CN107739263A - A kind of biological organic fertilizer with prevention and control soil-borne disease function and preparation method thereof - Google Patents

A kind of biological organic fertilizer with prevention and control soil-borne disease function and preparation method thereof Download PDF

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Publication number
CN107739263A
CN107739263A CN201711360529.4A CN201711360529A CN107739263A CN 107739263 A CN107739263 A CN 107739263A CN 201711360529 A CN201711360529 A CN 201711360529A CN 107739263 A CN107739263 A CN 107739263A
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parts
prevention
borne disease
soil
biological organic
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郑喜芝
杜新芳
曹瑜
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Shouguang Hi Tech Biological Technology Co Ltd
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Shouguang Hi Tech Biological Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

It is as made from the raw material of following parts by weight the invention discloses a kind of biological organic fertilizer with prevention and control soil-borne disease function and preparation method thereof:100 160 parts of feces of livestock and poultry, 60 80 parts of stalk, 20 30 parts of wormcast, 0.4 0.6 parts of complex micro organism fungicide, 0.1 0.3 parts of fermentation accelerant, 35 parts of Pul.On the one hand the biological organic fertilizer that the present invention has prevention and control soil-borne disease function can increase soil fertility; be advantageous to Zinc fractions crumb structure so as to improved soil character; improve the activity of defensive ferment; ensure supply of the root to aerial part moisture and nutrient and basic element of cell division isoreactivity material; be advantageous to the enhancing of above-ground plant parts normal activity; crop yield is significantly improved, and strengthens resistance against diseases for plant and lays a good foundation;On the other hand pathogen can be suppressed, is effectively improved soil microflora, suppresses soil-borne disease.

