CN107722594A - The composite auxiliary agent of few additive low toxicity - Google Patents

The composite auxiliary agent of few additive low toxicity Download PDF

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Publication number
CN107722594A
CN107722594A CN201711031211.1A CN201711031211A CN107722594A CN 107722594 A CN107722594 A CN 107722594A CN 201711031211 A CN201711031211 A CN 201711031211A CN 107722594 A CN107722594 A CN 107722594A
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CN
China
Prior art keywords
parts
zinc
low toxicity
auxiliary agent
composite auxiliary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711031211.1A
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Chinese (zh)
Inventor
李睿阳
倪玉英
倪念英
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Sichuan Mei Saier Science And Technology Ltd
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Sichuan Mei Saier Science And Technology Ltd
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Publication date
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Priority to CN201711031211.1A priority Critical patent/CN107722594A/en
Publication of CN107722594A publication Critical patent/CN107722594A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses the composite auxiliary agent of few additive low toxicity, including 20 30 parts of silane coupler, 10 15 parts of titanate coupling agent, 58 parts of polyethylene glycol, 8 10 parts of dispersant, 13 parts of calcium stearate, 35 parts of dioctyl phthalate, 26 parts of talcum powder, 13 parts of lubricant, 0.8 2.5 parts of modification of chitosan, 0.6 1.2 parts of alginates, 0.3 0.8 parts of sodium fluoride, zinc-plated 10 20 parts of carbon black, 47 parts of sodium carbonate, 68 parts of ternary chlorine vinegar resin, 20 35 parts of deionized water, 10 16 parts of butyl acrylate, 23 parts of pentaerythritol triacrylate, 24 parts of polystyrene, 0.5 1.5 parts of maleic anhydride, 13 parts of glycerine, 69 parts of zinc stearate.The processing aid that invention is provided, dosage is few, and effect is good, can be at lower levels, you can dispersiveness, compatibility and the processing fluidity of plastics, and escaped in process without toxic gas, production security is improved, addition is reduced, reduces toxicity, is ensured physically and mentally healthy.

