CN107747213A - 一种棉织物浸轧整理专用整理剂 - Google Patents

一种棉织物浸轧整理专用整理剂 Download PDF

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CN107747213A
CN107747213A CN201710981695.XA CN201710981695A CN107747213A CN 107747213 A CN107747213 A CN 107747213A CN 201710981695 A CN201710981695 A CN 201710981695A CN 107747213 A CN107747213 A CN 107747213A
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潘学东
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Anhui Yayuan Printing And Dyeing Co Ltd
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Abstract

本发明公开了一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂5‑15份、磷酸二氢铵2‑9份、磷酸硼1‑5份、硝酸锌0.2‑1.3份、脂肪醇聚氧乙烯醚0.1‑1份、聚丙二醇0.2‑1.5份、羧甲基纤维素15‑25份、氨基硅油0.5‑2份、马来海松酸3‑8份、瓜尔胶0.2‑0.8份、失水山梨醇单油酸酯3‑12份、奎宁0.3‑2份、正十二烷基三甲氧基硅烷0.1‑1.2份、硅溶胶30‑100份、抗菌剂2‑10份、水300份。本发明提出的棉织物浸轧整理专用整理剂，其能显著提高棉织物的阻燃性和抗菌性，同时使棉织物耐水洗、不易变形。

Description

一种棉织物浸轧整理专用整理剂
技术领域
本发明涉及印染技术领域，尤其涉及一种棉织物浸轧整理专用整理剂。
背景技术
棉织物是一种天然纤维织物，由于其具有手感佳以及穿着舒适的特性，较其它合成纤维具有更加广泛的应用。但是一方面，由于棉属于易燃物品，是火灾的潜在成因，大多需要进行阻燃整理以满足不同程度的防火需求，另一方面，棉织物例如袜子、内衣、棉被、毛巾等等在潮湿环境下使用时，容易被周围的部分微生物侵入，它们以汗液、油脂等作为养分迅速繁殖，给人们的身心健康带来严重影响，然而现有的整理剂其阻燃性和抗菌性不是很好，阻燃和抗菌的持续性等均有待进一步加强。
发明内容
基于背景技术存在的技术问题，本发明提出了一种棉织物浸轧整理专用整理剂，其能显著提高棉织物的阻燃性和抗菌性，同时使棉织物耐水洗、不易变形。
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂5-15份、磷酸二氢铵2-9份、磷酸硼1-5份、硝酸锌0.2-1.3份、脂肪醇聚氧乙烯醚0.1-1份、聚丙二醇0.2-1.5份、羧甲基纤维素15-25份、氨基硅油0.5-2份、马来海松酸3-8份、瓜尔胶0.2-0.8份、失水山梨醇单油酸酯3-12份、奎宁0.3-2份、正十二烷基三甲氧基硅烷0.1-1.2份、硅溶胶30-100份、抗菌剂2-10份、水300份。
优选地，所述磷氮阻燃剂按照以下工艺进行制备：将甲醇钠、9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺加入丙酮中，升温至55-60℃后保温反应50-130min，反应结束后减压蒸馏得到物料A；将三聚氯氰加入丙酮中，搅拌均匀后在0-5℃下加入部分物料A，搅拌反应20-50min，升温至45-55℃后加入剩余的物料A，反应40-60min后蒸馏、烘干得到所述磷氮阻燃剂。
优选地，9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物、丙烯酰胺的重量比为20-25：5-8。
优选地，三聚氯氰、物料A的重量比为15-20：58-65。
优选地，所述部分物料A的重量为物料A总重量的30-50wt％。
优选地，所述抗菌剂由艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚组成。
优选地，艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮、茶多酚的重量比为2-10：1-3：4-15。
