CN107691467A - A kind of emamectin benzoate and efficient cypermethrin compounded agricultural chemical composition for disinsection and its preparation - Google Patents
A kind of emamectin benzoate and efficient cypermethrin compounded agricultural chemical composition for disinsection and its preparation Download PDFInfo
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- CN107691467A CN107691467A CN201710952538.6A CN201710952538A CN107691467A CN 107691467 A CN107691467 A CN 107691467A CN 201710952538 A CN201710952538 A CN 201710952538A CN 107691467 A CN107691467 A CN 107691467A
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- emamectin benzoate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention discloses a kind of emamectin benzoate and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is prepared by raw materials such as emamectin benzoate, effective cypermethrin, pleocidin, α terpinols, matrine, nicotine, rotenone, fennel artemisin and stemonines, the composition of the present invention can also be configured to the preparations such as missible oil, microemulsion, aqueous emulsion, suspending agent, wettable powder, water dispersible granules, micro-capsule suspension, suspension emulsion, oil suspending agent, granule and pulvis with acceptable carrier combination in Pesticide Science, and it is convenient to use and preserve；The farm chemical ingredients of different mechanism of action are compounded, serve the complementary, effect of synergy；And low toxicity is efficient, the lasting period is long, residual is few, organic environmental-protection, is not likely to produce the resistance to the action of a drug, reduces Pesticide use amount, reduce use cost and planting cost, mitigate the pollution to environment, be that worm composition pesticide is controlled in a kind of environment-friendly insect prevention, have broad application prospects.
Description
Technical field
The present invention relates to the agricultural chemicals in agriculture field, a kind of emamectin benzoate and efficient cypermethrin compounded is more particularly related to
Agricultural chemical composition for disinsection and its preparation.
Background technology
Emamectin benzoate (full name is emamectin-benzoate) is a kind of microbial source low toxicity Insecticidal and acaricidal agent, is
The high-performance bio medicament synthesized on the basis of AVM, it is active it is high, insecticidal spectrum is wide, compatibility is good, the lasting period is long,
The features such as safe to use, the mode of action have action of contace poison concurrently based on stomach toxicity.Its insecticidal mechanism is to hinder pest movements nerve,
Larva and other many insects and mite class to lepidopterous insects it is active high, and to beneficial insect during pest control
Do not injure, be advantageous to the integrated control to insect, expand insecticidal spectrum in addition, reduce the toxicity to people and animals.
Effective cypermethrin is a kind of pyrethroid insecticides, and bioactivity is higher, is the efficient different of cypermethrin
Structure body, have and tag and stomach poison function.Insecticidal spectrum is wide, knocks down that speed is fast, and insecticidal activity is compared with cypermethrin height.Suitable for preventing and treating cotton
Insect and sanitary insect pest in the various plants such as flower, vegetables, fruit tree, tea tree, forest.
A kind of long-term use of insecticide, insect easily develop immunity to drugs, and make the increase of insecticide dosage, a large amount of killing insects
Natural enemy, increase desinsection cost, pollute environment, cause that high poison, dosage are big, residual is more, drug effect is poor.By the agricultural chemicals of different mechanism of action
Composition is compounded, and is to prevent and treat the very common method of resistant insect.The good formula of compound synergic, can improve actual prevention effect,
According to pest resistance to insecticide governance theory, the different composition of mechanism of action is compounded in appropriate proportion, insect can be delayed to resist
The generation and development of the property of medicine, extend the service life of agricultural chemicals, be the important means of integrated control crop pest.
From current resistance monitoring result show many regional beet armyworms in being produced to emamectin benzoate to high-caliber resistance,
Some other must be selected not have the medicament of cross resistance to carry out rationally wheel to use or mixed, with the decline of sharp field resistance, simultaneously
Strengthen the resistance monitoring to emamectin benzoate, pay attention to assessing the effect of its resistance management, so as to reach to the efficient of this medicament and protect
Shield property utilizes, and gives full play to its efficient control action.
Therefore, for prior art the defects of, the present invention propose a kind of emamectin benzoate and efficient cypermethrin compounded desinsection
Composition pesticide and its preparation, it is intended that solve the shortcomings that prior art is present.
The content of the invention
The defects of it is an object of the invention to overcome prior art to exist, there is provided a kind of emamectin benzoate and effective cypermethrin are answered
The agricultural chemical composition for disinsection and its preparation matched somebody with somebody, it can effectively prevent the lepidoptera pest, coleopteran pest and Diptera of all kinds of crops
The insect pests such as insect, reasonable mixture ratio of components, prevention effect is good, and drug cost is low, is not likely to produce the resistance to the action of a drug.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of emamectin benzoate and efficient cypermethrin compounded agricultural chemical composition for disinsection, including component A and component B, its feature
It is：
Described component A includes emamectin benzoate, effective cypermethrin, pleocidin and alpha-terpineol；
Described component B includes matrine, nicotine, rotenone, fennel artemisin, stemonine and nimbin；
The mass ratio of the component A and component B are 4-23：1.
Preferably, the mass ratio of the component A and component B are 12-16：1.
Preferably, in described component A, emamectin benzoate, effective cypermethrin, the mass ratio of pleocidin and alpha-terpineol are
2-6：1-3：0.5-3：0.5-2.
Preferably, in described component B, matrine, nicotine, rotenone, the mass ratio of fennel artemisin and stemonine are 1-3：
1-3：1-3：2-5：2-5.
Preferably, the formulation of the agricultural chemical composition for disinsection is solid pharmaceutical preparation, or is microemulsion.
