CN107673598A - A kind of high-cleanness coloured glaze - Google Patents

A kind of high-cleanness coloured glaze Download PDF

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Publication number
CN107673598A
CN107673598A CN201710849460.5A CN201710849460A CN107673598A CN 107673598 A CN107673598 A CN 107673598A CN 201710849460 A CN201710849460 A CN 201710849460A CN 107673598 A CN107673598 A CN 107673598A
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CN
China
Prior art keywords
parts
weight
agent
coloured glaze
cleanness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710849460.5A
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Chinese (zh)
Inventor
张永志
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Xinyi Gangfa Trading Co Ltd
Original Assignee
Xinyi Gangfa Trading Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinyi Gangfa Trading Co Ltd filed Critical Xinyi Gangfa Trading Co Ltd
Priority to CN201710849460.5A priority Critical patent/CN107673598A/en
Publication of CN107673598A publication Critical patent/CN107673598A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/004Refining agents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C03C14/002Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high-cleanness coloured glaze, it is made up of the raw material of following parts by weight:12 parts of 40 50 parts of quartz sand, 10 20 parts of cosolvent, 5 10 parts of oxidant, 15 20 parts of fining agent, 5 10 parts of colouring agent, 23 parts of fluorescent whitening agent, 58 parts of reinforcing agent, 25 parts of binding agent, 12 parts of suspending agent and colouring aid;Quartz sand, cosolvent and fining agent three's adding proportion sum account for the 55 70% of gross weight number, and colouring agent, fluorescent whitening agent, reinforcing agent and binding agent adding proportion sum account for the 15 20% of gross mass number;The parts by weight that binding agent includes amino acid are 25 parts, the parts by weight of phenolic resin are 25 parts and bentonite parts by weight are 23 parts.The present invention is not only nontoxic, and cleanliness factor is good, and the rigidity of coloured glaze, stability and intensity are high, physical life length.

