CN102086612B - Water-proof agent for fruit cultivating bag paper and preparation method and application thereof - Google Patents
Water-proof agent for fruit cultivating bag paper and preparation method and application thereof Download PDFInfo
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- CN102086612B CN102086612B CN 201010219773 CN201010219773A CN102086612B CN 102086612 B CN102086612 B CN 102086612B CN 201010219773 CN201010219773 CN 201010219773 CN 201010219773 A CN201010219773 A CN 201010219773A CN 102086612 B CN102086612 B CN 102086612B
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Abstract
The invention discloses a water-proof agent for fruit cultivating bag paper and a preparation method and application thereof. The water-proof agent for the fruit cultivating bag paper comprises the following components: reactive polysiloxane, an emulsifier and deionized water. One or both of a wet strength agent and emulsion paraffin can be added into the components so as to enhance the wrinkle resistance of paper sheets. The invention also discloses the application of the water-proof agent for the fruit cultivating bag paper in enhancing of the waterproofness of raw fruit cultivating bag paper. The water-proof agent is applied by the following steps of: diluting the water-proof agent for the fruit cultivating bag paper with water; soaking the raw fruit cultivating bag paper; and drying. The performances such as water resistance, waterproofness, air permeability, wrinkle resistance and the like of the raw fruit cultivating bag paper treated by the water-proof agent for the fruit cultivating bag paper are remarkably improved or enhanced. The water-proof agent has a short degradation period, and meets requirements for fruit cultivating period and environmental protection.
Description
Technical field
The present invention relates to waterproofing agent, relate in particular to fruit cultivating bag paper waterproofing agent and preparation method thereof, the invention still further relates to this fruit cultivating bag paper waterproofing agent as the purposes of fruit cultivating bag paper special-purpose water-proof agent, belong to fruit cultivating bag paper waterproofing agent field.
Background technology
In recent years, due to people's living standard significantly improve with market on demand high-quality, pollution-free fruit is increased greatly.Use protected by bagging in the fruit growing overall process, become a kind of development trend.Adopt bagging to educate fruit, can prevent agricultural chemicals to the pollution of fruit, reduce ultraviolet ray, wind sand and disease and pest to the impact of fruit, thereby make the fruit appearance fresh and tender, attractive in appearance, inherent meat tender sweet and crisp, moisture is sufficient etc.Can improve fancy fruit output, fruit grade and survival rate.
The fruit cultivating bag paper waterproofing agent can be divided into coating waterproofing agent and the large class of response type waterproofing agent two.Domestic most employing mode of filming is filmed with paraffin and is seen manyly, and cost is low, simple to operate, but effect is bad, and typical problem is that fruit is easily because the poor generation of fruit cultivating bag paper gas permeability " interior burning " phenomenon, cause fruit quality to descend or rot, and this fruit cultivating bag paper is difficult to degrade in the short time.The external response type product that mostly adopts, the waterproofing agent price of fluorinated is high, although effect is all good, is not suitable for domestic national conditions.Also have some import organosilicon fruit cultivating bag paper waterproofing agents to use at home, but cost is also higher.
Based on above-mentioned situation, in conjunction with home products, make cost more moderate, the response type waterproofing agent of superior performance is the requirement of domestic market, both waterproof, water resistant and have good wet epistasis energy, product environmental protection.
Summary of the invention
One of the object of the invention is to provide a kind of fruit cultivating bag paper waterproofing agent;
Two of the object of the invention is to provide a kind of method for preparing above-mentioned fruit cultivating bag paper waterproofing agent;
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of fruit cultivating bag paper waterproofing agent, its component comprises: reactive polysiloxane, emulsifying agent and deionized water;
Preferably, the weight portion of each component is:
Reactive polysiloxane 30-40 part, emulsifying agent 1-8 part and deionized water 40-55 part;
Preferred, the weight portion of each component is:
40 parts of reactive polysiloxanes, 55 parts of 5 parts of emulsifying agents and deionized waters;
In order to improve the wrinkle resistance of paper, can add separately wet strength agent or emulsified wax in said components, also can add simultaneously wet strength agent and emulsified wax; Wherein, the weight portion of the wet strength agent that adds is preferably the 8-10 weight portion, more preferably 9 weight portions; The weight portion of the emulsified wax that adds is preferably the 5-8 weight portion, more preferably 6 weight portions;
Described reactive polysiloxane can be various silicone oil products, can be for example prestox silicone oil product;
Described emulsifying agent can be nonionic emulsifier, can be for example polyoxyethylene ether or polyoxypropylene ethers nonionic emulsifier;
Described wet strength agent is papermaking polyamide-epoxy chloropropane resin (PAE) modification wet strength agent commonly used.
