CN107683046B - Method for producing shell, shell and electronic equipment - Google Patents

Method for producing shell, shell and electronic equipment Download PDF

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Publication number
CN107683046B
CN107683046B CN201711040203.3A CN201711040203A CN107683046B CN 107683046 B CN107683046 B CN 107683046B CN 201711040203 A CN201711040203 A CN 201711040203A CN 107683046 B CN107683046 B CN 107683046B
Authority
CN
China
Prior art keywords
layer
shell
graphene
coloring layer
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201711040203.3A
Other languages
Chinese (zh)
Other versions
CN107683046A (en
Inventor
杨光明
张涛
孙文峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Oppo Mobile Telecommunications Corp Ltd
Original Assignee
Guangdong Oppo Mobile Telecommunications Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Oppo Mobile Telecommunications Corp Ltd filed Critical Guangdong Oppo Mobile Telecommunications Corp Ltd
Priority to CN201711040203.3A priority Critical patent/CN107683046B/en
Publication of CN107683046A publication Critical patent/CN107683046A/en
Application granted granted Critical
Publication of CN107683046B publication Critical patent/CN107683046B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/02Details
    • H05K5/0217Mechanical details of casings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/18Layered products comprising a layer of metal comprising iron or steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/02Details
    • H05K5/0217Mechanical details of casings
    • H05K5/0243Mechanical details of casings for decorative purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment

Abstract

The embodiment of the present application discloses a kind of method for producing shell, shell and electronic equipment; by in substrate towards sequentially forming coloring layer and protective layer on the surface on the outside of electronic equipment; the color of the coloring layer penetrates the protective layer; the protective layer is a graphene layer; when finger touches the shell; since graphene has hydrophilic and oleophobic property, the grease on finger is not easy to be attached to protective layer, so that the surface of shell fingerprint not easy to stick.

Description

Method for producing shell, shell and electronic equipment
Technical field
This application involves technical field of electronic equipment, and in particular to a kind of method for producing shell, shell and electronic equipment.
Background technique
Currently, electronic equipment, for example mobile phone, tablet computer housing outer surface be easy viscous fingerprint.
Summary of the invention
The embodiment of the present application provides a kind of method for producing shell, shell and electronic equipment, can make grease on finger not It easily is attached to protective layer, so that the surface of shell fingerprint not easy to stick.
The embodiment of the present application provides a kind of method for producing shell, and the shell is applied to electronic equipment, the shell production Method includes:
A substrate is provided, the substrate includes first surface and second surface, and the first surface is towards in electronic equipment Side, second surface is towards on the outside of electronic equipment;
In the second surface of the substrate, coloring layer is set;And
Protective layer is set on the coloring layer, and the color of the coloring layer penetrates the protective layer, and the protective layer is One graphene layer.
The embodiment of the present application also provides a kind of shell, is applied to electronic equipment, and the shell includes a substrate, a coloring layer With a protective layer, the substrate includes first surface and second surface, and the first surface is towards on the inside of electronic equipment, the second table Facing towards on the outside of electronic equipment, the coloring layer and the protective layer are set in turn in the second surface of the substrate, described The color of chromatograph penetrates the protective layer, and the protective layer is a graphene layer.
The embodiment of the present application also provides a kind of electronic equipment, including shell, the shell includes a substrate, a coloring layer With a protective layer, the substrate includes first surface and second surface, and the first surface is towards on the inside of electronic equipment, the second table Facing towards on the outside of electronic equipment, the coloring layer and the protective layer are set in turn in the second surface of the substrate, described The color of chromatograph penetrates the protective layer, and the protective layer is a graphene layer.
Method for producing shell provided by the embodiments of the present application, by substrate towards on the surface on the outside of electronic equipment successively Coloring layer and protective layer are formed, the color of the coloring layer penetrates the protective layer, and the protective layer is a graphene layer, works as hand Refer to that, since graphene has hydrophilic and oleophobic property, the grease on finger is not easy to be attached to protective layer, to make when touching the shell Obtain the surface fingerprint not easy to stick of shell.
Detailed description of the invention
In order to more clearly explain the technical solutions in the embodiments of the present application, make required in being described below to embodiment Attached drawing is briefly described, it should be apparent that, the drawings in the following description are only some examples of the present application, for For those skilled in the art, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is the structural schematic diagram of electronic equipment provided by the embodiments of the present application.
