CN102632738B - Digital image film and preparation method thereof - Google Patents
Digital image film and preparation method thereof Download PDFInfo
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- CN102632738B CN102632738B CN201210057788.0A CN201210057788A CN102632738B CN 102632738 B CN102632738 B CN 102632738B CN 201210057788 A CN201210057788 A CN 201210057788A CN 102632738 B CN102632738 B CN 102632738B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 5
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- 239000002344 surface layer Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims description 44
- 239000011248 coating agent Substances 0.000 claims description 43
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- -1 20-40 parts Substances 0.000 claims description 24
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 12
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- 238000003756 stirring Methods 0.000 claims description 12
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- 239000002253 acid Substances 0.000 claims description 11
- 150000007513 acids Chemical class 0.000 claims description 11
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- 238000000465 moulding Methods 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims 3
- 235000010215 titanium dioxide Nutrition 0.000 claims 3
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- VBUNOIXRZNJNAD-UHFFFAOYSA-N ponazuril Chemical compound CC1=CC(N2C(N(C)C(=O)NC2=O)=O)=CC=C1OC1=CC=C(S(=O)(=O)C(F)(F)F)C=C1 VBUNOIXRZNJNAD-UHFFFAOYSA-N 0.000 description 1
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Images
Abstract
The invention provides a digital image film and a preparation method thereof. The digital image film is composed of a film base, a bottom layer and a surface layer, wherein the upper and lower surfaces of the film base are respectively coated with the bottom layer and the surface layer, and the bottom layer is positioned between the surface layer and the film base. The digital image film provided by the invention has strong water resistance, is soaked in the water for 24 hours, and can not drop; the product has good flexibility on a laser printer, the digital image film and the preparation method can overcome the problems that paper jam in the common digital printing process of the existing paper product is overcome; and the definition and saturation of the printed image are poor, the color loses colors (the product can improve the reducibility of the color) and the like.
Description
Technical field
The present invention relates to a kind of print media, particularly a kind of digital image film of printing field for modern handle official bussiness, exquisite ad decoration, photo and medical image.
Background technology
Digital image film is the product just having risen in recent years, is mainly to meet or the adaptation market demand growing to letter quality material.Digital image film is the print media of colour or black and white digital-code printer, the carrier that is digital code informations such as connecing digital printing device output image, word, feature is exquisite in texture, smooth surface, state is translucent, the image color and luster printing is beautiful, well arranged, and texture and class are all better than common printing paper.Be mainly used in the fields such as modern handle official bussiness, exquisite advertisement, decoration, photo and medical image printing.But existing product face coat is not very even, and coating is insecure with engaging of base material, and coating is anti-zoned, resistance to scraping is general or even poor, as they after soaked 24 hours, are had to the coating shedding of part.The problems such as even some product there will be paperboard in print procedure, and the image definition, the saturation degree that print are inadequate, color colour cast (both having improved the reproducibility of color).Therefore existing product can not meet the demand of existing office.And at present the standard of constant digital image film quality is mainly that firmness, water-resistance, heat resistance, the coating uniformity, transparency, surface flatness and carbon dust from coating judged in conjunction with several respects such as firmness.The firmness of its floating coat refers to: face coat is combined firmly degree with base material, evaluation method is: 1, with applying adhesive tape, at coating surface, after approximately 10 minutes, open adhesive tape, coating is without coming off and dry linting phenomenon; 2, with nail, gently scrape coating Wu's dry linting phenomenon.Water-resistance: product was immersed in normal-temperature water after 24 hours, and coating is without hollowing, obscission, and with finger, to wipe be for several times both that water-resistance is good without dry linting phenomenon.Heat resistance: at 200 ℃ of temperature, toast approximately 1 minute coating without coming off, hollowing and obviously metachromatism both there is good heat resistance.The coating uniformity: product is seen without obvious following phenomenon and is good evenness light, A, without obvious striped in length and breadth, B, without obvious bright spot, C, without obvious cotton-shaped decorative pattern, D, without obvious fish-eye shaped speckle.See-through: both transparencies, all-transparent is 100%, opaque is 0%.Surface flatness: smooth surface or degree of roughness.Carbon dust binding strength: the carbon dust and the coating binding strength that are printed on this product surface.Carbon dust is scraped or is wiped with nail or dry cloth, and binding strength is good.
Summary of the invention
The object of the invention is to overcome the deficiency of above-mentioned existing digital image film existence, provide a kind of resistance to scraping, scratch resistant, water-resistance is good and face coat digital image film more uniformly.