Preferably, the preparation method of the solid pharmaceutical preparation comprises the following steps：
Described component A and component B are added in filling carrier, add surfactant and/or disintegrant, is mixed
Pulvis uniformly is made；Or on the basis of pulvis, add appropriate wetting agent and be further prepared into granule.
Preferably, the preparation method of the microemulsion comprises the following steps：
Described component A and component B are added in reactor, add solvent, dissolution of raw material is added breast afterwards completely
Agent is remixed uniformly, adds water, antifreezing agent and stabilizer while stirring, and 15- is stirred under 2000-4000rpm rotating speed
30min, produce.
Preferably, described filling carrier is kaolin, diatomite, bentonite, white carbon, clay, talcum powder, quartz
It is more than one or both of sand, starch；
Described surfactant is neopelex, lauryl sodium sulfate, sodium butylnaphthalenesulfonate, lignin
Sodium sulfonate, sodium methylene bis-naphthalene sulfonate, sodium laureth sulfate, polyoxyethylene fatty alkyl ether sulfonate, dodecyl sulphate calcium,
One or both of calcium dodecyl benzene sulfonate, calcium lignosulfonate, polyethers ichthyodin, phenethyl phenol polyethenoxy ether with
On；
Described wetting agent is sodium sulphate, sldium lauryl sulfate, lignosulfonates, APES phosphoric acid
Salt, petroleum sodium sulfonate, alkylnaphthalene sulfonate, fatty acid ester sulfate, APES, AEO,
It is more than one or both of spaonin powder, tea seed cake powder, silkworm excrement；
Described disintegrant is one in sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite
Kind is two or more.
Preferably, described solvent be water, DMF, methanol, ethanol, ethylene glycol, propane diols, acetone,
One kind in cyclohexanone, pyrrolidones, toluene, dimethylbenzene, ethyl acetate, dimethylformamide, vegetable oil, petroleum ether, acetonitrile
It is or two or more；
Described emulsifying agent is tri ethanol ammonium salt, APES formaldehyde condensation product, alkylbenzene naphthalene sulfonate, alkane
Base phenol polyethenoxy ether phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, diphenyl phenol gather
Oxygen ethene polyoxy formaldehyde condensation products, agriculture breast 300#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, one kind in TWEEN Series or two
More than kind；
Described antifreezing agent is polyethylene glycol, glycerine or sorbierite；
Described stabilizer is BHT, triethanolamine, tributyl phosphate, xylitol, mannitol, pentaerythrite, sodium citrate
One or both of more than.
Preferably, the present composition can also be prepared into missible oil, aqueous emulsion with acceptable carrier combination in Pesticide Science, hang
The preparations such as floating agent, wettable powder, water dispersible granules, micro-capsule suspension, suspension emulsion, oil suspending agent；In the preparation effectively into
The cumulant divided is the 0.5-75% of total formulation weight.
Emamectin benzoate of the present invention and efficient cypermethrin compounded agricultural chemical composition for disinsection and its preparation are in preventing and treating Lepidoptera, sheath
Application on wing mesh and Diptera pest.
Acceptable carrier includes but is not limited to following in the Pesticide Science of the present invention：
Emulsifying agent：Tri ethanol ammonium salt, APES formaldehyde condensation product, alkylbenzene naphthalene sulfonate, alkyl phenol gather
Oxygen ethene ether phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, diphenyl phenol polyethenoxy
Polyoxy formaldehyde condensation products, agriculture breast 300#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, TWEEN Series etc..
Solvent：Water, DMF, methanol, ethanol, ethylene glycol, propane diols, acetone, cyclohexanone, pyrrolidines
Ketone, toluene, dimethylbenzene, ethyl acetate, dimethylformamide, vegetable oil, petroleum ether, acetonitrile etc..
Synergist：Organosilicon, thiophene ketone, azone, double to kill.
Antifreezing agent：Polyethylene glycol, glycerine, sorbierite etc..
Stabilizer：BHT, triethanolamine, tributyl phosphate, xylitol, mannitol, pentaerythrite, sodium citrate etc..
Defoamer：Polypropylene glycerol aether, polyether-modified silicon, silicone emulsion etc.
Thickener：Polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, guar gum, aluminium-magnesium silicate, phenolic resin, hydroxyl first
Base cellulose, sodium alginate, gypsum etc..
PH value regulator：Ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc..
Dispersant：Methylcellulose, polycarboxylate, sodium methylene bis-naphthalene sulfonate, sodium lignin sulfonate, fatty acid amide N- first
Base taurine sodium salt, APES sulfate, lignosulfite, fatty acid ester sulfate, alkyl naphthalene sulfonic acid
Salt, APES, AEO etc..
Wetting agent：Sodium sulphate, sldium lauryl sulfate, lignosulfonates, APES phosphate, oil sulphur
Sour sodium, alkylnaphthalene sulfonate, fatty acid ester sulfate, APES, AEO, spaonin powder, tea
Withered powder, silkworm excrement etc..
Disintegrant：Sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc..
Filling carrier：Kaolin, diatomite, bentonite, white carbon, clay, talcum powder, quartz sand, starch etc..
Capsule-core solvent：Dimethyl methyl phthalein amine, ethanol, isopropanol, n-butanol, n-octyl alcohol, n-amyl alcohol, acetone, cyclohexanone, two
Toluene, ethyl acetate, 1-METHYLPYRROLIDONE, diethyl phthalate, acetonitrile, dichloromethane, dibutyl phthalate
Deng.
Cyst material：Polyureas, Lauxite, polyamide, PIC, Arabic gum, gelatin, alginate etc..
Cosolvent：Water, ethanol, glycerine, propane diols, liquid paraffin, vegetable oil etc..