The present invention's all raw materials used all can be bought from commercial channels and obtain, and its specification meets industry standard.
Another object of the present invention is to provide a kind of method for preparing above-mentioned fruit cultivating bag paper waterproofing agent;
A kind of method for preparing above-mentioned fruit cultivating bag paper waterproofing agent comprises the following steps:
(1), take each component by described weight portion;
(2), each component is mixed, stir, obtain O/w emulsion, and get final product.
Fruit cultivating bag paper waterproofing agent of the present invention comprises at the application process of processing the fruit bag body paper: with fruit cultivating bag paper waterproofing agent dilute with water of the present invention, and dipping fruit bag body paper, drying gets final product; Preferably, fruit cultivating bag paper waterproofing agent of the present invention is diluted with 20-60 times of water, preferred, fruit cultivating bag paper waterproofing agent of the present invention is diluted dipping fruit bag body paper, drying with 40 times of water.
Through the handled fruit bag body paper of fruit cultivating bag paper waterproofing agent of the present invention; the performances such as its WATER RESISTANCE, water proofing property, gas permeability and wrinkle resistance are significantly improved or improve; degradation cycle short (degradation time is 120 days after measured) satisfies and to educate the fruit cycle and to the requirement of environmental protection.
The specific embodiment
Further describe the present invention below in conjunction with specific embodiment, advantage and disadvantage of the present invention will be more clear along with description.But these embodiment are only exemplary, scope of the present invention are not consisted of any restriction.It will be understood by those skilled in the art that lower without departing from the spirit and scope of the present invention and can modify or replace details and the form of technical solution of the present invention, but these modifications and replacement all fall within the scope of protection of the present invention.
Test material:
1, in the present embodiment, reactive polysiloxane used is prestox silicone oil, can
Hangzhou development of evil in febrile disease trade Co., Ltd, Xiamen chemical raw material section of Ai Kema group, Guangzhou big uncle chemical industry Co., Ltd etc. locate to buy, and its major traits is as follows:
Density: 0.956
Fusing point: 17-18 ℃
Boiling point: 175-176 ℃
Refractive index: 1.395-1.397
Flash-point: 56 ℃
Water-soluble: insoluble.
2, " emulsified wax " used in the present embodiment can reach chemical industry Co., Ltd etc. in Shanghai Kenduola Wax Industry Co., Ltd., Shanghai Joule Wax Industry Co.,Ltd, Dongguan Australia and buy, and its major traits is as follows:
Emulsified wax
Product pH:7.5-8.5
Solid content: 45-50%
Outward appearance: the oyster white mobility is better.
Can water arbitrarily than dilution.
3, " wet strength agent " in the present invention can be " polyamide-epoxy chloropropane resin (PAE) modification wet strength agent ", and can be in the Tai’an prosperous spring Chemical Industry Science Co., Ltd, source, Jinsui River, Weifang City chemical industry Co., Ltd etc. buy, and its major traits is as follows:
Product pH:4.0-7.0
Solid content (%): 12.5 ± 0.5%
Viscosity 25:15-40mPa.s
Outward appearance: faint yellow to amber transparency liquid.
4, the present embodiment is used " emulsifying agent " for nonionic emulsifier polyoxyethylene ether (can be available from the chemical plant, Lvshun, its trade name is No. 11, emulsifying agent) or polyethenoxy ether (can be available from the chemical plant, Lvshun, its trade name is No. 12);
The preparation of embodiment 1 fruit cultivating bag paper waterproofing agent
1, take each component by the described weight of table 1
Table 1
2, each raw material is mixed after, stir, obtain oil-in-water emulsion, and get final product.
The preparation of embodiment 2 fruit cultivating bag paper waterproofing agents
1, state weight by table 2 and take each component;
Table 2
2, each raw material is mixed after, stir, obtain oil-in-water emulsion, and get final product.
The preparation of embodiment 3 fruit cultivating bag paper waterproofing agents
1, take each component by table 3 weight;
Table 3
2, each raw material is mixed after, stir, obtain oil-in-water emulsion, and get final product.
