CN105218235B - Preparation method of nutritional water-retaining soil-loosening compound fertilizer - Google Patents
Preparation method of nutritional water-retaining soil-loosening compound fertilizer Download PDFInfo
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- CN105218235B CN105218235B CN201510643407.0A CN201510643407A CN105218235B CN 105218235 B CN105218235 B CN 105218235B CN 201510643407 A CN201510643407 A CN 201510643407A CN 105218235 B CN105218235 B CN 105218235B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 102
- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 150000001875 compounds Chemical class 0.000 title abstract description 5
- 235000016709 nutrition Nutrition 0.000 title abstract description 4
- 239000002689 soil Substances 0.000 claims abstract description 101
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 58
- 102000004190 Enzymes Human genes 0.000 claims abstract description 40
- 108090000790 Enzymes Proteins 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 37
- 229920002101 Chitin Polymers 0.000 claims abstract description 30
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000015097 nutrients Nutrition 0.000 claims abstract description 27
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 21
- 229920001661 Chitosan Polymers 0.000 claims abstract description 18
- 239000011573 trace mineral Substances 0.000 claims abstract description 18
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 13
- 230000001070 adhesive effect Effects 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- 210000002421 cell wall Anatomy 0.000 claims abstract description 10
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 8
- 238000012216 screening Methods 0.000 claims abstract description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000005469 granulation Methods 0.000 claims abstract description 5
- 230000003179 granulation Effects 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 230000000717 retained effect Effects 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 21
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 14
- 239000004327 boric acid Substances 0.000 claims description 14
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 14
- 229960001763 zinc sulfate Drugs 0.000 claims description 14
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 14
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000004365 Protease Substances 0.000 claims description 12
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 12
- 229940072033 potash Drugs 0.000 claims description 12
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 12
- 235000015320 potassium carbonate Nutrition 0.000 claims description 12
- 108091005804 Peptidases Proteins 0.000 claims description 11
- 239000002686 phosphate fertilizer Substances 0.000 claims description 11
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 10
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 10
- 239000011790 ferrous sulphate Substances 0.000 claims description 10
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 10
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 10
- 229940099596 manganese sulfate Drugs 0.000 claims description 10
- 235000007079 manganese sulphate Nutrition 0.000 claims description 10
- 239000011702 manganese sulphate Substances 0.000 claims description 10
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 10
- 238000000855 fermentation Methods 0.000 claims description 9
- 230000004151 fermentation Effects 0.000 claims description 9
- 239000005696 Diammonium phosphate Substances 0.000 claims description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 230000006837 decompression Effects 0.000 claims description 7
- 230000007062 hydrolysis Effects 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 6
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 6
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 6
- 235000011151 potassium sulphates Nutrition 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 235000013922 glutamic acid Nutrition 0.000 claims description 5
- 239000004220 glutamic acid Substances 0.000 claims description 5
- 230000000149 penetrating effect Effects 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 3
- 230000000813 microbial effect Effects 0.000 claims description 3
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 3
- 239000006012 monoammonium phosphate Substances 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 239000007767 bonding agent Substances 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 2
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 2
- 235000019419 proteases Nutrition 0.000 claims 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
- 101000693530 Staphylococcus aureus Staphylokinase Proteins 0.000 claims 1
- 235000007686 potassium Nutrition 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 11
- 238000001035 drying Methods 0.000 abstract description 4
- 230000009467 reduction Effects 0.000 abstract description 4
- 230000009920 chelation Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 12
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- 235000002017 Zea mays subsp mays Nutrition 0.000 description 12
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 11
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- 239000000126 substance Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
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- 230000020176 deacylation Effects 0.000 description 3
- 238000005947 deacylation reaction Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
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- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- MPNNOLHYOHFJKL-UHFFFAOYSA-N peroxyphosphoric acid Chemical group OOP(O)(O)=O MPNNOLHYOHFJKL-UHFFFAOYSA-N 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
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- 229930192334 Auxin Natural products 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 101710099573 Casein kinase II subunit alpha Proteins 0.000 description 1
- 101710159482 Casein kinase II subunit alpha' Proteins 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 101710180313 Protease 3 Proteins 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- MBLBDJOUHNCFQT-LXGUWJNJSA-N aldehydo-N-acetyl-D-glucosamine Chemical compound CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 description 1
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- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
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Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a preparation method of a nutritional water-retaining soil-loosening compound fertilizer, which comprises the following steps: step one, preparing a compound enzyme solution; step two, putting the trace elements into gamma-polyglutamic acid solution for chelation reaction to prepare a granulation adhesive; step three, selecting a medicine, an enzyme preparation and citric acid, fermenting and filter-pressing to obtain mycelium residues, putting the mycelium residues into a high-temperature high-pressure wall breaking tank, introducing saturated steam, and instantly reducing pressure to break cell walls of the mycelium to prepare an organic mixture of chitin and chitosan; and step four, drying and crushing the organic mixed material obtained in the step three to obtain a water-retaining soil-loosening master batch, mixing the water-retaining soil-loosening master batch with inorganic nutrients, uniformly stirring, putting the mixture into a granulator, spraying a granulation binder, granulating and screening to obtain the nutritional water-retaining soil-loosening compound fertilizer. The invention has the advantages of rich nutrients, reduction of water and soil loss, improvement of soil moisture content, increase of soil volume weight, loosening of soil, remarkable improvement of nutrient utilization rate and promotion of agricultural yield increase.