The technical scheme that the present invention adopted is to achieve these goals: a kind of digital image film, it is characterized in that being formed by sheet base, bottom and surface layer, and wherein the upper and lower faces of sheet base all scribbles bottom and surface layer, and bottom is between surface layer and sheet base, wherein
Bottom is comprised of the raw material of following parts by weight: 10-40 parts of PVA liquid, 40-60 parts of water-resistance adhesives, 20-40 parts, water, 1-4 parts, butanols;
Surface layer is comprised of the raw material of following parts by weight: titanium dioxide (TiO
2) 20-50 parts, 20-50 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 20-50 parts, 1-6 parts of hexa metaphosphoric acids, 110-350 parts, water, 100-200 parts of PVA liquid, 35-600 parts of water-resistance adhesives, 2-5 parts, amino resins, 1-2 parts of AEOs, 0.2-0.5 part of fluorescent whitening agent.
The technical scheme being more preferably in the present invention is that described base is plastic sheeting, preferably PET, PVC, PC, PP material.
The proportioning that in the present invention, bottom is more preferably is comprised of the raw material of following parts by weight: 20-30 parts of PVA liquid, 45-55 parts of water-resistance adhesives, 26-34 parts, water, 1-4 parts, butanols, further the raw material by following parts by weight forms: 25 parts of PVA liquid, 48 parts of water-resistance adhesives, 30 parts, water, 3 parts, butanols.
The surface layer proportioning being more preferably in the present invention is comprised of the raw material of following parts by weight: titanium dioxide (TiO
2) 25-40 parts, 25-40 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 25-40 parts, 2-5 parts of hexa metaphosphoric acids, 150-300 parts, water, 120-180 parts of PVA liquid, 100-550 parts of water-resistance adhesives, 2-5 parts, amino resins, 1-2 parts of AEOs, 0.2-0.5 part of fluorescent whitening agent.
The surface layer being more preferably is comprised of the raw material of following parts by weight: titanium dioxide (TiO
2) 30 parts, 30 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 30 parts, 3 parts of hexa metaphosphoric acids, 220 parts, water, 140 parts of PVA liquid, 450 parts of water-resistance adhesives, 3 parts, amino resins, 2 parts of AEOs, 0.4 part of fluorescent whitening agent.
The present invention also provides a kind of method of preparing above-mentioned digital image film, it is characterized in that comprising the steps:
A, by the raw material proportioning of above-mentioned bottom raw material proportioning and surface layer respectively mixed material and stir 1-2 hours, prepare investment precoat and subbing, stand for standby use after filtering;
B, selection plastic sheeting are as sheet base base material;
C, sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar;
D, the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering;
E, the second face of sheet base in step D is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming;
F, by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
In above-mentioned steps, pretreatment is that electric spark or plasma treatment by corona discharge makes sheet primary surface produce ozone, nitrogen oxide etc., they and film surface are carried out oxidation reaction and are generated polar activation group and form trickle trace line, are beneficial to the binding strength of coating expansion and raising and coating.
For existing market to high-quality digital image material, require us to complete formula Design and production technology to determine, make product there is following characteristics:
1, product surface coating is more even, has obviously improved product appearance quality, and this is one of most important index of this class material quality height.
2, coating is very firm with engaging of base material, coating have well anti-zoned, resistance to scraping is good.
3, coating has very strong water-resistance, soaked 24 hours, can not come off.
The problems such as 4, product is good to the adaptability of laser printer, has overcome common paperboard in digital printing process, and the image definition, the saturation degree that print are inadequate, color colour cast (both having improved the reproducibility of color).
Accompanying drawing explanation
Fig. 1 is product structure schematic diagram of the present invention.
In figure: 1-sheet base, 2-bottom, 3-surface layer.
Specific embodiments
As shown in Figure 1: a kind of digital image film, sheet base 1, bottom 2 and surface layer 3, consist of, wherein the upper and lower faces of sheet base 1 all scribbles bottom 2 and surface layer 3, and bottom 2 is between surface layer 3 and sheet base 1, sheet base adopts plastic sheeting to make, and best is PET, PVC, PC, PP material.