Fig. 2 is the structural schematic diagram of shell provided by the embodiments of the present application.
Fig. 3 is the structural schematic diagram of rear cover provided by the embodiments of the present application.
Fig. 4 is sectional view of the Fig. 3 in the first embodiment in the direction A-A.
Fig. 5 is another structural schematic diagram of shell provided by the embodiments of the present application.
Fig. 6 is another structural schematic diagram of rear cover provided by the embodiments of the present application.
Fig. 7 is another structural schematic diagram of electronic equipment provided by the embodiments of the present application.
Fig. 8 is the first flow diagram of rear cover production method provided by the embodiments of the present application.
Fig. 9 is second of flow diagram of rear cover production method provided by the embodiments of the present application.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present application, technical solutions in the embodiments of the present application carries out clear, complete Site preparation description.Obviously, described embodiments are only a part of embodiments of the present application, instead of all the embodiments.It is based on Embodiment in the application, those skilled in the art's every other implementation obtained without creative efforts Example, shall fall in the protection scope of this application.
In the description of the present application, it is to be understood that term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside", " up time The orientation or positional relationship of the instructions such as needle ", " counterclockwise " is to be based on the orientation or positional relationship shown in the drawings, and is merely for convenience of It describes the application and simplifies description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with spy Fixed orientation construction and operation, therefore should not be understood as the limitation to the application.In addition, term " first ", " second " are only used for Purpose is described, relative importance is not understood to indicate or imply or implicitly indicates the quantity of indicated technical characteristic. " first " is defined as a result, the feature of " second " can explicitly or implicitly include one or more feature.? In the description of the present application, the meaning of " plurality " is two or more, unless otherwise specifically defined.
In the description of the present application, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can To be mechanical connection, it is also possible to be electrically connected or can mutually communicate;It can be directly connected, it can also be by between intermediary It connects connected, can be the connection inside two elements or the interaction relationship of two elements.For the ordinary skill of this field For personnel, the concrete meaning of above-mentioned term in this application can be understood as the case may be.
In this application unless specifically defined or limited otherwise, fisrt feature second feature "upper" or "lower" It may include that the first and second features directly contact, also may include that the first and second features are not direct contacts but pass through it Between other characterisation contact.Moreover, fisrt feature includes the first spy above the second feature " above ", " above " and " above " Sign is right above second feature and oblique upper, or is merely representative of first feature horizontal height higher than second feature.Fisrt feature exists Second feature " under ", " lower section " and " following " include that fisrt feature is directly below and diagonally below the second feature, or is merely representative of First feature horizontal height is less than second feature.
Following disclosure provides many different embodiments or example is used to realize the different structure of the application.In order to Simplify disclosure herein, hereinafter the component of specific examples and setting are described.Certainly, they are merely examples, and And purpose does not lie in limitation the application.In addition, the application can in different examples repeat reference numerals and/or reference letter, This repetition is for purposes of simplicity and clarity, itself not indicate between discussed various embodiments and/or setting Relationship.In addition, this application provides various specific techniques and material example, but those of ordinary skill in the art can be with Recognize the application of other techniques and/or the use of other materials.
The embodiment of the present application provides a kind of method for producing shell, shell and electronic equipment.It will carry out respectively below detailed Explanation.
In the present embodiment, it will be described from the angle of rear cover production method, the method for producing shell can be formed Shell, the shell can be set in the electronic device, such as mobile phone, tablet computer, palm PC (Personal Digital Assistant, PDA) etc..
Please refer to the structural schematic diagram that 1, Fig. 1 is electronic equipment provided by the embodiments of the present application.The electronic equipment 1 includes Shell 10, display screen 20, printed circuit board 30, battery 40.
Referring to Fig. 2, Fig. 2 is the structural schematic diagram of shell provided by the embodiments of the present application.
Wherein, the shell 10 may include cover board 11, center 12 and rear cover 13.The cover board 11,12 and of the center The intercombination of rear cover 13 forms the shell 10.The shell 10, which has, passes through the cover board 11, the center 12 and institute A confined space of the formation of rear cover 13 is stated, to accommodate the devices such as display screen 20, printed circuit board 30, battery 40.
In some embodiments, the lid of cover board 11 is set on the center 12.The lid of rear cover 13 is set to the center On 12.The cover board 11 and rear cover 13 are located at the opposite face of the center 12.The cover board 11 and rear cover 13 are oppositely arranged.It is described The confined space of shell 10 is between the cover board 11 and rear cover 13.
