization surface coating modification, it is to avoid deliquescence, caking, the generation of metathesis reaction after compounding, effectively The fertilizer efficiency loss that after preventing Water soluble fertilizer to be dissolved in water, nutrient Ion leakage causes.

Claims (6)

1. silico-calcium capsule fertilizer, it is characterised in that include that following components forms according to parts by weight: mine tailings 60~80 parts, sulfur Acid ammonium 16~25 parts, agricultural magnesium sulfate 15~25 parts, agricultural zinc sulfate 1~2 parts, agricultural ferrous sulfate 1~2 parts, agricultural Borax 1 ~2 parts, silica 1~2 parts, soluble starch 3~10 parts, trace element 4~7 parts, bentonite 3~8 parts, hydrophilic high score Sub-material 15~25 parts, surface active agent 5~10 parts, citric acid powder 1~5 parts, aminoacid 5~20 parts, hardship Chinaberry skin 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi episperm 5~15 parts, Rhizoma Atractylodis 10~15 parts, cellulase 1~2 parts.
Silico-calcium capsule fertilizer the most according to claim 1, it is characterised in that described mine tailings are during MAP produces Phosphorus emplaster.
Silico-calcium capsule fertilizer the most according to claim 1, it is characterised in that described surfactant is sucrose ester, alkyl A kind of or any several combination in sulfonate, amino acid salts.
Silico-calcium capsule fertilizer the most according to claim 1, it is characterised in that described hydrophilic high molecular material spreads out for dimension element A kind of or any several combination in biology, chitosan, sodium alginate.
Silico-calcium capsule fertilizer the most according to claim 1, it is characterised in that described trace element is copper amino acid chelate: Chelating amino acids manganese: chelating amino acids molybdenum is made according to the weight ratio of 1:0.3~0.5:1.
The preparation method of silico-calcium capsule fertilizer the most according to claim 1, it is characterised in that comprise the following steps:
A, by mine tailings 60~80 parts, ammonium sulfate 16~25 parts, bentonite 3~8 parts of mix homogeneously, be allowed to react certain time;
B, in the product of step A add agricultural magnesium sulfate 15~25 parts, agricultural zinc sulfate 1~2 parts, agricultural ferrous sulfate 1~2 Part, agricultural Borax 1~2 parts, continue reaction after mix homogeneously;
C, take outside Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi plant Skin 5~15 parts, Rhizoma Atractylodis 10~15 parts soak and add surface active agent 5~10 parts, titanium dioxide after pulverizing in water Silicon 1~2 parts, cellulase 1~2 parts carry out enzymolysis, control temperature, are filtrated to get herb liquid and are dried to powder and product in step B Uniformly mixing, dries and makes granule;
D, citric acid powder 1~5 parts being added water is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 4~7 parts are uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Particle surface sprays atomized water by particle surface moistening, adds aminoacid 5~20 parts, hydrophilic high molecular material 15~25 successively Part in sugar coating machine, making aminoacid be coated on the surface of granulated fertilizer, hydrophilic high molecular material is wrapped in granulated fertilizer outermost Layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment Powder 3~10 parts, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain silico-calcium capsule fertilizer after drying.
CN201610549019.0A 2016-07-13 2016-07-13 Silico-calcium capsule fertilizer and preparation method thereof Pending CN106187598A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085017A (en) * 2017-12-29 2018-05-29 薛彦芳 A kind of salt-soda soil soil conditioner and preparation method thereof
CN108178682A (en) * 2017-12-29 2018-06-19 广东大众农业科技股份有限公司 A kind of biomass carbon soil conditioner of siliceous calcium and magnesium and preparation method thereof
CN110734336A (en) * 2019-11-28 2020-01-31 哈尔滨坤丰生物工程有限公司 microelement empty capsule used by plants and application method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343198A (en) * 2007-07-09 2009-01-14 襄樊隆福矿业有限公司 Complex fertilizer prepared with industry tail slag special for tobacco leaf and preparation method thereof
CN103396213A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich microcapsule fertilizer and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343198A (en) * 2007-07-09 2009-01-14 襄樊隆福矿业有限公司 Complex fertilizer prepared with industry tail slag special for tobacco leaf and preparation method thereof
CN103396213A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich microcapsule fertilizer and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘程等: "《表面活性剂性质理论与应用》", 30 June 2003, 北京工业大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085017A (en) * 2017-12-29 2018-05-29 薛彦芳 A kind of salt-soda soil soil conditioner and preparation method thereof
CN108178682A (en) * 2017-12-29 2018-06-19 广东大众农业科技股份有限公司 A kind of biomass carbon soil conditioner of siliceous calcium and magnesium and preparation method thereof
CN110734336A (en) * 2019-11-28 2020-01-31 哈尔滨坤丰生物工程有限公司 microelement empty capsule used by plants and application method thereof

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Application publication date: 20161207