Description

The composite auxiliary agent of few additive low toxicity
Technical field
The present invention relates to promoter additive, and in particular to the composite auxiliary agent of few additive low toxicity.
Background technology
Plastic additive is called plastic additive, is that polymer (synthetic resin) carries out during processing and forming being to improve its processability Can or for improvement resin performance itself deficiency and some compounds that must add.For example, in order to reduce Corvic Forming temperature, the plasticizer for making product soft and adding;And for example in order to prepare light weight, antivibration, heat-insulated, sound insulation foam plastic Expect and to add foaming agent;The heat decomposition temperature of some plastics and processing and forming temperature are very close, are added without heat stabilizer just It can not be molded.Thus, plastic additive occupies special consequence in plastics processing.For plastics processing product One big analog assistant, including plasticizer, heat stabilizer, antioxidant, light stabilizer, fire retardant, foaming agent, antistatic additive, mould inhibitor, Colouring agent and brightening agent (see pigment), filler, coupling agent, lubricant, releasing agent etc..Wherein colouring agent, brightening agent and filling Agent is not plastics specialty chemicals, but general compounding ingredient.Addition of the prior art is big, toxicity is big, easily produces Harmful material.
The content of the invention
The technical problems to be solved by the invention are that addition of the prior art is big, toxicity is big, are easily produced to human body Harmful material is, and it is an object of the present invention to provide the composite auxiliary agent of few additive low toxicity, reduces addition, reduces toxicity, ensure body Heart health.
The present invention is achieved through the following technical solutions:
Few additive low toxicity composite auxiliary agent, including silane coupler 20-30 parts, titanate coupling agent 10-15 parts, Polyethylene glycol 5-8 parts, dispersant 8-10 parts, calcium stearate 1-3 parts, dioctyl phthalate 3-5 parts, talcum powder 2-6 parts, profit Lubrication prescription 1-3 parts, modification of chitosan 0.8-2.5 parts, alginates 0.6-1.2 parts, sodium fluoride 0.3-0.8 parts, zinc-plated carbon black 10-20 Part, sodium carbonate 4-7 parts, ternary chlorine vinegar resin 6-8 parts, deionized water 20-35 parts, butyl acrylate 10-16 parts, pentaerythrite three Acrylate 2-3 parts, polystyrene 2-4 parts, maleic anhydride 0.5-1.5 parts, glycerine 1-3 parts, zinc stearate 6-9 parts.
Further, the composite auxiliary agent of few additive low toxicity, including 30 parts of silane coupler, titanate coupling agent 15 Part, 8 parts of polyethylene glycol, 10 parts of dispersant, 3 parts of calcium stearate, 5 parts of dioctyl phthalate, 6 parts of talcum powder, lubricant 3 Part, 2.5 parts of modification of chitosan, 1.2 parts of alginates, 0.8 part of sodium fluoride, 20 parts of zinc-plated carbon black, 7 parts of sodium carbonate, ternary chlorine vinegar tree 8 parts of fat, 35 parts of deionized water, 16 parts of butyl acrylate, 3 parts of pentaerythritol triacrylate, 4 parts of polystyrene, maleic anhydride 1.5 parts, 3 parts of glycerine, 9 parts of zinc stearate.
Further, the composite auxiliary agent of few additive low toxicity, including 20 parts of silane coupler, titanate coupling agent 10 Part, 5 parts of polyethylene glycol, 8 parts of dispersant, 1 part of calcium stearate, 3 parts of dioctyl phthalate, 2 parts of talcum powder, lubricant 3 Part, 0.8 part of modification of chitosan, 0.6 part of alginates, 0.3 part of sodium fluoride, 10 parts of zinc-plated carbon black, 4 parts of sodium carbonate, ternary chlorine vinegar tree 6 parts of fat, 20 parts of deionized water, 10 parts of butyl acrylate, 2 parts of pentaerythritol triacrylate, 2 parts of polystyrene, maleic anhydride 0.5 part, 1 part of glycerine, 6 parts of zinc stearate.
