CN107759081A - Fluorescence high transparency azure stone handicraft - Google Patents
Fluorescence high transparency azure stone handicraft Download PDFInfo
- Publication number
- CN107759081A CN107759081A CN201710889872.1A CN201710889872A CN107759081A CN 107759081 A CN107759081 A CN 107759081A CN 201710889872 A CN201710889872 A CN 201710889872A CN 107759081 A CN107759081 A CN 107759081A
- Authority
- CN
- China
- Prior art keywords
- fluorescence
- high transparency
- stone handicraft
- azure stone
- coloured glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/29—Mixtures
Abstract
The present invention relates to a kind of fluorescence high transparency azure stone handicraft, including coloured glaze body, fluorescence coating positioned at coloured glaze body surface and the crystal layer positioned at fluorescence layer surface, coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler composition, water soluble organic polymer binding agent is polyacrylic acid, polyvinyl alcohol, polyacrylamide, polyethyleneimine, ethyl cellulose, one or more in hydroxypropyl cellulose and chitosan, fining agent is potassium chloride, sodium nitrate, one or more in methylcellulose and polyvinylpyrrolidone.The azure stone handicraft of the present invention can exhale fluorescence, and transparency is high.
Description
Technical field
The present invention relates to colored glaze product field, more particularly to a kind of fluorescence high transparency azure stone handicraft.
Background technology
Coloured glaze refers to that with the synthetic quartz of a variety of colors be raw material, is formed using the dewaxing of Ancient Bronze lost wax casting method high temperature
Crystal works.Its color stream cloud drenches color, Meron U.S. and shone；Its quality is glittering and translucent, bright and glittering.The transparency of azure stone handicraft
Its sight can be had a strong impact on, and its burning process requires high.The transparency of existing azure stone handicraft has much room for improvement.In addition,
Existing azure stone handicraft does not possess fluorescence property typically.
The content of the invention
In order to solve the above technical problems, it is an object of the invention to provide a kind of fluorescence high transparency azure stone handicraft, the present invention
Azure stone handicraft can exhale fluorescence, and transparency is high.
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
Layer and the crystal layer positioned at fluorescence layer surface, coloured glaze body are glued by quartz sand, soda ash, oxidant, water soluble organic polymer
Tie agent, fining agent and filler composition, water soluble organic polymer binding agent be polyacrylic acid, polyvinyl alcohol, polyacrylamide,
One or more in polyethyleneimine, ethyl cellulose, hydroxypropyl cellulose and chitosan, fining agent are potassium chloride, nitric acid
One or more in sodium, methylcellulose and polyvinylpyrrolidone.
Further, oxidant is the one or more in lead oxide, potassium nitrate, aluminum oxide and ceria.
Further, filler is the one or more in calcium carbonate, calcium oxide, talcum powder and expanded perlite.
Further, the material of fluorescence coating is inorganic fluorescent material, and inorganic fluorescent material includes alkaline earth sulfide, aluminium
Hydrochlorate and rare earth lanthanide.
Further, alkaline earth sulfide is zinc sulphide or calcium sulfide.
Further, aluminate SrAl2O4、CaAl2O4And BaAl2O4In one or more.
Further, the one or more in rare earth lanthanide Eu, Er, Nd, Sm and La elements.
Further, in mass, quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent with
And the mass ratio of filler is 60-70：10-15：10-20：1-10：1-5：20-30.
Further, the thickness ratio of fluorescence coating and crystal layer is 1：2-5.
By such scheme, the present invention at least has advantages below：
Azure stone handicraft cleanliness factor of the invention is good, non-friable, transparency is high；Fluorescence coating and crystal layer in coloured glaze body
It can make it that there is fluorescence and crystal gloss respectively, improve ornamental performance, and fluorescence coating is located at the lower section of crystal layer so that
The fluorescence that handicraft is sent is softer；Water soluble organic polymer binding agent is not only environmentally friendly but also can reduce the difficulty of burning process,
Sintering temperature can be substantially reduced；Fining agent causes final product to have high optical transmittance function, and fining agent environmental protection is without dirt
Dye, cost are low.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, below with presently preferred embodiments of the present invention and coordinate detailed description as after.