Description
Technical field
The present invention relates to a kind of preparation methods of complex fertilizer more particularly to a kind of auxotype to be retained the complex fertilizer that loosens the soil
Preparation method.
Background technology
Since chemical fertilizer input amount increases year by year, the use of a large amount of fertilizer and pesticides solves the problems, such as staple food supply, improves grain
Yield.But the use of a large amount of chemical fertilizer brings prodigious environmental problem year after year, and utilization rate of fertilizer declines, soil hardening, water conservation
Ability declines, and soil erosion is further exacerbated by the deterioration of soil physical chemistry environment, largely threatens the sustainable development of agricultural
Exhibition threatens grain security.
It is answered currently, most of complex fertilizer enterprises produce water conservation soil-loosening function by way of adding chemical floc
Complex fertilizer material, mainly there is two major classes:1, inorganic chemistry class, mainly aluminium polychloride, aluminum sulfate etc., there are apparent dosage compared with
Greatly, aluminium composition is high, has certain toxic action to crop, there is apparent enrichment effect, and threat is generated to human health, long
Phase applies, and secondary pollution is generated to soil;2, organic polymer class, mainly polyacrylamide, loosen the soil, Water-saving effect compared with
It is good, but it is formed using industrial chemicals acrylamide polymerization, a large amount of toxic acrylamide monomers is remained, to crops and human body
All toxic effect.Clay or bentonite are mostly used in existing complex fertilizer production technology as binder, dosage acts on when few
Less, dosage is big and reduces active constituent content, is not easy to dissolve in being manured into soil, and influences fertilizer release, to soil use not
Greatly.
And solve the above problems, and can be abundant with nutrient, soil erosion is reduced, soil moisture content is improved, increases soil
Unit weight, chesson significantly improve plant recovery of nutrient, the auxotype of agricultural production and income are promoted to be retained the complex fertilizer that loosens the soil,
It has not been reported in the prior art.
Invention content
It is an object of the invention to solve deficiency in the prior art, it is abundant to provide a kind of nutrient, can reduce water and soil stream
It loses, improves soil moisture content, increase the soil weight, chesson, the battalion for significantly improving plant recovery of nutrient, promoting agricultural production and income
The type of supporting is retained the preparation method for the complex fertilizer that loosens the soil.
To achieve the goals above, the technical solution of use is the present invention:
A kind of auxotype is retained the preparation method for the complex fertilizer that loosens the soil, and includes the following steps:
Step 1: preparing complex enzyme liquid:Choose protease, deacetylase mass ratio 1:1~2, complex enzyme hydrolysis preparation is obtained, with
Water mixture is preactivated, mass ratio 1:30~50, coolant-temperature gage is controlled at 30~45 DEG C, now with the current;
Step 2: preparing adhesive for granulating:Trace element is crushed to 60~80 mesh, puts into gamma-polyglutamic acid liquid, makes
Trace element carries out chelatropic reaction with gamma-polyglutamic acid in reaction kettle and prepares granulation bonding agent, pH value 4.5~7.0, reaction temperature
Degree control reacts 10~30min, trace element and gamma-polyglutamic acid mass ratio 10~50 at 30~45 DEG C:1000, micro member
Element is one or more of ferrous sulfate, zinc sulfate, copper sulphate, manganese sulfate, boric acid mixture;
Step 3: preparing chitin and chitosan organic mixture:Press filtration after selection pharmacy, enzyme preparation, citric acid fermentation,
The mycelium residue of obtained water content 60%~70%, wherein mycelium account for 60% or more, put into high temperature and pressure broken wall tank, lead to
Enter saturated vapor, until temperature reaches 110~120 DEG C in tank, after maintaining 10~20min, stops, for steam, into broken wall tank leading to
Enter pressure-air, until broken wall pressure tank reaches 1.0~1.5Mpa;Then instant decompression release makes pressure drop to normal pressure, makes mycelia
Body cell wall ruptures, and obtains the organic mixture rich in chitin, then puts into batch mixer, sprays into complex enzyme while stirring
Liquid is uniformly mixed, and pH controls digest 3.0~4.0 and digest 48h~96h in pond, and temperature is controlled at 25~45 DEG C, obtains crust
Element and chitosan organic mixture;
Step 4: the chitin and chitosan organic mixture material obtained by step 3 is dried at 80 DEG C, crushing 20~
40 mesh obtain being retained the masterbatch that loosens the soil;Loosen the soil masterbatch and inorganic nutrients of water conservation are mixed and stirred for uniformly, putting into comminutor, penetrating
The adhesive for granulating of step 3 preparation is granulated, screening, packs, obtains auxotype and be retained the complex fertilizer that loosens the soil.
