CN104710231A - Chitosanoligosaccharide compounding preparation for increasing wheat yield, and applications thereof - Google Patents

Chitosanoligosaccharide compounding preparation for increasing wheat yield, and applications thereof Download PDF

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Publication number
CN104710231A
CN104710231A CN201310689965.1A CN201310689965A CN104710231A CN 104710231 A CN104710231 A CN 104710231A CN 201310689965 A CN201310689965 A CN 201310689965A CN 104710231 A CN104710231 A CN 104710231A
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China
Prior art keywords
compound preparation
oligochitosan
wheat
derivative
seed
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CN201310689965.1A
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Chinese (zh)
Inventor
尹恒
王梦雨
杜昱光
赵小明
王文霞
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Dalian Institute of Chemical Physics of CAS
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Dalian Institute of Chemical Physics of CAS
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Priority to CN201310689965.1A priority Critical patent/CN104710231A/en
Publication of CN104710231A publication Critical patent/CN104710231A/en
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Abstract

The present invention discloses a chitosanoligosaccharide compounding preparation having a wheat yield increasing effect. The chitosanoligosaccharide compounding preparation is characterized by comprising, by weight, 0.005-0.02% of chitosanoligosaccharide or a chitosanoligosaccharide derivative, 0.1-5% of amino acids, 0.3-1.2% of trace elements, 0.02%-0.5% of a plant growth regulator, and the balance of a solvent or carrier. The present invention further provides a method for using the compounding preparation to improve the wheat yield. According to the present invention, the chitosanoligosaccharide in the compounding preparation is saccharide molecules formed by connecting two or more glucosamine through a glycosidic bond, and the agent adopting the chitosanoligosaccharide and the chitosanoligosaccharide derivative as the main component has advantages of safety, no toxicity, environmental protection, broad and durable effect, and the like; and with the application of the compounding preparation to carry out spray, seed soaking and other treatments, the wheat yield can be significantly increased, and the cost is significantly lower than the cost of the similar products.