Embodiment
With reference to embodiment, the embodiment of the present invention is described in further detail.Following examples are used for
Illustrate the present invention, but be not limited to the scope of the present invention.
Embodiment 1
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
The thickness ratio of layer and the crystal layer positioned at fluorescence layer surface, fluorescence coating and crystal layer is 1:2.The material of fluorescence coating is inorganic glimmering
Luminescent material, inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.Specifically, alkaline-earth metal sulphur
Compound is zinc sulphide；Aluminate is SrAl2O4And BaAl2O4；Rare earth lanthanide is Eu, Er and Sm element.
Coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler group
Into.Wherein, in mass, the matter of quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler
Amount is than being 60:15:10:1:5:20.Specifically, oxidant by etc. quality lead oxide and ceria form.It is water-soluble organic
High polymer binder by etc. polyacrylic acid, polyvinyl alcohol and the polyethyleneimine of quality form.Fining agent by etc. quality chlorination
Potassium, methylcellulose and polyvinylpyrrolidone composition.Filler by etc. quality calcium carbonate and talcum powder form.
Embodiment 2
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
The thickness ratio of layer and the crystal layer positioned at fluorescence layer surface, fluorescence coating and crystal layer is 1:2.The material of fluorescence coating is inorganic glimmering
Luminescent material, inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.Specifically, alkaline-earth metal sulphur
Compound is calcium sulfide；Aluminate is SrAl2O4And BaAl2O4；Rare earth lanthanide is La elements.
Coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler group
Into.Wherein, in mass, the matter of quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler
Amount is than being 70:10:20:10:1:30.Specifically, oxidant by etc. lead oxide, potassium nitrate and the aluminum oxide of quality form.It is water-soluble
Property organic polymer binding agent by etc. polyacrylamide, ethyl cellulose and the chitosan of quality form.Fining agent by etc. quality
Potassium chloride, methylcellulose and polyvinylpyrrolidone composition.Filler by etc. quality calcium carbonate and expanded perlite form.
Embodiment 3
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
The thickness ratio of layer and the crystal layer positioned at fluorescence layer surface, fluorescence coating and crystal layer is 1:5.The material of fluorescence coating is inorganic glimmering
Luminescent material, inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.Specifically, alkaline-earth metal sulphur
Compound is calcium sulfide；Aluminate is CaAl2O4；Rare earth lanthanide is Eu and Er elements.
Coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler group
Into.Wherein, in mass, the matter of quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler
Amount is than being 65:12:15:8:3:25.Specifically, oxidant is aluminum oxide.Water soluble organic polymer binding agent by etc. quality
Polyacrylamide, ethyl cellulose and chitosan composition.Fining agent by etc. quality potassium chloride and polyvinylpyrrolidone form.
Filler is calcium carbonate.
Embodiment 4
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
The thickness ratio of layer and the crystal layer positioned at fluorescence layer surface, fluorescence coating and crystal layer is 1:2.The material of fluorescence coating is inorganic glimmering
Luminescent material, inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.Specifically, alkaline-earth metal sulphur
Compound is calcium sulfide；Aluminate is SrAl2O4、CaAl2O4And BaAl2O4；Rare earth lanthanide is Nd, Sm and La element.
Coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler group
Into.Wherein, in mass, the matter of quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler
Amount is than being 70:10:20:10:1:25.Specifically, oxidant is ceria.Water soluble organic polymer binding agent gathers for shell
Sugar.Fining agent by etc. potassium chloride, methylcellulose and the polyvinylpyrrolidone of quality form.Filler by etc. quality calcium carbonate
Formed with expanded perlite.