The cover board 11 can be transparent glass cover plate.In some embodiments, the cover board 11 can be with such as Glass cover-plate made of the materials such as sapphire.
The center 12 can be metal shell, such as aluminium alloy center 12.It should be noted that in the embodiment of the present application The material of frame 12 is not limited to this, and can also use other way, such as: the center 12 can ceramic center, glass center. For another example: the center 12 can be plastic cement center.Also such as: the center 12 can be metal and the mutually matched knot of plastic cement Structure can be formed plastic portions and being molded on sheet metal.
The rear cover 13 can be with metal back cover, such as aluminium alloy rear cover, stainless steel rear cover.The rear cover 13 can also be glass Glass rear cover or ceramic rear cover.
Also referring to Fig. 3, Fig. 3 is the structural schematic diagram of rear cover provided by the embodiments of the present application.
The rear cover 13 may include the inner surface 131 being oppositely arranged and outer surface 132.The inner surface of the rear cover 13 131, close to center 12 and cover board 11, constitute a part of the inner surface of the shell 10.The outer surface 132 of the rear cover 13 is remote From center 12 and cover board 11, a part of the outer surface of the shell 10 is constituted.The rear cover 13 can also include through-hole 133, The through-hole 133 can be used for installing camera.
Referring to Figure 4 together, Fig. 4 is sectional view of the Fig. 3 in the direction A-A.
For purposes of illustration only, being illustrated by taking rear cover 13 as an example to shell below.
The rear cover 13 may include a substrate 134, a coloring layer 136 and a protective layer 135.136 He of coloring layer Protective layer 135 is set in turn in surface namely the coloring layer 136 of the rear cover 13 far from cover board 11 and is set to the protection Between layer 135 and the outer surface of the shell 11.
Wherein, the substrate 134 can use aluminium, such as aluminium alloy, can also use stainless steel, can also use glass Glass, ceramics etc..
The substrate 134 includes first surface 1341 and second surface 1342.The first surface 1341 is set towards electronics Standby inside, second surface 1342 is towards on the outside of electronic equipment.In one embodiment, the first surface 1341 is towards cover board 11 It is arranged with the direction of center 12.The first surface 1341 can be the inner surface 131 of rear cover 13.The first surface 1341 is The inner surface of the shell 11.The second surface 1342 faces away from the direction setting of cover board 11 and center 12.Described second Surface 1342 is the outer surface of the shell 11.
The coloring layer 136 is set to the second surface 1342 of the substrate 134.
The coloring layer 136 can form layer of oxide layer by once oxidation.Such as: monochrome oxidation forms the oxidation Layer, can specifically be formed by being coloured after oxidation technology.
It should be noted that in some embodiments, it is also possible to being formed using oxidation twice or oxidation more than twice more Layer oxide layer.
In one embodiment, in order to enable the coloring layer 136 to be attached to the of the substrate 134 strongerly Two surfaces 1342 can be processed by shot blasting the second surface 1342 of the substrate 134, to increase the of the substrate 134 The flatness on the surface on two surfaces 1342, to increase the coloring layer 136 in the second surface 1342 of the substrate 134 Adhesive force, and then the coloring layer 136 is enable to be firmly adhered to the second surface 1342 of the substrate 134.
In one embodiment, the coloring layer 136 can have multiple painted areas, and different painted areas settings are different Color, to form pattern.
The coloring layer 136 may include a color layers 1361 and a hyaline layer 1362.Color layers 1361 and described Hyaline layer 1362 is set in turn in the second surface 1342 of the substrate 134.The color layers 1361 can be above-described Oxide layer.The hyaline layer 1362 can be celluloid paint layer.
It should be noted that the coloring layer 136 can not also include the hyaline layer 1362.
The protective layer 135 is set to the coloring layer 136.The color of the coloring layer 136 penetrates the protective layer 135, so that the protective layer 135 does not block the color of the coloring layer 136.The protective layer 135 is a graphene layer
In one embodiment, graphene oxide can be first prepared, Nano sol is then prepared, then by hydrophilic polymeric The agent of object water-sensitive and crosslinking first solution of film forming agent formation soluble in water, then that Nano sol and the first solution be mixed to form second is molten Then graphene oxide is added in the second solution by liquid, form graphene presoma.