Description

A kind of oligochitosan compound preparation for improving wheat yield and application thereof
Technical field
The invention belongs to agrochemical field, particularly relate to the regulation and control of growing of plant, specifically a kind of with oligochitosan or oligochitosan derivative be main active substances wheat increase yield compound preparation and application method thereof.
Background technology
In agriculture production, increasing the yield per unit area is the primary goal of wheat planting.And affect the many factors of wheat yield, comprising: the too high meeting of soil salt produces salt damage to wheat; Arid, hot dry wind, makes wheat wilt withered; Early the winter, cold spell in later spring can make the dead seedling of wheat frostbite serious; Disease and pest can make wheat catch an illness, and above various abiotic and biotic all can make wheat yield even have no harvest.
The Technology development improving wheat yield in current actual production comprises breed breeding, and improve vegetative storage level, moderate control is nourished and grown, and ensures good agro-farming envrionment conditions and application growth regulator and micro-fertilizer etc.
Wherein the process of breeding high-yield amount kind is complicated, and cost is high, and genetic stability is poor, and is easily subject to the impact of environmental factors, causes final tiller effect and expection to have larger gap.With the stylish research field relating to genetically modified crops wide in variety, social recognition degree is low.
By regulating liquid manure to improve wheat vegetative storage, the soil that selection soil fertility is high, nitrogen phosphorus enriches, soil moisture content is enriched or input fertilizer carry out planting the output that can improve wheat.But China's agriculture plantation water conservancy projects weak foundation and soil fertility much barrenr, organize agricultural tillage not easily to realize efficiently.
By preparations such as applied chemistry agricultural chemicals and micro-fertilizer, to improve wheat growth state, photosynthesis can also be promoted, improves output in actual production.But chemical regulator there will be saline Land, disease and pest resistance improves, the side effects such as food safety reduction.
Compared with improving the means of wheat yield above, the wheat growth conditioning agent of green high-efficient is used to demonstrate obvious advantage.Application wheat growth conditioning agent can promote that wheat is to the absorption of nutrient, stimulating growth, improves the output of wheat.
And promotion wheat increase yield the effect of increasing income can be played, the non-harmful plant-growth regulator there be limited evidence currently of of environmental protection again.
Summary of the invention
The object of the invention is to propose a kind of compound preparation for improving wheat yield being functionally active molecule with oligochitosan or oligochitosan derivative.
For achieving the above object, technical scheme of the present invention is:
The main active ingredient of oligochitosan compound preparation of the present invention is made up of oligochitosan or oligochitosan derivative, amino acid, trace element and plant-growth regulator.Wherein each compositions in weight percentage is respectively oligochitosan or oligochitosan derivative (0.001% ~ 0.02%), amino acid (0.1% ~ 1%), trace element (0.3% ~ 1.2%), plant-growth regulator (0.02% ~ 5%), and all the other compositions are solvent or carrier.
Oligochitosan in oligochitosan compound preparation of the present invention or oligochitosan derivatives active composition, its oligochitosan used between the polymerization degree 2 ~ 20, deacetylation more than 90%.Oligochitosan derivative is including, but not limited to oligochitosan sulfate derivative, oligochitosan acid salt derivative, oligochitosan phosphoric acid derivatives, oligochitosan sulphonamide derivatives, oligochitosan acylisothiocyanate analog derivative, oligochitosan guanidine derivative etc.
Amino acid in oligochitosan compound preparation of the present invention, including, but not limited to one or two or more kinds conbined usage in glycine, L-Ala, leucine, Isoleucine, α-amino-isovaleric acid, Gelucystine, Gelucystine, methionine(Met), Threonine, Serine, phenylalanine, tyrosine, tryptophane, proline(Pro), oxyproline, L-glutamic acid, aspartic acid.
Trace element in oligochitosan compound preparation of the present invention, including, but not limited to one or two or more kinds conbined usage in iron, zinc, copper, molybdenum, boron and manganese.
Plant-growth regulator in oligochitosan compound preparation of the present invention, including, but not limited to forchlorfenuron, one or two or more kinds conbined usage in Plant hormones regulators,gibberellins, phytokinin, paclobutrazol and polyamines.
Oligochitosan compound preparation of the present invention, can add solvent or carrier is made into aqua, missible oil, soluble liquid, aqueous emulsion, microemulsion, suspension agent, soluble powder, wettable powder, granule, water-dispersible granules, microcapsule, tablet.
By wheat growth stage with the germination and emergence phase, Wintering Period of tillering, turns green the jointing stage, booting heading stage, the flowering and grouting phase is after the criteria for classifying, uses compound preparation, one or more methods following can be adopted to process to more than one or two stage in each stage of Wheat Development;
(1) wheat seed is processed, treatment process including, but not limited to seed dressing, seed soaking or the method such as vexed kind, wherein seed dressing refers to and is mixed with seed by compound preparation; Seed soaking refers to that a seed or seedling are immersed in certain density compound preparation, and after certain hour, seed or seedling absorb medicament; Vexed kind refers to the method for compound preparation and seed being mixed the vexed certain hour of rear heap and sowing.
(2) in germination and emergence phase of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different.
(3) at the Wintering Period of tillering of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different.
(4) in jointing stage of turning green of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different.
(5) at booting heading stage of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different.
(6) in flowering and grouting phase of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different.
The application process in each vegetative period above-mentioned refers to any effective conventional method during applications of pesticide, includes but not limited to powder injection process, spraying process, executes daraf(reciprocal of farad), soil treatment method or smog method etc.