Further, auxotype obtained by the step 4 is retained the complex fertilizer that loosens the soil, and composition weight percent is:Crust
Element and chitosan organic mixture 10 ~ 30%, inorganic nutrients 60 ~ 85%, adhesive for granulating 2 ~ 10%.
Further, the inorganic nutrients in the step 4 are nitrogenous fertilizer, phosphate fertilizer, potash fertilizer;The nitrogenous fertilizer is urea, nitric acid
One or more of ammonium, ammonium chloride or ammonium sulfate;The phosphate fertilizer is one kind in calcium superphosphate, monoammonium phosphate or Diammonium phosphate (DAP)
Or it is several;The potash fertilizer is one or more of potassium chloride, potassium nitrate, potassium dihydrogen phosphate or potassium sulfate.
Further, gamma-polyglutamic acid liquid is glutamic acid through obtained by microbial fermentation in the step 2, and concentration is
3.5%, trace element is ferrous sulfate 10%, zinc sulfate 60%, copper sulphate 5%, manganese sulfate 5%, the mixing of boric acid 20% or ferrous sulfate
5%, zinc sulfate 70%, copper sulphate 5%, manganese sulfate 5%, the mixing of boric acid 15% or zinc sulfate 70%, boric acid 30% mix.
Further, the nitrogenous fertilizer is urea;The phosphate fertilizer is Diammonium phosphate (DAP);The potash fertilizer is potassium sulfate.
Further, complex enzyme hydrolysis liquid straying quatity is 1 of the organic mixture quality rich in chitin in the step 3
~5 ‰;It digests pond and heat cycles pipe is set, summer room temperature digests 48h~72h, and winter heat cycles pipe digests 72~96h.
Further, be passed through saturated vapor in the step 3 high temperature high pressure broken wall tank, until in tank temperature reach 115~
120 DEG C, 15~20min is maintained, later, stops, for steam, pressure-air being passed through into broken wall tank, until broken wall pressure tank reaches
1.2~1.5Mpa;Then instant decompression is discharged into vapour and separates and collects in device admittedly, obtains the organic mixture rich in chitin.
Further, trace element and gamma-polyglutamic acid mass ratio 20~50 in the step 3:1000, temperature control
At 35~45 DEG C, 20~30min is reacted.
Further, complex enzyme and water mixture are preactivated in the step 1, mass ratio 1:30~40, water temperature control exists
35~40 DEG C, soak time is 30~60min.
Further, protease and deacetylase mass ratio 1 in the step 1:1~1.5;Protease is neutral protein
Enzyme.
The beneficial effects of the invention are as follows:Biofermentation industry mycelium residue is handled using physics steam explosion technology, moment is quick-fried
Broken bacteria cell wall, cell wall become very tiny, and the chitin being located on the inside of cell wall is enable directly to release, and coordinate
Complex enzyme formulation deacylation obtains the small molecule organic mixture rich in chitin and chitosan.High temperature and pressure wink during steam explosion
Between discharge, mycelium fiber formed rich in ultra micro gap spongy water-absorbing-retaining material, make full use of tunning, breach
The inorganic water-keeping material of chemistry, i.e. nuisance present in polyacrylamide, acrylates, polyaluminium chloride etc. are added in conventional fertilizers
Matter increases and the single limitation of product efficacy, effectively overcomes arid area and sand area, water shortage, not water holding, no
Fertilizer conservation, not drought-enduring, nutrient are easy to be lost in a series of problems, such as causing crop production reduction, soil erosion.
Creative utilizes bio-pharmaceuticals, enzyme preparation, citric acid fermentation trade waste, on the one hand uses instantaneous steam explosion skill
Art effectively kills various mushrooms, harmful worm's ovum in residue and achievees the purpose that deodorization, anti-self-dissolving;Biological enzymolysis deacylation makes chitosan
Content is further promoted, and chitosan is a kind of environmentally protective organic polymer coargulator, since it contains hydroxyl, carboxyl, ammonia
Base and other active groups can adsorb soil particle suitable for soil, form soil aggregate structure, reach ventilative, loosen the soil
Purpose, meanwhile, it is natural plant nutrient growth promoter, plant insecticide can be given, it is disease-resistant, play the role of fertilizer, and can divide
Plant and animal residues and minor metallic element in soil are solved, to be converted into the nutrient of plant, enhances via plant immunity, promotes to plant
The health of object mixes application with inorganic fertilizer, can dramatically increase the absorption of Plant To Nutrient element, promotes crop yield
It increases income.
