CN107691468A - A kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof - Google Patents

A kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof Download PDF

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Publication number
CN107691468A
CN107691468A CN201711265543.6A CN201711265543A CN107691468A CN 107691468 A CN107691468 A CN 107691468A CN 201711265543 A CN201711265543 A CN 201711265543A CN 107691468 A CN107691468 A CN 107691468A
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CN
China
Prior art keywords
tebufenpyrad
etoxazole
mite
compositional acaricide
emulsifying agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711265543.6A
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Chinese (zh)
Inventor
李贤才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agricultural Chemical Co Ltd Xuzhou Feng
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Agricultural Chemical Co Ltd Xuzhou Feng
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Publication date
Application filed by Agricultural Chemical Co Ltd Xuzhou Feng filed Critical Agricultural Chemical Co Ltd Xuzhou Feng
Priority to CN201711265543.6A priority Critical patent/CN107691468A/en
Publication of CN107691468A publication Critical patent/CN107691468A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/761,3-Oxazoles; Hydrogenated 1,3-oxazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of insecticide, in particular to a kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof, it is made up of following weight percents composition:Tebufenpyrad 10% ~ 20%, etoxazole 10 ~ 20%, Butacide 1% ~ 10%, emulsifying agent 3% ~ 6%, surfactant 1% ~ 4%, dimethylbenzene 15% ~ 30%, surplus are water.The Stability Analysis of Structures of the present invention, compared with single dose, prevention effect is significantly improved, and a medicine is controlled more, and a dispenser can prevent and treat young mite, deutonymph simultaneously, into each state evil mite such as mite, reduce preventing and treating recruitment cost.In addition, being provided simultaneously with quick-acting and long-acting two major features, production and use cost substantially reduce, environment friendly and pollution-free.

