CN107669510A - A kind of hair shield type composition using novel cation shield type agent - Google Patents
A kind of hair shield type composition using novel cation shield type agent Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Abstract
The invention discloses a kind of hair shield type composition using novel cation shield type agent, including following weight percent composition：0.1 3.0% acrylate crosspolymers；0.1 0.3% hydroxyethyl cellulose；0.5 3.0% NMF；0.3 2.5% hydrophilic modifying grease；0.2 2.0% cation shield type agent；0.01 0.5% solubilizer；Surplus is water.This hair shield type composition using working substance deposition technique, is effectively improved grease deposition efficiency, is improved hair glossiness, it is low and deep that long-term use will not cause hair to dry up using the grease of cationic system collocation hydrophilic modifying.Solve " playing white bits " that current shield type product occurs, " hair is dry and astringent ", the problems such as " conditioning performance is poor ".
Description
Technical field
The present invention relates to cosmetic field, and in particular to a kind of hair shield type using novel cation shield type agent combines
Thing.
Background technology
At present, hair shield type cosmetics on the market are divided into three major types, and the first kind is traditional hair jelly, it main
Raw material is that organic solvent such as ethanol adds resin, high polymer film forming agent, adds Throwing to penetrate agent and initiates merely strong so that Sprayable is correct
Shield type acts on, and it belongs to dry type crosspoint shield type, does not possess hair care function typically.Second class is mousse, it have concurrently shield type and
Hair care function, ethanol as solvent is added typically in preparation or makees solubilizer, added Throwing to penetrate agent and spray bubble Droplets shapes to hair progress
Shield type, this shield type Li wrap up shield type in wet type.3rd class is gel, and its preparation is to select the raw material with thinly-sliced change fluidity
A kind of transparent colloid of stiff is made, is acted on pump type pressure spray form on hair quality, selection of this product to manual pump mouth has
Certain limitation, this shield type belong to dry-and wet-type parcel shield type.Qu be the above this it is several hair care shield type cosmetics have it can not
All being closed in the shortcomings that overcoming, especially first kind hair jelly and the second class mousse has ethanol, and the presence of ethanol can bring many bad
Consequence.First, ethanol and water have the intermiscibility of unlimited ratio and strong volatility, and it is contacted with hair quality will destroy hair quality
The water weighing apparatus of itself, and produces phenomenon of losing water, long-term use close ethanol hair cosmetic can make hair become withered and yellow, jag,
Embrittlement and it is easily broken；Secondly as ethanol has extremely strong permeability and degreasing, penetrated into quickly inside hair quality after being contacted with hair,
Cutin-softening layer, hair is become loose, largely damage the health of hair；3rd, due to the above-mentioned spy of ethanol
Property, the moisture-keeping functions of other hair cosmetics are also have impact on, weaken the hair care effect of hair care product in itself.
Further, since above-mentioned traditional hair jelly class and mousse class close substantial amounts of volatile organic components, therefore the safety used
Property it is poor, if using or storage it is improper, easily occur unexpected, jeopardize personal safety, cause environmental pollution.
The content of the invention
The technical problems to be solved by the invention are in view of the deficienciess of the prior art, providing a kind of different from above-mentioned
A kind of hair shield type composition of hair shield type cosmetics, it is free of ethanol, is pure water based composition and use thereof in packaging, and there is seldom organic to wave
Composition is sent out, is applied to using conventional pump pump head with hand on hair, the protection of layer of transparent can be formed on the hair of user
Film.The grease of cationic system collocation hydrophilic modifying, using working substance deposition technique, effectively improves grease deposition efficiency, improves
Hair glossiness, it is low and deep that long-term use will not cause hair to dry up.Solve " playing white bits " that current shield type product occurs, " head
It is dry puckery ", the problems such as " conditioning performance is poor ".
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of hair shield type composition using novel cation shield type agent, including following weight percent composition：
0.1-3.0% acrylate crosspolymers；
0.1-0.3% hydroxyethyl cellulose；
0.5-3.0% NMF；
0.3-2.5% hydrophilic modifying grease；
0.2-2.0% cation shield type agent；
0.01-0.5% solubilizer；
Surplus is water.
Further, the additive of following percentage by weight is included：
0.02-0.1% chelating agent；
0.001-0.1% conditioner；
0.02-0.5% preservative；
0.001-1% essence.
Further, described acrylate crosspolymers are selected from acrylic acid（Ester）Analog copolymer, carbomer, acrylic acid
（Ester）At least one of class/C10-30 alkylol acrylamide acid esters cross-linked polymers.Select the purpose of such polymer：1. stabilization
System, there is provided viscosity.2. make product appearance transparency higher.Wherein, preferred mass ratio is 3:1 carbomer：Acrylic acid（Ester）
Class/C10-30 alkylol acrylamide acid esters cross-linked polymer combination.
