CN107696654A - A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology - Google Patents

A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology Download PDF

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Publication number
CN107696654A
CN107696654A CN201710800193.2A CN201710800193A CN107696654A CN 107696654 A CN107696654 A CN 107696654A CN 201710800193 A CN201710800193 A CN 201710800193A CN 107696654 A CN107696654 A CN 107696654A
Authority
CN
China
Prior art keywords
low smell
solvent
pvc
layer
based ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710800193.2A
Other languages
Chinese (zh)
Inventor
李剑锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Liansheng Decorative Material Co Ltd
Original Assignee
Foshan Liansheng Decorative Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Liansheng Decorative Material Co Ltd filed Critical Foshan Liansheng Decorative Material Co Ltd
Priority to CN201710800193.2A priority Critical patent/CN107696654A/en
Publication of CN107696654A publication Critical patent/CN107696654A/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/06—Embossing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of low smell solvent-borne type PVC decorative Film of environmental protection and its preparation technology, including PVC base layer, low smell solvent-based ink printing layer and PVC surface layer, the low smell solvent that the low smell solvent-based ink printing layer is made up of 40% butanone and the mixing of 60% n-propyl is printed on PVC base layer after adding low smell printing-ink toning dilution, and PVC surface lamination line is fitted in low smell solvent-based ink printing layer；The low smell solvent that its low smell solvent-based ink printing layer is made up of 40% butanone and the mixing of 60% n-propyl is printed on PVC base layer after adding low smell printing-ink toning dilution, no solvent residue, low peculiar smell；The characteristics of with environmentally friendly low smell, the existing PVC decorative Film of tradition is may replace, beneficial to environmental protection and health；Solve the problems, such as that existing PVC decorative Film is dense using dissolvent residual and peculiar smell existing for the printing of usual vehicle type ink.