The graphene presoma is coated on the coloring layer 136, then pass through drying and toasts the coloring layer 136 On graphene presoma obtain graphene layer.
In one embodiment, the graphene presoma can be coated by the way of spin coating, spraying or immersion In on the coloring layer 136.
In one embodiment, the graphene presoma on the coloring layer 136 can be carried out using vacuum oven Baking is to obtain graphene layer.
In one embodiment, the time of baking can be with 1 hour.In one embodiment, the time of baking can be 20 Minute was to 40 minutes.In one embodiment, the temperature of baking can be lower than 300 degrees Celsius.In one embodiment, baking Temperature can be 100 degrees Celsius to 200 degrees Celsius.
In one embodiment, first layer graphene presoma can be first coated on the coloring layer 136, then passed through Graphene presoma that is dry and toasting on the coloring layer 136 obtains first layer graphene layer, then again in the first layer Second layer graphene presoma is coated on graphene layer, before then passing through drying and toasting the graphene on the coloring layer 136 It drives body and obtains second layer graphene layer, and so on, can be by repeatedly coating and toasting the step of, adjusts graphene layer The number of plies, to control the thickness of the protective layer 135.
In one embodiment, the thickness of the protective layer 135 is less than 500 microns.When the thickness of protective layer 135 is greater than At 500 microns, since the thickness of the protective layer 135 is larger, causes the photopermeability of the protective layer 135 poor, be easy to block The color of the coloring layer 136.
In one embodiment, in order to enable the protective layer 135 to be attached to the coloring layer 136 strongerly, The coloring layer 136 can be processed by shot blasting, to increase the flatness on the surface of the coloring layer 136, to increase The protective layer 135 is in the adhesive force of the coloring layer 136, and then it is described so that the protective layer 135 is firmly adhered to Coloring layer 136.
It should be noted that the structure of the embodiment of the present application shell is not limited to this, for example, referring to Fig. 5, Fig. 5 is this Apply for another structural schematic diagram for the shell that embodiment provides.
The shell 10a includes cover board 16 and rear cover 17.In some embodiments, the cover board 16 directly lid is set to described On rear cover 17.The cover board 16 and the intercombination of the rear cover 17 form the shell 10a.The shell 10a, which has, passes through institute The confined space that cover board 16 and rear cover 17 are formed is stated, to accommodate the devices such as display screen 20, printed circuit board 30, battery 40.
Compared to shell 10 shown in Fig. 2, the shell 10a of Fig. 5 does not include center, or perhaps by the center in Fig. 2 12 and rear cover 13 be integrally formed formed 17 structure of a rear cover.
Specifically, referring to Fig. 6, Fig. 6 is another structural schematic diagram of rear cover provided by the embodiments of the present application.
In some embodiments, rear cover 17 includes inner surface 171 and outer surface 172,172 phase of inner surface 171 and outer surface To setting, the whole surface of rear cover 17 is formed.Each layer structure of the rear cover 17 can be refering to rear cover 13, and details are not described herein.
In the housing 10, the printed circuit board 30 can be the mainboard of electronic equipment 1 for the installation of printed circuit board 30, Antenna, motor, microphone, camera, light sensor, receiver and processor etc. are can integrate on printed circuit board 30 Functional unit.In some embodiments, the printed circuit board 30 is fixed in shell 10.Specifically, the printed circuit board 30 can be screwed on center 12 by screw, card can also be fitted on center 12 by the way of buckle.It should be noted that The embodiment of the present application printed circuit board 30 is specifically not limited to this fixed to the mode on center 12, can with other way, than Such as by way of buckling and screw is fixed jointly.
In the housing 10, battery 40 is electrically connected with the printed circuit board 30 for the battery 40 installation, with to electronics Equipment 1 provides power supply.Shell 10 can be used as the battery cover of battery 40.Shell 10 covers battery 40 to protect battery 40, specifically Be that rear cover 13 covers battery 40 to protect battery 40, reduce battery 40 due to electronic equipment 1 collision, fall etc. and be subject to Damage.
The display screen 20 is installed in the housing 10, meanwhile, the display screen 20 is electrically connected on printed circuit board 30, with Form the display surface of electronic equipment 1.The display screen 20 includes display area 14 and non-display area 15.The display area 14 It can be used to show the picture of electronic equipment 1 or carry out touching manipulation etc. for user.The top region of the non-display area 15 Domain opens up the aperture for sound and light conduction, and fingerprint mould group, touch controlled key can be set on 15 bottom of non-display area Equal functional units.Wherein the cover board 11 is installed on display screen 20, to cover display screen 20, is formed identical with display screen 20 Display area and non-display area, specifically can display area refering to display screen 20 and non-display area.