Further, described NMF is selected from least one of polyethylene glycol, glycerine, propane diols, Natrulon H-10.
Wherein, preferred mass ratio is 2:1 propane diols：Natrulon H-10 combines, and moisturizing will not produce glutinous soapy feeling simultaneously.
Further, described hydrophilic modifying grease is selected from olive oil PEG-7 esters, PEG-6 caprylic/capric glyceride
At least one of class, PEG-7 glyceryl cocoates, glyceryl oleate.Compared with non-hydrophilic modified grease, this quasi-grease energy
Keep product appearance it is transparent, while can poppet shampoo humidity, glossiness, and product smear feel, shortcoming be not easy it is attached
On hair, be not easy to be resident during smearing, the lifting that produces appreciable results is difficult under normal service condition.Therefore need to by with
Above-mentioned cation shield type agent collocation, using working substance deposition technique, improves this quasi-grease deposition efficiency.Utilize cation shield type agent
Combined with hydrophilic modifying grease and to form working substance carrier and can bring the effect of fairly obvious instant conditioning.
Further, described cation shield type agent is selected from acrylic acid（Ester）Analog copolymer AMP salt, polyquaternium -4,
At least one of Polyquaternium-67.The cation shield type agent be supplied to product be better than presently commercially available shield type product performance,
While having shield type effect, white bits are not played, and hair is glossy, can plastotype repeatedly.And be water-soluble material, avoid making using ethanol
Hair is damaged for solvent and solubilizer
Further, described solubilizer be selected from PEG-40 rilanit specials, PEG-60 rilanit specials, Tween-20,
At least one of Tween-40.
Further, described chelating agent is in disodium EDTA, the disodium salt of ethylenediamine tetra-acetic acid four
It is at least one.
Further, described conditioner is selected from pomegranate rind extract, tea seed extract, soapberry fruit extract, transparent
At least one of matter acid sodium, sugar Thallus Laminariae (Thallus Eckloniae) extract.Described conditioner contains the hydrophilic radicals such as hydroxyl, amino and carboxyl,
With being in the surface of molecule stereo structure as moisturizing factor, thus also there is good moisture-keeping function, their moisture retention is not
By environment（Temperature, humidity）Influence.
Further, described preservative is selected from dimethyloldimethylhydantoin, methylisothiazolinone, to hydroxyl
At least one of methyl benzoate, propylparaben, Phenoxyethanol, phenmethylol, Geogard 221.
The present invention has the advantages that：
The present invention is a kind of hair shield type composition using novel cation shield type agent, and with novel cation, composition is applied
Hair can be made to form a kind of transparent diaphragm after using on hair, there is good gas permeability, keep the preferable moulding of hair
With good cardability, make hair quality bright, wetting, and with the effect for disturbing the injury of ultraviolet and other chemical substances to hair quality
Fruit.And can have good shield type, performance of keeping humidity, while have appropriate hair conditioning ability, white bits will not be produced, and gently not
Stimulate.Using pure water basigamy system, without ethanol, manufactured hair cosmetic quality is tended to be gentle, hair quality is not formed
Injury, it can reach and double hairdressing, the function of hair care.
Using working substance deposition technique, it is possible to increase hydrophilic modifying grease deposition efficiency.Utilize cation shield type agent and parent
Water modified grease combines to form working substance carrier, and adsorption mechanism of the carrier on hair is " solid floccules deposition " and " become muddy
Turbid flocculate Electrostatic Absorption ", this make it that the deposition of cation shield type agent is selective, when carrier is inhaled by Coulomb force electrostatic
After being attached on hair, the negative electrical charge on hair is reduced, and those carriers adsorbed by Coulomb force, which just adsorb, no longer to be adsorbed, so as to
Control the absorption of carrier.To hair carry come it is good protect type effect and glossiness, while lifting feel, will not over-deposit,
Cause the discomfort such as greasy.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
A kind of hair shield type composition using novel cation shield type agent of embodiment 1
Following each components are mixed according to the following formulation：
Amounts of components（Gram)
Carbomer 3.0；
Hydroxyethyl cellulose 0.3；
Glycerine 3.0；
Polyquaternium -4 2.0；
PEG-6 caprylic/caprics glyceride type 2.5；
Disodium EDTA 0.02；
PEG-60 rilanit specials 0.01；
Methylisothiazolinone 0.08；
Tea seed extract 0.01, soapberry fruit extract 0.05；
Water 89.03.
After mixing each component, a kind of hyalomucoid is made after aging is stood, specific preparation method is that this area is public
Know general knowledge, do not illustrate herein.
It will obtain obtaining preferable shield type effect after thing is applied on hair using conventional pump pump head with hand.
