CN107739248A - Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof - Google Patents
Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof Download PDFInfo
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- CN107739248A CN107739248A CN201711133983.6A CN201711133983A CN107739248A CN 107739248 A CN107739248 A CN 107739248A CN 201711133983 A CN201711133983 A CN 201711133983A CN 107739248 A CN107739248 A CN 107739248A
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- Prior art keywords
- sugar alcohol
- soil improvement
- land soil
- alkaline land
- boron
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof.The alkaline land soil improvement is mainly made with liquid sugar alcohol boron fertilizer by strengthen being complexed including boric acid, sugar alcohol compound, stabilizer, bioactive substance and surfactant, wherein, sugar alcohol compound >=50g/l, boron >=150g/l, bioactive substance >=10g/l.Knowwhy of the present invention based on crop biological physiology chemistry, technology is complexed using sugar alcohol, greatly strengthen the mobility of boron；By adding the bioactive substances such as salicylic acid, the application effect of the boron fertilizer enhanced；By adding biosurfactant, fertilizer good dispersion is quick, it is easier to is absorbed by crops utilization；Fertilizer effective content is high, and boron (B) content is up to 150g/l, and boron exists in the form of the complex state acid that crop is easy to absorb, and nutritive validity is good, beneficial to raising fruit yield and improves fruit quality.
Description
Technical field
The present invention relates to agricultural biotechnologies and fertilizer field, and in particular to one kind is applied to slight saline and alkaline regional economy and made
Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof of thing.
Background technology
A kind of boron important trace element necessary to be fruit tree.Boron element has important function for crop：Boron has
Help the formation of chlorophyll, played an important role in carbohydrate metabolism, transport, promote sugar to turn from blade to reproductive organs
Fortune, promote the formation of auxin (indole acetic acid) in plant, irritate the growth of pollen germination and pollen tube, improve fruit-setting rate.
Boron can promote cell division and elongation, can suppress the formation of poisonous phenolate thing.Boron can promote nitrogen metabolism and improvement in plant
Needs of the root system to oxygen.Strengthen root function, promote root system development.Boron can also improve the viscosity of cellular plasm, and enhancing is anti-
Sick power.In addition, the regular supply of boron, can increase the content of vitamin and sugar in fruit, total acid content is reduced, improves sugar-acid ratio, from
And promote fruit quality.
This formic acid of salicylic acid (salicylic, SA) chemical name neighbour's hydroxyl, it is a kind of be widely present in it is a kind of small in plant
Molecular phenolics material, it is the intermediate product of phenylalanine metabolic pathway, belongs to the derivative of meat silicic acid.The transpiration of participation plant,
A variety of physiological and biochemical procedures such as seed is sprouted, bloomed, be solid, stomata closing, heat production；Plant is induced to produce disease-resistant, salt resistance, cold-resistant
Etc. a variety of physiological characters, plant cell mitochondria cyanide-resistant respiration and non-phosphorylating approach are may also participate in, improves jasmine in plant
Acid metabolic is horizontal.Salicylic physiological action：Salicylic acid, which can induce, blooms, and salicylic acid can improve crop to the resistance of adverse circumstance and resistance to
Property.
The species of boron fertilizer is more in the market, there is particle, powdery and liquid.Graininess boron fertilizer, which is mainly used in base, to be applied, powder
The boron fertilizer (boric acid, borax etc.) of shape is mainly used in foliage-spray, but the solubility of pulvis is small, and utilization rate is low；Liquid sugar alcohol boron fertilizer
It can be mixed with water arbitrary proportion, facilitate the administration of boron fertilizer, content is up to 150g/L, has been especially added with the bioactivity such as salicylic acid
Material, the physiological activity of flowering phase of crop can be adjusted, promote crop to absorb boron, improved boron and turn in plant
Move.Crop absorbs boron element, to absorb based on borate, and poor mobility of the boron in crop body, but boron can and mannose
The polyalcohols such as alcohol, D-sorbite form stable complex, improve the mobility of boron.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of mobility that can strengthen boron, are easy to be absorbed by crops,
Nutritive validity is good, be advantageous to improve fruit yield and improve fruit quality alkaline land soil improvement liquid sugar alcohol boron fertilizer and its
Preparation method.
In order to solve the above technical problems, the technical scheme is that：
Liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement, mainly by living including boric acid, sugar alcohol compound, stabilizer, biology
Property material and surfactant carry out strengthen complexing be made, wherein, sugar alcohol compound >=50g/l, boron >=150g/l, bioactivity
Material >=10g/l.
Preferably, the sugar alcohol compound is the mixed of one or both of mannitol and D-sorbite arbitrary proportion
Compound.
Preferably, the bioactive substance is the mixing of one or both of salicylic acid and chitosan oligosaccharide arbitrary proportion
Thing.
Preferably, the stabilizer is any ratio of one or more in MEA, diethanol amine and triethanolamine
The mixture of example；The surfactant is APG.