Gamma-polyglutamic acid is biofermentation preparation, can be decomposed and be absorbed and utilized by edaphons such as bacteriums, to environment friend
It is good, with ultrahydrophilic and water holding capacity, when being applied in soil, thin film, tool can be formed on plant root hair surface layer
Have a function of protection root hair, nutrient even more in soil, moisture content and root hair intimate contact optimal transport platform, can be very efficient
Improve dissolving, storage, conveying and the absorption of fertilizer.With excellent metal ion chelating capacity, sulfuric acid can be effectively prevented
Root, phosphate radical, oxalate and metallic element generate precipitation, and crop is enable more effectively to absorb phosphorus in soil, calcium, magnesium and micro-
Secondary element promotes the development of crop root, enhances disease resistance, meanwhile, in biofermentation production process, generate raised growth element
It with class auxin substance, is manured into soil, absorption of the crop to various nutrients can be promoted, enhance crop anti-adversity, more conducively
Crop is got bumper crops, and quality is promoted.Using gamma-polyglutamic acid chelated microelement liquid as binder, replace traditional clay, swelling
Soil, while the dosage of steam is reduced, energy consumption is reduced, exhaust gas discharge is reduced, reduces production cost, itself is to crops and soil
There is good effect, for being granulated, particle is uniformly, bright, intensity is big, additionally provides organic matter, amino acid, humic acid, Neng Goujin
One step improves the effect and quality of complex fertilizer.
Specific implementation mode
With reference to embodiment, the invention will be further elaborated.
Content above and in materials described below refers both to weight or parts by weight.
Embodiment 1
A kind of auxotype is retained the preparation method for the complex fertilizer that loosens the soil, and includes the following steps:
Ferrous sulfate, zinc sulfate, copper sulphate, manganese sulfate, boric acid are chosen, 60 mesh sieve is crushed respectively, by ferrous sulfate
10%, zinc sulfate 60%, copper sulphate 5%, manganese sulfate 5%, 20% ratio of boric acid are uniformly mixed, and obtain microelement powder, spare;It chooses
Protease, deacetylase are uniformly mixed in protease 50%, 50% ratio of deacetylase, obtain complex enzyme, spare;By above-mentioned egg
White enzyme and deacetylase mass ratio 1:The complex enzyme of 1 proportional quantity, with warm water(35~40 DEG C)By complex enzyme:Warm water mixed ratio is
1:40 amounts are preactivated, and soak time is 30min, now with the current;
It is prepared by adhesive for granulating:Mixed trace elements obtained by above-mentioned steps are taken to measure 50kg input 1000kg γ-according to the ratio poly-
In glutamic acid liquid, chelatropic reaction is carried out in reaction kettle, and trace element and gamma-polyglutamic acid chelatropic reaction, temperature control is made to exist
30 ~ 35 DEG C, 30min is reacted, complex fertilizer adhesive for granulating is prepared;
The mycelium residue that press filtration obtains after selection pharmacy, enzyme preparation, citric acid fermentation(Water content 60%-70%), wherein
Mycelium accounts for 60% or more, puts into high temperature and pressure broken wall tank, is passed through saturated vapor, until temperature reaches 110 ~ 115 DEG C in tank, dimension
10 ~ 15min is held, later, stops, for steam, pressure-air being passed through into broken wall tank, until broken wall pressure tank reaches 1.2 ~ 1.5Mpa,
Maintain 10min;Then instant decompression release makes pressure drop to normal pressure, and mycelial cell wall is made to rupture, and obtains rich in chitin
Organic mixture is then put into batch mixer, sprays into the obtained complex enzyme liquid of above-mentioned steps while stirring, is uniformly mixed, pH
Control digests 48h in 3.0~4.0, input enzymolysis pond, and temperature is controlled at 35 DEG C~45 DEG C.Complex enzyme hydrolysis liquid straying quatity accounts for richness
Organic mixture ratio containing chitin is 5 ‰.The water conservation rich in chitin, chitosan is obtained to loosen the soil organic mixture;
Above-mentioned steps products therefrom is put into the equipment such as material drier, controls drying and dewatering at 80 DEG C of temperature, pulverizer
It is crushed to 40 mesh.Complex fertilizer raw material is chosen, the raw material is nitrogenous fertilizer, phosphate fertilizer, potash fertilizer.The nitrogenous fertilizer is urea, ammonium sulfate;Institute
It is peroxophosphoric acid diammonium to state phosphate fertilizer;The potash fertilizer is potassium sulfate.
Gained in above steps is obtained into object, that is, powder object, inorganic nutrients are measured be mixed and stirred for uniformly according to the ratio, input
Rotary drum granulator, penetrating binder are granulated, screening, pack, obtain auxotype and be retained the complex fertilizer that loosens the soil.Auxotype water conservation pine
Native complex fertilizer, by weight:It is retained the organic materials 10% that loosens the soil, inorganic nutrients 80%, binder 10%.