Grease auxiliary agent：Jatropha curcas oil, soybean oil, corn oil, Jatropha curcas oil methyl esters, Jatropha curcas oil ethyl ester, methyl oleate, oil
Acetoacetic ester, coconut oil methyl ester, coconut oil ethyl ester, soybean oil methyl esters, rosin mixed ester etc..
Surfactant：Neopelex, lauryl sodium sulfate, sodium butylnaphthalenesulfonate, sodium lignin sulfonate,
Sodium methylene bis-naphthalene sulfonate, sodium laureth sulfate, polyoxyethylene fatty alkyl ether sulfonate, dodecyl sulphate calcium, dodecane
Base benzene sulfonic acid calcium, calcium lignosulfonate, polyethers ichthyodin, phenethyl phenol polyethenoxy ether etc..
Method 1：Missible oil
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into insecticidal emulsifiable concentrate of the present invention.
Above-mentioned missible oil often includes one of emulsifying agent, solvent, synergist or whole with auxiliary material.
Method 2：Aqueous emulsion
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into disinsection aqueous emulsion of the present invention.
Above-mentioned aqueous emulsion often includes one of emulsifying agent, solvent, stabilizer, antifreezing agent, defoamer, thickener or complete with auxiliary material
Portion.
Method 3：Suspending agent
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into insecticidal suspending agent of the present invention.
Above-mentioned suspending agent often includes one of dispersant, antifreezing agent, thickener, defoamer, pH adjusting agent or whole with auxiliary material.
Method 4：Wettable powder
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into desinsection wettable of the present invention
Pulvis.
Above-mentioned wettable powder often includes one of dispersant, wetting agent, filling carrier or whole with auxiliary material.
Method 5：Water dispersible granules
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into insecticide of the present invention and disperseed
Granula.
Above-mentioned water dispersible granules often include one of dispersant, wetting agent, disintegrant, filling carrier or whole with auxiliary material.
Method 6：Micro-capsule suspension
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into desinsection microcapsules of the present invention
Suspending agent.
Above-mentioned micro-capsule suspension often includes capsule-core solvent, cyst material, dispersant, antifreezing agent, pH adjusting agent with auxiliary material
One of or all.
Method 7：Suspension emulsion
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into insecticidal suspending agent of the present invention.
Above-mentioned suspending agent often includes one of emulsifying agent, cosolvent, thickener, antifreezing agent, water or whole with auxiliary material.
Method 8：Oil suspending agent
Raw material are weighed in mass ratio, add conventional auxiliary material, and routinely production method is prepared into desinsection oil suspending agent of the present invention.
Above-mentioned oil suspending agent often includes one of dispersant, wetting agent, thickener, defoamer, antifreezing agent, grease auxiliary agent with auxiliary material
Or all.
The present invention is by adopting the above-described technical solution, have the advantages that：
1st, the present inventor is on the basis of substantial amounts of indoor virulence and field control effectiveness test, to emamectin benzoate and efficient chlorine cyanogen chrysanthemum
The compounded formula screening of ester has made intensive studies, and emamectin benzoate activity is high, insecticidal spectrum is wide, compatibility is good, the lasting period is long, uses
Safety, active high, the stopping feed at once after larva contact of larva and other many insects and mite class to lepidopterous insects
The irreversible paralysis of generation, reach within 3-4 days highest death, be advantageous to the integrated control to insect；Effective cypermethrin has
Tag and stomach poison function, insecticidal spectrum is wide, knocks down that speed is fast, also the insect in cave can be driven to climb out of and contact insecticide, strengthened
Insecticidal effect；Using emamectin benzoate and efficient cypermethrin compounded, while activity is knocked down with long lasting period adult, to insect
Larva lethality is strong, can significantly reduce the quantity of insect, the prevention effect improved to insect pest is used alone than single dose, from root
Reach prevention in sheet and administer the effect of insect pest；Secondly, emamectin benzoate and efficient cypermethrin compounded there is good Synergistic
Effect, each component in mixture can be made to reduce Pesticide use concentration in the case where activity is not lost, made so as to reduce agricultural chemicals
Dosage, use cost is reduced, and alleviate the pollution to environment；
2nd, alpha-terpineol has good permeability, spreadability and resistance of rainwater washing against ability, can improve medicament flushing liquor
Physical behavior, surface tension and contact angle are reduced, so as to reduce float of mist droplet, the active ingredient in agricultural chemicals is penetrated into target rapidly
Body gap and opened in extended surface, greatly enhance the area coverage sprayed insecticide and penetration, improve agricultural chemicals on Target crops
Deposition, increase the efficiency of medicament, improve prevention effect and utilization rate；
3rd, the present invention additionally uses botanical pesticide matrine, nicotine, rotenone, fennel artemisin, stemonine and nimbin etc.