Present invention also offers the preparation method of above-mentioned alkaline land soil improvement liquid sugar alcohol boron fertilizer, including following step
Suddenly：
(1) by the sugar alcohol compound that parts by weight are 15~25 parts, 70~90 DEG C is warming up to, is dissolved to clarification；
(2) be slowly added to parts by weight be respectively 55~65 parts boric acid, 0.5~2 part of bioactive substance, control temperature
70~90 DEG C, complex reaction is carried out, stirring keeps 2~5h；
(3) stabilizer that parts by weight are 2-4 parts is added, is warming up to 100~110 DEG C, continues stirring and keeps 2~5h；
(4) after being cooled to 30~60 DEG C, the surfactant that parts by weight are 0.5~2 part is added, regulation pH value is 7~10,
Stir and obtain finished product.
Wherein：
The sugar alcohol compound is the mixture of one or both of mannitol and D-sorbite arbitrary proportion.
The bioactive substance is the mixture of one or both of salicylic acid and chitosan oligosaccharide arbitrary proportion.
The stabilizer is the mixing of one or more of arbitrary proportions in MEA, diethanol amine and triethanolamine
Thing；The surfactant is APG.
Preferably, the regulation pH value method is to be adjusted with 0.1 (wt) % citric acid or 0.1 (wt) % potassium hydroxide
PH value is saved to 8~9.
The theoretical foundation of development ＆ production of the present invention：Boric acid category weak acid, its acidity constant are Ka=5.8 × 10-10, certain
At a temperature of after polyalcohol is strengthened, complex acid can be generated, and in strengthening process, add stabilizer alcohol amine substance, led to
Cross and form stable nitrogen, the ligand of boron, strengthen the complexing power of polyalcohol and boric acid.
Liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement of the present invention, can be applied to slight saline and alkaline region crops or warp
Help crop, rape " colored and unreal ", cotton " flower bud is without flower " and fruit tree " bud drop, fallen flowers, shedding ", wheat " not harvesting " etc. can be prevented and treated
Boron deficiency element symptom, there is notable effect of increasing production, and improve fruit quality.
The present invention has the advantages that compared with prior art：
(1) knowwhy based on crop biological physiology chemistry, technology is complexed using sugar alcohol, greatly strengthen the movement of boron
Property；
(2) by adding the bioactive substances such as salicylic acid, the application effect of the boron fertilizer enhanced；
(3) by adding biosurfactant, fertilizer good dispersion is quick, it is easier to is absorbed by crops utilization；
(4) effective content is high, and boron (B) content is up to 150g/l, and the complex state acid shape that boron is easy to absorb with crop
State is present, and nutritive validity is good, beneficial to raising fruit yield and improves fruit quality.
Embodiment
With reference to specific embodiment, the present invention is expanded on further, but the present invention is not only limited to these embodiments.
Embodiment
Liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement, is mainly prepared by following components according to the parts by weight：Sugar
19 parts of alcohol compound, 64 parts of boric acid, 2 parts of stabilizer, 1 part of bioactive substance, 1 part of surfactant, surplus are water.
Specific preparation method is as follows：
(1) by the sugar alcohol compound that parts by weight are 19 parts, 80 DEG C is warming up to, is dissolved to clarification；
(2) be slowly added to parts by weight be respectively 64 parts boric acid, 1 part of bioactive substance, control 80 DEG C of temperature, carry out
Complex reaction, stirring keep 2~3h；
(3) stabilizer that parts by weight are 2 parts is added, is warming up to 100~110 DEG C, continues stirring and keeps 2~3h；
(4) after being cooled to 60 DEG C, the surfactant that parts by weight are 1 part is added, with 0.1 (wt) % citric acid or 0.1
(wt) % potassium hydroxide adjusts pH value to 8~9, stirs and obtains finished product.
Sugar alcohol compound described in the present embodiment is the mixture of mannitol and D-sorbite arbitrary proportion；The biology
Active material is the mixture of salicylic acid and chitosan oligosaccharide arbitrary proportion；The stabilizer is MEA, diethanol amine and three second
The mixture of hydramine arbitrary proportion；The surfactant is APG.
Wherein, sugar alcohol compound >=50g/l, boron >=150g/l, bioactive substance >=10g/l.
It is demonstrated experimentally that alkaline land soil improvement of the present invention is applied to slight saline and alkaline region agriculture with liquid sugar alcohol boron fertilizer
Crop or industrial crops, rape " colored and unreal ", cotton " flower bud is without flower " and fruit tree " bud drop, fallen flowers, shedding ", wheat can be prevented and treated
The boron deficiency such as " not harvesting " element symptom, there is notable effect of increasing production, and improve fruit quality.