Oligochitosan compound preparation of the present invention is applied in the planting process of wheat, the functional attributes of the plant exciton of oligochitosan can be played, improve wheat to the resistivity of disease and pest, promote that its propagation is bred, finally reach and improve the function of wheat yield, to have use cost low for this compound preparation simultaneously, and efficiency time is long, action effect is good, the advantages such as environmental protection.Compare with chitosan and higher molecular weight oligochitosan, have that relative molecular mass is little, the advantage of good water solubility, thus be easy to use.
Tool of the present invention has the following advantages:
1. the present invention using the oligochitosan of biogenetic derivation as wheat shell oligosaccharides compound preparation, green, environmental protection, nuisanceless, pollution-free, nuisanceless.
2. the main active ingredient oligochitosan wide material sources in the present invention, cheap, be suitable for large-scale promotion.
3. the wheat shell oligosaccharides compound preparation in the present invention is that usage quantity is few, and efficiency time is long by working to plant self-regulation, and effect extensively and can not produce resistance.
4. the wheat shell oligosaccharides compound preparation in the present invention can use by Some substitute chemistry Agrotechnical formulation, reduces chemical residual, solves food-safety problem.
Embodiment
In order to understand the present invention, further illustrating the present invention with embodiment down, but not limiting the present invention.
Embodiment 1: oligochitosan compound preparation aqua is prepared
By the 150mg polymerization degree 2 ~ 20, the oligochitosan that deacetylation is greater than 90% is dissolved in 1L water, adds 4.5g Plant hormones regulators,gibberellins, 15g L-glutamic acid and 3.3g zinc sulfate successively simultaneously, dissolves successively.Make the oligochitosan compound preparation aqua of the raising wheat yield of 150mg/L.
Embodiment 2 oligochitosan compound preparation is on the impact of wheat tillering number and grain number per spike
100mg oligochitosan is dissolved in 1L water, adds 1.5g phytokinin and 5.3g zinc sulfate successively, 12g tryptophane simultaneously, dissolve the oligochitosan compound preparation aqua making the raising wheat yield of 200mg/L.Experiment is divided into two groups, is respectively the wheat of oligochitosan compound preparation process and the wheat of single oligochitosan aqueous solution process.Start spray this oligochitosan compound preparation of dilution and the single oligochitosan aqueous solution after entering seedling stage, every 20 days 1 time, every mu of consumption is 18L aqua at every turn.The statistics after jointing until wheat is turned green.Obtain result display through statistics, significantly improve (table 1) through the wheat tillering number of oligochitosan compound preparation process and grain number per spike, and successful is higher than single oligochitosan treatment group.
Table 1 oligochitosan compound preparation is on the impact of wheat tillering number and grain number per spike
By result as seen after this oligochitosan compound preparation, Plant Height in Wheat increases by 0.6%, and tiller number increases by 6.4%.Wheat grains per spike increases by 5.1% simultaneously, and infertile spikelet number reduces 11.6%, and oligochitosan compound preparation obviously facilitates tillering of wheat, adds wheat yield.
Raising effect to wheat yield after embodiment 3 phosphorylation oligochitosan compound preparation Dressing Wheat Species
This test adopts the composite system of phosphorylation oligochitosan of 1L mass concentration 50mg/L, wherein containing 1.5g forchlorfenuron and 10g zinc sulfate, and 15g tyrosine.Dressing is carried out to 1 kilogram of wheat.Subjects is the wheat of western agriculture 9871 kind.At wheat aging time, its mature spike number, grain number per spike and thousand seed weight are measured, establish same kind and with the control group of the seed dressing of clear water in proportion simultaneously, to compare the Application effects of phosphorylation oligochitosan compound preparation.Wheat mature spike number after experimental result shows the seed dressing of this phosphorylation oligochitosan compound preparation comparatively blank group increases by 5.4%, and grain number per spike increases by 1.71%, and thousand seed weight and output improve respectively 3.9% and 6.8%(table 1).
Raising effect to wheat yield after table 2 phosphorylation oligochitosan compound preparation Dressing Wheat Species
The raising effect of embodiment 4 oligochitosan hydrochloride compound preparation to wheat yield after jointing stage spray wheat of turning green
Adopt the oligochitosan hydrochloride of mass concentration 150mg/L and the composite of 4g copper sulfate, 20g L-glutamic acid and 2g uniconazole composition to carry out spray process built in the jointing stage of turning green to wheat, use aqua 20L for every mu.After wheat maturation, its mature spike number, grain number per spike and thousand seed weight are measured.Wheat mature spike number after experiment finds the oligochitosan compound preparation seed dressing of this raising wheat yield increases by 10.0% compared with the blank group of clear water process, and grain number per spike increases by 0.63%, output increased 9.8%(table 3).
Table 3 oligochitosan hydrochloride compound preparation is turned green raising effect to wheat yield after spray wheat
Embodiment 5 oligochitosan nicotinoyl isocyanate derivative compound preparation is on the impact of wheat yield
At late March to early April, to the oligochitosan nicotinoyl isocyanate derivative of winter wheat 75mg/L in addition, add 0.8g uniconazole and 5.5g zinc sulfate, the oligochitosan compound preparation of 15g phenylalanine simultaneously.Under not taking other to improve the condition of output means, once, spray 1 month, uses aqua 15L for every mu to every 10 days sprays at every turn continuously.Correlation parameter is calculated after wheat maturation.Result show through oligochitosan nicotinoyl isocyanate derivative be the output of the wheat of the oligochitosan compound preparation process of main component apparently higher than control group, output compared with clear water process blank group improve reach 9.4%(table 4).
Table 4 oligochitosan nicotinoyl isocyanate derivative compound preparation is on the impact of wheat yield