Embodiment 1:
By 10 parts of PVA liquid, 40 parts of water-resistance adhesives, 20 parts, water, the raw material that butanols is 1 part mixes and stirs 1-2 hours, standing after filtering, and makes subbing, standby; Again by titanium dioxide (TiO
2) 20 parts, 20 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 20 parts, the raw material of 1 part of hexa metaphosphoric acid, 110 parts, water, 100 parts of PVA liquid, 35 parts of water-resistance adhesives, 2 parts, amino resins, 1 part of AEO, 0.2 part of fluorescent whitening agent mix and stir 1-2 hours, standing after filtering, make investment precoat, standby.Then select plastic sheeting as sheet base base material, and sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar; Again the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering; Again the second face of aforementioned base is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming; Finally by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
Embodiment 2:
By 20 parts of PVA liquid, 45 parts of water-resistance adhesives, 26 parts, water, the raw material that butanols is 1 part mixes and stirs 1-2 hours, standing after filtering, and makes subbing, standby; Again by titanium dioxide (TiO
2) 25 parts, 25 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 25 parts, 2 parts of hexa metaphosphoric acids, 150 parts, water, 120 parts of PVA liquid, 100 parts of water-resistance adhesives, 2 parts, amino resins, 1 part of AEO, 0.3 part of fluorescent whitening agent.Raw material mix and stir 1-2 hours, standing after filtering, make investment precoat, standby.Then select plastic sheeting as sheet base base material, and sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar; Again the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering; Again the second face of aforementioned base is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming; Finally by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
Embodiment 3:
By 25 parts of PVA liquid, 48 parts of water-resistance adhesives, 30 parts, water, the raw material that butanols is 3 parts mixes and stirs 1-2 hours, standing after filtering, and makes subbing, standby; Again by titanium dioxide (TiO
2) 30 parts, 30 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 30 parts, the raw material of 3 parts of hexa metaphosphoric acids, 220 parts, water, 140 parts of PVA liquid, 450 parts of water-resistance adhesives, 3 parts, amino resins, 2 parts of AEOs, 0.4 part of fluorescent whitening agent mix and stir 1-2 hours, standing after filtering, make investment precoat, standby.Then select plastic sheeting as sheet base base material, and sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar; Again the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering; Again the second face of aforementioned base is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming; Finally by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
Embodiment 4:
By 30 parts of PVA liquid, 55 parts of water-resistance adhesives, 34 parts, water, the raw material that butanols is 3.5 parts mixes and stirs 1-2 hours, standing after filtering, and makes subbing, standby; Again by titanium dioxide (TiO
2) 40 parts, 40 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 40 parts, 5 parts of hexa metaphosphoric acids, 300 parts, water, 118 parts of PVA liquid, 550 parts of water-resistance adhesives, 5 parts, amino resins, 2 parts of AEOs, 0.4 part of fluorescent whitening agent.Raw material mix and stir 1-2 hours, standing after filtering, make investment precoat, standby.Then select plastic sheeting as sheet base base material, and sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar; Again the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering; Again the second face of aforementioned base is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming; Finally by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
Embodiment 5:
By 40 parts of P:PVA liquid, 60 parts of water-resistance adhesives, 40 parts, water, the raw material that butanols is 4 parts mixes and stirs 1-2 hours, standing after filtering, and makes subbing, standby; Again by titanium dioxide (TiO
2) 50 parts, 50 parts, zinc oxide (ZnO), kaolin (Al
2o
3siO
2) 50 parts, the raw material of 6 parts of hexa metaphosphoric acids, 350 parts, water, 200 parts of PVA liquid, 600 parts of water-resistance adhesives, 5 parts, amino resins, 2 parts of AEOs, 0.5 part of fluorescent whitening agent mix and stir 1-2 hours, standing after filtering, make investment precoat, standby.Then select plastic sheeting as sheet base base material, and sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar; Again the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering; Again the second face of aforementioned base is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming; Finally by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
All adopt the criterion of background technology the inside to judge the finished product of above-mentioned 5 embodiment, the properties of product of each embodiment, as following table, wherein judge that grade is as 1-5, and from 1 to 5 expression product quality is bad to good degree, 1 expression is the poorest defective, and 5 expressions are best.