It should be noted that the structure of the display screen 20 is not limited to this.For example, the display screen can be screen comprehensively Or anisotropic screen, specifically, referring to Fig. 7, Fig. 7 is another structural schematic diagram of electronic equipment provided by the embodiments of the present application.Fig. 7 In electronic equipment and Fig. 1 in the difference of electronic equipment be: the non-display area 15a is formed directly into display screen 20a On, for example in the non-display area 15a of display screen 20a it is arranged to transparent configuration, so that optical signal passes through, or directly showing The non-display area of screen 20a is opened up for structures such as the aperture of light conduction or notches, can be by front camera, photoelectric sensor Etc. being set to non-display area position, so that front camera is taken pictures, photoelectric sensor detection.The display area 14a is paved with Electronic equipment 1a whole surface.It should be noted that shell 10, printed circuit board 30 and battery 40 in the electronic equipment 1a Equal devices can be refering to the above content, and details are not described herein.
The present invention also provides a kind of production methods of shell.
It should be noted that be illustrated by taking rear cover as an example below, but the embodiment of the present application method for producing shell is not It is limited to rear cover.
Also referring to Fig. 8, Fig. 8 is the flow diagram of rear cover production method provided by the embodiments of the present application.The shell Body production method the following steps are included:
Step S101 provides a substrate 134, and the substrate 134 includes first surface 1341 and second surface 1342, described First surface 1341 is towards on the inside of electronic equipment, and second surface 1342 is towards on the outside of electronic equipment.
The substrate 134 can be metal material, such as aluminium, further, such as aluminium alloy.It should be noted that The substrate 134 can be directly commercially available, and can also be obtained to sheet fabrication, for example, aluminum alloy plate materials are forged and pressed, when The process such as effect obtain.The substrate 134 can also be using glass, ceramics etc..
The first surface 1341 is arranged towards the direction of cover board 11 and center 12.After the first surface 1341 can be The inner surface 131 of lid 13.The first surface 1341 is the inner surface of the shell 11.The second surface 1342 faces away from The setting of the direction of cover board 11 and center 12.The second surface 1342 is the outer surface of the shell 11.
Coloring layer 136 is arranged in the second surface 1342 of the substrate 134 in step S102.
In one embodiment, referring to Fig. 9, the step S102 can be with are as follows:
Step S1021: the second surface 1342 of the substrate 134 is processed by shot blasting;
Step S1022: coloring layer 136 is set on the second surface 1342 of the substrate 134 of the polishing treatment; And
Step S1023: the coloring layer 136 is processed by shot blasting.
In one embodiment, in order to enable the coloring layer 136 to be attached to the of the substrate 134 strongerly Two surfaces 1342 can be processed by shot blasting the second surface 1342 of the substrate 134, to increase the of the substrate 134 The flatness on the surface on two surfaces 1342, to increase the coloring layer 136 in the second surface 1342 of the substrate 134 Adhesive force, and then the coloring layer 136 is enable to be firmly adhered to the second surface 1342 of the substrate 134.
In one embodiment, described in order to enable protective layer 135 be attached in the next steps strongerly Chromatograph 136 can be processed by shot blasting the coloring layer 136, to increase the flatness on the surface of the coloring layer 136, from And the protective layer 135 is increased in the adhesive force of the coloring layer 136, and then keep the protective layer 135 attached securely In the coloring layer 136.
It in some embodiments, can be by the way of mechanical, chemistry, electrochemistry or ultrasonic wave etc. to the substrate 134 Second surface 1342 or the coloring layer 136 realize polishing.So that the second surface 1342 of the substrate 134 or described 136 roughness of chromatograph reduces, to obtain the second surface 1342 or the coloring layer of the substrate 134 of bright, flat surface 136.Wherein, chemical polishing mode be the second surface 1342 or the coloring layer 136 of the substrate 134 are carried out it is regular molten Solution reaches smooth.Wherein, electrochemical polish mode is by the second surface 1342 or the coloring layer of the substrate 134 136 are used as anode, insoluble petal for cathode, and the two poles of the earth are immersed in electrolytic cell simultaneously, lead to direct current and generate selective sun Pole solution, so that the second surface 1342 of the substrate 134 or 136 brightness of the coloring layer increase greatly.It is wherein mechanical The mode of polishing is the second surface 1342 or the coloring layer 136 by cutting the substrate 134, so that the substrate 134 Second surface 1342 or the coloring layer 136 are plastically deformed the protrusion after removing polishing and obtain even surface.Wherein ultrasonic wave is thrown The mode of light is by the substrate 134 or to be provided with the substrate 134 of coloring layer 136 and be put into abrasive suspension and set together In ultrasound field, by the oscillation action of ultrasonic wave, make second surface 1342 or the coloring of the abrasive material in the substrate 134 136 grinding-polishing of layer.
