CN107780204A - A kind of chemical fiber plus material antimildew and antibacterial agent - Google Patents
A kind of chemical fiber plus material antimildew and antibacterial agent Download PDFInfo
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- CN107780204A CN107780204A CN201711287820.3A CN201711287820A CN107780204A CN 107780204 A CN107780204 A CN 107780204A CN 201711287820 A CN201711287820 A CN 201711287820A CN 107780204 A CN107780204 A CN 107780204A
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- antimildew
- antibacterial agent
- chemical fiber
- plus material
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of chemical fiber plus material antimildew and antibacterial agent, is made up of according to mass fraction following component：1 18 parts of Nano Silver composite particles, 13 parts of soluble silane coupling agent, 40 55 parts of chitosan, 16 30 parts of quaternary ammonium compound, 28 parts of Inonotus obliquus, 100 200 parts of water.The antimildew and antibacterial agent has preferable bacteriostasis property, protects skin, while the antiseptic preparation technology of the present invention is also simple, and has good storage stability.Inonotus obliquus and chitosan will not injure skin after being used for clothing, after being bakeed using low-power ultraviolet and high temperature, handled again with 2-glycidyl bis-phenol solution, action time of the antiseptic in fabric can not only be extended, moreover it is possible to improve the feel and heat resistance of fabric.
Description
Technical field
The present invention relates to antimildew and antibacterial agent.
Background technology
With the continuous improvement of living standards of the people, the demand of anti-biotic material, antibacterial garment will be continuously increased, especially
It is as medical matters clothes, is the ideal of effective protection medical personnel and patient, and the townwear city with antibacterial functions
Field is then more wide.As the increasingly extensive and more effective, lasting of anti-biotic material application field, antibacterial deodourizing hygienic finishing are new
Technology is continually developed, and antibacterial garment industry turns into the developing emerging industry of world's materials industry, progressively highlights
Its huge internal potential and development prospect.
In antibacterial ion, because silver ion has has a broad antifungal spectrum, sterilization of high efficiency, is not likely to produce drug-fast feature,
The principle of silver sterilization is exactly to block the physiology reproductive process of bacterium.In the environment of warm moist, silver ion has very high
Bioactivity, easily it is combined with other materials so that the protein coagulating inside and outside bacterial cell membrane, so as to block bacterial cell
Breathing and breeding.Environment gets over warm moist, and ventilating air permeability is poorer, and the activity of silver ion is stronger, is general nano material
120 times of bactericidal potency, therefore silver ion is very suitable for being applied to antibiotic facing material field.In numerous metal ions, mercury, silver,
Cadmium, copper, zinc etc. are respectively provided with stronger antibacterial ability, but only silver, zinc and copper safe and non-toxic, without side effects such as skin irritations
Ion, and the antibacterial ability of silver ion is much stronger than zinc ion and copper ion.
The content of the invention
In view of the above the shortcomings that prior art, the present invention provides a kind of chemical fiber plus material antimildew and antibacterial agent so that fabric
Effect with long acting antibiotic.
In order to achieve the above objects and other related objects, the present invention provides a kind of chemical fiber plus material antimildew and antibacterial agent, according to matter
Amount number is made up of following component：Nano Silver composite particles 1-18 parts, soluble silane coupling agent 1-3 parts, chitosan 40-55
Part, quaternary ammonium compound 16-30 parts, Inonotus obliquus 2-8 parts, water 100-200 parts.
Preferably, the chitosan is N, N, N- trimethyl chitins, diethylmethyl chitosan, or n-trimethyl chitosan chloride
The one or more of O- Methacrylamide-N- hydroxypropyl dodecyl dimethyl ammonium chloride chitosans.
Preferably, the quaternary ammonium compound is selected from following at least one materials：Dialkyl dimethyl ammonium chloride, alkyl
The double ammoniums of (dodecyl dimethyl) ethylene two of dimethyl benzylamine chloride, dimethyl benzyl ammonium chloride, bromination.
Preferably, described Nano Silver composite particles are nano-silver loaded SiO2 particles.
Preferably, described nano-silver loaded SiO2 particles comprise the following steps：Nanometer SiO2 powder is scattered in hydroxyl
In methylated cellulose aqueous solution, nanosized SiO_2 dispersion liquid is formed；It is molten that nanosized SiO_2 dispersant liquid drop added into AgNO3 under the conditions of lucifuge
In liquid, the pH value for adjusting solution is 7-9, reacts 2-5 hours, centrifuges, re-dry is washed with deionized, that is, nanometer is made
Silver load SiO2 particles.
Preferably, the mass volume ratio of described Nanometer SiO2 powder and the hydroxymethyl cellulose aqueous solution is 1g：6-12mL,
The mass fraction of the described hydroxymethyl cellulose aqueous solution is 3-12%, described Nanometer SiO2 powder and AgNO3 solution matter
Amount volume ratio is 1g：4-7mL, the molar concentration of described silver nitrate solution is 0.1mol/L.
