CN107793795B - 一种朱砂浮雕画颜料及其制备方法 - Google Patents
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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Abstract
本发明属于工艺品加工技术领域，尤其涉及一种朱砂浮雕画颜料，包括以下原料：朱砂、赭石、二氧化钛、二氧化锡、硫酸钡、高岭土、添加剂、云母、混合胶、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷；本发明制备的浮雕画颜料，朱砂和赭石为主原料，用仙人掌、苦荞、槐花、山茶油为原料制备添加剂，配合混合胶和纤维素类原料，在朱砂和赭石表面可以形成致密的保护膜的同时，使得各个粒子更加紧密的连接在一起，阻止了紫外光破坏了朱砂的晶体机构，吸收的光量子只穿透粒子的外表面，保持了原来晶体的结构，改变了朱砂耐光性差的特点。进一步通过特殊的制备工艺，使得耐制备的颜料耐高温，耐酸，从而保持了颜料的色泽。
Description
技术领域
本发明属于工艺品加工技术领域，尤其涉及一种朱砂浮雕画颜料及其制备方法。
背景技术
朱砂即硫化汞，化学品名称HgS；朱砂又称辰砂、丹砂、赤丹、汞沙，是硫化汞的天然矿石，大红色，有金刚光泽至金属光泽，属三方晶系。
颜料是指不溶于水及一般有机溶剂的有色物质,是经调配处理后能涂在物体表面而着色的物质。颜料是美术绘画的物质基础和重要组成部分。颜料决定色彩,色彩又影响着作品的质量和效果。
由于朱砂色泽精致，常用于许多传统艺术品的着色，如陶瓷、塘瓷、泥瓦瓷、字画、雕刻品。朱砂上彩浮雕，常规的朱砂颜料在光、热、湿气、酸碱的环境中，容易出现裂纹、脱落、掉色，严重影响了艺术品的美观。
发明内容
本发明为解决上述技术问题，提供了一种朱砂浮雕画颜料及其制备方法，具体是通过以下技术方案来实现。
一种朱砂浮雕画颜料，包括以下质量份原料：朱砂粉10-200份、赭石10-160份、二氧化钛1-80份、二氧化锡2-65份、硫酸钡5-55份、高岭土7-40份、添加剂10-35份、云母5-30份、混合胶5-30份、六偏磷酸钠1-25份、硝酸纤维素1-20份、乙基纤维素1-20份、聚醚改性有机硅氧烷1-15份。
进一步，所述的朱砂浮雕画颜料，包括以下质量份原料：朱砂粉130-150份、赭石80-100份、二氧化钛40-55份、二氧化锡30-33份、硫酸钡27-28.5份、高岭土20-23.7份、添加剂20-22.7份、云母20-21.3份、混合胶17.8-19份、六偏磷酸钠15.6-17份、硝酸纤维素10-12份、乙基纤维素9.5-11份、聚醚改性有机硅氧烷7-8份。
进一步，所述的混合胶，是将聚氯乙烯、聚丙烯、明胶按照质量比2.8:1.2:4混合而成。
进一步，所述的添加剂，包括以下质量份原料：仙人掌40-43份、苦荞30-33.2份、槐花20-23份、山茶油3-5份。
进一步，所述的添加剂，包括以下制备步骤：
1)槐花粉碎，50-60℃，炒制20-30min，110-120℃炒制5-7min，得混合料，加入5-7倍槐花质量的溶液1，30-40℃搅拌20-30min，过滤，加入0.2-0.3％滤液质量的氢氧化钠，搅拌，过滤，滤液减压蒸馏回收溶剂，得浸膏1；
2)苦荞碳化，得粉末1；
3)仙人掌捣碎，加入3-5倍碱液，搅拌30-40min，过滤，取滤液，滤液干燥，得固体1；其中所述的碱液，为浓度为0.67-0.72mol/L；
4)浸膏1、粉末1、固体1、山茶油混合，得混合料，加入0.2-0.3％混合料质量的甘油，混合既得。
进一步，所述的溶液1为丙酮、乙醇、三氯甲烷、环己烷按照体积比2.2-2.6:13.6-14:0.8-1.5:1.3-1.5混合而成。
进一步，所述的朱砂浮雕画颜料，包括以下制备步骤：
1)朱砂粉、赭石混合粉碎，得料1；
2)添加剂和混合胶混合，50-60℃加热30-40min，1200-1300r/min搅拌1-2h，得料2；