Emamectin benzoate and effective cypermethrin are compounded, compared with full chemistry agricultural chemicals, have low toxicity efficiently, lasting period length, organic environmental-protection,
The features such as being not likely to produce the resistance to the action of a drug, be advantageous to No-harmful apple orchard, can have well as the favourable agents of field control insect pest
Application value；
4th, compound insecticidal composition pesticide of the invention is 82.1% to 1 day preventive effect after the medicine of diamondback moth, 3 days preventive effects after medicine
For 88.2%, 7 days preventive effects are 94.5% after medicine, preventing and treating field brassicaceous vegetable diamondback moth quick-acting is strong, prevention effect is good,
Lasting period is longer, is advantageous to improve the quality of vegetables；For eucalyptus looper, beet armyworm, rice leaf roller, the small food heart of peach
Worm, predacious diving beetle, rice weevil, cutworm, corn borer etc. have carried out Toxicity Determination and field control effectiveness test, for preventing and treating Lepidoptera,
The insect pest of coleoptera and Diptera has excellent effect, has an obvious synergistic function, and prevention effect is good；
5th, compound insecticidal composition pesticide of the invention can be made into missible oil, microemulsion, aqueous emulsion, suspending agent, wettable powder
All kinds of preparations such as agent, water dispersible granules, micro-capsule suspension, suspension emulsion, oil suspending agent, granule and pulvis, it is easy to use, it can expire
Sufficient varying environment uses and preserved demand, and applicable elements are wide；
As can be seen here, compound insecticidal composition pesticide of the invention is compounded the farm chemical ingredients of different mechanism of action,
Each growth phase of the insect of Lepidoptera, coleoptera and Diptera is all effectively prevented and treated, serves the complementary, effect of synergy；
And low toxicity efficiently, the lasting period is long, residual is few, organic environmental-protection, is not likely to produce the resistance to the action of a drug, reduces Pesticide use amount, reduce use into
Sheet and planting cost, mitigate the pollution to environment, are that worm composition pesticide is controlled in a kind of environment-friendly insect prevention, have wide answer
Use prospect.
Embodiment
For the objects, technical solutions and advantages of the present invention are more clearly understood, preferred embodiment is enumerated below, to this hair
Bright further description.However, it is necessary to illustrate, many details listed in specification are used for the purpose of making reader to this
The one or more aspects of invention have a thorough explanation, can also realize the present invention's even without these specific details
These aspects.
The microemulsion of embodiment 1
Weigh active ingredient emamectin benzoate 0.2kg, effective cypermethrin 0.1kg, pleocidin 0.05kg, alpha-terpineol
0.05kg, matrine 0.01kg, nicotine 0.02kg, rotenone 0.03kg, fennel artemisin 0.02kg, stemonine 0.02kg；Weigh again
Methanol 3kg, alkylbenzene sodium naphthalene sulfonate 1kg, polyethylene glycol 0.01kg, triethanolamine 0.02kg, purified water complement to 100kg；
Active ingredient and methanol are added in reactor, alkylbenzene sodium naphthalene sulfonate is added after making active ingredient dissolving completely
Agent remixes uniformly, adds purified water, polyethylene glycol and triethanolamine while stirring, is stirred under 2000rpm rotating speed
30min, produce.
The pulvis of embodiment 2
Weigh active ingredient emamectin benzoate 1.8kg, effective cypermethrin 0.6kg, pleocidin 0.6kg, alpha-terpineol
0.6kg, matrine 0.15kg, nicotine 0.05kg, rotenone 0.05kg, fennel artemisin 0.15kg, stemonine 0.1kg；Carbon is weighed again
Sour hydrogen sodium 0.04kg, neopelex 0.8kg, talcum powder complement to 100kg；
By active ingredient and talcum powder through air-flow crushing and after stirring, neopelex and bicarbonate are added
Sodium, granulation, dry, produce.
The granule of embodiment 3
Weigh active ingredient emamectin benzoate 2.4kg, effective cypermethrin 1.5kg, pleocidin 0.9kg, alpha-terpineol
1.2kg, matrine 0.1kg, nicotine 0.1kg, rotenone 0.1kg, fennel artemisin 0.5kg, stemonine 0.2kg；Aluminium chloride is weighed again
0.1kg, calcium dodecyl benzene sulfonate 1.5kg, sldium lauryl sulfate 0.8kg, bentonite complement to 100kg；
By active ingredient and bentonite through air-flow crushing and after stirring, calcium dodecyl benzene sulfonate, aluminium chloride are added
And sldium lauryl sulfate, granulation, dry, produce.
The missible oil of embodiment 4
Weigh active ingredient emamectin benzoate 18kg, effective cypermethrin 6kg, pleocidin 6kg, alpha-terpineol 6kg, matrine
0.3kg, nicotine 0.9kg, rotenone 0.3kg, fennel artemisin 0.6kg, stemonine 0.9kg；Agriculture breast 500#5kg, organosilicon are weighed again
0.5kg, ethylene glycol complement to 100kg；
By agriculture breast 500#, organosilicon and ethylene glycol are added in reactor, sequentially add active ingredient, set reactor
Rotating speed is 3000rpm, and 20min is to homogeneous liquid for stirring, produces.
The aqueous emulsion of embodiment 5
Weigh active ingredient emamectin benzoate 16kg, effective cypermethrin 4kg, pleocidin 8kg, alpha-terpineol 4kg, matrine
0.2kg, nicotine 0.2kg, rotenone 0.2kg, fennel artemisin 0.4kg, stemonine 1kg；Diphenyl phenol polyethenoxy polyoxy is weighed again
Propylene ether 3kg, acetone 20kg, BHT0.1kg, polyethylene glycol 0.1kg, polypropylene glycerol aether 0.5kg, polyvinyl alcohol 2kg, mend
Sufficient purified water is to 100kg；
By active ingredient and acetone, diphenyl phenol polyethenoxy polyethenoxy ether adds cutting kettle, after stirring 20min, obtains
Obtain oil phase；
By BHT, polyethylene glycol, stirred after polyvinyl alcohol and purified water mixing, obtain aqueous phase；
The rotating speed for setting homogenizer is 4500rpm, makes in the case of homogenizer high shear, oil phase is slowly added into aqueous phase
In, polypropylene glycerol aether is added after addition, above-mentioned rotating speed high shear 20min is continued to, produces.