Embodiment 2
A kind of auxotype is retained the preparation method for the complex fertilizer that loosens the soil, and includes the following steps:
Choose ferrous sulfate, zinc sulfate, copper sulphate, manganese sulfate, boric acid, crushed respectively 60 mesh sieve, by ferrous sulfate 5%,
Zinc sulfate 70%, copper sulphate 5%, manganese sulfate 5%, 15% ratio of boric acid are uniformly mixed, and obtain microelement powder, spare;Choose albumen
Enzyme, deacetylase are uniformly mixed in protease 3 3%, 67% ratio of deacetylase, obtain complex enzyme, spare;By above-mentioned protease
With deacetylase mass ratio 1:The complex enzyme of 2 proportional quantities, with warm water(35 DEG C~40 DEG C)By complex enzyme:Warm water mixed ratio is 1:
40 amounts are preactivated, and soak time is 30min, now with the current;
It is prepared by adhesive for granulating:Mixed trace elements obtained by above-mentioned steps are taken to measure 40kg input 1000kg γ-according to the ratio poly-
In glutamic acid liquid, chelatropic reaction is carried out in reaction kettle, and trace element and gamma-polyglutamic acid chelatropic reaction, temperature control is made to exist
30 ~ 35 DEG C, 25min is reacted, complex fertilizer adhesive for granulating is prepared;
The mycelium residue that press filtration obtains after selection pharmacy, enzyme preparation, citric acid fermentation(Water content 60%-70%), wherein
Mycelium accounts for 60% or more, puts into high temperature and pressure broken wall tank, is passed through saturated vapor, until temperature reaches 115 ~ 120 DEG C in tank, dimension
15min is held, later, stops, for steam, pressure-air being passed through into broken wall tank, until broken wall pressure tank reaches 1.5Mpa, maintain
10min;Then instant decompression release makes pressure drop to normal pressure, and mycelial cell wall is made to rupture, and obtains organic rich in chitin
Mixture is then put into batch mixer, sprays into the obtained complex enzyme liquid of above-mentioned steps while stirring, is uniformly mixed, pH controls
In 3.0~4.0, input enzymolysis pond, 72h is digested, temperature is controlled at 35 DEG C~40 DEG C.Complex enzyme hydrolysis liquid straying quatity is accounted for rich in first
The organic mixture ratio of shell element is 5 ‰.The water conservation rich in chitin, chitosan is obtained to loosen the soil organic mixture;
Above-mentioned steps products therefrom is put into the equipment such as material drier, controls drying and dewatering at 80 DEG C of temperature, pulverizer
It is crushed to 40 mesh.Complex fertilizer raw material is chosen, the raw material is nitrogenous fertilizer, phosphate fertilizer, potash fertilizer.The nitrogenous fertilizer is urea, ammonium sulfate;Institute
It is peroxophosphoric acid monoammonium to state phosphate fertilizer;The potash fertilizer is potassium chloride.
Gained in above steps is obtained into object, that is, powder object, inorganic nutrients are measured be mixed and stirred for uniformly according to the ratio, input
Rotary drum granulator, penetrating binder are granulated, screening, pack, obtain auxotype and be retained the complex fertilizer that loosens the soil.Auxotype water conservation pine
Native complex fertilizer, by weight:It is retained the organic materials 15% that loosens the soil, inorganic nutrients 75%, binder 10%.
Embodiment 3
A kind of auxotype is retained the preparation method for the complex fertilizer that loosens the soil, and includes the following steps:
Zinc sulfate, boric acid are chosen, crushed 60 mesh sieve respectively, is uniformly mixed, obtains in zinc sulfate 70%, 30% ratio of boric acid
Microelement powder, it is spare;Protease, deacetylase are chosen, is uniformly mixed, obtains in protease 50%, 50% ratio of deacetylase
Complex enzyme, it is spare;By above-mentioned protease and deacetylase mass ratio 1:The complex enzyme of 1 proportional quantity, with warm water(35~40 DEG C)It presses
Complex enzyme:Warm water mixed ratio is 1:40 amounts are preactivated, and soak time is 30min, now with the current;
It is prepared by adhesive for granulating:Mixed trace elements obtained by above-mentioned steps are taken to measure 50kg input 1000kg γ-according to the ratio poly-
In glutamic acid liquid, chelatropic reaction is carried out in reaction kettle, and trace element and gamma-polyglutamic acid chelatropic reaction, temperature control is made to exist
30 ~ 35 DEG C, 30min is reacted, complex fertilizer adhesive for granulating is prepared;
It is prepared by chitin:The mycelium residue that press filtration obtains after selection pharmacy, enzyme preparation, citric acid fermentation(Water content
60%-70%), wherein mycelium accounts for 60% or more, puts into high temperature and pressure broken wall tank, saturated vapor is passed through, until temperature reaches in tank
110 ~ 115 DEG C, 10 ~ 15min is maintained, later, stops, for steam, pressure-air being passed through into broken wall tank, until broken wall pressure tank reaches
To 1.2 ~ 1.5Mpa, 10min is maintained;Then instant decompression release makes pressure drop to normal pressure, so that mycelial cell wall is ruptured, obtains
Organic mixture rich in chitin is then put into batch mixer, sprays into the obtained complex enzyme liquid of above-mentioned steps while stirring,
It is uniformly mixed, pH controls digest 72h in 3.0~4.0, input enzymolysis pond, and temperature is controlled at 35 DEG C~40 DEG C.Complex enzyme hydrolysis
It is 5 ‰ that liquid straying quatity, which accounts for the organic mixture ratio rich in chitin,.Obtain the water conservation rich in chitin, chitosan loosen the soil it is organic
Mixture;
Above-mentioned steps products therefrom is put into the equipment such as material drier, controls drying and dewatering at 80 DEG C of temperature, pulverizer
It is crushed to 40 mesh.Complex fertilizer raw material is chosen, the raw material is nitrogenous fertilizer, potash fertilizer.The nitrogenous fertilizer is urea, ammonium sulfate;The potassium
Fertilizer is potassium sulfate.