| Product index | Embodiment 1 | |
|
Embodiment 4 | Embodiment 5 |
| Coating firmness | 5 | 5 | 5 | 5 | 5 |
| Coating water-resistance | 5 | 5 | 5 | 5 | 5 |
| Coating heat resistance | 5 | 5 | 5 | 5 | 5 |
| The coating uniformity | 5 | 5 | 4 | 4 | 5 |
| Coating transparency | 4 | 4 | 5 | 5 | 4 |
| Surface flatness | 5 | 5 | 5 | 5 | 5 |
| Carbon dust binding strength | 5 | 5 | 5 | 5 | 5 |
Water-resistance adhesive described in the present invention can be the mixed liquor of EVA liquid or PU liquid or EVA and PU etc.Described AEO is called again levelling agent or peregal, belong to nonionic surface active agent, outward appearance is milky or ecru ointment shape, when molecular weight is higher, be solid shape (can make as requested chip solid), soluble in water, ethanol, ethylene glycol etc., have cloud point, and 1% aqueous ph value is neutral.Acidproof, alkaline-resisting, the resistance to hard water of energy, heat-resisting, resistance to heavy metallic salt.Various dyestuffs are had to powerful level-dyeing property, slow metachromia, permeability, diffusivity, and during kiering, tool helps experienced performance, can be with various surfactants and dyestuff with molten use.
The present invention is at plastic film chip base two-sided barrier coating and surface layer respectively, and coating structure is as Fig. 1.In figure, bottom is tie coat, plays a part sheet base and surface layer strong bonded.Primer is selected very crucial.Surface layer, has electricity Jie property of good water imbibition and applicable printer to carbon dust, smooth surface is fine and smooth, and coating uniformity, could obtain high-quality image.Surface layer is translucent, is generally white, also can mix colours on request.To printing, ink powder absorbability is good, weather-proof, good heat resistance because selecting for bottom and investment precoat, and stable chemical nature, through repetition test and screening: titanium dioxide, zinc oxide, kaolin etc. are good pigment/filler.
Sizing material: select polyurethane (PU), EVA emulsion, PVOH (PVA) etc. be sizing material, good to printing ink powder absorbability, good to pigment/filler look dissolubility, resistance to marquis, the feature such as heat-resisting, resistance to acids and bases good, good film-forming property.
Function additive: be mainly to coating there is froth breaking, moistening, levelability and brighten, the function such as anti-oxidant, antistatic.
Sheet base film selection range in the present invention is wider, and optional transparent or opaque plastic sheeting is made base material, as plastic sheetings such as PET, PVC, PC, PP, and our first-selected PET polyester film, its advantage is: heat-resisting, good weatherability, folding resistance is good, deflection is good.Thickness is optional 100um, 125um, 150um etc. as required.Before the coating of sheet base, must make sheet primary surface have hydrophilic polar through corona or plasma treatment, be convenient to even coating, and strengthen sheet base and coating binding strength, first primer be coated with fabric again.
Claims (8)
1. a digital image film, is characterized in that consisting of sheet base, bottom and surface layer, and the upper and lower faces of described base all scribbles bottom and surface layer, bottom between surface layer and sheet base, wherein,
Bottom is comprised of the raw material of following parts by weight: 10-40 parts of PVA liquid, 40-60 parts of water-resistance adhesives, 20-40 parts, water, 1-4 parts, butanols;
Surface layer is comprised of the raw material of following parts by weight: 20-50 parts of titanium dioxides, 20-50 parts, zinc oxide, 20-50 parts of kaolin, 1-6 parts of hexa metaphosphoric acids, 110-350 parts, water, 100-200 parts of PVA liquid, 35-600 parts of water-resistance adhesives, 2-5 parts, amino resins, 1-2 parts of AEOs, 0.2-0.5 part of fluorescent whitening agent.
2. digital image film according to claim 1, is characterized in that described base is plastic sheeting.
3. digital image film according to claim 2, is characterized in that described base is PET, PVC, PC, PP material.
4. digital image film according to claim 1, is characterized in that described bottom is comprised of the raw material of following parts by weight: 20-30 parts of PVA liquid, 45-55 parts of water-resistance adhesives, 26-34 parts, water, 1-4 parts, butanols.
5. digital image film according to claim 4, is characterized in that described bottom is comprised of the raw material of following parts by weight: 25 parts of PVA liquid, 48 parts of water-resistance adhesives, 30 parts, water, 3 parts, butanols.
6. digital image film according to claim 1, is characterized in that described surface layer is comprised of the raw material of following parts by weight: 25-40 parts of titanium dioxides, 25-40 parts, zinc oxide, 25-40 parts of kaolin, 2-5 parts of hexa metaphosphoric acids, 150-300 parts, water, 120-180 parts of PVA liquid, 100-550 parts of water-resistance adhesives, 2-5 parts, amino resins, 1-2 parts of AEOs, 0.2-0.5 part of fluorescent whitening agent.