Description

A kind of biological organic fertilizer with prevention and control soil-borne disease function and preparation method thereof
Technical field
The invention belongs to technical field of biological organic fertilizer, and in particular to a kind of biology with prevention and control soil-borne disease function has Machine fertilizer and preparation method thereof.
Background technology
As aquaculture industry of China separates with planting industry, scale, intensive culture industry institute are dissolved without enough farmlands Substantial amounts of Stock raising waste is produced, ecological environment is caused to have a strong impact on.And the chemical fertilizer amount of application cumulative year after year in farmland, The contribution bottleneck of crop yield is increasingly highlighted.
Agricultural production fertilising feature in China's is to fertilize, a large amount of chronic administrations of chemical fertilizer cause crops quality to drop partially It is low, cause soil hardening, organic matter decline, soil and crop root Tiny ecosystem destructurized, even more result in soil and pass plant What disease was spread unchecked.Soil-borne disease refers to that pathogen is lived in soil, from crop root or stem infringement crop when condition is suitable Caused by disease.The ashamed thing soil-borne disease of agriculture is distribution wide, harm weight, is difficult to the crop disease prevented and treated.It is universal in countries in the world Occur, China is particularly acute, and according to incompletely statistics, long-term onset area is up to more than 600 ten thousand hectares.Current disease prevention and control mainly according to By chemical prevention and control, but the problems such as chronic administration chemical agent also results in medicament residual and environmental pollution;In agriculture conventional pipe In reason, as long as phytopathogen can have the several years in soil, crop rotation means receive greatly to limit to when disease breaks out, and the mode such as grafting is even more Substantially increase prevention and control cost.Therefore, with reference to disease-resistant variety seed selection and possess the biological prevention and control of beneficial bacterium etc. of antagonism function Preventing control method by be following soilborne fungal pathogens prevention and control trend.
Biological organic fertilizer, which has, often applies the advantages of not bringing any toxic side effect but, while dosage is big, has and fosters and apply fertilizer The effect of soil.Under the support energetically of national organic matter Improving Project, country encourages large area application of organic fertilizers.But city There is presently no the bio-organic fertilizer product to soil-borne disease prevention and control function on field.
The content of the invention
The invention provides a kind of economical and effective, the biological organic for improving crop yield, having prevention and control soil-borne disease function Fertilizer.
Present invention also offers the preparation method of the biological organic fertilizer with prevention and control soil-borne disease function.
The purpose of the present invention is achieved by the following technical solution:
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 100-160 parts, stalk 60-80 parts, wormcast 20-30 parts, complex micro organism fungicide 0.4-0.6 parts, fermentation accelerant 0.1-0.3 Part, Pul 3-5 parts;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans: 0.5-0.9:Made from 0.8-1.2 volume ratio.
Described, fermentation accelerant is as made from the raw material of following parts by weight:Alginic acid 3-5 parts, corn peptide 2-4 parts, 1 part of glucose 6-8 parts and sodium citrate.
Described, stalk is vegetables straw or maize straw.
A kind of preparation method of the biological organic fertilizer with prevention and control soil-borne disease function, is prepared by following steps 's:
1)Will feces of livestock and poultry and stalk crush after be well mixed, spray aqueous solution of urea, moisture control is 55% ± 3%, tiling, Tiling thickness is 40-50cm, wormcast is uniformly sprinkled upon above, places 2-4 days, obtain material;
2)Activation culture is carried out to bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans with pre-culture medium, It is 10 to obtain cell concentration respectively8-1010CFU·ml-1Pre-culture;Then mix by volume, obtain composite microbial bacteria Agent;
3)Complex micro organism fungicide and fermentation accelerant are well mixed, more than 12h is placed, obtains zymotic fluid;
4)Zymotic fluid is uniformly sprayed in material, is well mixed, piles long pile, moisture control is 55% ± 3%;Treat heap temperature When being increased to 50 DEG C, first time turning is carried out;When heap temperature rise is to 60 DEG C, second of turning is carried out;Continue fermentation 10-15 days, entirely Process fermentation temperature must not be higher than 65 DEG C, and moisture control obtains fermentation material 55% ± 3%;
5)Pul is taken, it is 150mgL to add water that concentration is made-1Pul solution;By Pul solution Uniformly it is sprayed in fermentation material, is well mixed, dries in the shade to water content≤30%, obtaining the biology with prevention and control soil-borne disease function has Machine fertilizer.
Described, the concentration of aqueous solution of urea is 2-4%.
Described, pre-culture medium is prepared with distilled water, sodium chloride-containing 10.0gL-1, tryptone 10.0gL-1And ferment Female powder 5.0gL-1, through obtained by 121 DEG C of sterilizing 20min.
The long pile of the present invention is trapezoidal pile, and heap is high more than 1.0 meters, and base heap is wide more than 1.5 meters;Winter environment temperature During less than 10 degree, trapezoidal a height of 1.5 meters of pile heap, a width of 2 meters of base heap.