The suspending agent of embodiment 6
Weigh active ingredient emamectin benzoate 8kg, effective cypermethrin 3kg, pleocidin 3kg, alpha-terpineol 4kg, matrine
0.4kg, nicotine 0.3kg, rotenone 0.6kg, fennel artemisin 0.6kg, stemonine 1.1kg；APES is weighed again
0.8kg, sorbierite 0.1kg, hydroxymethyl cellulose 4kg, polyether-modified silicon 0.2kg, purified water complement to 100kg；
By APES, sorbierite, it is uniform to be put into shear-mixed in cutter after hydroxymethyl cellulose mixing,
Then active ingredient and purified water are added, 3h is ground in ball crusher, polyether-modified silicon is then added, produces.
The wettable powder of embodiment 7
Weigh emamectin benzoate 29kg, effective cypermethrin 17kg, pleocidin 11kg, alpha-terpineol 12kg, matrine
0.5kg, nicotine 0.4kg, rotenone 0.4kg, fennel artemisin 0.8kg, stemonine 0.9kg, sodium methylene bis-naphthalene sulfonate 3.5kg, fat
Fat alcohol APEO 5kg, diatomite complement to 100kg；
Crushed after above-mentioned raw materials are well mixed through fluid bed airflow milling equipment, be well mixed, produce.
The water dispersible granules of embodiment 8
Weigh emamectin benzoate 15kg, effective cypermethrin 3kg, pleocidin 1.5kg, alpha-terpineol 4.5kg, matrine
0.4kg, nicotine 0.3kg, rotenone 0.6kg, fennel artemisin 0.7kg, stemonine 1kg, methylcellulose 4kg, fatty acid ester sulfuric acid
Sodium 3kg, sodium chloride 0.5kg, clay complement to 100kg；
Crushed after above-mentioned raw materials are mixed with micro jet, add in fluidized-bed granulation dryer after kneading
Row is granulated, dried, after screening, produces.
The micro-capsule suspension of embodiment 9
Weigh active ingredient emamectin benzoate 24kg, effective cypermethrin 4kg, pleocidin 5kg, alpha-terpineol 3kg, matrine
0.6kg, nicotine 0.7kg, rotenone 0.5kg, fennel artemisin 1.4kg, stemonine 0.8kg；Cyclohexanone 30kg, polyamide are weighed again
10kg, alkyl phenol polyethenoxy ether sodium sulfate 5kg, sorbierite 1kg, purified water complement to 135kg.
Active ingredient and polyamide are dissolved in cyclohexanone, purified water is added after high-speed stirred, organic phase is scattered in water
Xiang Zhong, after precipitation, making the automatic film forming in active ingredient surface, form microcapsules so that microcapsules are scattered to be suspended in aqueous phase,
Alkyl phenol polyethenoxy ether sodium sulfate and sorbierite are added, is produced.
The suspension emulsion of embodiment 10
Weigh active ingredient emamectin benzoate 20kg, effective cypermethrin 14kg, pleocidin 6kg, alpha-terpineol 10kg, kuh-seng
Alkali 0.6kg, nicotine 0.8kg, rotenone 0.7kg, fennel artemisin 1.6kg, stemonine 1.3kg；Triethanol ammonium sodium 3kg is weighed again, is planted
Thing oil 5kg, xanthans 2kg, glycerine 0.5kg, purified water complement to 100kg.
Stirred after active ingredient is mixed with vegetable oil, dissolve active ingredient, obtain oil phase；
Add triethanolamine sodium, xanthans and glycerine while stirring in purified water, stir and obtain aqueous phase；By water
Mutually it is directly added into oil phase, stirs 30min, produce.
The oil suspending agent of embodiment 11
Weigh active ingredient emamectin benzoate 13kg, effective cypermethrin 10kg, pleocidin 4kg, alpha-terpineol 6kg, kuh-seng
Alkali 0.5kg, nicotine 0.5kg, rotenone 0.4kg, fennel artemisin 0.7kg, stemonine 0.9kg；Methylcellulose 5kg, alkane are weighed again
Base phenol polyethenoxy ether 2kg, hydroxymethyl cellulose 3kg, glycerine 0.5kg, silicone emulsion 1kg, soybean oil complement to 100kg.
The above-mentioned raw material in addition to polypropylene glycerol aether is added in high-shear emulsion machine and shears 15min, Ran Hou
3h is ground in ball crusher, particle diameter below 5 μm, is then added silicone emulsion, produces.
Dispersant, wetting agent, thickener, antifreezing agent, grease auxiliary agent
The microemulsion of embodiment 12
Weigh active ingredient emamectin benzoate 12kg, effective cypermethrin 7kg, pleocidin 9kg, alpha-terpineol 11kg, kuh-seng
Alkali 0.4kg, nicotine 0.4kg, rotenone 0.9kg, fennel artemisin 0.6kg, stemonine 0.7kg；Ethanol 20kg, agriculture breast 300# are weighed again
5kg, glycerine 0.1kg, tributyl phosphate 0.5kg, purified water complement to 100kg；
Active ingredient and ethanol are added in reactor, addition agriculture breast 300# is remixed after making active ingredient dissolving completely
Uniformly, purified water, glycerine and tributyl phosphate are added while stirring, are stirred 15min under 4000rpm rotating speed, are produced.
The pulvis of embodiment 13
Weigh active ingredient emamectin benzoate 24kg, effective cypermethrin 12kg, pleocidin 12kg, alpha-terpineol 8kg, kuh-seng
Alkali 0.9kg, nicotine 0.5kg, rotenone 0.7kg, fennel artemisin 0.8kg, stemonine 1.1kg；Magnesium chloride 1kg, laruyl alcohol are weighed again
Ether sodium sulfate 2kgg, kaolin complement to 100kg；
By active ingredient and kaolin through air-flow crushing and after stirring, sodium laureth sulfate and magnesium chloride are added,
Granulation, dry, produce.