7. digital image film according to claim 6, is characterized in that described surface layer is comprised of the raw material of following parts by weight: 30 parts of titanium dioxides, 30 parts, zinc oxide, 30 parts of kaolin, 3 parts of hexa metaphosphoric acids, 220 parts, water, 140 parts of PVA liquid, 450 parts of water-resistance adhesives, 3 parts, amino resins, 2 parts of AEOs, 0.4 part of fluorescent whitening agent.
8. the method for preparing digital image film described in claim 1, is characterized in that this preparation method comprises the steps:
A, by the raw material proportioning of the bottom raw material proportioning described in claim 1 and surface layer respectively mixed material and stir 1-2 hours, prepare investment precoat and subbing, stand for standby use after filtering;
B, selection plastic sheeting are as sheet base base material;
C, sheet base is carried out to corona or plasma treatment, make sheet primary surface there is hydrophilic polar;
D, the sheet base of handling well is delivered to apparatus for coating, one side is successively evenly coated subbing and investment precoat successively therein, enters drying tunnel and dry after gauge stick metering;
E, the second face of sheet base in step D is successively coated to subbing and investment precoat successively through apparatus for coating again, after gauge stick metering, enter drying tunnel drying forming;
F, by the product of above-mentioned moulding through cutting, sorting, dress bag be finished product-digital image film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210057788.0A CN102632738B (en) | 2012-03-07 | 2012-03-07 | Digital image film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210057788.0A CN102632738B (en) | 2012-03-07 | 2012-03-07 | Digital image film and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102632738A CN102632738A (en) | 2012-08-15 |
| CN102632738B true CN102632738B (en) | 2014-02-05 |
Family
ID=46617393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210057788.0A Expired - Fee Related CN102632738B (en) | 2012-03-07 | 2012-03-07 | Digital image film and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102632738B (en) |
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| CN102922893B (en) * | 2012-10-30 | 2015-02-18 | 江苏格美高科技发展有限公司 | Medical laser color printing and imaging PET (Polyester) film and preparation method thereof |
| CN103897517A (en) * | 2012-12-27 | 2014-07-02 | 青岛佳艺影像新材料技术有限公司 | Preparation method of front-spraying backlit inkjet film coating liquid |
| CN104972777A (en) * | 2014-04-10 | 2015-10-14 | 黄震山 | Medical color film with PPES as base material and production method thereof |
| CN110183705B (en) * | 2019-05-31 | 2021-11-05 | 南阳九鼎材料科技股份有限公司 | PET substrate priming technology |
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| JP2000158800A (en) * | 1998-11-25 | 2000-06-13 | Sekisui Chem Co Ltd | Recording material for aqueous ink |
| JP2001347754A (en) * | 2000-04-05 | 2001-12-18 | Kuraray Co Ltd | Writing material |
| EP1345780A1 (en) * | 2000-12-28 | 2003-09-24 | Fuji Photo Film B.V. | Ink jet recording medium |
| CN1579803A (en) * | 2003-08-09 | 2005-02-16 | 三星电子株式会社 | Ink receiving layer composition of recording medium of ink-jet printer and the recording medium using same |
| CN1729105A (en) * | 2002-11-22 | 2006-02-01 | 王子制纸株式会社 | Ink jet recording material |
| CN102133826A (en) * | 2010-12-29 | 2011-07-27 | 天津美迪亚影像材料有限公司 | Silver card for inkjet printing |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000158800A (en) * | 1998-11-25 | 2000-06-13 | Sekisui Chem Co Ltd | Recording material for aqueous ink |
| JP2001347754A (en) * | 2000-04-05 | 2001-12-18 | Kuraray Co Ltd | Writing material |
| EP1345780A1 (en) * | 2000-12-28 | 2003-09-24 | Fuji Photo Film B.V. | Ink jet recording medium |
| CN1729105A (en) * | 2002-11-22 | 2006-02-01 | 王子制纸株式会社 | Ink jet recording material |
| CN1579803A (en) * | 2003-08-09 | 2005-02-16 | 三星电子株式会社 | Ink receiving layer composition of recording medium of ink-jet printer and the recording medium using same |
| CN102133826A (en) * | 2010-12-29 | 2011-07-27 | 天津美迪亚影像材料有限公司 | Silver card for inkjet printing |
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| CN102632738A (en) | 2012-08-15 |
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Address after: 611230, Tongxin village, Chongyang Town, Chongzhou City, Sichuan, Chengdu six Patentee after: Chengdu Double Star New Material Co.,Ltd. Address before: 611230, Tongxin village, Chongyang Town, Chongzhou City, Sichuan, Chengdu six Patentee before: Chongzhou Shuangxing Special Paper Factory |
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