The bacillus thuringiensis of the present invention(Bacillus thuringiensis)Purchased from China General Microbiological strain Preservation administrative center(Address:Yard 1, BeiChen xi Road, Chaoyang District, Beijing City 3 Institute of Microorganism, Academia Sinica), numbering CGMCC No.13005;The false anthropi of solution sugar of the present invention(Pseudochrobactrum saccharolyticum)It is purchased from China General Microbiological culture presevation administrative center(Address:The Yard 1, BeiChen xi Road, Chaoyang District, Beijing City 3 Chinese Academy of Sciences is micro- Biological study institute), numbering CGMCC No.8749;The Thiobacillus ferrooxidans of the present invention(Acidithiobacillus ferrooxidans)Purchased from purchased from China typical culture collection center(Address:Wuchang, wuhan Luo Jia Shan), numbering CCTCC NO M2013102。
Beneficial effects of the present invention:In the present invention, complex micro organism fungicide produces a variety of to soil-borne disease during the fermentation The inhibited metabolite of evil, a large amount of beneficial activity factors caused by fermentation, can be killed in being manured into soil a variety of has Evil bacterium.The tunning of feces of livestock and poultry, stalk and wormcast can significantly improve microbial biomass and microbial activity in soil.This On the one hand biological organic fertilizer of the invention with prevention and control soil-borne disease function can increase soil fertility, be advantageous to Zinc fractions granule Structure improves the activity of defensive ferment, induces the synthesis of aldehydes matter and lignin, improve root system and live so as to improved soil character Power, promote cell to increase, division, the synthesis of nucleic acid and protein, ensure root to aerial part moisture and nutrient and cell point The supply of plain isoreactivity material is split, is advantageous to the enhancing of above-ground plant parts normal activity, significantly improves crop yield, and to plant Strain enhancing resistance against diseases is laid a good foundation;On the other hand pathogen can be suppressed, is effectively improved soil microflora, pressed down Soil-borne disease processed occurs.
Embodiment
Following embodiment facilitates a better understanding of the present invention, but does not limit the present invention.Experiment in following embodiments Method, it is conventional method unless otherwise specified.
Embodiment 1
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 160 parts, 60 parts of stalk, 20 parts of wormcast, 0.4 part of complex micro organism fungicide, 0.3 part of fermentation accelerant, 3 parts of Pul;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans: 0.9:Made from 0.8 volume ratio.
Described, fermentation accelerant is as made from the raw material of following parts by weight:3 parts of alginic acid, 4 parts of corn peptide, grape 1 part of 6 parts of sugar and sodium citrate.
Described, stalk is vegetables straw.
A kind of preparation method of the biological organic fertilizer with prevention and control soil-borne disease function, is prepared by following steps 's:
1)Will feces of livestock and poultry and stalk crush after be well mixed, spray aqueous solution of urea, moisture control is 55% ± 3%, tiling, Tiling thickness is 40-50cm, wormcast is uniformly sprinkled upon above, places 2 days, obtain material;
2)Activation culture is carried out to bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans with pre-culture medium, It is 10 to obtain cell concentration respectively8-1010CFU·ml-1Pre-culture;Then mix by volume, obtain composite microbial bacteria Agent;
3)Complex micro organism fungicide and fermentation accelerant are well mixed, more than 12h is placed, obtains zymotic fluid;
4)Zymotic fluid is uniformly sprayed in material, is well mixed, piles long pile, moisture control is 55% ± 3%;Treat heap temperature When being increased to 50 DEG C, first time turning is carried out;When heap temperature rise is to 60 DEG C, second of turning is carried out;Continue fermentation 15 days, overall process Fermentation temperature must not be higher than 65 DEG C, and moisture control obtains fermentation material 55% ± 3%;
5)Pul is taken, it is 150mgL to add water that concentration is made-1Pul solution;By Pul solution Uniformly it is sprayed in fermentation material, is well mixed, dries in the shade to water content≤30%, obtaining the biology with prevention and control soil-borne disease function has Machine fertilizer.
Described, the concentration of aqueous solution of urea is 2%.
Described, pre-culture medium is prepared with distilled water, sodium chloride-containing 10.0gL-1, tryptone 10.0gL-1And ferment Female powder 5.0gL-1, through obtained by 121 DEG C of sterilizing 20min.
Embodiment 2
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 130 parts, 70 parts of stalk, 25 parts of wormcast, 0.5 part of complex micro organism fungicide, 0.2 part of fermentation accelerant, 4 parts of Pul;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans: 0.7:Made from 1 volume ratio.
Described, fermentation accelerant is as made from the raw material of following parts by weight:4 parts of alginic acid, 3 parts of corn peptide, grape 1 part of 7 parts of sugar and sodium citrate.
Described, stalk is maize straw.
A kind of preparation method of the biological organic fertilizer with prevention and control soil-borne disease function, is prepared by following steps 's:
1)Will feces of livestock and poultry and stalk crush after be well mixed, spray aqueous solution of urea, moisture control is 55% ± 3%, tiling, Tiling thickness is 40-50cm, wormcast is uniformly sprinkled upon above, places 3 days, obtain material;
2)Activation culture is carried out to bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans with pre-culture medium, It is 10 to obtain cell concentration respectively8-1010CFU·ml-1Pre-culture;Then mix by volume, obtain composite microbial bacteria Agent;
3)Complex micro organism fungicide and fermentation accelerant are well mixed, more than 12h is placed, obtains zymotic fluid;
4)Zymotic fluid is uniformly sprayed in material, is well mixed, piles long pile, moisture control is 55% ± 3%;Treat heap temperature When being increased to 50 DEG C, first time turning is carried out;When heap temperature rise is to 60 DEG C, second of turning is carried out;Continue fermentation 13 days, overall process Fermentation temperature must not be higher than 65 DEG C, and moisture control obtains fermentation material 55% ± 3%;