3)料1、料2、二氧化钛、二氧化锡、硫酸钡、高岭土、云母份、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷混合，得料3，加入0.2-0.35％料3质量的甲酸，0.1-0.15％尿素，1000-1300r/min搅拌2-3h，80-85℃处理2-3min，40-45℃搅拌1-2h，2-6℃放置30-40min，50-60℃搅拌1-1.3h，装瓶既得。
本发明的有益效果：通过以上分析发现，本发明制备的浮雕画颜料，朱砂和赭石为主原料，用仙人掌、苦荞、槐花、山茶油为原料制备添加剂，配合混合胶和纤维素类原料，在朱砂和赭石表面可以形成致密的保护膜的同时，使得各个粒子更加紧密的连接在一起，阻止了紫外光破坏了朱砂的晶体机构，吸收的光量子只穿透粒子的外表面，保持了原来晶体的结构，改变了朱砂耐光性差的特点。进一步通过特殊的制备工艺，使得耐制备的颜料耐高温，耐酸，从而保持了颜料的色泽。
具体实施方式
下面对本发明的具体实施方式作进一步详细的说明，但本发明并不局限于这些实施方式，任何在本实施例基本精神上的改进或代替，仍属于本发明权利要求所要求保护的范围。
实施例1
一种朱砂浮雕画颜料，包括以下质量份原料：朱砂粉130g、赭石80g、二氧化钛40g、二氧化锡30g、硫酸钡27g、高岭土20g、添加剂20g、云母20g、混合胶17.8g份、六偏磷酸钠15.6g、硝酸纤维素10g、乙基纤维素9.5g、聚醚改性有机硅氧烷7g。
所述的混合胶，是将聚氯乙烯、聚丙烯、明胶按照质量比2.8:1.2:4混合而成。
所述的添加剂，包括以下质量份原料：仙人掌40g、苦荞30g、槐花20g、山茶油3g。
所述的添加剂，包括以下制备步骤：
1)槐花粉碎，50℃，炒制20min，110℃炒制5min，得混合料，加入5倍槐花质量的溶液1，30℃搅拌20min，过滤，加入0.2％滤液质量的氢氧化钠，搅拌，过滤，滤液减压蒸馏回收溶剂，得浸膏1；
2)苦荞碳化，得粉末1；
3)仙人掌捣碎，加入3倍碱液，搅拌30min，过滤，取滤液，滤液干燥，得固体1；其中所述的碱液，为浓度为0.67mol/L；
4)浸膏1、粉末1、固体1、山茶油混合，得混合料，加入0.2％混合料质量的甘油，混合既得。
所述的溶液1为丙酮、乙醇、三氯甲烷、环己烷按照体积比2.2:13.6:0.8:1.3混合而成。
所述的朱砂浮雕画颜料，包括以下制备步骤：
1)朱砂粉、赭石混合粉碎，得料1；
2)添加剂和混合胶混合，50℃加热30min，1200r/min搅拌1h，得料2；
3)料1、料2、二氧化钛、二氧化锡、硫酸钡、高岭土、云母份、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷混合，得料3，加入0.2％料3质量的甲酸，0.1％尿素，1000r/min搅拌2h，80℃处理2min，40℃搅拌1h，2℃放置30min，50℃搅拌1h，装瓶既得。
实施例2
一种朱砂浮雕画颜料，包括以下质量份原料：朱砂粉145g、赭石90g、二氧化钛50g、二氧化锡32g、硫酸钡28g、高岭土22g、添加剂22g、云母21g、混合胶18.5g份、六偏磷酸钠16.6g、硝酸纤维素11g、乙基纤维素10g、聚醚改性有机硅氧烷7.8g。
所述的混合胶，是将聚氯乙烯、聚丙烯、明胶按照质量比2.8:1.2:4混合而成。
所述的添加剂，包括以下质量份原料：仙人掌41g、苦荞32g、槐花21g、山茶油4g。
所述的添加剂，包括以下制备步骤：
1)槐花粉碎，55℃，炒制25min，115℃炒制6min，得混合料，加入6倍槐花质量的溶液1，35℃搅拌25min，过滤，加入0.25％滤液质量的氢氧化钠，搅拌，过滤，滤液减压蒸馏回收溶剂，得浸膏1；
2)苦荞碳化，得粉末1；
3)仙人掌捣碎，加入4倍碱液，搅拌35min，过滤，取滤液，滤液干燥，得固体1；其中所述的碱液，为浓度为0.70mol/L；
4)浸膏1、粉末1、固体1、山茶油混合，得混合料，加入0.25％混合料质量的甘油，混合既得。
所述的溶液1为丙酮、乙醇、三氯甲烷、环己烷按照体积比2.4:13.8:1.2:1.4混合而成。
所述的朱砂浮雕画颜料，包括以下制备步骤：
1)朱砂粉、赭石混合粉碎，得料1；
2)添加剂和混合胶混合，55℃加热35min，1250r/min搅拌1.2h，得料2；