The granule of embodiment 14
Weigh active ingredient emamectin benzoate 34kg, effective cypermethrin 18kg, pleocidin 10kg, alpha-terpineol 8kg, kuh-seng
Alkali 0.7kg, nicotine 0.6kg, rotenone 1.5kg, fennel artemisin 1.4kg, stemonine 0.8kg；Urea 0.9kg, methylene are weighed again
Double sodium naphthalene sulfonate 2.5kg, ammonium sulfate 1kg, quartz sand complement to 100kg；
By active ingredient and quartz sand through air-flow crushing and after stirring, add sodium methylene bis-naphthalene sulfonate, urea and
Ammonium sulfate, granulation, dry, produce.
The missible oil of embodiment 15
Weigh active ingredient emamectin benzoate 18kg, effective cypermethrin 10kg, pleocidin 12kg, alpha-terpineol 5kg, kuh-seng
Alkali 0.4kg, nicotine 0.3kg, rotenone 0.3kg, fennel artemisin 0.9kg, stemonine 1.1kg；Agriculture breast 600#8kg, azone are weighed again
0.9kg, cyclohexanone complement to 100kg；
By agriculture breast 600#, azone and cyclohexanone are added in reactor, sequentially add active ingredient, set reactor to turn
Speed is 2500rpm, and 30min is to homogeneous liquid for stirring, produces.
The aqueous emulsion of embodiment 16
Weigh active ingredient emamectin benzoate 15kg, effective cypermethrin 9kg, pleocidin 11kg, alpha-terpineol 7kg, kuh-seng
Alkali 0.7kg, nicotine 0.4kg, rotenone 0.5kg, fennel artemisin 1.2kg, stemonine 1.2kg；APES is weighed again
Sodium phosphate 6kg, methanol 25kg, triethanolamine 0.5kg, glycerine 0.4kg, polyether-modified silicon 0.7kg, polyvinyl acetate 3kg,
Purified water is supplied to 100kg；
By active ingredient and methanol, APES sodium phosphate adds cutting kettle, after stirring 30min, obtains oil
Phase；
By triethanolamine, glycerine, stirred after polyvinyl acetate and purified water mixing, obtain aqueous phase；
The rotating speed for setting homogenizer is 5000rpm, makes in the case of homogenizer high shear, oil phase is slowly added into aqueous phase
In, polyether-modified silicon is added after addition, above-mentioned rotating speed high shear 15min is continued to, produces.
The suspending agent of embodiment 17
Weigh active ingredient emamectin benzoate 27kg, effective cypermethrin 15kg, pleocidin 8kg, alpha-terpineol 7kg, kuh-seng
Alkali 0.4kg, nicotine 0.4kg, rotenone 0.3kg, fennel artemisin 1.2kg, stemonine 0.7kg；Sodium methylene bis-naphthalene sulfonate is weighed again
1kg, polyethylene glycol 0.5kg, gelatin 2kg, polypropylene glycerol aether 0.2kg, purified water complement to 100kg；
By sodium methylene bis-naphthalene sulfonate, polyethylene glycol, it is uniform to be put into shear-mixed in cutter after gelatin mixing, Ran Houzai
Active ingredient and purified water are added, 4h is ground in ball crusher, then adds polypropylene glycerol aether, is produced.
The wettable powder of embodiment 18
Weigh emamectin benzoate 19kg, effective cypermethrin 6kg, pleocidin 8kg, alpha-terpineol 6kg, matrine 0.2kg, cigarette
Alkali 0.3kg, rotenone 0.5kg, fennel artemisin 0.5kg, stemonine 0.5kg, APES 5kg, alkyl phenol polyoxy second
Alkene ether 6kg, white carbon supply to 100kg；
Crushed after above-mentioned raw materials are well mixed through fluid bed airflow milling equipment, be well mixed, produce.
The water dispersible granules of embodiment 19
Weigh emamectin benzoate 10kg, effective cypermethrin 5kg, pleocidin 6kg, alpha-terpineol 5kg, matrine 0.7kg, cigarette
Alkali 0.4kg, rotenone 0.5kg, fennel artemisin 1.1kg, stemonine 1.3kg, alkylnaphthalene sulfonate 2kg, APES
Sodium phosphate 1kg, magnesium chloride 0.2kg, talcum powder complement to 100kg；
Crushed after above-mentioned raw materials are mixed with micro jet, add in fluidized-bed granulation dryer after kneading
Row is granulated, dried, after screening, produces.
The micro-capsule suspension of embodiment 20
Weigh active ingredient emamectin benzoate 14kg, effective cypermethrin 9kg, pleocidin 6kg, alpha-terpineol 5kg, matrine
0.6kg, nicotine 1kg, rotenone 1.2kg, fennel artemisin 1.4kg, stemonine 1.8kg；Acetone 35kg, Arabic gum 8kg are weighed again,
APES 1kg, polyethylene glycol 0.5kg, purified water complement to 100kg.
Active ingredient and Arabic gum are dissolved in acetone, purified water is added after high-speed stirred, organic phase is scattered in water
Xiang Zhong, after precipitation, making the automatic film forming in active ingredient surface, form microcapsules so that microcapsules are scattered to be suspended in aqueous phase,
APES and polyethylene glycol are added, is produced.
The suspension emulsion of embodiment 21
Weigh active ingredient emamectin benzoate 15kg, effective cypermethrin 11kg, pleocidin 8kg, alpha-terpineol 6kg, kuh-seng
Alkali 1.1kg, nicotine 1.1kg, rotenone 1.4kg, fennel artemisin 1.6kg, stemonine 1.8kg；3kg, ethanol 5kg, marine alga are weighed again
Sour sodium 2kg, glycerine 0.5kg, purified water complement to 100kg.