5)Pul is taken, it is 150mgL to add water that concentration is made-1Pul solution;By Pul solution Uniformly it is sprayed in fermentation material, is well mixed, dries in the shade to water content≤30%, obtaining the biology with prevention and control soil-borne disease function has Machine fertilizer.
Described, the concentration of aqueous solution of urea is 3%.
Described, pre-culture medium is prepared with distilled water, sodium chloride-containing 10.0gL-1, tryptone 10.0gL-1And ferment Female powder 5.0gL-1, through obtained by 121 DEG C of sterilizing 20min.
Embodiment 3
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 100 parts, 80 parts of stalk, 30 parts of wormcast, 0.6 part of complex micro organism fungicide, 0.1 part of fermentation accelerant, 5 parts of Pul;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans: 0.5:Made from 1.2 volume ratio.
Described, fermentation accelerant is as made from the raw material of following parts by weight:5 parts of alginic acid, 2 parts of corn peptide, grape 1 part of 8 parts of sugar and sodium citrate.
Described, stalk is vegetables straw.
A kind of preparation method of the biological organic fertilizer with prevention and control soil-borne disease function, is prepared by following steps 's:
1)Will feces of livestock and poultry and stalk crush after be well mixed, spray aqueous solution of urea, moisture control is 55% ± 3%, tiling, Tiling thickness is 40-50cm, wormcast is uniformly sprinkled upon above, places 4 days, obtain material;
2)Activation culture is carried out to bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans with pre-culture medium, It is 10 to obtain cell concentration respectively8-1010CFU·ml-1Pre-culture;Then mix by volume, obtain composite microbial bacteria Agent;
3)Complex micro organism fungicide and fermentation accelerant are well mixed, more than 12h is placed, obtains zymotic fluid;
4)Zymotic fluid is uniformly sprayed in material, is well mixed, piles long pile, moisture control is 55% ± 3%;Treat heap temperature When being increased to 50 DEG C, first time turning is carried out;When heap temperature rise is to 60 DEG C, second of turning is carried out;Continue fermentation 10 days, overall process Fermentation temperature must not be higher than 65 DEG C, and moisture control obtains fermentation material 55% ± 3%;
5)Pul is taken, it is 150mgL to add water that concentration is made-1Pul solution;By Pul solution Uniformly it is sprayed in fermentation material, is well mixed, dries in the shade to water content≤30%, obtaining the biology with prevention and control soil-borne disease function has Machine fertilizer.
Described, the concentration of aqueous solution of urea is 4%.
Described, pre-culture medium is prepared with distilled water, sodium chloride-containing 10.0gL-1, tryptone 10.0gL-1And ferment Female powder 5.0gL-1, through obtained by 121 DEG C of sterilizing 20min.
Comparative example 1
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 130 parts, 70 parts of stalk, 25 parts of wormcast, 0.5 part of complex micro organism fungicide, 0.2 part of fermentation accelerant, 4 parts of Pul;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis and Thiobacillus ferrooxidans:0.7:1 volume ratio system .
Remaining is the same as embodiment 2.
Comparative example 2
A kind of biological organic fertilizer with prevention and control soil-borne disease function, is as made from the raw material of following parts by weight:Feces of livestock and poultry 130 parts, 70 parts of stalk, 0.5 part of complex micro organism fungicide, 0.2 part of fermentation accelerant, 4 parts of Pul;
Remaining is the same as embodiment 2.
Soy bean test effect
The soy bean test field of biological organic fertilizer prepared by embodiment 1-3 and comparative example 1-2 before soybean planting is tested, with Machine is divided into 5 groups, and every group 2 mu, every piece of experimental plot Fertilizer application amount is 200kg/ mus, and other conditions are identical, statistics soybean yields, frost Mildew, root rot disease rate.Result of the test is as shown in table 1.
The soy bean test result of table 1
Remarks:When counting downy mildew, root rot disease rate, the soil of 100 square metres of areas in experimental plot is randomly selected, counts it Middle downy mildew, root rot disease rate plant quantity.
Cotton test effect
Select that 6 pieces of soil properties are consistent, fertility is uniformly medium, and cotton wilt and verticillium wilt are fallen ill heavier cotton field, packet For experimental plot 1-5 and control field, wherein experimental plot 1-3 applies biological organic fertilizer 200kg/ mus prepared by embodiment 1-3, examination respectively Test field 1-2 and apply biological organic fertilizer 200kg/ mus prepared by comparative example 1-2 respectively, soil 200kg/ mus are applied in control field.
Each experimental plot uses ten point samplings, and 100 plants are sampled per experimental plot, cotton wilt and verticillium wilt are adjusted Look into, record and count the incidence of disease and control rate, as a result as shown in table 2.The computational methods of the incidence of disease and control rate are as follows:
The incidence of disease(%)=morbidity strain number/investigation total strain number × 100;
Control rate(%)=(Compare the field incidence of disease-experimental plot incidence of disease)/ control field the incidence of disease × 100.
After the harvest of cotton field, cottonseed yield is recorded, and calculates rate of growth, computational methods are as follows:
Rate of growth(%)=(Experimental plot seed cotton yield-control field seed cotton yield)/ control field seed cotton yield × 100.
The cotton test result of table 2
Described above is only the preferred embodiment of the present invention, it should be pointed out that:Come for those skilled in the art Say, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should be regarded as Protection scope of the present invention.