Description

A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology
Technical field
The invention belongs to PVC decorative Film technical field, and in particular to a kind of no solvent residue, the environmentally friendly low smell of low peculiar smell Solvent-borne type PVC decorative Film and its preparation technology.
Background technology
With the development of social economy, growth in the living standard, people are increasing to the decoration demand of household, to life Bioplasm amount and environment protection health are increasingly focused on.Post print exquisite pattern decorative film Wood-based Panel Furniture it is elegant in appearance, meet masses Aesthetic conceptions, received by more and more people.But home decoration film in the market is using PVC as base material, using solvent-based ink Carry out printed facing layer, finish coat prints out generally by usual vehicle type ink, and the PVC decorative Film produced and processed out has Dissolvent residual, PVC decorative Film carry dense peculiar smell, both not environmentally, also can produce harm to health.
The content of the invention
In view of the shortcomings of the prior art, the present invention is intended to provide a kind of no solvent residue, the environmentally friendly low smell of low peculiar smell are molten Formulation PVC decorative Film and its preparation technology.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of low smell solvent-borne type PVC decorative Film of environmental protection, including PVC base layer, low smell solvent-based ink printing layer and PVC surface layer, the low gas that the low smell solvent-based ink printing layer is made up of 40% butanone and the mixing of 60% n-propyl Taste solvent is printed on PVC base layer after adding low smell printing-ink toning dilution, and PVC surface lamination line is fitted in low smell In solvent-based ink printing layer.
Preferably, the PVC base layer is low smell PVC base.
Preferably, the PVC surface layer is low smell PVC veneers.
A kind of environmentally friendly low smell solvent-borne type PVC decorative Film preparation technology, comprises the following steps：
A, prepared by low smell solvent, and low smell solvent is made up of 40% butanone and the mixing of 60% n-propyl；
B, prepared by low smell solvent-based ink, is mixed colours after obtained low smell solvent in step a is added into low smell ink, And open it is dilute to viscosity be 18-22 seconds/examine No. 3 cups of grace；
C, low smell solvent-based ink printing, it is molten with obtained low smell in step b on circulating pump by branched roller chromatography Based ink, it is 18-22 seconds/examine No. 3 cups of grace to control viscosity with automatic viscometer, and coating blade uses ceramic blade, scrapes nose angle Spend for 45 degree, printed on PVC base layer and low smell solvent-based ink printing layer is made；
D, printing layer is dried, and press oven is lengthened to 2 meters, and obtained low smell solvent-based ink in step c is printed Brush layer is dried；
E, embossing fitting, it is 40m/min to control make-up machine speed, and temperature is 160 DEG C, and PVC surface lamination line is fitted in In low smell solvent-based ink printing layer after step d drying.
The present invention has the advantages that：
Its low smell solvent-based ink printing layer of the invention is made up of low 40% butanone and the mixing of 60% n-propyl Smell solvent is printed on PVC base layer after adding low smell printing-ink toning dilution, no solvent residue, low peculiar smell；Have The characteristics of environmentally friendly low smell, the existing PVC decorative Film of tradition is may replace, beneficial to environmental protection and health.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the low smell solvent-borne type PVC decorative Film of environmental protection of the present invention.
In figure：1st, PVC base layer；2nd, low smell solvent-based ink printing layer；3rd, PVC surface layer.
Embodiment
Below in conjunction with the accompanying drawings and specific embodiment, the invention will be further described, in order to be more clearly understood that this The claimed technological thought of invention.
The low smell solvent-borne type PVC decorative Film of a kind of environmental protection of the present invention as shown in Figure 1, including PVC base layer 1, low smell are molten Based ink printing layer 2 and PVC surface layer 3, the low smell solvent-based ink printing layer 2 by 40% butanone and 60% just The low smell solvent of propyl ester mixing composition is printed on PVC base layer 1 after adding low smell printing-ink toning dilution, PVC tables The embossing of surface layer 3 is fitted in low smell solvent-based ink printing layer 2.It is made up of 40% butanone and the mixing of 60% n-propyl Low smell solvent can avoid solvent in itself and ink residue volatilization.
Wherein, PVC base layer 1 is low smell PVC base.PVC surface layer 3 is low smell PVC veneers.
A kind of environmentally friendly low smell solvent-borne type PVC decorative Film preparation technology, comprises the following steps：
A, prepared by low smell solvent, and low smell solvent is made up of 40% butanone and the mixing of 60% n-propyl；
B, prepared by low smell solvent-based ink, is mixed colours after obtained low smell solvent in step a is added into low smell ink, And open it is dilute to viscosity be 18-22 seconds/examine No. 3 cups of grace；
C, low smell solvent-based ink printing, it is molten with obtained low smell in step b on circulating pump by branched roller chromatography Based ink, it is 18-22 seconds/examine No. 3 cups of grace to control viscosity with automatic viscometer, and coating blade uses ceramic blade, scrapes nose angle Spend for 45 degree, printed on PVC base layer 1 and low smell solvent-based ink printing layer 2 is made；
D, printing layer is dried, and press oven is lengthened to 2 meters, and obtained low smell solvent-based ink in step c is printed Brush layer 2 is dried；
E, embossing fitting, it is 40m/min to control make-up machine speed, and temperature is 160 DEG C, and the embossing of PVC surface layer 3 is fitted in In low smell solvent-based ink printing layer 2 after step d drying.
Tested through SGS, take the low smell solvent-borne type PVC decorative Film 200cm of environmental protection of the invention2, it is 23 ± 2 in test temperature DEG C, the resting period be 24 ± 1h under conditions of carry out odor characteristics test, test result is as follows：
Opinion rating
Test man 1 2.5
Test man 2 2.0
Test man 3 2.0
Test man 4 2.0
Test man 5 2.0
Average value 2.0
According to SGS odor characteristics test evaluation classification standards, such as following table：
Grade Evaluation criteria
1 Nothing is discovered
2 Discover, but do not allow people to feel ill
3 Directly discover, but still do not allow people to feel ill
4 People is allowed to feel to feel bad
5 Allow people feel be difficult by
6 It can not receive
It may determine that according to test result, the odor characteristics evaluation of the low smell solvent-borne type PVC decorative Film of present invention environmental protection Grade is 2.0, has the characteristics of environmentally friendly low smell, beneficial to environmental protection and health, people will not be allowed to feel ill.
For those skilled in the art, technical scheme that can be as described above and design, make other each Kind is corresponding to be changed and deforms, and all these change and deformed the protection model that should all belong to the claims in the present invention Within enclosing.