Stirred after active ingredient is mixed with ethanol, dissolve active ingredient, obtain oil phase；
Add APES sodium phosphate, ammonium alginate and glycerine while stirring in purified water, stirring is equal
Even acquisition aqueous phase；Aqueous phase is directly added into oil phase, 35min is stirred, produces.
The oil suspending agent of embodiment 22
Weigh active ingredient emamectin benzoate 23kg, effective cypermethrin 18kg, pleocidin 12kg, alpha-terpineol 7kg, kuh-seng
Alkali 1kg, nicotine 1.4kg, rotenone 1.2kg, fennel artemisin 2.8kg, stemonine 1.6kg；Fatty acid amide N- methyl ox sulphurs are weighed again
Sour sodium 5kg, APES 3kg, phenolic resin 3kg, sorbierite 0.5kg, polyether-modified silicon 1.5kg, Jatropha curcas oil
Complement to 100kg.
The above-mentioned raw material in addition to polypropylene glycerol aether is added in high-shear emulsion machine and shears 20min, Ran Hou
4h is ground in ball crusher, particle diameter below 4 μm, is then added polypropylene glycerol aether, produces.
First, Toxicity Determination
1.1 test objective
Test toxicity test of the agricultural chemical composition for disinsection to diamondback moth of the present invention.
1.2 subjects
The anti-deltamethrin of diamondback moth, through the generation of indoor feeding more than 100, using polypide is neat, at the beginning of three age of the same size
Larva is for examination.
1.3 reagent agent
1-22 insecticide pesticide preparations of the embodiment of the present invention.
1.4 test method
Reagent agent is determined with analysis pure acetone by proportional diluted into 5-7 concentration series, each concentration sets 5 weights
It is multiple, every repeatedly 10 larvas.10 larvas are placed in 5cm culture dishes during measure, after carbon dioxide light anesthesia, with 5 μ l
Microsyringe 0.5 μ l decoctions are put on every larva chest backboard.Then plus fresh cabbage leaves make feed, are placed in artificial gas
Case is waited, in 25 DEG C, 16L:Raised under 8d Thermo-Photo sensitives, investigate dead larvae number after 48h respectively, the control death rate is no more than 5%
Shi Youxiao is determined.Co-toxicity coefficient is calculated according to Sun-Johnson methods, synegism evaluation is carried out according to co-toxicity coefficient, if poison altogether
Coefficient ＞ 120 is synergistic effect, if 120 >=co-toxicity coefficient ＞ 80 is summation action, if co-toxicity coefficient≤80 are antagonism.
1.5 result of the test
Result of the test is shown in Table 1.
Table 1
From table 1, when emamectin benzoate and effective cypermethrin carry out mixture, each proportioning co-toxicity coefficient has addition to make
With the co-toxicity coefficient of 90.9% processing has reached more than 120, has obvious synergistic function, illustrates the embodiment of the present invention
The agricultural chemical composition for disinsection and its preparation of offer show as obvious synergistic effect to the virulence of diamondback moth, and prevention effect is good.
2nd, field control effectiveness test
1.1 test objective
Diamondback moth field control effectiveness test.
1.2 test method
Experiment is located at Nanning Wuming area vegetable garden, experimental field uniform soil quality, and farming is good, medium fertility, soil
Subacidity.Wild cabbage is planted in ridge railway carriage or compartment, and wild cabbage is in balling initial stage, grown fine, diamondback moth generally occurs.
This experiment is divided into tri- test group, control group A, control group B groups, and every group of 22 processing, each processing is one plant
Wild cabbage.In wild cabbage balling dispenser at initial stage, using sprayer to cabbage leaves positive and negative even spraying dispenser.Test group respectively processing point
2000 times of liquid (pulvis directly sprays) of 1-22 of embodiment of the present invention insecticide pesticide preparation are not sprayed, and control group A sprays respectively
2000 times of liquid of Recompounded pesticide (30% Diacloden and 40% thiacloprid), control group B spray equivalent clear water.Every plant of wild cabbage sprays 0.8-
1.5L decoction.
Spraying time is mid-May then, investigates insect population before dispenser, and 1 day after dispenser, adjusted within 3 days, 7 days
The remaining quantity of diamondback moth on every plant of wild cabbage is looked into, the Revision insect recluced rate and prevention effect of each processing are calculated with this.
1.3 result of the test
Result of the test is shown in Table 2.
Table 2
As shown in table 2, insecticide pesticide preparation provided in an embodiment of the present invention is preferable to diamondback moth preventive effect, is averaged within 1 day after medicine
Preventive effect is 82.1%, than control group A prevention effect increase by 18.1%；3 days average preventive effects are 88.2% after medicine, compared to control group A
Prevention effect increase by 29.1%；7 days average preventive effects are 94.5% after medicine, compared to control group A prevention effect increase by 25.5%；It is and right
According to group B, diamondback moth doubles remaining after only spray clear water 7 days, and diamondback moth insect pest situation substantially aggravates.Can from table 2
Go out, agricultural chemical composition for disinsection of the invention and its preparation preventing and treating field brassicaceous vegetable diamondback moth quick-acting is strong, prevention effect
Well, the lasting period is longer.