Embodiment 5
A kind of fluorescence high transparency azure stone handicraft of the present invention, including coloured glaze body, the fluorescence positioned at coloured glaze body surface
The thickness ratio of layer and the crystal layer positioned at fluorescence layer surface, fluorescence coating and crystal layer is 1:3.The material of fluorescence coating is inorganic glimmering
Luminescent material, inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.Specifically, alkaline-earth metal sulphur
Compound is zinc sulphide；Aluminate is CaAl2O4；Rare earth lanthanide is Nd, Sm and La element.
Coloured glaze body is by quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler group
Into.Wherein, in mass, the matter of quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, fining agent and filler
Amount is than being 70:10:20:10:1:25.Specifically, oxidant is ceria.Water soluble organic polymer binding agent by etc. quality
Polyvinyl alcohol and polyacrylamide composition.Fining agent by etc. quality sodium chloride and methylcellulose form.Filler by etc. matter
Calcium oxide, talcum powder and the expanded perlite composition of amount.
Described above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is some improvement and
Modification, these improvement and modification also should be regarded as protection scope of the present invention.
Claims (9)
- A kind of 1. fluorescence high transparency azure stone handicraft, it is characterised in that：Including coloured glaze body, positioned at the coloured glaze body surface Fluorescence coating and the crystal layer positioned at the fluorescence layer surface, the coloured glaze body is by quartz sand, soda ash, oxidant, water solubility Organic polymer binding agent, fining agent and filler composition, the water soluble organic polymer binding agent are polyacrylic acid, poly- second One or more in enol, polyacrylamide, polyethyleneimine, ethyl cellulose, hydroxypropyl cellulose and chitosan, it is described Fining agent is the one or more in potassium chloride, sodium nitrate and methylcellulose and polyvinylpyrrolidone.
- 2. fluorescence high transparency azure stone handicraft according to claim 1, it is characterised in that：The oxidant be lead oxide, One or more in potassium nitrate, aluminum oxide and ceria.
- 3. fluorescence high transparency azure stone handicraft according to claim 1, it is characterised in that：The filler is calcium carbonate, oxygen Change the one or more in calcium, talcum powder and expanded perlite.
- 4. fluorescence high transparency azure stone handicraft according to claim 1, it is characterised in that：The material of the fluorescence coating is nothing Machine fluorescent material, the inorganic fluorescent material include alkaline earth sulfide, aluminate and rare earth lanthanide.
- 5. fluorescence high transparency azure stone handicraft according to claim 4, it is characterised in that：The alkaline earth sulfide is Zinc sulphide or calcium sulfide.
- 6. fluorescence high transparency azure stone handicraft according to claim 4, it is characterised in that：The aluminate is SrAl2O4、 CaAl2O4And BaAl2O4In one or more.
- 7. fluorescence high transparency azure stone handicraft according to claim 4, it is characterised in that：The rare earth lanthanide is One or more in Eu, Er, Nd, Sm and La element.
- 8. the fluorescence high transparency azure stone handicraft according to any one of claim 1-7, it is characterised in that：In mass, The quartz sand, soda ash, oxidant, water soluble organic polymer binding agent, the mass ratio of fining agent and filler are 60-70： 10-15：10-20：1-10：1-5：20-30.