Claims (8)

1. an oligochitosan compound preparation, is characterized in that: this compound preparation effective ingredient comprises oligochitosan and/or oligochitosan derivative, amino acid, trace element and plant-growth regulator composition;
Wherein each compositions in weight percentage is respectively oligochitosan and/or oligochitosan derivative (0.005% ~ 0.02%), amino acid (0.1% ~ 5%), trace element (0.3% ~ 1.2%), plant-growth regulator (0.02% ~ 0.5%), and all the other compositions are solvent or carrier.
2. compound preparation according to claim 1, is characterized in that: the oligochitosan used between the polymerization degree 2 ~ 20, deacetylation more than 90%;
Oligochitosan derivative is including, but not limited to one or two or more kinds in oligochitosan sulfate derivative, oligochitosan acid salt derivative, oligochitosan phosphoric acid derivatives, oligochitosan sulphonamide derivatives, oligochitosan acylisothiocyanate analog derivative, oligochitosan guanidine derivative.
3. compound preparation according to claim 1, is characterized in that: the amino acid used in compound preparation is including, but not limited to one or two or more kinds conbined usage in glycine, L-Ala, leucine, Isoleucine, α-amino-isovaleric acid, Gelucystine, Gelucystine, methionine(Met), Threonine, Serine, phenylalanine, tyrosine, tryptophane, proline(Pro), oxyproline, L-glutamic acid, aspartic acid.
4. compound preparation according to claim 1, is characterized in that: the trace element used in compound preparation is including, but not limited to one or two or more kinds conbined usage in iron, zinc, copper, molybdenum, boron and manganese.
5. compound preparation according to claim 1, is characterized in that: the plant-growth regulator used in compound preparation is including, but not limited to one or two or more kinds conbined usage in forchlorfenuron, Plant hormones regulators,gibberellins, phytokinin, paclobutrazol and polyamines.
6. compound preparation according to claim 1, is characterized in that: adding the formulation that solvent or carrier be made into compound preparation is aqua, emulsion, microemulsion, suspension agent, soluble powder, wettable powder, granule, water-dispersible granules, microcapsule or tablet.
7. an application for oligochitosan compound preparation described in claim 1, is characterized by: described oligochitosan compound preparation is for improving the output of wheat; Wheat yield 1%-10% can be improved.
8. application according to claim 7, it is characterized in that: by wheat growth stage with the germination and emergence phase, to tiller Wintering Period, turn green the jointing stage, booting heading stage, the flowering and grouting phase is after the criteria for classifying, uses compound preparation, one or more methods following can be adopted to process to more than one or two stage in each stage of Wheat Development;
(1) process wheat seed, treatment process is including, but not limited to seed dressing, seed soaking or vexed kind of method, and wherein seed dressing refers to and mixed with seed by compound preparation; Seed soaking refers to that a seed or seedling are immersed in compound preparation, absorbs medicament by seed or seedling; Vexed kind refers to mixes the vexed method sowed again of rear heap by compound preparation and seed;
(2) in germination and emergence phase of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different;
(3) at the Wintering Period of tillering of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different;
(4) in jointing stage of turning green of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different;
(5) at booting heading stage of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different;
(6) in flowering and grouting phase of wheat to winter wheat compound preparation, application times can be once or more than secondary, the concentration at every turn used can be identical or different;
The application process in each vegetative period above-mentioned refers to any effective conventional method during applications of pesticide, includes but not limited to powder injection process, spraying process, executes daraf(reciprocal of farad), soil treatment method or smog method etc.
CN201310689965.1A 2013-12-12 2013-12-12 Chitosanoligosaccharide compounding preparation for increasing wheat yield, and applications thereof Pending CN104710231A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272598A (en) * 2015-10-23 2016-01-27 金正大生态工程集团股份有限公司 Wheat seed dressing agent and preparation method thereof
CN109632564A (en) * 2019-01-14 2019-04-16 江苏里下河地区农业科学研究所 The measuring method of grain water content after a kind of wheat physiological maturity
CN109734513A (en) * 2019-03-01 2019-05-10 江苏双林海洋生物药业有限公司 The Glucosamine trace element water-soluble fertilizer and preparation method and purposes of raising quality of agricultural product
CN111978124A (en) * 2020-09-24 2020-11-24 河南荣莉莱智慧农业发展有限公司 Compound agent for wheat rooting, seedling strengthening and tillering promotion
CN112006037A (en) * 2020-09-04 2020-12-01 安徽省四达农药化工有限公司 Plant growth regulator containing chitosan oligosaccharide and application thereof
CN112250507A (en) * 2020-11-02 2021-01-22 河南荣莉莱智慧农业发展有限公司 Fly-prevention plant protection compound agent for wheat in jointing stage
CN113461459A (en) * 2021-07-19 2021-10-01 北京局气网络技术有限公司 Compound chitosan oligosaccharide preparation for improving saline-alkali resistance of wheat and preparation method thereof
CN115039777B (en) * 2022-07-19 2024-04-12 河南科技大学 Compound plant growth regulator containing OPDA and COS and application thereof