Further, the composite auxiliary agent of few additive low toxicity, including 23 parts of silane coupler, titanate coupling agent 13 Part, polyethylene glycol 5-8 parts, 8.6 parts of dispersant, 2.4 parts of calcium stearate, 4.6 parts of dioctyl phthalate, 3 parts of talcum powder, profit 2 parts of lubrication prescription, 1.6 parts of modification of chitosan, 0.6 part of alginates, 0.8 part of sodium fluoride, 13 parts of zinc-plated carbon black, 5 parts of sodium carbonate, ternary 6 parts of vinyl chloride-vinyl acetate resin, 25 parts of deionized water, 16 parts of butyl acrylate, 3 parts of pentaerythritol triacrylate, 3 parts of polystyrene, horse Come 1.2 parts of acid anhydrides, 2 parts of glycerine, 7 parts of zinc stearate.
The present invention compared with prior art, has the following advantages and advantages:Processing aid provided by the present invention, Dosage is few, and effect is good, can be at lower levels, you can dispersiveness, compatibility and the processing fluidity of plastics, and in process Escaped without toxic gas, improve production security, reduced addition, reduce toxicity, ensured physically and mentally healthy.
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment, the present invention is made Further to describe in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this The restriction of invention.
Embodiment 1
Few additive low toxicity composite auxiliary agent, including silane coupler 20-30 parts, titanate coupling agent 10-15 parts, Polyethylene glycol 5-8 parts, dispersant 8-10 parts, calcium stearate 1-3 parts, dioctyl phthalate 3-5 parts, talcum powder 2-6 parts, profit Lubrication prescription 1-3 parts, modification of chitosan 0.8-2.5 parts, alginates 0.6-1.2 parts, sodium fluoride 0.3-0.8 parts, zinc-plated carbon black 10-20 Part, sodium carbonate 4-7 parts, ternary chlorine vinegar resin 6-8 parts, deionized water 20-35 parts, butyl acrylate 10-16 parts, pentaerythrite three Acrylate 2-3 parts, polystyrene 2-4 parts, maleic anhydride 0.5-1.5 parts, glycerine 1-3 parts, zinc stearate 6-9 parts.
Embodiment 2
The composite auxiliary agent of few additive low toxicity, including 30 parts of silane coupler, 15 parts of titanate coupling agent, poly- second two 8 parts of alcohol, 10 parts of dispersant, 3 parts of calcium stearate, 5 parts of dioctyl phthalate, 6 parts of talcum powder, 3 parts of lubricant, modified shell 2.5 parts of glycan, 1.2 parts of alginates, 0.8 part of sodium fluoride, 20 parts of zinc-plated carbon black, 7 parts of sodium carbonate, 8 parts of ternary chlorine vinegar resin, go from Sub- 35 parts of water, 16 parts of butyl acrylate, 3 parts of pentaerythritol triacrylate, 4 parts of polystyrene, 1.5 parts of maleic anhydride, glycerine 3 Part, 9 parts of zinc stearate.
Embodiment 3
The composite auxiliary agent of few additive low toxicity, including 20 parts of silane coupler, 10 parts of titanate coupling agent, poly- second two 5 parts of alcohol, 8 parts of dispersant, 1 part of calcium stearate, 3 parts of dioctyl phthalate, 2 parts of talcum powder, 3 parts of lubricant, modified shell gather 0.8 part of sugar, 0.6 part of alginates, 0.3 part of sodium fluoride, 10 parts of zinc-plated carbon black, 4 parts of sodium carbonate, 6 parts of ternary chlorine vinegar resin, deionization 20 parts of water, 10 parts of butyl acrylate, 2 parts of pentaerythritol triacrylate, 2 parts of polystyrene, 0.5 part of maleic anhydride, glycerine 1 Part, 6 parts of zinc stearate.
Embodiment 4
The composite auxiliary agent of few additive low toxicity, including 23 parts of silane coupler, 13 parts of titanate coupling agent, poly- second two Alcohol 5-8 parts, 8.6 parts of dispersant, 2.4 parts of calcium stearate, 4.6 parts of dioctyl phthalate, 3 parts of talcum powder, lubricant 2 Part, 1.6 parts of modification of chitosan, 0.6 part of alginates, 0.8 part of sodium fluoride, 13 parts of zinc-plated carbon black, 5 parts of sodium carbonate, ternary chlorine vinegar tree 6 parts of fat, 25 parts of deionized water, 16 parts of butyl acrylate, 3 parts of pentaerythritol triacrylate, 3 parts of polystyrene, maleic anhydride 1.2 parts, 2 parts of glycerine, 7 parts of zinc stearate.
Above-described embodiment, the purpose of the present invention, technical scheme and beneficial effect are carried out further Describe in detail, should be understood that the embodiment that the foregoing is only the present invention, be not intended to limit the present invention Protection domain, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc., all should include Within protection scope of the present invention.