In addition, the applicant also indulges volume using the agricultural chemical composition for disinsection of the present invention for eucalyptus looper, beet armyworm, rice
Leaf snout moth's larva, small heart-eating peach worm, tangerine lyonetid, Caloptiliatheivora, predacious diving beetle, rice weevil, cutworm, corn borer etc. have carried out Toxicity Determination and field
Between the test of pesticide effectiveness, preventing and treating Lepidoptera, coleoptera and Diptera insect pest have excellent effect, there is obvious Synergistic
Effect.
Claims (10)
1. a kind of emamectin benzoate and efficient cypermethrin compounded agricultural chemical composition for disinsection, including component A and component B, its feature exist
In：
Described component A includes emamectin benzoate, effective cypermethrin, pleocidin and alpha-terpineol；
Described component B includes matrine, nicotine, rotenone, fennel artemisin and stemonine；
The mass ratio of the component A and component B are 4-23：1.
2. emamectin benzoate according to claim 1 and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is characterised in that：
The mass ratio of the component A and component B are 12-16：1.
3. emamectin benzoate according to claim 1 or 2 and efficient cypermethrin compounded agricultural chemical composition for disinsection, its feature exist
In：In described component A, emamectin benzoate, effective cypermethrin, the mass ratio of pleocidin and alpha-terpineol are 2-6：1-3：0.5-
3：0.5-2.
4. emamectin benzoate according to claim 1 or 2 and efficient cypermethrin compounded agricultural chemical composition for disinsection, its feature exist
In：In described component B, matrine, nicotine, rotenone, the mass ratio of fennel artemisin and stemonine are 1-3：1-3：1-3：2-5：
2-5。
5. emamectin benzoate according to claim 1 or 2 and efficient cypermethrin compounded agricultural chemical composition for disinsection, its feature exist
In：The formulation of the agricultural chemical composition for disinsection is solid pharmaceutical preparation, or is microemulsion.
6. emamectin benzoate according to claim 5 and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is characterised in that
The preparation method of the solid pharmaceutical preparation comprises the following steps：
Described component A and component B are added in filling carrier, add surfactant and/or disintegrant, is well mixed
Pulvis is made；Or on the basis of pulvis, add appropriate wetting agent and be further prepared into granule.
7. emamectin benzoate according to claim 5 and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is characterised in that
The preparation method of the microemulsion comprises the following steps：
Described component A and component B are added in reactor, solvent is added, dissolution of raw material is added emulsifying agent afterwards completely
Remix uniformly, add water, antifreezing agent and stabilizer while stirring, 15-30min is stirred under 2000-4000rpm rotating speed,
Produce.
8. emamectin benzoate according to claim 6 and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is characterised in that：
Described filling carrier is one in kaolin, diatomite, bentonite, white carbon, clay, talcum powder, quartz sand, starch
Kind is two or more；
Described surfactant is neopelex, lauryl sodium sulfate, sodium butylnaphthalenesulfonate, lignin sulfonic acid
Sodium, sodium methylene bis-naphthalene sulfonate, sodium laureth sulfate, polyoxyethylene fatty alkyl ether sulfonate, dodecyl sulphate calcium, 12
It is more than one or both of alkyl benzene calcium sulfonate, calcium lignosulfonate, polyethers ichthyodin, phenethyl phenol polyethenoxy ether；
Described wetting agent is sodium sulphate, sldium lauryl sulfate, lignosulfonates, APES phosphate, stone
Oily sodium sulfonate, alkylnaphthalene sulfonate, fatty acid ester sulfate, APES, AEO, gleditsia sinensis
It is more than one or both of powder, tea seed cake powder, silkworm excrement；
Described disintegrant be sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, one kind in bentonite or
It is two or more.
9. emamectin benzoate according to claim 7 and efficient cypermethrin compounded agricultural chemical composition for disinsection, it is characterised in that：
Described solvent is water, DMF, methanol, ethanol, ethylene glycol, propane diols, acetone, cyclohexanone, pyrroles
It is more than one or both of alkanone, toluene, dimethylbenzene, ethyl acetate, dimethylformamide, vegetable oil, petroleum ether, acetonitrile；
Described emulsifying agent is tri ethanol ammonium salt, APES formaldehyde condensation product, alkylbenzene naphthalene sulfonate, alkyl phenol
Polyoxyethylene ether phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, diphenyl phenol polyoxy second
One or both of alkene polyoxy formaldehyde condensation products, agriculture breast 300#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, TWEEN Series with
On；
Described antifreezing agent is polyethylene glycol, glycerine or sorbierite；
Described stabilizer is in BHT, triethanolamine, tributyl phosphate, xylitol, mannitol, pentaerythrite, sodium citrate
It is one or more kinds of.
10. a kind of emamectin benzoate and efficient cypermethrin compounded insecticide pesticide preparation, as the emamectin benzoate described in claim 1 or 2
It is prepared with acceptable carrier combination on efficient cypermethrin compounded agricultural chemical composition for disinsection and Pesticide Science.
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| CN111011372A (en) * | 2019-12-25 | 2020-04-17 | 山东省绿士农药有限公司 | Micro-capsule suspension-suspending agent containing efficient fluorine-chlorine-hydrogen-pyrethrin and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105145621A (en) * | 2015-09-28 | 2015-12-16 | 全椒县花溪湖特种水产合作社 | Drug preventing and curing tobacco aphids |
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2017
- 2017-10-13 CN CN201710952538.6A patent/CN107691467A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105145621A (en) * | 2015-09-28 | 2015-12-16 | 全椒县花溪湖特种水产合作社 | Drug preventing and curing tobacco aphids |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111011372A (en) * | 2019-12-25 | 2020-04-17 | 山东省绿士农药有限公司 | Micro-capsule suspension-suspending agent containing efficient fluorine-chlorine-hydrogen-pyrethrin and preparation method thereof |
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