Preferably, described soluble silane coupling agent, its chemical structural formula are：
Me is-CH3 in formula, and X is-OCH2CH3 or-OCH3, and Y is-CH=CH2, and Z is-OH, and molecular weight is 0.5-1.0 ten thousand.
As described above, a kind of chemical fiber plus material antimildew and antibacterial agent of the present invention, has the advantages that：The antimildew and antibacterial agent
With preferable bacteriostasis property, skin is protected, while the antiseptic preparation technology of the present invention is also simple, and there is good storage
Stability.Inonotus obliquus and chitosan will not injure skin after being used for clothing, after being bakeed using low-power ultraviolet and high temperature, then
Handled with 2-glycidyl bis-phenol solution, action time of the antiseptic in fabric can not only be extended, moreover it is possible to improve fabric
Feel and heat resistance.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
A kind of chemical fiber plus material antimildew and antibacterial agent, it is made up of according to mass fraction following component：According to mass fraction by following
Component forms：Nano Silver composite particles 1-18 parts, soluble silane coupling agent 1-3 parts, chitosan 40-55 parts, quaternary ammonium salt
Compound 16-30 parts, Inonotus obliquus 2-8 parts, water 100-200 parts.
In the present embodiment, the chitosan is N, N, N- trimethyl chitins, diethylmethyl chitosan, or quaternized
The one or more of chitosan O- Methacrylamide-N- hydroxypropyl dodecyl dimethyl ammonium chloride chitosans.
In the present embodiment, the quaternary ammonium compound is selected from following at least one materials：Double alkyl dimethyl chlorinations
The double ammoniums of (dodecyl dimethyl) ethylene two of ammonium, alkyl dimethyl benzylamine chloride, dimethyl benzyl ammonium chloride, bromination.
In the present embodiment, described Nano Silver composite particles are nano-silver loaded SiO2 particles.
In the present embodiment, described nano-silver loaded SiO2 particles comprise the following steps：By Nanometer SiO2 powder point
Dissipate in the hydroxymethyl cellulose aqueous solution, form nanosized SiO_2 dispersion liquid；Nanosized SiO_2 dispersant liquid drop is added under the conditions of lucifuge
In AgNO3 solution, the pH value for adjusting solution is 7-9, reacts 2-5 hours, centrifuges, re-dry is washed with deionized, i.e.,
Nano-silver loaded SiO2 particles are made.
In the present embodiment, the mass volume ratio of described Nanometer SiO2 powder and the hydroxymethyl cellulose aqueous solution is 1g：
6-12mL, the mass fraction of the described hydroxymethyl cellulose aqueous solution is 3-12%, and described Nanometer SiO2 powder and AgNO3 are molten
The mass volume ratio of liquid is 1g：4-7mL, the molar concentration of described silver nitrate solution is 0.1mol/L.
In the present embodiment, described soluble silane coupling agent, its chemical structural formula are：
Me is-CH3 in formula, and X is-OCH2CH3 or-OCH3, and Y is-CH=CH2, and Z is-OH, and molecular weight is 0.5-1.0 ten thousand.
In summary, the present invention provides a kind of chemical fiber plus material antimildew and antibacterial agent, and the antimildew and antibacterial agent has preferably antibacterial
Performance, skin is protected, while the antiseptic preparation technology of the present invention is also simple, and there is good storage stability.The brown hole of birch
Bacterium and chitosan will not injure skin after being used for clothing, after being bakeed using low-power ultraviolet and high temperature, then use 2-glycidyl
Bis-phenol solution is handled, and can not only extend action time of the antiseptic in fabric, moreover it is possible to improves the feel of fabric and heat-resisting
Property.So the present invention effectively overcomes various shortcoming of the prior art and has high industrial utilization.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (7)
- A kind of 1. chemical fiber plus material antimildew and antibacterial agent, it is characterised in that：It is made up of according to mass fraction following component：Nano Silver is compound Particle 1-18 parts, soluble silane coupling agent 1-3 parts, chitosan 40-55 parts, quaternary ammonium compound 16-30 parts, Inonotus obliquus 2-8 parts, water 100-200 parts.
- A kind of 2. chemical fiber plus material antimildew and antibacterial agent according to claim 1, it is characterised in that：The chitosan is N, N, N- Trimethyl chitin, diethylmethyl chitosan, or n-trimethyl chitosan chloride O- Methacrylamide-N- hydroxypropyls dodecyl two The one or more of ammonio methacrylate chitosan.
- A kind of 3. chemical fiber plus material antimildew and antibacterial agent according to claim 1 or 2, it is characterised in that：The quaternary ammonium salt Compound is selected from following at least one materials：Dialkyl dimethyl ammonium chloride, alkyl dimethyl benzylamine chloride, dimethyl benzyl chlorine Change the double ammoniums of (dodecyl dimethyl) ethylene two of ammonium, bromination.