Claims (4)

1. the composite auxiliary agent of few additive low toxicity, it is characterised in that be coupled including silane coupler 20-30 parts, titanate esters Agent 10-15 parts, polyethylene glycol 5-8 parts, dispersant 8-10 parts, calcium stearate 1-3 parts, dioctyl phthalate 3-5 parts, talcum It is powder 2-6 parts, lubricant 1-3 parts, modification of chitosan 0.8-2.5 parts, alginates 0.6-1.2 parts, sodium fluoride 0.3-0.8 parts, zinc-plated Carbon black 10-20 parts, sodium carbonate 4-7 parts, ternary chlorine vinegar resin 6-8 parts, deionized water 20-35 parts, butyl acrylate 10-16 parts, Pentaerythritol triacrylate 2-3 parts, polystyrene 2-4 parts, maleic anhydride 0.5-1.5 parts, glycerine 1-3 parts, zinc stearate 6-9 Part.
2. the composite auxiliary agent of few additive low toxicity according to claim 1, it is characterised in that including silane coupler 30 parts, 15 parts of titanate coupling agent, 8 parts of polyethylene glycol, 10 parts of dispersant, 3 parts of calcium stearate, 5 parts of dioctyl phthalate, 6 parts of talcum powder, 3 parts of lubricant, 2.5 parts of modification of chitosan, 1.2 parts of alginates, 0.8 part of sodium fluoride, 20 parts of zinc-plated carbon black, carbonic acid 7 parts of sodium, 8 parts of ternary chlorine vinegar resin, 35 parts of deionized water, 16 parts of butyl acrylate, 3 parts of pentaerythritol triacrylate, polyphenyl 4 parts of ethene, 1.5 parts of maleic anhydride, 3 parts of glycerine, 9 parts of zinc stearate.
3. the composite auxiliary agent of few additive low toxicity according to claim 1, it is characterised in that including silane coupler 20 parts, 10 parts of titanate coupling agent, 5 parts of polyethylene glycol, 8 parts of dispersant, 1 part of calcium stearate, 3 parts of dioctyl phthalate, 2 parts of talcum powder, 3 parts of lubricant, 0.8 part of modification of chitosan, 0.6 part of alginates, 0.3 part of sodium fluoride, 10 parts of zinc-plated carbon black, carbonic acid 4 parts of sodium, 6 parts of ternary chlorine vinegar resin, 20 parts of deionized water, 10 parts of butyl acrylate, 2 parts of pentaerythritol triacrylate, polyphenyl 2 parts of ethene, 0.5 part of maleic anhydride, 1 part of glycerine, 6 parts of zinc stearate.
4. the composite auxiliary agent of few additive low toxicity according to claim 1, it is characterised in that including silane coupler 23 parts, 13 parts of titanate coupling agent, polyethylene glycol 5-8 parts, 8.6 parts of dispersant, 2.4 parts of calcium stearate, phthalic acid two it is pungent 4.6 parts of ester, 3 parts of talcum powder, 2 parts of lubricant, 1.6 parts of modification of chitosan, 0.6 part of alginates, 0.8 part of sodium fluoride, zinc-plated carbon black 13 parts, 5 parts of sodium carbonate, 6 parts of ternary chlorine vinegar resin, 25 parts of deionized water, 16 parts of butyl acrylate, pentaerythritol triacrylate 3 parts, 3 parts of polystyrene, 1.2 parts of maleic anhydride, 2 parts of glycerine, 7 parts of zinc stearate.
CN201711031211.1A 2017-10-27 2017-10-27 The composite auxiliary agent of few additive low toxicity Pending CN107722594A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294112A (en) * 2018-09-03 2019-02-01 李永平 A kind of micro- super film of contraction

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11293074A (en) * 1998-04-14 1999-10-26 Achilles Corp Vinyl chloride-based resin composition
CN105482307A (en) * 2015-12-30 2016-04-13 李栋军 Processing aid of PVC (polyvinyl chloride) plastics
CN105482215A (en) * 2015-12-29 2016-04-13 王璐 High-stability anti-aging additive used for polyolefin
CN106188957A (en) * 2016-07-28 2016-12-07 安吉威龙塑木环保材料有限公司 A kind of wood plastic composite processing aid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11293074A (en) * 1998-04-14 1999-10-26 Achilles Corp Vinyl chloride-based resin composition
CN105482215A (en) * 2015-12-29 2016-04-13 王璐 High-stability anti-aging additive used for polyolefin
CN105482307A (en) * 2015-12-30 2016-04-13 李栋军 Processing aid of PVC (polyvinyl chloride) plastics
CN106188957A (en) * 2016-07-28 2016-12-07 安吉威龙塑木环保材料有限公司 A kind of wood plastic composite processing aid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294112A (en) * 2018-09-03 2019-02-01 李永平 A kind of micro- super film of contraction

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Application publication date: 20180223