Description

A kind of high-cleanness coloured glaze
Technical field
The invention belongs to coloured glaze technical field, more particularly to a kind of high-cleanness coloured glaze.
Background technology
Coloured glaze is a kind of silicate product, is had a long history, and its quality is glittering and translucent, fully demonstrates Asians's Exquisite, fine and smooth and implicit, the main component of coloured glaze is silica, aluminum oxide, fluxing agent and pigment etc..
Coloured glaze has the good characteristics such as low, the material property length of softening point, is so easy to technique to manufacture, is adapted to coloured glaze shaping, coloured glaze The quality of product is embodied in good luster, and bubble, striped, calculus are few.The softening point of coloured glaze, material property are depended primarily in coloured glaze formula The species and its ratio of composition, and fining agent is added in coloured glaze basic ingredient can reduce coloured glaze fusion temperature, melt matter Amount is improved, the defects of avoiding producing bubble, striped, calculus.Fining agent can release decomposition gas in coloured glaze production process Body, or itself gasification, produce substantial amounts of bubble, receive the minute bubbles on periphery, rise with blub and promote coloured glaze to clarify.
Currently used fining agent has ceria, white arsenic etc., but white arsenic is extremely toxic substance, threatens operator's health And seriously pollute environment;The clarifying effect of ceria is fine, but settling time is longer, and cerium is rare earth element, cost compared with It is expensive.
The content of the invention
The present invention solves the technical problem of a kind of high-cleanness coloured glaze is provided, not only nontoxic, cleanliness factor is good, and And rigidity, stability and the intensity of coloured glaze are high, physical life length.
In order to solve the above technical problems, one aspect of the present invention is:A kind of high-cleanness coloured glaze is provided, by with The raw material of lower parts by weight is made:Quartz sand 40-50 parts, cosolvent 10-20 parts, oxidant 5-10 parts, fining agent 15-20 parts, Toner 5-10 parts, fluorescent whitening agent 2-3 parts, reinforcing agent 5-8 parts, binding agent 2-5 parts, suspending agent 1-2 parts and colouring aid 1-2 Part;
The quartz sand, the cosolvent and the fining agent three adding proportion sum account for the 55- of gross weight number 70%, the colouring agent, the fluorescent whitening agent, the reinforcing agent and the binding agent adding proportion sum account for gross mass The 15-20% of number;
The parts by weight that the binding agent includes amino acid are 2-5 parts, the parts by weight of phenolic resin are 2-5 parts and organic Bentonitic parts by weight are 2-3 parts.
Further say, the colouring agent includes:The parts by weight of cupric oxide are 1-2 parts, the parts by weight of cuprous oxide Parts by weight for 2-3 parts and cobalt sesquioxide are 3-6 parts.
Further say, the dyeing assistant includes:The parts by weight of hydrogen peroxide are 1-2 parts, the weight of sodium hydroxide The parts by weight that number is 1-2 parts, the parts by weight of sodium dichromate are 2-3 parts and sodium hypochlorite are 1-1.5 parts.
Further say, the fining agent is at least one of antimony oxide or sodium chloride.
Further say, the reinforcing agent is glass fibre or ore deposit fiber.
Further say, the cosolvent includes:The parts by weight of potassium nitrate are 5-10 parts, the parts by weight of sodium sulphate are The parts by weight of 5-8 parts and carbonic acid fiber are 2-5 parts.
Further say, the particle diameter of the quartz sand is 1-2mm.
The beneficial effects of the invention are as follows:
The present invention with the addition of reinforcing agent wherein using quartz sand as primary raw material, and reinforcing agent is that glass fibre or ore deposit are fine Dimension, so as to improve the rigidity of coloured glaze, stability and intensity, can improve the performance and service life of coloured glaze product;Fining agent is Antimony oxide or sodium chloride, nontoxic, cleanliness factor is good;Binding agent is amino acid, phenolic resin and organobentonite, is utilized Organobentonite laminated structure and its it can be swelled in water or organic solvent and be dispersed into colloid, utilize amino acid and phenolic resin shape Into gel, strengthen the intensity of coloured glaze.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that apparent clearly defined so as to be made to protection scope of the present invention.
Embodiment:A kind of high-cleanness coloured glaze, is made up of the raw material of following parts by weight:Quartz sand 40-50 parts, cosolvent 10- 20 parts, oxidant 5-10 parts, fining agent 15-20 parts, colouring agent 5-10 parts, fluorescent whitening agent 2-3 parts, reinforcing agent 5-8 parts, bonding Agent 2-5 parts, suspending agent 1-2 parts and colouring aid 1-2 parts;
The quartz sand, the cosolvent and the fining agent three adding proportion sum account for the 55- of gross weight number 70%, the colouring agent, the fluorescent whitening agent, the reinforcing agent and the binding agent adding proportion sum account for gross mass The 15-20% of number;
The parts by weight that the binding agent includes amino acid are 2-5 parts, the parts by weight of phenolic resin are 2-5 parts and organic Bentonitic parts by weight are 2-3 parts.
The colouring agent includes:The parts by weight of cupric oxide are 1-2 parts, the parts by weight of cuprous oxide are 2-3 parts and three The parts by weight for aoxidizing two cobalts are 3-6 parts.
The dyeing assistant includes:The parts by weight of hydrogen peroxide are 1-2 parts, the parts by weight of sodium hydroxide be 1-2 parts, The parts by weight of sodium dichromate are that the parts by weight of 2-3 parts and sodium hypochlorite are 1-1.5 parts.
The fining agent is at least one of antimony oxide or sodium chloride.
The reinforcing agent is glass fibre or ore deposit fiber.
The cosolvent includes:The parts by weight of potassium nitrate are 5-10 parts, the parts by weight of sodium sulphate are 5-8 parts and carbonic acid The parts by weight of fiber are 2-5 parts.
The particle diameter of the quartz sand is 1-2mm.
The operation principle of the present invention is as follows:The present invention with the addition of reinforcing agent wherein using quartz sand as primary raw material, increase Strong agent is glass fibre or ore deposit fiber, so as to improve the rigidity of coloured glaze, stability and intensity, can improve the performance of coloured glaze product And service life;Fining agent is antimony oxide or sodium chloride, and nontoxic, cleanliness factor is good;Binding agent is amino acid, phenolic aldehyde tree Fat and organobentonite, it can be swelled using organobentonite laminated structure and its in water or organic solvent and be dispersed into colloid, profit Gel is formed with amino acid and phenolic resin, strengthens the intensity of coloured glaze.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair The equivalent structure transformation that bright specification is made, or other related technical areas are directly or indirectly used in, similarly it is included in In the scope of patent protection of the present invention.