In some embodiments, to the substrate 134 second surface 1342 or the coloring layer 136 carry out at polishing Before reason, first the second surface 1342 to the substrate 134 or the coloring layer 136 grinding process can be carried out, it is then right again The second surface 1342 or the coloring layer 136 of the substrate 134 after grinding process are processed by shot blasting, imitate polishing treatment Fruit more preferably so that the second surface 1342 or the coloring layer 136 of the substrate 134 are more smooth.Here, need to illustrate It is that the grinding process can be understood as to the roughing before polishing treatment.I.e., it is possible to first be carried out to rear exterior surface primary thick Polishing, then primary thin polishing is carried out, complete polishing treatment.
The coloring layer 136 is set to the second surface 1342 of the substrate 134.The coloring layer 136 can pass through one Secondary oxidation forms layer of oxide layer.Such as: monochrome oxidation forms the oxide layer, specifically can be by carrying out after oxidation technology Color is formed.
It should be noted that in some embodiments, it is also possible to being formed using oxidation twice or oxidation more than twice more Layer oxide layer.
In one embodiment, the coloring layer 136 can have multiple painted areas, and different painted areas settings are different Color, to form pattern.
The coloring layer 136 may include a color layers 1361 and a hyaline layer 1362.Color layers 1361 and described Hyaline layer 1362 is set in turn in the second surface 1342 of the substrate 134.The color layers 1361 can be above-described Oxide layer.The hyaline layer 1362 can be celluloid paint layer.
It should be noted that the coloring layer 136 can not also include the hyaline layer 1362.
Step S103, is arranged protective layer 135 on the coloring layer 136, and the protective layer 135 is a graphene layer.
The method can also include step S104: configuration graphene presoma.
In one embodiment, graphene oxide can be first prepared, Nano sol is then prepared, then by hydrophilic polymeric The agent of object water-sensitive and crosslinking first solution of film forming agent formation soluble in water, then that Nano sol and the first solution be mixed to form second is molten Then graphene oxide is added in the second solution by liquid, form graphene presoma.
The step S104 can be carried out before the step S101, can also be carried out after the step S102. The step S101, step S102 and step S104 are carried out before the step S103.
The step S103 can be with are as follows:
Step S1031: the graphene presoma is coated on the coloring layer 136.
Step S1032: graphene presoma that is dry and toasting on the coloring layer 136 obtains graphene layer.
The graphene presoma is coated on the coloring layer 136, then pass through drying and toasts the coloring layer 136 On graphene presoma obtain graphene layer.
In one embodiment, the graphene presoma can be coated by the way of spin coating, spraying or immersion In on the coloring layer 136.
In one embodiment, the graphene presoma on the coloring layer 136 can be carried out using vacuum oven Baking is to obtain graphene layer.
In one embodiment, the time of baking can be with 1 hour.In one embodiment, the time of baking can be 20 Minute was to 40 minutes.In one embodiment, the temperature of baking can be lower than 300 degrees Celsius.In one embodiment, baking Temperature can be 100 degrees Celsius to 200 degrees Celsius.
The step S1031 and step S1032 can be repeated as many times.
In one embodiment, first layer graphene presoma can be first coated on the coloring layer 136, then passed through Graphene presoma that is dry and toasting on the coloring layer 136 obtains first layer graphene layer, then again in the first layer Second layer graphene presoma is coated on graphene layer, before then passing through drying and toasting the graphene on the coloring layer 136 It drives body and obtains second layer graphene layer, and so on, can be by repeatedly coating and toasting the step of, adjusts graphene layer The number of plies, to control the thickness of the protective layer 135.