Claims (6)

1. a kind of biological organic fertilizer with prevention and control soil-borne disease function, it is characterised in that be by the raw material system of following parts by weight :Feces of livestock and poultry 100-160 parts, stalk 60-80 parts, wormcast 20-30 parts, complex micro organism fungicide 0.4-0.6 parts, fermentation Accelerator 0.1-0.3 parts, Pul 3-5 parts;
The complex micro organism fungicide is according to 1 by bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans: 0.5-0.9:Made from 0.8-1.2 volume ratio.
2. there is the biological organic fertilizer of prevention and control soil-borne disease function according to claim 1, it is characterised in that the fermentation promotees It is as made from the raw material of following parts by weight to enter agent:Alginic acid 3-5 parts, corn peptide 2-4 parts, glucose 6-8 parts and sodium citrate 1 Part.
3. there is the biological organic fertilizer of prevention and control soil-borne disease function according to claim 1, it is characterised in that the stalk is Vegetables straw or maize straw.
4. the preparation method of the biological organic fertilizer with prevention and control soil-borne disease function, its feature exist described in a kind of claim 1-3 In being prepared by following steps:
1)Will feces of livestock and poultry and stalk crush after be well mixed, spray aqueous solution of urea, moisture control is 55% ± 3%, tiling, Tiling thickness is 40-50cm, wormcast is uniformly sprinkled upon above, places 2-4 days, obtain material;
2)Activation culture is carried out to bacillus thuringiensis, the false anthropi of solution sugar and Thiobacillus ferrooxidans with pre-culture medium, It is 10 to obtain cell concentration respectively8-1010CFU·ml-1Pre-culture;Then mix by volume, obtain composite microbial bacteria Agent;
3)Complex micro organism fungicide and fermentation accelerant are well mixed, more than 12h is placed, obtains zymotic fluid;
4)Zymotic fluid is uniformly sprayed in material, is well mixed, piles long pile, moisture control is 55% ± 3%;Treat heap temperature When being increased to 50 DEG C, first time turning is carried out;When heap temperature rise is to 60 DEG C, second of turning is carried out;Continue fermentation 10-15 days, entirely Process fermentation temperature must not be higher than 65 DEG C, and moisture control obtains fermentation material 55% ± 3%;
5)Pul is taken, it is 150mgL to add water that concentration is made-1Pul solution;Pul solution is equal It is even to be sprayed in fermentation material, it is well mixed, dries in the shade to water content≤30%, obtain the biological organic with prevention and control soil-borne disease function Fertilizer.
5. the preparation method of the biological organic fertilizer with prevention and control soil-borne disease function according to claim 4, it is characterised in that The concentration of the aqueous solution of urea is 2-4%.
6. the preparation method of the biological organic fertilizer with prevention and control soil-borne disease function according to claim 4, it is characterised in that The pre-culture medium is prepared with distilled water, sodium chloride-containing 10.0gL-1, tryptone 10.0gL-1With dusty yeast 5.0gL-1, through obtained by 121 DEG C of sterilizing 20min.
CN201711360529.4A 2017-12-18 2017-12-18 A kind of biological organic fertilizer with prevention and control soil-borne disease function and preparation method thereof Pending CN107739263A (en)

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Publication number Priority date Publication date Assignee Title
CN108299107A (en) * 2018-04-16 2018-07-20 史丹利化肥遂平有限公司 A kind of fertilizer specially for wheat and its manufacturing method
CN108314578A (en) * 2018-02-28 2018-07-24 河北百禾丰化肥有限公司 One kind is rich in silico-calcium potassium magnesium biological organic type soil conditioner and preparation method thereof
CN108329138A (en) * 2018-04-20 2018-07-27 史丹利化肥遂平有限公司 A kind of prevention and control soil-borne disease type biological organic fertilizer and preparation method thereof
CN110845269A (en) * 2019-12-02 2020-02-28 南宁汉和生物科技股份有限公司 Preparation method of polymyxin-containing preparation for inhibiting soil-borne diseases

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314578A (en) * 2018-02-28 2018-07-24 河北百禾丰化肥有限公司 One kind is rich in silico-calcium potassium magnesium biological organic type soil conditioner and preparation method thereof
CN108299107A (en) * 2018-04-16 2018-07-20 史丹利化肥遂平有限公司 A kind of fertilizer specially for wheat and its manufacturing method
CN108329138A (en) * 2018-04-20 2018-07-27 史丹利化肥遂平有限公司 A kind of prevention and control soil-borne disease type biological organic fertilizer and preparation method thereof
CN110845269A (en) * 2019-12-02 2020-02-28 南宁汉和生物科技股份有限公司 Preparation method of polymyxin-containing preparation for inhibiting soil-borne diseases

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Application publication date: 20180227