本发明所述棉织物浸轧整理专用整理剂，其原料中加入了磷氮阻燃剂，优选方式中，在磷氮阻燃剂的制备过程中，首先以9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺为原料，通过控制反应的条件，使9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺发生了加成反应得到了物料A，之后与三聚氯氰配合后，物料A中的氨基与三聚氯氰中的氯发生了反应，从而将三聚氯氰、9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺结合为一体，得到了所述磷氮阻燃剂，将其加入体系中，在体系分散均匀，一方面，因在体系中引入了磷杂菲以及类三嗪结构，赋予织物优异的耐热性和阻燃性，一方面，在阻燃剂中加入了磷酸二氢铵，其与磷氮阻燃剂具有协同作用，降低了磷氮阻燃剂的用量，提高了阻燃效果，另一方面，与正十二烷基三甲氧基硅烷和硅溶胶配合，赋予织物优异的阻燃性、疏水性和耐热性，同时在体系中加入了奎宁，其能够快速与棉织物中的棉纤维素大分子交联吸附在织物表面，热稳定性高，能够捕捉燃烧过程中产生的高能量游离基，并且能够迅速将高能量的游离基转移使其失活，阻止游离基反应的进行，从而抑制或者中断燃烧的连锁反应，进一步提高了棉织物的阻燃性能；抗菌剂以艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚为组成，加入体系中，与正十二烷基三甲氧基硅烷配合后能赋予棉织物优异的抗菌性。
本发明所述棉织物浸轧整理专用整理剂原料易得,可利用普通的轧、焙、烘工艺整理棉织物，所得棉织物阻燃性能和抗菌性能优良，且耐水洗，抗菌阻燃持久性好。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂15份、磷酸二氢铵2份、磷酸硼5份、硝酸锌0.2份、脂肪醇聚氧乙烯醚1份、聚丙二醇0.2份、羧甲基纤维素25份、氨基硅油0.5份、马来海松酸8份、瓜尔胶0.2份、失水山梨醇单油酸酯12份、奎宁0.3份、正十二烷基三甲氧基硅烷1.2份、硅溶胶30份、抗菌剂10份、水300份。
实施例2
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂5份、磷酸二氢铵9份、磷酸硼1份、硝酸锌1.3份、脂肪醇聚氧乙烯醚0.1份、聚丙二醇1.5份、羧甲基纤维素15份、氨基硅油2份、马来海松酸3份、瓜尔胶0.8份、失水山梨醇单油酸酯3份、奎宁2份、正十二烷基三甲氧基硅烷0.1份、硅溶胶100份、抗菌剂2份、水300份。
实施例3
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂12份、磷酸二氢铵4份、磷酸硼4.3份、硝酸锌0.4份、脂肪醇聚氧乙烯醚0.9份、聚丙二醇0.4份、羧甲基纤维素24份、氨基硅油1份、马来海松酸7.3份、瓜尔胶0.3份、失水山梨醇单油酸酯11份、奎宁0.6份、正十二烷基三甲氧基硅烷1份、硅溶胶45份、抗菌剂4份、水300份；
其中，所述磷氮阻燃剂按照以下工艺进行制备：将甲醇钠、9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺加入丙酮中，其中，9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物、丙烯酰胺的重量比为20：8，升温至55℃后保温反应130min，反应结束后减压蒸馏得到物料A；将三聚氯氰加入丙酮中，搅拌均匀后在0℃下加入部分物料A，搅拌反应50min，升温至45℃后加入剩余的物料A，其中，三聚氯氰、物料A的重量比为20：58，反应60min后蒸馏、烘干得到所述磷氮阻燃剂；
所述部分物料A的重量为物料A总重量的30wt％；
所述抗菌剂由艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚组成，且艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮、茶多酚的重量比为10：1：15。
实施例4
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂7份、磷酸二氢铵8.5份、磷酸硼2份、硝酸锌1.1份、脂肪醇聚氧乙烯醚0.3份、聚丙二醇1.3份、羧甲基纤维素19份、氨基硅油1.7份、马来海松酸3.6份、瓜尔胶0.7份、失水山梨醇单油酸酯4份、奎宁1.8份、正十二烷基三甲氧基硅烷0.3份、硅溶胶68份、抗菌剂8份、水300份；