Gained in above steps is obtained into object, that is, powder object, inorganic nutrients are measured be mixed and stirred for uniformly according to the ratio, input
Rotary drum granulator, penetrating binder are granulated, screening, pack, obtain auxotype and be retained the complex fertilizer that loosens the soil.Auxotype water conservation pine
Native complex fertilizer, by weight:It is retained the organic materials 20% that loosens the soil, inorganic nutrients 70%, binder 10%.
Comparative example
There is positive effect compared with ordinary compound fertilizer using complex fertilizer of the present invention, is illustrated by testing, it is as a result as follows:
1, test material and method;
1.1 test period:2013
1.2 test site:The villages Dai Shu of the cities XX.
1.3 for trying soil:Experimental plot soil is hills sandy soil, soil organic matter content 25.5g/kg, pH6.0, alkaline hydrolysis
Nitrogen 110.9mg/kg, rapid available phosphorus 10.3mg/kg, available potassium 100.2mg/kg.
1.4 trial crops:Corn.Kind is Zheng Dan 958.
1.5 for trying fertilizer:Auxotype is retained the complex fertilizer that loosens the soil:Water conservation according to 2 each step process of embodiment is loosened the soil
Inorganic fertilizer is chosen in agent:Nitrogenous fertilizer, phosphate fertilizer, potash fertilizer choose binder:Gamma-polyglutamic acid chelated microelement, pH5.0, production
Auxotype water conservation loosen the soil complex fertilizer, particularly:100 parts are retained loosen the soil agent, 340 parts of monoammonium phosphate(Containing P2O544%、
N11%), 250 parts of potassium chloride(Containing K2O60%), 200 parts of small particle ureas(Containing N46.2%), 100 parts of ammonium sulfate(Containing N20.5%),
Batch mixer is put into, is uniformly mixed, rotary drum granulator is put into, sprays into binder, it is loose to obtain auxotype water conservation for granulation, screening, packaging
Native complex fertilizer.
Compare fertilizer:Conventional complex fertilizer(Containing N 15%, contain P2O515%, contain K2The complex fertilizer of O 15%).
1.6 experimental design:
1.6.1 it handles 1.:Auxotype is retained the complex fertilizer that loosens the soil(Containing N15%, P2O515%、K2O15%), before corn planting
Site preparation is spread fertilizer over the fields, 50 kgs/acre.
1.6.2 it handles 2.:CK I, common fertilizer(Containing N 15%, contain P2O515%, contain K2The complex fertilizer of O 15%), corn
Site preparation is spread fertilizer over the fields before plantation, 50 kgs/acre.
1.6.3 it handles 3.:CK II, common fertilizer(Containing N 15%, contain P2O515%, contain K2The complex fertilizer of O 15%), beautiful
Site preparation is spread fertilizer over the fields before rice plantation, 60 kgs/acre.
3 processing, are repeated 3 times, 9 cells totally, and random district's groups arrangement, 2.7 mu of plot area tests 4 mu of plot.Experiment
2.4 meters wide protection row is arranged in ground surrounding.
1.7 Main Cultivation management measures:
1.7.1 it was sowed April 25 for examination corn, fertilising, rotary tillage, mechanical planting, 4500 plants/acre of thickness of sowing, fields for spring sowing
Plantation, centre do not have top dressing.
1.7.2 according to testing program, 1. auxotype is retained the complex fertilizer to loosen the soil for processing(Containing N15%, P2O515%、
K2O15%), site preparation is spread fertilizer over the fields before corn planting, 50 kgs/acre;2. check plot processing applies common fertilizer in the same time(Containing N
15%, contain P2O515%, contain K2The complex fertilizer of O 15%), site preparation is spread fertilizer over the fields before corn planting, 50 kgs/acre;It handles 3., with for the moment
Between before common fertilizer corn planting site preparation spread fertilizer over the fields, 60 kgs/acre.
Fertilising, watering, weeding, the diseases prevention management respectively handled is identical.Experimental plot peanut demonstration test corn is opened on the 7th in September
Begin harvest, and harvesting time-division cell individually harvests, individually weighs, calculates each cell production.
Influence of 2.1 different disposals for corn yield
Test result show Yield-increasing Baallus In Maize auxotype water conservation loosen the soil complex fertilizer processing average product be 786.6 kilograms/
Mu increases 65.2-85.5 kgs/acre, rate of growth 9.04%-12.20% with than compareing.