Description

A kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof
Technical field
The present invention relates to agricultural chemicals, more particularly to a kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof.
Background technology
Tebufenpyrad, belong to amide-type acaricide, to evil mite based on action of contace poison, there is permeability, but nothing to plant tissue Absorbability.Effective to mite class each breeding time, available for fruit tree, tea tree, cotton, vegetables preventing and treating, the lasting period was up to more than 40 days. Etoxazole, the main embry ogenesis for suppressing mite ovum and from young mite to the molting process into mite is effective to ovum and young mite, into mite It is invalid, but there is infertility effect well into mite to female, rain fastness is strong, and the lasting period is up to 50 days.Tebufenpyrad is used alone Or etoxazole except mite, though duration length, less efficient, and environment can be caused necessarily to influence.
The content of the invention
For above-mentioned deficiency of the prior art, the invention provides a kind of tebufenpyrad etoxazole Compositional acaricide and its Preparation method, its Stability Analysis of Structures, environment-friendly high-efficiency and efficacy time are grown.
In order to reach foregoing invention purpose, the technical solution adopted by the present invention is:
A kind of tebufenpyrad etoxazole Compositional acaricide, is made up of following weight percents composition:Tebufenpyrad 10% ~ 20%, second mite Azoles 10 ~ 20%, Butacide 1% ~ 10%, emulsifying agent 3% ~ 6%, surfactant 1% ~ 4%, dimethylbenzene 15% ~ 30%, surplus are water.
Further, the emulsifying agent uses gamma cyhalothrin, calcium dodecyl benzene sulfonate or gamma cyhalothrin With the mixed liquor of both calcium dodecyl benzene sulfonates.
Further, the surfactant is phenethyl phenol polyethenoxy ether or Ben-zylphenol Polyoxyethyl Ether.
A kind of preparation method of tebufenpyrad etoxazole Compositional acaricide, comprises the following steps:
(1)Weighed according to above-mentioned weight proportion;
(2)Tebufenpyrad, etoxazole, Butacide, emulsifying agent, surfactant, dimethylbenzene are added agitator tank and stirred;
(3)Water is added to stir into agitator tank to being mixed thoroughly.
Beneficial effects of the present invention are:Stability Analysis of Structures, compared with single dose, prevention effect is significantly improved, and a medicine is controlled more, and one Secondary dispenser can prevent and treat young mite, deutonymph simultaneously, into each state evil mite such as mite, reduce preventing and treating recruitment cost.In addition, be provided simultaneously with it is quick-acting and Long-acting two major features, production and use cost substantially reduce, environment friendly and pollution-free.
Embodiment
In order that present disclosure is easier to be clearly understood, below by the technical scheme in the embodiment of the present invention It is clearly and completely described.
Tebufenpyrad:Belong to amide-type acaricide, to evil mite based on action of contace poison, there is permeability, but nothing to plant tissue Absorbability.Effective to mite class each breeding time, available for fruit tree, tea tree, cotton, vegetables preventing and treating, the lasting period was up to more than 40 days.
Etoxazole:Mainly suppress the embry ogenesis of mite ovum and from young mite to the molting process into mite, have to ovum and young mite Effect, to invalid into mite, but there is infertility effect well into mite to female, rain fastness is strong, and the lasting period is up to 50 days.Synergy Ether:Transparent oily liquid, it is not soluble in water, dissolve in organic solvent.Broad spectrum activity synergist, the desinsection of a variety of insecticides can be improved Activity.
Emulsifying agent:Using gamma cyhalothrin, calcium dodecyl benzene sulfonate or gamma cyhalothrin and dodecyl The mixed liquor of both benzene sulfonic acid calcium.
Gamma cyhalothrin:Insecticidal spectrum is wide, and activity is higher, and drug effect is rapid, resistance of rainwater washing against after sprinkling, but long-term use of Resistance easily is produced to it, the insect and evil mite to sucking mouth parts have certain preventive effect, but to the dosage of mite than conventional use Amount increase by 1 ~ 2 times, suitable for peanut, soybean, cotton, fruit tree, vegetables insect.
Calcium dodecyl benzene sulfonate:Also referred to as farm chemical emulgent 500#, it is mainly used in preparing blended pesticide emulsifier Purposes, for farm chemical emulgent, it may also be used for textile finish oil, ceramic tile detergent, grinding finish, cement dispersants etc..
Dimethylbenzene:Colourless transparent liquid, can be with absolute ethyl alcohol, ether and other many immiscible organic solvents.
A kind of tebufenpyrad etoxazole Compositional acaricide, is made up of following weight percents composition:Tebufenpyrad 10% ~ 20%, Etoxazole 10 ~ 20%, Butacide 1% ~ 10%, emulsifying agent 3% ~ 6%, surfactant 1% ~ 4%, dimethylbenzene 15% ~ 30%, surplus are water.
Further, the emulsifying agent uses gamma cyhalothrin, calcium dodecyl benzene sulfonate or gamma cyhalothrin With the mixed liquor of both calcium dodecyl benzene sulfonates.
Further, the surfactant is phenethyl phenol polyethenoxy ether or Ben-zylphenol Polyoxyethyl Ether.
Embodiment one:
A kind of tebufenpyrad etoxazole Compositional acaricide, is made up of following weight percents composition:Tebufenpyrad 15%, etoxazole 15%, Butacide 5%, calcium dodecyl benzene sulfonate 4%, phenethyl phenol polyethenoxy ether 2%, dimethylbenzene 25%, surplus is water.
A kind of preparation method of tebufenpyrad etoxazole Compositional acaricide, comprises the following steps:
(1)Weighed according to above-mentioned weight proportion;
(2)Tebufenpyrad, etoxazole, Butacide, calcium dodecyl benzene sulfonate, phenethyl phenol polyethenoxy ether, dimethylbenzene are added Agitator tank stirs;
(3)Water is added to stir into agitator tank to being mixed thoroughly.
Embodiment two:
A kind of tebufenpyrad etoxazole Compositional acaricide, is made up of following weight percents composition:Tebufenpyrad 20%, etoxazole 10%, Butacide 8%, gamma cyhalothrin 5%, phenethyl phenol polyethenoxy ether 2%, dimethylbenzene 25%, surplus is water.
A kind of preparation method of tebufenpyrad etoxazole Compositional acaricide, comprises the following steps:
(1)Weighed according to above-mentioned weight proportion;
(2)Tebufenpyrad, etoxazole, Butacide, gamma cyhalothrin, phenethyl phenol polyethenoxy ether, dimethylbenzene are added and stirred Tank is mixed to stir;
(3)Water is added to stir into agitator tank to being mixed thoroughly.
Beneficial effects of the present invention are:Stability Analysis of Structures, compared with single dose, prevention effect is significantly improved, and a medicine is controlled more, and one Secondary dispenser can prevent and treat young mite, deutonymph simultaneously, into each state evil mite such as mite, reduce preventing and treating recruitment cost.In addition, be provided simultaneously with it is quick-acting and Long-acting two major features, production and use cost substantially reduce, environment friendly and pollution-free.
The preferred embodiment of patent of the present invention is the foregoing is only, is not intended to limit the invention patent, it is all at this All any modification, equivalent and improvement made within the spirit and principle of patent of invention etc., should be included in patent of the present invention Protection domain within.