The preparation of embodiment 4 fruit cultivating bag paper waterproofing agents
1, take each component by the described weight of table 4;
Table 4
2, each raw material is mixed after, stir, obtain oil-in-water emulsion, and get final product.
The effect test of test example 1 fruit cultivating bag paper waterproofing agent of the present invention
1, the preparation of test sample:
The O/W emulsion that embodiment 1 is prepared is diluted with 40 times of water, and dipping fruit bag body paper carried out 120 ℃ of dry 3-5 minutes;
2, detection method and result
2.1 water repellency test: " lotus leaf effect " is obvious, and after water droplet was sprinkled upon the test sample paper, paper tiltedly rose, paper noresidue washmarking.
2.2 the water imbibition of test sample and permeability test
Testing result sees Table 5.
Table 5
2.3 Degrading experiment
The test sample degradation time is 120 days after measured, satisfies to educate the fruit cycle and to the requirement of environmental protection.
The effect test of test example 2 fruit cultivating bag paper waterproofing agent of the present invention
1, the preparation of test sample:
The O/W emulsion that embodiment 2 is prepared is diluted with 50 times of water, and dipping fruit bag body paper carried out 120 ℃ of dry 3-5 minutes;
2, detection method and result
2.1 water repellency test: test sample " lotus leaf effect " is obvious, and after water droplet was sprinkled upon paper, paper tiltedly rose, and paper is without washmarking.
2.2 the water imbibition of test sample and permeability test
Testing result sees Table 6
Table 6
2.3 Degrading experiment
The degradation time of test sample is 120 days after measured, satisfies to educate the fruit cycle and to the requirement of environmental protection.
The effect test of test example 3 fruit cultivating bag paper waterproofing agent of the present invention
1, the preparation of test sample:
40 times of water dilutions of the O/W emulsion that embodiment 3 is prepared, dipping fruit bag body paper (fruit bag body paper has been added with wet strength agent) carried out 120 ℃ of dry 3-5 minutes;
2, detection method and result
2.1 water repellency test: after water droplet dropped on the paper of test sample, " lotus leaf effect " was obvious, and paper tiltedly rises, paper noresidue washmarking.
2.2 the water imbibition of test sample and permeability test
Testing result sees Table 7.
Table 7
From test result, test sample still can satisfy waterproof and gas permeability etc., and other wants water, wrinkling do not occur.
2.3 Degrading experiment
The test sample degradation time is 120 days after measured, satisfies to educate the fruit cycle and to the requirement of environmental protection.
The effect test of test example 4 fruit cultivating bag paper waterproofing agent of the present invention
1, the preparation of test sample:
40 times of water dilutions of the O/W emulsion that embodiment 4 is prepared, dipping fruit bag body paper (fruit bag body paper has been added with wet strength agent) carried out 120 ℃ of dry 3-5 minutes;
2, detection method and result
2.1 water repellency test: after water droplet dropped on the paper of test sample, " lotus leaf effect " was obvious, and paper tiltedly rises, paper noresidue washmarking.
2.2 the water imbibition of test sample and permeability test
Testing result sees Table 8.
Table 8
From test result, test sample still can satisfy other requirements such as waterproof and gas permeability, wrinkling do not occur.
2.3 Degrading experiment
The test sample degradation time is 120 days after measured, satisfies to educate the fruit cycle and to the requirement of environmental protection.
Claims (11)
1. a fruit cultivating bag paper waterproofing agent, is characterized in that, its component comprises: reactive polysiloxane, emulsifying agent, deionized water, wet strength agent and emulsified wax; The weight portion of described each component is: reactive polysiloxane 30-40 part, emulsifying agent 5-8 part, deionized water 40-55 part, wet strength agent 8-10 part, emulsified wax 5-8 part.
2. according to fruit cultivating bag paper waterproofing agent claimed in claim 1, it is characterized in that 40 parts of reactive polysiloxanes, 5 parts of emulsifying agents, 55 parts of deionized waters, 9 parts of wet strength agents, 6 parts of emulsified waxes.
3. according to fruit cultivating bag paper waterproofing agent claimed in claim 1, it is characterized in that: described reactive polysiloxane is the silicone oil product.