Influence of 1 different disposal of table to corn yield
Influence of 2.2 different disposals for the soil weight
The soil weight refers to the quality of unit volume original-state soil dry ground.Soil weight size reflects soil texture, breathes freely
The height of property, water permeability and water holding capacity, the soil weight is smaller to illustrate that soil texture, air-and water-permeable performance are better.
For different disposal, soil weight measurement is carried out to each processing in corn growth season, specific assay method is:To each
Cell carries out five point samplings, acquires the soil layer of 5-10cm depth, individually measures its soil weight, be averaged later, obtain
To each processing soil weight, measurement result is as shown in the following table 2.
The soil weight (unit when table 2 respectively handles harvest:g/cm3)
After the data of table 2 can be seen that the complex fertilizer that loosens the soil using auxotype of the present invention water conservation, relative comparison fertilizer,
The soil weight has different degrees of reduction, this illustrates that the auxotype water conservation of the present invention loosens the soil complex fertilizer with apparent effect of loosening the soil
Fruit, this is conducive to the volume increase of crop, increases income.
The innovation of the invention consists in that selecting chitin, chitosan and gamma-polyglutamic acid liquid compounding as complex fertilizer
It is retained the ingredient that loosens the soil, chitin, chitosan and gamma-polyglutamic acid water conservation, flocculation is given full play to, breaches in conventional fertilizers
The inorganic water-keeping material of addition chemistry, i.e., the harmful substance present in polyacrylamide, acrylates, polyaluminium chloride etc. increases and production
The single limitation of product effect, effectively overcome arid area and sand area, water shortage, not water holding, non-fertilizer conservation, intolerant to
Drought, nutrient are easy to be lost in a series of problems, such as causing crop production reduction, soil erosion.Meanwhile making full use of China's pharmacy, enzyme system
A large amount of mycelium residues that agent, Citric Acid Production generate are organically combined, cooperation using physics steam explosion technology and enzymolysis deacylation technique
Trace element chelated technique, produces good water-retaining property, effective water conservation of loosening the soil is loosened the soil agent, and abundance is cheap,
At low cost, effect is good, can be widely used in complex fertilizer production, and peasant is easily accepted by, and is conducive to batch production large-scale production and utilizes.Together
When, the present invention is retained the advantages of complex fertilizer that loosens the soil also has both chitin and gamma-polyglutamic acid fertilizer, and it is respective to give full play to its
Advantageous effect, using soil, cocoa effectively improves soil aggregate structure, effectively improves soil, improves soil water-retaining, fertilizer conservation energy
Power improves the living environment of crop, breaks the bridging of soil intermediate ion, reduces soil hardening, the potentiality that Yan Zi Eng occurs, increases
Strong soil ion exchange capacity, improves soil physical chemistry environment and micro-ecological environment, promotes crop root growth development, promotes crop
Absorption to nutrient.
Chitin is extracted from natural shrimp shell, crab shell or microbial mycelial, is had with a kind of environmentally protective
Machine high polymer coagulant imposes on the adsorbable soil particle of soil containing hydroxyl, carboxyl, amino and other active groups, is formed
Soil aggregate structure, and adsorption moisture achieve the purpose that water conservation is loosened the soil.Fungal mycelium is an important sources of chitin,
Pharmacy, enzyme preparation, organic acid fermentation process generate a large amount of waste mycelias, typically contain 20-40%'s in these mycelial cell walls
Chitin and chitosan.China is pharmacy, enzyme preparation, organic acid especially Citric Acid Production big country, there is a large amount of fermented hypha
Body residue, this is agriculturally using providing high-quality cheap raw material.
Gamma-polyglutamic acid has splendid biodegradability, film forming, at fibroid, plasticity, caking property, superpower
Much unique physics and chemistry such as hydrophily and water holding capacity and biological characteristics.It is large-scale that it can have the technology of biofermentation
Production, can have plant water retention and improve the nitrogen nutrition utilization rate of fertilizer, can reduce the use needed for plant growth
Water, the water conservation soil-loosening function additive particularly suitable as soil.
Above description is not limitation of the present invention, and the present invention is also not limited to the example above, the art
The variations, modifications, additions or substitutions that technical staff is made in the essential scope of the present invention should also belong to the protection of the present invention
Range.