3)料1、料2、二氧化钛、二氧化锡、硫酸钡、高岭土、云母份、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷混合，得料3，加入0.3％料3质量的甲酸，0.13％尿素，1200r/min搅拌2.3h，82℃处理2.3min，43℃搅拌1.2h，4℃放置35min，55℃搅拌1.1h，装瓶既得。
实施例3
一种朱砂浮雕画颜料，包括以下质量份原料：朱砂粉150g、赭石100g、二氧化钛55g、二氧化锡33g、硫酸钡28.5g、高岭土23.7g、添加剂22.7g、云母21.3g、混合胶19g、六偏磷酸钠17g、硝酸纤维素12g、乙基纤维素11g、聚醚改性有机硅氧烷8g。
所述的混合胶，是将聚氯乙烯、聚丙烯、明胶按照质量比2.8:1.2:4混合而成。
所述的添加剂，包括以下质量份原料：仙人掌43g、苦荞33.2g、槐花23g、山茶油5g。
所述的添加剂，包括以下制备步骤：
1)槐花粉碎，60℃，炒制30min，120℃炒制7min，得混合料，加入7倍槐花质量的溶液1，40℃搅拌30min，过滤，加入0.3％滤液质量的氢氧化钠，搅拌，过滤，滤液减压蒸馏回收溶剂，得浸膏1；
2)苦荞碳化，得粉末1；
3)仙人掌捣碎，加入5倍碱液，搅拌40min，过滤，取滤液，滤液干燥，得固体1；其中所述的碱液，为浓度为0.72mol/L；
4)浸膏1、粉末1、固体1、山茶油混合，得混合料，加入0.3％混合料质量的甘油，混合既得。
所述的溶液1为丙酮、乙醇、三氯甲烷、环己烷按照体积比2.6:14:1.5:1.5混合而成。
所述的朱砂浮雕画颜料，包括以下制备步骤：
1)朱砂粉、赭石混合粉碎，得料1；
2)添加剂和混合胶混合，60℃加热40min，1300r/min搅拌2h，得料2；
3)料1、料2、二氧化钛、二氧化锡、硫酸钡、高岭土、云母份、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷混合，得料3，加入0.35％料3质量的甲酸，0.15％尿素，1300r/min搅拌3h，85℃处理3min，45℃搅拌2h，6℃放置40min，60℃搅拌1.3h，装瓶既得。
实施例4
实施例4不加入添加剂，其它制备步骤与实施例3相同。
实施例5
实施例5在制备步骤中不加入甲酸和尿素，其它制备步骤与实施例3相同。
实施例6
实施例6在制备步骤中没有在6℃放置40min，其它制备步骤与实施例3相同。
实验例
1、效果评价
按照实施例1-6的方法制备颜料，分别取每个实施例得颜料涂抹于浮雕上，参照文献报道的方法进行测量(纵浩.中国画颜料老化色差值分析[D].安徽大学,2005.)颜料色差变化。
1)紫外光处理
实验条件：波长253.7nm，30w，灯距30cm，总照射时间120h，每24h测样。结果如表1所示
表2紫外光处理下浮雕色差变化结果(△E)
| 24h | 48h | 72h | 96h | 120h | |
| 实施例1 | 0.14 | 0.23 | 0.56 | 0.86 | 1.21 |
| 实施例2 | 0.17 | 0.21 | 0.60 | 0.90 | 1.18 |
| 实施例3 | 0.18 | 0.24 | 0.51 | 0.85 | 1.16 |
| 实施例4 | 0.86 | 1.23 | 2.83 | 3.53 | 3.98 |
| 实施例5 | 0.67 | 1.21 | 2.85 | 3.66 | 3.89 |
| 实施例6 | 0.65 | 1.18 | 3.01 | 3.48 | 3.86 |
2)干热老化结果
各试样在空气热老化实验箱中105℃士2℃的条件下，每24h测试其色差。
表2干热处理下浮雕色差变化结果(△E)
| 24h | 48h | 72h | 96h | 120h | |
| 实施例1 | 0.15 | 0.25 | 0.40 | 0.46 | 0.74 |
| 实施例2 | 0.16 | 0.24 | 0.38 | 0.43 | 0.68 |
| 实施例3 | 0.14 | 0.26 | 0.41 | 0.47 | 0.76 |
| 实施例4 | 0.66 | 1.33 | 1.63 | 2.01 | 2.38 |
| 实施例5 | 0.64 | 1.36 | 1.85 | 2.06 | 2.25 |