- 9. fluorescence high transparency azure stone handicraft according to claim 1, it is characterised in that：The fluorescence coating and the crystal The thickness ratio of layer is 1：2-5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710889872.1A CN107759081A (en) | 2017-09-27 | 2017-09-27 | Fluorescence high transparency azure stone handicraft |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710889872.1A CN107759081A (en) | 2017-09-27 | 2017-09-27 | Fluorescence high transparency azure stone handicraft |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107759081A true CN107759081A (en) | 2018-03-06 |
Family
ID=61266764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710889872.1A Pending CN107759081A (en) | 2017-09-27 | 2017-09-27 | Fluorescence high transparency azure stone handicraft |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107759081A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6382111B1 (en) * | 2000-12-05 | 2002-05-07 | Hamid Hojaji | Methods to solidify cremation residues |
| CN103131216A (en) * | 2011-12-01 | 2013-06-05 | 萧一修 | Excited light fluorescent paint or glass and application thereof |
| CN104161684A (en) * | 2009-07-20 | 2014-11-26 | 莱雅公司 | Emulsion containing a bismuth oxychloride dispersion |
| CN106277777A (en) * | 2016-08-12 | 2017-01-04 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze formula of high transparency azure stone handicraft |
-
2017
- 2017-09-27 CN CN201710889872.1A patent/CN107759081A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6382111B1 (en) * | 2000-12-05 | 2002-05-07 | Hamid Hojaji | Methods to solidify cremation residues |
| CN104161684A (en) * | 2009-07-20 | 2014-11-26 | 莱雅公司 | Emulsion containing a bismuth oxychloride dispersion |
| CN103131216A (en) * | 2011-12-01 | 2013-06-05 | 萧一修 | Excited light fluorescent paint or glass and application thereof |
| CN106277777A (en) * | 2016-08-12 | 2017-01-04 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze formula of high transparency azure stone handicraft |
Non-Patent Citations (2)
| Title |
|---|
| 张莉编著: "《中华文脉 中国陶瓷艺术 琉璃》", 31 October 2013, 哈尔滨：黑龙江美术出版社 * |
| 徐潜主编: "《中国古代艺术珍品》", 28 February 2014, 长春：吉林文史出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110845227B (en) | Positioning crystal-patterned light-transmitting ceramic tile and preparation method thereof | |
| CN106673438B (en) | There is unreal star stone glazed tile of aventurine effect and preparation method thereof on a kind of surface | |
| CN106542735B (en) | A kind of wear-resisting complete super flat thick throwing glaze of raw material and its application | |
| CN112225454B (en) | Low-glossiness high-stain-resistance composite glaze, granite ceramic tile using composite glaze and preparation method of granite ceramic tile | |
| CN101348329B (en) | Manufacturing process of furnace transmutation enamel | |
| CN106966598A (en) | A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely | |
| CN109384476A (en) | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof | |
| CN106278387B (en) | There is the glazed tile and preparation method thereof of gold decorative effect on surface | |
| CN110903033B (en) | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same | |
| CN103224415B (en) | One-time sintered cobalt blue frit dry particles and preparation method thereof | |
| CN104355607A (en) | High-strength semitransparent ceramic sheet and preparation method thereof | |
| CN108484123A (en) | A kind of Ceramic Tiles and preparation method thereof of high additive metallurgical steel slag waste material | |
| CN102351573A (en) | Preparation method and intermediate product of optical relievo illusion glazed brick | |
| CN103833420A (en) | Manufacturing method of antique black colored glaze and formula thereof | |
| KR100759053B1 (en) | Glaze composition producing crystal and manufacturing method thereof | |
| CN107265865B (en) | Easy clean protection glaze and preparation method thereof | |
| CN108658463B (en) | Fluorescent glaze, ceramic product prepared from fluorescent glaze and method for preparing ceramic product | |
| CN103835465B (en) | A kind of long-afterglow fluorescent Ceramic Tiles | |
| CN104860646A (en) | Glazed tile prepared from black soil | |
| CN107721393B (en) | Preparation method of underglaze color painted porcelain with micro characters | |
| CN105753317A (en) | Batch for ocean blue aluminosilicate glass and method for manufacturing same by aid of batch | |
| CN103896633B (en) | A kind of manufacture method of long-afterglow fluorescent ceramic tile | |
| CN107759081A (en) | Fluorescence high transparency azure stone handicraft | |
| CN105218162A (en) | A kind of ceramic metal glaze and preparation method thereof | |
| CN107032617A (en) | A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180306 |
|
| RJ01 | Rejection of invention patent application after publication |