Claims (10)
- The preparation method of complex fertilizer 1. a kind of auxotype water conservation is loosened the soil, includes the following steps:Step 1: preparing complex enzyme liquid:Choose protease, deacetylase mass ratio 1:1~2, complex enzyme hydrolysis preparation is obtained, it is mixed with water With preactivated, mass ratio 1:30~50, coolant-temperature gage is controlled at 30~45 DEG C, now with the current;Step 2: preparing adhesive for granulating:Trace element is crushed to 60~80 mesh, puts into gamma-polyglutamic acid liquid, makes micro Element carries out chelatropic reaction with gamma-polyglutamic acid in reaction kettle and prepares granulation bonding agent, pH value 4.5~7.0, reaction temperature control System reacts 10~30min, trace element and gamma-polyglutamic acid mass ratio 10~50 at 30~45 DEG C:1000, trace element is One or more of ferrous sulfate, zinc sulfate, copper sulphate, manganese sulfate, boric acid mixture;Step 3: preparing chitin and chitosan organic mixture:Press filtration after selection pharmacy, enzyme preparation, citric acid fermentation, obtains Water content 60%~70% mycelium residue, wherein mycelium accounts for 60% or more, puts into high temperature and pressure broken wall tank, be passed through Saturated vapor after maintaining 10~20min, stops, for steam, being passed through into broken wall tank until temperature reaches 110~120 DEG C in tank Pressure-air, until broken wall pressure tank reaches 1.0~1.5Mpa;Then instant decompression release makes pressure drop to normal pressure, makes mycelium Cell wall rupture obtains the organic mixture rich in chitin, then puts into batch mixer, sprays into complex enzyme liquid while stirring, It is uniformly mixed, pH controls digest 3.0~4.0 and digest 48h~96h in pond, and temperature is controlled at 25~45 DEG C, obtains chitin With chitosan organic mixture;Step 4: the chitin and chitosan organic mixture material obtained by step 3 is dried at 80 DEG C, 20~40 mesh are crushed, It obtains being retained the masterbatch that loosens the soil;Loosen the soil masterbatch and inorganic nutrients of water conservation are mixed and stirred for uniformly, putting into comminutor, penetrating step 2 The adhesive for granulating of preparation is granulated, screening, packs, obtains auxotype and be retained the complex fertilizer that loosens the soil.
- The preparation method of complex fertilizer 2. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Four gained auxotypes are retained the complex fertilizer that loosens the soil, and composition weight percent is:Chitin and chitosan organic mixture 10~ 30%, inorganic nutrients 60~85%, adhesive for granulating 2~10%.
- The preparation method of complex fertilizer 3. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Inorganic nutrients in four are nitrogenous fertilizer, phosphate fertilizer, potash fertilizer;The nitrogenous fertilizer be urea, ammonium nitrate, ammonium chloride or ammonium sulfate in one kind or It is several;The phosphate fertilizer is one or more of calcium superphosphate, monoammonium phosphate or Diammonium phosphate (DAP);The potash fertilizer is potassium chloride, nitre One or more of sour potassium, potassium dihydrogen phosphate or potassium sulfate.
- The preparation method of complex fertilizer 4. auxotype water conservation according to claim 3 is loosened the soil, it is characterised in that:The nitrogenous fertilizer For urea;The phosphate fertilizer is Diammonium phosphate (DAP);The potash fertilizer is potassium sulfate.
- The preparation method of complex fertilizer 5. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Gamma-polyglutamic acid liquid is glutamic acid through obtained by microbial fermentation, concentration is 3.5% in two, trace element be ferrous sulfate 10%, Zinc sulfate 60%, copper sulphate 5%, manganese sulfate 5%, the mixing of boric acid 20% or ferrous sulfate 5%, zinc sulfate 70%, copper sulphate 5%, manganese sulfate 5%, the mixing of boric acid 15% or zinc sulfate 70%, boric acid 30% mix.
- The preparation method of complex fertilizer 6. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Complex enzyme hydrolysis liquid straying quatity is 1~5 ‰ of the organic mixture quality rich in chitin in three;It digests pond and heat cycles is set Pipe, summer room temperature digest 48h~72h, and winter heat cycles pipe digests 72~96h.
- The preparation method of complex fertilizer 7. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step It is passed through saturated vapor in three high temperature high pressure broken wall tanks, until temperature reaches 115~120 DEG C in tank, maintains 15~20min, later, Stop, for steam, pressure-air being passed through into broken wall tank, until broken wall pressure tank reaches 1.2~1.5Mpa;Then instant decompression is released It is put into vapour to separate and collect in device admittedly, obtains the organic mixture rich in chitin.
- The preparation method of complex fertilizer 8. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Trace element and gamma-polyglutamic acid mass ratio 20~50 in three:1000, temperature is controlled at 35~45 DEG C, reacts 20~30min.
- The preparation method of complex fertilizer 9. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Complex enzyme and water mixture are preactivated in one, mass ratio 1:30~40, water temperature control at 35~40 DEG C, soak time is 30~ 60min。
- The preparation method of complex fertilizer 10. auxotype water conservation according to claim 1 is loosened the soil, it is characterised in that:The step Protease and deacetylase mass ratio 1 in rapid one:1~1.5;Protease is neutral proteinase.
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CN108503462A (en) * | 2018-06-27 | 2018-09-07 | 山东三方化工集团有限公司 | A kind of polymeric amino acid fertilizer and preparation method thereof improving plant recovery of nutrient |
CN112409094B (en) * | 2020-11-27 | 2022-04-15 | 重庆大学 | Human excrement hydrothermal carbon-based coated urea fertilizer and preparation method thereof |
CN113149772A (en) * | 2021-05-26 | 2021-07-23 | 绥化市中强农业科技发展有限公司 | Special compound disease-resistant microbial fertilizer for corn and preparation method thereof |
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