Claims (4)

  1. A kind of 1. environmentally friendly low smell solvent-borne type PVC decorative Film, it is characterised in that：Including PVC base layer (1), low smell solvent-borne type Ink printed layer (2) and PVC surface layer (3), the low smell solvent-based ink printing layer (2) is by 40% butanone and 60% The low smell solvent of n-propyl mixing composition is printed on PVC base layer (1) after adding low smell printing-ink toning dilution, PVC surface layer (3) embossing is fitted on low smell solvent-based ink printing layer (2).
  2. A kind of 2. environmentally friendly low smell solvent-borne type PVC decorative Film as claimed in claim 1, it is characterised in that：The PVC base layer (1) it is low smell PVC base.
  3. A kind of 3. environmentally friendly low smell solvent-borne type PVC decorative Film as claimed in claim 1, it is characterised in that：The PVC surface layer (3) it is low smell PVC veneers.
  4. 4. a kind of environmentally friendly low smell solvent-borne type PVC decorative Film preparation technology, comprises the following steps：
    A, prepared by low smell solvent, and low smell solvent is made up of 40% butanone and the mixing of 60% n-propyl；
    B, prepared by low smell solvent-based ink, is mixed colours after obtained low smell solvent in step a is added into low smell ink, and open It is dilute to viscosity be 18-22 seconds/examine No. 3 cups of grace；
    C, low smell solvent-based ink printing, by branched roller chromatography, with obtained low smell solvent-borne type in step b on circulating pump Ink, it is 18-22 seconds/examine No. 3 cups of grace to control viscosity with automatic viscometer, and coating blade uses ceramic blade, and scraper angle is 45 degree, printed on PVC base layer (1) and low smell solvent-based ink printing layer (2) is made；
    D, printing layer is dried, and press oven is lengthened to 2 meters, to obtained low smell solvent-based ink printing layer in step c (2) dried；
    Embossing fitting, it be 40m/min control make-up machine speed, and temperature is 160 DEG C, PVC surface layer (3) is embossed be fitted in by On low smell solvent-based ink printing layer (2) after step d drying.
CN201710800193.2A 2017-09-07 2017-09-07 A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology Pending CN107696654A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710800193.2A CN107696654A (en) 2017-09-07 2017-09-07 A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710800193.2A CN107696654A (en) 2017-09-07 2017-09-07 A kind of environmentally friendly low smell solvent-borne type PVC decorative Film and its preparation technology

Publications (1)

Publication Number Publication Date
CN107696654A true CN107696654A (en) 2018-02-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111976248A (en) * 2020-08-28 2020-11-24 浙江亚厦装饰股份有限公司 Stain-resistant scratch-resistant PVC decorative film and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104371420A (en) * 2014-10-30 2015-02-25 佛山市天元汇邦装饰材料有限公司 Waterborne ink and preparation method thereof as well as application of waterborne ink in PP (Polypropylene) decorative film
CN104710876A (en) * 2013-12-14 2015-06-17 上海泉灵信息科技有限公司 Black color-variable printing ink specially used for ceramic cups
CN105482548A (en) * 2015-12-28 2016-04-13 佛山市天元汇邦装饰材料有限公司 Environment-friendly PVC (polyvinyl chloride) decorative film and preparation method thereof
CN105670383A (en) * 2016-02-26 2016-06-15 鞍山文雷科技有限公司 Preparation method of environmental-friendly waterborne high-temperature-resistance ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104710876A (en) * 2013-12-14 2015-06-17 上海泉灵信息科技有限公司 Black color-variable printing ink specially used for ceramic cups
CN104371420A (en) * 2014-10-30 2015-02-25 佛山市天元汇邦装饰材料有限公司 Waterborne ink and preparation method thereof as well as application of waterborne ink in PP (Polypropylene) decorative film
CN105482548A (en) * 2015-12-28 2016-04-13 佛山市天元汇邦装饰材料有限公司 Environment-friendly PVC (polyvinyl chloride) decorative film and preparation method thereof
CN105670383A (en) * 2016-02-26 2016-06-15 鞍山文雷科技有限公司 Preparation method of environmental-friendly waterborne high-temperature-resistance ink

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
伍秋海 林武辉: "《实用软包装生产技术手册》", 31 August 2015 *
印刷工业出版社编辑部: "《油墨生产及应用技术》", 30 November 2011 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111976248A (en) * 2020-08-28 2020-11-24 浙江亚厦装饰股份有限公司 Stain-resistant scratch-resistant PVC decorative film and preparation method thereof

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Application publication date: 20180216