Claims (4)

1. a kind of tebufenpyrad etoxazole Compositional acaricide, it is characterised in that be made up of following weight percents composition:Tebufenpyrad 10% ~ 20%, etoxazole 10 ~ 20%, Butacide 1% ~ 10%, emulsifying agent 3% ~ 6%, surfactant 1% ~ 4%, dimethylbenzene 15% ~ 30%, Surplus is water.
A kind of 2. tebufenpyrad etoxazole Compositional acaricide according to claim 1, it is characterised in that:The emulsifying agent is adopted With the mixing of gamma cyhalothrin, calcium dodecyl benzene sulfonate or gamma cyhalothrin and both calcium dodecyl benzene sulfonates Liquid.
A kind of 3. tebufenpyrad etoxazole Compositional acaricide according to claim 1, it is characterised in that:The surface-active Agent is phenethyl phenol polyethenoxy ether or Ben-zylphenol Polyoxyethyl Ether.
A kind of 4. preparation method of tebufenpyrad etoxazole Compositional acaricide according to claim 1, it is characterised in that:Bag Include following steps:
(1)Weighed according to above-mentioned weight proportion;
(2)Tebufenpyrad, etoxazole, Butacide, emulsifying agent, surfactant, dimethylbenzene are added agitator tank and stirred;
(3)Water is added to stir into agitator tank to being mixed thoroughly.
CN201711265543.6A 2017-12-05 2017-12-05 A kind of tebufenpyrad etoxazole Compositional acaricide and preparation method thereof Pending CN107691468A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108323526A (en) * 2018-04-28 2018-07-27 中国农业科学院兰州兽医研究所 A kind of special tickicide composition of gamma cyhalothrin and etoxazole compounding

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102308809A (en) * 2011-04-26 2012-01-11 陕西韦尔奇作物保护有限公司 Pesticide composition containing etoxazole

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102308809A (en) * 2011-04-26 2012-01-11 陕西韦尔奇作物保护有限公司 Pesticide composition containing etoxazole

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
刘正坪: "《蔬菜病虫害防治技术问答》", 30 June 2007, 中国农业大学出版社 *
刘步林: "《农药剂型加工技术》", 31 October 1998, 化学工业出版社 *
张保民等: "《农药剂型及助剂应用》", 31 December 1995, 中原农民出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108323526A (en) * 2018-04-28 2018-07-27 中国农业科学院兰州兽医研究所 A kind of special tickicide composition of gamma cyhalothrin and etoxazole compounding

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Application publication date: 20180216

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