The color of the coloring layer 136 penetrates the protective layer 135 so that the protective layer 135 do not block it is described The color of chromatograph 136.
In one embodiment, the thickness of the protective layer 135 is less than 500 microns.When the thickness of protective layer 135 is greater than At 500 microns, since the thickness of the protective layer 135 is larger, causes the photopermeability of the protective layer 135 poor, be easy to block The color of the coloring layer 136.
In summary, method for producing shell provided by the embodiments of the present application, by substrate towards on the outside of electronic equipment Coloring layer and protective layer are sequentially formed on surface, the protective layer is a graphene layer, when finger touches the shell, due to Graphene has hydrophilic and oleophobic property, and the grease on finger is not easy to be attached to protective layer, so that the surface of shell finger not easy to stick Escutcheon.
It will be understood by those skilled in the art that the structure of electronic equipment 1 shown in Fig. 1 is not constituted to electronic equipment 1 Restriction.Electronic equipment 1 may include perhaps combining certain components or different portions than illustrating more or fewer components Part arrangement.Electronic equipment 1 can also include memory, bluetooth module etc., and details are not described herein.
Method for producing shell provided by the embodiments of the present application, shell and electronic equipment are described in detail above, this Specific case is applied in text, and the principle and implementation of this application are described, the explanation of above example is only intended to Help understands the application.Meanwhile for those skilled in the art, according to the thought of the application, it in specific embodiment and answers With in range, there will be changes, in conclusion the contents of this specification should not be construed as limiting the present application.

Claims (8)

1. a kind of method for producing shell, the shell is applied to electronic equipment, which is characterized in that the method for producing shell packet It includes:
One substrate is provided, the substrate includes first surface and second surface, and the first surface is towards on the inside of electronic equipment, and the Two surfaces are towards on the outside of electronic equipment;
In the second surface of the substrate, coloring layer is set;
Prepare graphene oxide and Nano sol;
By the agent of hydrophilic polymer water-sensitive and crosslinking first solution of film forming agent formation soluble in water;
Nano sol and the first solution are mixed to form the second solution;
Graphene oxide is added in the second solution, graphene presoma is formed;
The graphene presoma is coated on the coloring layer;
It dries and toasts the graphene presoma on the coloring layer to obtain graphene layer;And
Protective layer is set on the coloring layer, and the color of the coloring layer penetrates the protective layer, and the protective layer is described Graphene layer.
2. method for producing shell as described in claim 1, which is characterized in that coloring layer is arranged in the second surface of the substrate The step of include:
The second surface of the substrate is processed by shot blasting;
In the second surface of the substrate of polishing treatment, coloring layer is set;And
The coloring layer is processed by shot blasting.
3. method for producing shell as claimed in claim 1 or 2, which is characterized in that described to coat the graphene presoma In the step of graphene presoma in the step and drying and the baking coloring layer on the coloring layer obtains graphene layer Repeatedly.
4. method for producing shell as described in claim 1, it is characterised in that: the thickness of the protective layer is less than 500 microns.
5. a kind of shell is applied to electronic equipment, it is characterised in that: the shell includes a substrate, a coloring layer and a protection Layer, the substrate includes first surface and second surface, and for the first surface towards electronic equipment inside, second surface direction is electric Sub- equipment outside, the coloring layer and the protective layer are set in turn in the second surface of the substrate, the face of the coloring layer Color penetrates the protective layer, and the protective layer is a graphene layer, and the graphene layer is made by following steps:
Prepare graphene oxide and Nano sol;
By the agent of hydrophilic polymer water-sensitive and crosslinking first solution of film forming agent formation soluble in water;
Nano sol and the first solution are mixed to form the second solution;
Graphene oxide is added in the second solution, graphene presoma is formed;
The graphene presoma is coated on the coloring layer;
It dries and toasts the graphene presoma on the coloring layer to obtain graphene layer.
6. shell as claimed in claim 5, it is characterised in that: the coloring layer includes a color layers and a hyaline layer, described Color layers and the hyaline layer are set in turn in the second surface of the substrate.
7. shell as claimed in claim 5, it is characterised in that: the thickness of the protective layer is less than 500 microns.
8. a kind of electronic equipment, which is characterized in that including shell, the shell is as described in any one of claim 5 to 7 Shell.
CN201711040203.3A 2017-10-30 2017-10-30 Method for producing shell, shell and electronic equipment Expired - Fee Related CN107683046B (en)

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