- A kind of 4. chemical fiber plus material antimildew and antibacterial agent according to claim 1, it is characterised in that：Compound of described Nano Silver Grain is nano-silver loaded SiO2 particles.
- A kind of 5. chemical fiber plus material antimildew and antibacterial agent according to claim 4, it is characterised in that：Described nano-silver loaded SiO2 particles comprise the following steps：Nanometer SiO2 powder is scattered in the hydroxymethyl cellulose aqueous solution, forms nanosized SiO_2 Dispersion liquid；Nanosized SiO_2 dispersant liquid drop is added in AgNO3 solution under the conditions of lucifuge, the pH value for adjusting solution is 7-9, reacts 2- 5 hours, centrifuge, re-dry is washed with deionized, that is, nano-silver loaded SiO2 particles are made.
- A kind of 6. chemical fiber plus material antimildew and antibacterial agent according to claim 5, it is characterised in that：Described Nanometer SiO2 powder Mass volume ratio with the hydroxymethyl cellulose aqueous solution is 1g：6-12mL, the quality point of the described hydroxymethyl cellulose aqueous solution Number is 3-12%, and the mass volume ratio of described Nanometer SiO2 powder and AgNO3 solution is 1g：4-7mL, described silver nitrate are molten The molar concentration of liquid is 0.1mol/L.
- A kind of 7. chemical fiber plus material antimildew and antibacterial agent according to claim 1, it is characterised in that：Described soluble silane is even Join agent, its chemical structural formula is：Me is-CH3 in formula, and X is-OCH2CH3 or-OCH3, and Y is-CH=CH2, and Z is-OH, and molecular weight is 0.5-1.0 ten thousand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711287820.3A CN107780204A (en) | 2017-12-07 | 2017-12-07 | A kind of chemical fiber plus material antimildew and antibacterial agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711287820.3A CN107780204A (en) | 2017-12-07 | 2017-12-07 | A kind of chemical fiber plus material antimildew and antibacterial agent |
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| CN107780204A true CN107780204A (en) | 2018-03-09 |
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| CN201711287820.3A Pending CN107780204A (en) | 2017-12-07 | 2017-12-07 | A kind of chemical fiber plus material antimildew and antibacterial agent |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109094135A (en) * | 2018-07-25 | 2018-12-28 | 江苏惟妙纺织科技有限公司 | A kind of bacteria mildew-proof disappears peculiar smell fabric and preparation method thereof |
| CN113026176A (en) * | 2021-03-15 | 2021-06-25 | 常州市赣鑫鹊针织服饰有限公司 | Copper wire and fiber interwoven antibacterial fabric |
| CN115214204A (en) * | 2022-06-15 | 2022-10-21 | 武汉中森医疗用品有限公司 | Antibacterial medical protective clothing fabric and preparation method thereof |
| CN115474807A (en) * | 2022-07-25 | 2022-12-16 | 浙江蚕缘家纺股份有限公司 | High-fluffiness silk quilt manufacturing process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106120313A (en) * | 2016-07-12 | 2016-11-16 | 苏州宇希新材料科技有限公司 | The preparation method of a kind of antimildew and antibacterial agent and the application in weaving face fabric thereof |
| CN106436317A (en) * | 2016-08-27 | 2017-02-22 | 新马（安徽）制衣有限公司 | Antibacterial fabric with relatively good durability and manufacturing process thereof |
| CN107164948A (en) * | 2017-06-25 | 2017-09-15 | 长沙善道新材料科技有限公司 | A kind of antibacterial and mouldproof nano fabrics and preparation method thereof |
-
2017
- 2017-12-07 CN CN201711287820.3A patent/CN107780204A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106120313A (en) * | 2016-07-12 | 2016-11-16 | 苏州宇希新材料科技有限公司 | The preparation method of a kind of antimildew and antibacterial agent and the application in weaving face fabric thereof |
| CN106436317A (en) * | 2016-08-27 | 2017-02-22 | 新马（安徽）制衣有限公司 | Antibacterial fabric with relatively good durability and manufacturing process thereof |
| CN107164948A (en) * | 2017-06-25 | 2017-09-15 | 长沙善道新材料科技有限公司 | A kind of antibacterial and mouldproof nano fabrics and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109094135A (en) * | 2018-07-25 | 2018-12-28 | 江苏惟妙纺织科技有限公司 | A kind of bacteria mildew-proof disappears peculiar smell fabric and preparation method thereof |
| CN113026176A (en) * | 2021-03-15 | 2021-06-25 | 常州市赣鑫鹊针织服饰有限公司 | Copper wire and fiber interwoven antibacterial fabric |
| CN115214204A (en) * | 2022-06-15 | 2022-10-21 | 武汉中森医疗用品有限公司 | Antibacterial medical protective clothing fabric and preparation method thereof |
| CN115474807A (en) * | 2022-07-25 | 2022-12-16 | 浙江蚕缘家纺股份有限公司 | High-fluffiness silk quilt manufacturing process |
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