Claims (7)

  1. A kind of 1. high-cleanness coloured glaze, it is characterised in that:It is made up of the raw material of following parts by weight:Quartz sand 40-50 parts, cosolvent 10-20 parts, oxidant 5-10 parts, fining agent 15-20 parts, colouring agent 5-10 parts, fluorescent whitening agent 2-3 parts, reinforcing agent 5-8 parts, Binding agent 2-5 parts, suspending agent 1-2 parts and colouring aid 1-2 parts;
    The quartz sand, the cosolvent and the fining agent three adding proportion sum account for the 55-70% of gross weight number, institute State colouring agent, the fluorescent whitening agent, the reinforcing agent and the binding agent adding proportion sum and account for gross mass number 15-20%;
    The parts by weight that the binding agent includes amino acid are 2-5 parts, the parts by weight of phenolic resin are 2-5 parts and organic swelling The parts by weight of soil are 2-3 parts.
  2. A kind of 2. high-cleanness coloured glaze according to claim 1, it is characterised in that:The colouring agent includes:The weight of cupric oxide The parts by weight that amount number is 1-2 parts, the parts by weight of cuprous oxide are 2-3 parts and cobalt sesquioxide are 3-6 parts.
  3. A kind of 3. high-cleanness coloured glaze according to claim 1, it is characterised in that:The dyeing assistant includes:Hydrogen peroxide Parts by weight be 1-2 parts, the parts by weight of sodium hydroxide are 1-2 parts, the parts by weight of sodium dichromate are 2-3 parts and hypochlorous acid The parts by weight of sodium are 1-1.5 parts.
  4. A kind of 4. high-cleanness coloured glaze according to claim 1, it is characterised in that:The fining agent is antimony oxide or chlorine Change at least one of sodium.
  5. A kind of 5. high-cleanness coloured glaze according to claim 1, it is characterised in that:The reinforcing agent is that glass fibre or ore deposit are fine Dimension.
  6. A kind of 6. high-cleanness coloured glaze according to claim 1, it is characterised in that:The cosolvent includes:The weight of potassium nitrate The parts by weight that amount number is 5-10 parts, the parts by weight of sodium sulphate are 5-8 parts and carbonic acid fiber are 2-5 parts.
  7. A kind of 7. high-cleanness coloured glaze according to claim 1, it is characterised in that:The particle diameter of the quartz sand is 1-2mm.
CN201710849460.5A 2017-09-20 2017-09-20 A kind of high-cleanness coloured glaze Pending CN107673598A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710849460.5A CN107673598A (en) 2017-09-20 2017-09-20 A kind of high-cleanness coloured glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710849460.5A CN107673598A (en) 2017-09-20 2017-09-20 A kind of high-cleanness coloured glaze

Publications (1)

Publication Number Publication Date
CN107673598A true CN107673598A (en) 2018-02-09

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108715515A (en) * 2018-08-03 2018-10-30 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set that can improve black tea fragrance and millet paste color and luster
CN108751705A (en) * 2018-07-11 2018-11-06 淄博泰康轻工制品有限公司 Glass or the automatic applique process of pottery
CN108821576A (en) * 2018-08-03 2018-11-16 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set convenient for observing and can be improved oolong tea soup look pool
CN108821577A (en) * 2018-08-03 2018-11-16 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set improving dark green tea millet paste color
CN108863061A (en) * 2018-08-07 2018-11-23 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set that yellow tea fragrance and millet paste color can be improved

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108751705A (en) * 2018-07-11 2018-11-06 淄博泰康轻工制品有限公司 Glass or the automatic applique process of pottery
CN108715515A (en) * 2018-08-03 2018-10-30 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set that can improve black tea fragrance and millet paste color and luster
CN108821576A (en) * 2018-08-03 2018-11-16 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set convenient for observing and can be improved oolong tea soup look pool
CN108821577A (en) * 2018-08-03 2018-11-16 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set improving dark green tea millet paste color
CN108863061A (en) * 2018-08-07 2018-11-23 太仓市高新区青沐文艺创作工作室 A kind of coloured glaze tea set that yellow tea fragrance and millet paste color can be improved

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Application publication date: 20180209