| 实施例6 | 0.63 | 1.28 | 1.71 | 2.08 | 2.36 |
3)在摩尔浓度为0.3N的H2SO4条件下，将试样放在盐雾老化箱中进行酸化处理，每24小时测取样值。
表3酸处理下浮雕色差变化结果(△E)
| 24h | 48h | 72h | 96h | 120h | |
| 实施例1 | 0.27 | 0.45 | 0.65 | 0.96 | 1.35 |
| 实施例2 | 0.23 | 0.43 | 0.68 | 0.93 | 1.36 |
| 实施例3 | 0.24 | 0.46 | 0.61 | 1.07 | 1.25 |
| 实施例4 | 0.76 | 1.27 | 1.53 | 2.21 | 2.68 |
| 实施例5 | 074 | 1.26 | 1.55 | 2.26 | 2.65 |
| 实施例6 | 0.78 | 1.32 | 1.61 | 2.28 | 2.66 |
通过以上分析发现，本发明制备的浮雕画颜料，朱砂和赭石为主原料，用仙人掌、苦荞、槐花、山茶油为原料制备添加剂，配合混合胶和纤维素类原料，在朱砂和赭石表面可以形成致密的保护膜的同时，使得各个粒子更加紧密的连接在一起，阻止了紫外光破坏了朱砂的晶体机构，吸收的光量子只穿透粒子的外表面，保持了原来晶体的结构，改变了朱砂耐光性差的特点。进一步通过特殊的制备工艺，使得耐制备的颜料耐高温，耐酸，从而保持了颜料的色泽。
Claims (4)
1.一种朱砂浮雕画颜料，其特征在于，包括以下质量份原料：朱砂10-200份、赭石10-160份、二氧化钛1-80份、二氧化锡2-65份、硫酸钡5-55份、高岭土7-40份、添加剂10-35份、云母5-30份、混合胶5-30份、六偏磷酸钠1-25份、硝酸纤维素1-20份、乙基纤维素1-20份、聚醚改性有机硅氧烷1-15份；
所述的混合胶，是将聚氯乙烯、聚丙烯、明胶按照质量比2.8:1.2:4混合而成；
所述的添加剂，包括以下质量份原料：仙人掌40-43份、苦荞30-33.2份、槐花20-23份、山茶油3-5份；
所述的朱砂浮雕画颜料，包括以下制备步骤：
1)朱砂粉、赭石混合粉碎，得料1；
2)添加剂和混合胶混合，50-60℃加热30-40min，1200-1300r/min搅拌1-2h，得料2；
3)料1、料2、二氧化钛、二氧化锡、硫酸钡、高岭土、云母、六偏磷酸钠、硝酸纤维素、乙基纤维素、聚醚改性有机硅氧烷混合，得料3，加入0.2-0.35％料3质量的甲酸，0.1-0.15％尿素，1000-1300r/min搅拌2-3h，80-85℃处理2-3min，40-45℃搅拌1-2h，2-6℃放置30-40min，50-60℃搅拌1-1.3h，装瓶即得。
2.如权利要求1所述的朱砂浮雕画颜料，其特征在于，所述的朱砂浮雕画颜料，包括以下质量份原料：朱砂130-150份、赭石80-100份、二氧化钛40-55份、二氧化锡30-33份、硫酸钡27-28.5份、高岭土20-23.7份、添加剂20-22.7份、云母20-21.3份、混合胶17.8-19份、六偏磷酸钠15.6-17份、硝酸纤维素10-12份、乙基纤维素9.5-11份、聚醚改性有机硅氧烷7-8份。
3.如权利要求1所述的朱砂浮雕画颜料，其特征在于，所述的添加剂，包括以下制备步骤：
1)槐花粉碎，50-60℃，炒制20-30min，110-120℃炒制5-7min，得混合料，加入5-7倍槐花质量的溶液1，30-40℃搅拌20-30min，过滤，加入0.2-0.3％滤液质量的氢氧化钠，搅拌，过滤，滤液减压蒸馏回收溶剂，得浸膏1；
2)苦荞碳化，得粉末1；
3)仙人掌捣碎，加入3-5倍碱液，搅拌30-40min，过滤，取滤液，滤液干燥，得固体1；其中所述的碱液，为浓度为0.67-0.72mol/L；
4)浸膏1、粉末1、固体1、山茶油混合，得混合料，加入0.2-0.3％混合料质量的甘油，混合既得。
4.如权利要求3所述的朱砂浮雕画颜料，其特征在于，所述的溶液1为丙酮、乙醇、三氯甲烷、环己烷按照体积比2.2-2.6:13.6-14:0.8-1.5:1.3-1.5混合而成。
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