其中，所述磷氮阻燃剂按照以下工艺进行制备：将甲醇钠、9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺加入丙酮中，其中，9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物、丙烯酰胺的重量比为25：5，升温至60℃后保温反应50min，反应结束后减压蒸馏得到物料A；将三聚氯氰加入丙酮中，搅拌均匀后在5℃下加入部分物料A，搅拌反应20min，升温至55℃后加入剩余的物料A，其中，三聚氯氰、物料A的重量比为15：65，反应40min后蒸馏、烘干得到所述磷氮阻燃剂；
所述部分物料A的重量为物料A总重量的50wt％；
所述抗菌剂由艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚组成，且艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮、茶多酚的重量比为2：3：4。
实施例5
本发明提出的一种棉织物浸轧整理专用整理剂，其原料按重量份包括：磷氮阻燃剂13份、磷酸二氢铵7份、磷酸硼3份、硝酸锌1份、脂肪醇聚氧乙烯醚0.3份、聚丙二醇1份、羧甲基纤维素21份、氨基硅油1.3份、马来海松酸4份、瓜尔胶0.5份、失水山梨醇单油酸酯9份、奎宁1.3份、正十二烷基三甲氧基硅烷0.8份、硅溶胶70份、抗菌剂5份、水300份；
其中，所述磷氮阻燃剂按照以下工艺进行制备：将甲醇钠、9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺加入丙酮中，其中，9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物、丙烯酰胺的重量比为21：7，升温至58℃后保温反应120min，反应结束后减压蒸馏得到物料A；将三聚氯氰加入丙酮中，搅拌均匀后在3℃下加入部分物料A，搅拌反应38min，升温至50℃后加入剩余的物料A，其中，三聚氯氰、物料A的重量比为18：60，反应55min后蒸馏、烘干得到所述磷氮阻燃剂；
所述部分物料A的重量为物料A总重量的40wt％；
所述抗菌剂由艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚组成，且艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮、茶多酚的重量比为5：2：13。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种棉织物浸轧整理专用整理剂，其特征在于，其原料按重量份包括：磷氮阻燃剂5-15份、磷酸二氢铵2-9份、磷酸硼1-5份、硝酸锌0.2-1.3份、脂肪醇聚氧乙烯醚0.1-1份、聚丙二醇0.2-1.5份、羧甲基纤维素15-25份、氨基硅油0.5-2份、马来海松酸3-8份、瓜尔胶0.2-0.8份、失水山梨醇单油酸酯3-12份、奎宁0.3-2份、正十二烷基三甲氧基硅烷0.1-1.2份、硅溶胶30-100份、抗菌剂2-10份、水300份。
2.根据权利要求1所述棉织物浸轧整理专用整理剂，其特征在于，所述磷氮阻燃剂按照以下工艺进行制备：将甲醇钠、9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物和丙烯酰胺加入丙酮中，升温至55-60℃后保温反应50-130min，反应结束后减压蒸馏得到物料A；将三聚氯氰加入丙酮中，搅拌均匀后在0-5℃下加入部分物料A，搅拌反应20-50min，升温至45-55℃后加入剩余的物料A，反应40-60min后蒸馏、烘干得到所述磷氮阻燃剂。
3.根据权利要求2所述棉织物浸轧整理专用整理剂，其特征在于，9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物、丙烯酰胺的重量比为20-25：5-8。
4.根据权利要求2或3所述棉织物浸轧整理专用整理剂，其特征在于，三聚氯氰、物料A的重量比为15-20：58-65。
5.根据权利要求2-4中任一项所述棉织物浸轧整理专用整理剂，其特征在于，所述部分物料A的重量为物料A总重量的30-50wt％。
6.根据权利要求1-5中任一项所述棉织物浸轧整理专用整理剂，其特征在于，所述抗菌剂由艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮和茶多酚组成。
7.根据权利要求6所述棉织物浸轧整理专用整理剂，其特征在于，艾蒿叶、2-羟基-3-甲基-2-环戊烯-1-酮、茶多酚的重量比为2-10：1-3：4-15。
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