4. according to fruit cultivating bag paper waterproofing agent claimed in claim 3, it is characterized in that: described silicone oil product is prestox silicone oil product.
5. according to fruit cultivating bag paper waterproofing agent claimed in claim 1, it is characterized in that: described emulsifying agent is nonionic emulsifier.
6. according to fruit cultivating bag paper waterproofing agent claimed in claim 5, it is characterized in that: described nonionic emulsifier is polyoxyethylene ether or polyoxypropylene.
7. according to fruit cultivating bag paper waterproofing agent claimed in claim 1, it is characterized in that: described wet strength agent is polyamide-epoxy chloropropane resin modification wet strength agent.
8. method for preparing any one described fruit cultivating bag paper waterproofing agent of claim 1-7 comprises: (1), take each component by described weight portion; (2), each component is mixed, stir, obtain oil-in-water emulsion, and get final product.
9. any one described fruit cultivating bag paper waterproofing agent of claim 1-7 at the application process of processing the fruit bag body paper, comprising: with described fruit cultivating bag paper waterproofing agent dilute with water, and dipping fruit bag body paper, drying gets final product.
10. according to application process claimed in claim 9, it is characterized in that: described fruit cultivating bag paper waterproofing agent is diluted dipping fruit bag body paper with 20-60 times of water.
11. according to application process claimed in claim 10, it is characterized in that: described fruit cultivating bag paper waterproofing agent is diluted dipping fruit bag body paper with 40 times of water.
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| CN102704330B (en) * | 2012-06-01 | 2015-10-07 | 安徽省金盾涂料有限责任公司 | Carton water-repellent paint |
| CN102845267A (en) * | 2012-10-12 | 2013-01-02 | 杨云峰 | Fruit bag |
| CN107700273B (en) * | 2016-08-09 | 2022-08-12 | 浙江鑫丰特种纸业股份有限公司 | Coating production line device for producing fruit-raising outer bag paper and production process method thereof |
| CN106801364A (en) * | 2017-01-18 | 2017-06-06 | 马凌 | A kind of fruit cultivating bag paper and its production technology |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101349028A (en) * | 2008-08-05 | 2009-01-21 | 广东省造纸研究所 | Improved fruit-nourishing sleeve bag paper coating preparation |
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| CN100480461C (en) * | 2007-02-15 | 2009-04-22 | 浙江工业大学 | Method of preparing fluorine and silicon containing hydrophobic and oil repellent fabric finishing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101349028A (en) * | 2008-08-05 | 2009-01-21 | 广东省造纸研究所 | Improved fruit-nourishing sleeve bag paper coating preparation |
Non-Patent Citations (1)
| Title |
|---|
| 刘伟等.新型育果袋纸防水剂的开发.《杭州化工》.2007,第37卷(第3期), * |
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Effective date of registration: 20180309 Address after: Room 1, unit 1, unit 2, room 2, Daxing District Park Road, Beijing, Beijing, room 317, room 3 Patentee after: BEIJING ZHITOUJIA INTELLECTUAL PROPERTY OPERATION CO.,LTD. Address before: Beijing 100080 Haidian District 38 Haidian Avenue branch bank building 716 Patentee before: YONGGANG WEIFANG (BEIJING) TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20180906 Address after: 225300 Zhangjiao Wang 20, Chai Hui, the port area of Gao Gang, Taizhou, Jiangsu Patentee after: Chen Deyan Address before: 102600 Beijing Daxing District Paradise Road four House 2 Building 1 unit 3 level 317 room. Patentee before: BEIJING ZHITOUJIA INTELLECTUAL PROPERTY OPERATION CO.,LTD. |
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Effective date of registration: 20181220 Address after: 200 000 No. 385 Xinshui Road, Qingpu Industrial Park, Qingpu District, Shanghai Patentee after: SHANGHAI JINXING PACKAGING MATERIALS CO.,LTD. Address before: 510000 Guangdong science and Technology Industrial Development Zone, Guangzhou, 231 and 233 podium B1B2 Building 1, two, three, four Patentee before: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Effective date of registration: 20181220 Address after: 510000 Guangdong science and Technology Industrial Development Zone, Guangzhou, 231 and 233 podium B1B2 Building 1, two, three, four Patentee after: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Address before: 225300 Zhangjiao Wang 20, Chai Hui, the port area of Gao Gang, Taizhou, Jiangsu Patentee before: Chen Deyan |
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