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CN101305738A (en) * 2007-05-18 2008-11-19 叶青 Agricultural mixed formulation constituted by chitosan oligosaccharide or the like
CN101347128A (en) * 2007-07-19 2009-01-21 么向和 Bactericidal and insect-killing 'Jun xian bi ke' formulation
CN101543230A (en) * 2008-03-28 2009-09-30 中国科学院大连化学物理研究所 Plant stress-resistant inducer and application thereof
CN102659472A (en) * 2012-04-26 2012-09-12 江南大学 Enhanced chitosan oligosaccharide plant growth modifier formula containing plant saponin

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101305738A (en) * 2007-05-18 2008-11-19 叶青 Agricultural mixed formulation constituted by chitosan oligosaccharide or the like
CN101347128A (en) * 2007-07-19 2009-01-21 么向和 Bactericidal and insect-killing 'Jun xian bi ke' formulation
CN101543230A (en) * 2008-03-28 2009-09-30 中国科学院大连化学物理研究所 Plant stress-resistant inducer and application thereof
CN102659472A (en) * 2012-04-26 2012-09-12 江南大学 Enhanced chitosan oligosaccharide plant growth modifier formula containing plant saponin

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105272598A (en) * 2015-10-23 2016-01-27 金正大生态工程集团股份有限公司 Wheat seed dressing agent and preparation method thereof
CN109632564A (en) * 2019-01-14 2019-04-16 江苏里下河地区农业科学研究所 The measuring method of grain water content after a kind of wheat physiological maturity
CN109734513A (en) * 2019-03-01 2019-05-10 江苏双林海洋生物药业有限公司 The Glucosamine trace element water-soluble fertilizer and preparation method and purposes of raising quality of agricultural product
CN112006037A (en) * 2020-09-04 2020-12-01 安徽省四达农药化工有限公司 Plant growth regulator containing chitosan oligosaccharide and application thereof
CN111978124A (en) * 2020-09-24 2020-11-24 河南荣莉莱智慧农业发展有限公司 Compound agent for wheat rooting, seedling strengthening and tillering promotion
CN112250507A (en) * 2020-11-02 2021-01-22 河南荣莉莱智慧农业发展有限公司 Fly-prevention plant protection compound agent for wheat in jointing stage
CN113461459A (en) * 2021-07-19 2021-10-01 北京局气网络技术有限公司 Compound chitosan oligosaccharide preparation for improving saline-alkali resistance of wheat and preparation method thereof
CN115039777B (en) * 2022-07-19 2024-04-12 河南科技大学 Compound plant growth regulator containing OPDA and COS and application thereof

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Application publication date: 20150617