The schematical embodiment of the present invention is the foregoing is only, is not limited to the scope of the present invention.It is any
Those skilled in the art, made equivalent variations and modification on the premise of the design of the present invention and principle is not departed from,
The scope of protection of the invention should be belonged to.
Claims (9)
1. liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement, it is characterised in that：Mainly by including boric acid, sugar alcohol compound, stably
Agent, bioactive substance and surfactant strengthen being complexed and are made, wherein, sugar alcohol compound >=50g/l, boron >=150g/
L, bioactive substance >=10g/l.
2. liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement as claimed in claim 1, it is characterised in that：The sugar alcohol compound
For the mixture of one or both of mannitol and D-sorbite arbitrary proportion.
3. liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement as claimed in claim 1, it is characterised in that：The biological active matter
Matter is the mixture of one or both of salicylic acid and chitosan oligosaccharide arbitrary proportion.
4. liquid sugar alcohol boron fertilizer is used in alkaline land soil improvement as claimed in claim 1, it is characterised in that：The stabilizer is single
The mixture of one or more of arbitrary proportions in monoethanolamine, diethanol amine and triethanolamine；The surfactant is alkyl
Glucosides.
5. the preparation method of alkaline land soil improvement liquid sugar alcohol boron fertilizer as claimed in claim 1, it is characterised in that including
Following steps：
(1) by the sugar alcohol compound that parts by weight are 15~25 parts, 70~90 DEG C is warming up to, is dissolved to clarification；
(2) be slowly added to parts by weight be respectively 55~65 parts boric acid, 0.5~2 part of bioactive substance, control temperature 70~
90 DEG C, complex reaction is carried out, stirring keeps 2~5h；
(3) stabilizer that parts by weight are 2-4 parts is added, is warming up to 100~110 DEG C, continues stirring and keeps 2~5h；
(4) after being cooled to 30~60 DEG C, the surfactant that parts by weight are 0.5~2 part is added, regulation pH value is 7~10, stirring
Uniformly obtain finished product.
6. the preparation method of alkaline land soil improvement liquid sugar alcohol boron fertilizer as claimed in claim 5, it is characterised in that：It is described
Sugar alcohol compound is the mixture of one or both of mannitol and D-sorbite arbitrary proportion.
7. the preparation method of alkaline land soil improvement liquid sugar alcohol boron fertilizer as claimed in claim 5, it is characterised in that：It is described
Bioactive substance is the mixture of one or both of salicylic acid and chitosan oligosaccharide arbitrary proportion.
8. the preparation method of alkaline land soil improvement liquid sugar alcohol boron fertilizer as claimed in claim 5, it is characterised in that：It is described
Stabilizer is the mixture of one or more of arbitrary proportions in MEA, diethanol amine and triethanolamine；Live on the surface
Property agent is APG.
9. the preparation method of the alkaline land soil improvement liquid sugar alcohol boron fertilizer as described in claim 5,6,7 or 8, its feature exist
In：The regulation pH value method is to adjust pH value to 8~9 with 0.1 (wt) % citric acid or 0.1 (wt) % potassium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711133983.6A CN107739248A (en) | 2017-11-16 | 2017-11-16 | Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711133983.6A CN107739248A (en) | 2017-11-16 | 2017-11-16 | Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107739248A true CN107739248A (en) | 2018-02-27 |
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|---|---|---|---|
| CN201711133983.6A Pending CN107739248A (en) | 2017-11-16 | 2017-11-16 | Alkaline land soil improvement liquid sugar alcohol boron fertilizer and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658675A (en) * | 2018-07-06 | 2018-10-16 | 南宁汉和生物科技股份有限公司 | A kind of high-content sugar alcohol calcium boron clear liquid fertilizer and preparation method thereof |
| CN114956900A (en) * | 2022-07-08 | 2022-08-30 | 云南勐牛生物技术有限公司 | Ionic boron liquid fertilizer and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103588564A (en) * | 2013-11-07 | 2014-02-19 | 华南农业大学 | Sugar alcohol calcium magnesium zinc boron compound liquid fertilizer and preparation method and applications thereof |
-
2017
- 2017-11-16 CN CN201711133983.6A patent/CN107739248A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103588564A (en) * | 2013-11-07 | 2014-02-19 | 华南农业大学 | Sugar alcohol calcium magnesium zinc boron compound liquid fertilizer and preparation method and applications thereof |
Non-Patent Citations (1)
| Title |
|---|
| 赵娟: "《植物生长调节剂在农业上的应用》", 30 September 2006, 北京:中国社会出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658675A (en) * | 2018-07-06 | 2018-10-16 | 南宁汉和生物科技股份有限公司 | A kind of high-content sugar alcohol calcium boron clear liquid fertilizer and preparation method thereof |
| CN114956900A (en) * | 2022-07-08 | 2022-08-30 | 云南勐牛生物技术有限公司 | Ionic boron liquid fertilizer and preparation method thereof |
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Application publication date: 20180227 |