A kind of hair shield type composition using novel cation shield type agent of embodiment 2
Following each components are mixed according to the following formulation：
Amounts of components（Gram)
Carbomer 2.0；
Hydroxyethyl cellulose 0.3；
Propane diols 3.0；
Polyquaternium -4 2.0；
Olive oil PEG-7 esters 2.0；
Disodium EDTA 0.02；
PEG-60 rilanit specials 0.01；
Methylisothiazolinone 0.08；
Essence 0.1；
Pomegranate rind extract 0.1；
Water 90.39.
After mixing each component, a kind of hyalomucoid is made after Over emulsfication and aging are stood, thing will be obtained and use conventional pumps
The shield type effect that formula pump head is doubled after being applied to hand on hair.
A kind of hair shield type composition using novel cation shield type agent of embodiment 3
Following each components are mixed according to the following formulation：
Amounts of components（Gram)
Acrylic acid（Ester）Class/C10-30 alkylol acrylamide acid esters cross-linked polymer 0.7；
Carbomer 2.1；
Hydroxyethyl cellulose 0.3；
Propane diols 2.0；
Natrulon H-10 1.0；
Olive oil PEG-7 esters 2.0；
Disodium EDTA 0.02；
PEG-60 rilanit specials 0.01；
Methylisothiazolinone 0.08；
Pomegranate rind extract 0.001, Sodium Hyaluronate 0.001, sugar Thallus Laminariae (Thallus Eckloniae) extract 0.001；
Water 91.787.
After mixing each component, a kind of hyalomucoid is made after Over emulsfication and aging are stood, thing will be obtained and use conventional pumps
The shield type effect that formula pump head is doubled after being applied to hand on hair.
A kind of hair shield type composition of the not cation of comparative example 1
Following each components are mixed according to the following formulation：
Amounts of components（Gram)
Hydroxyethyl cellulose 0.3；
Propane diols 3.0；
Polyvinylpyrrolidone 2.0；
Disodium EDTA 0.02；
PEG-60 rilanit specials 0.01；
Methylisothiazolinone 0.08；
Water.
After mixing each component, a kind of hyalomucoid is made after Over emulsfication and aging are stood, thing will be obtained and use conventional pumps
The shield type effect that formula pump head is doubled after being applied to hand on hair.
The effect of to above-mentioned 4 compositions, carries out instrument efficacy assessment, two methods of human body evaluation carry out effect and commented
Estimate, arbitrarily select 32 volunteers and more than use carry out sensory experience assessment after 4 compositions respectively, finally draw such as the institute of table 1
Show average result.
Table 1：The effect of embodiment and comparative example, assesses test result
| Assessment item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Hair gloss | 1.5 | 1.8 | 1.6 | 1.2 |
| Bend work(conservation rate（Data after five tests） | 42% | 50% | 45% | 38% |
| Do work value（MJ） | 1.8 | 2.2 | 2.5 | 1.6 |
| Amount of bow（MM） | 22 | 25 | 25 | 22 |
| Bending resistance deformation recovery rate | 89% | 93% | 95% | 70% |
| Shape the duration（Hour） | 5 | 8 | 10 | 4 |
| Tester's usage experience is assessed | 8 | 9 | 9 | 7 |
From above test data, embodiment 1-3 employs present composition raw material composition and configuration proportion is prepared into
The sizing class product arrived, there is synergistic function between raw material, for comparative example, tool is significantly improved glossiness
Effect, and secondary modeling ability is strong.The hair style retention time is longer, is all better than commercial approved product in terms of user's experience sense.Its
In in 3 embodiments, the best results of embodiment 2.
Instrument efficacy assessment method takes the testing standard of our company：HAB/R-WI-125《Hair cosmetic efficacy assessment
Method》；
HAB/R-WI-135《The test of hair three-point bending performance》；HAB/R-WI-136《The test of hair gloss》, briefly
Test specification is as follows：
Hair weight：2.12g ；It is long：20cm；It is wide：3 cm
Amount of samples：0.424g (the 20% of hair weight)
Sample treatment：A branch of hair piece is taken, long 20cm is cut to, wide 3cm hair piece, weighs, is drenched with clear water by piece is sent out, dried in the air to half
It is dry standby；0.424g samples are weighed with Subtraction method to be put on forefinger, and sample is uniformly applied on hair piece with forefinger and thumb, will
Hair piece is placed on 24 ± 1 DEG C, and 50 ± 5RH% of humidity space is placed 5 hours, then carries out constancy test.
Claims (10)
1. a kind of hair shield type composition using novel cation shield type agent, it is characterised in that including following percentage by weight
Component：
0.1-3.0% acrylate crosspolymers；
0.1-0.3% hydroxyethyl cellulose；
0.5-3.0% NMF；
0.3-2.5% hydrophilic modifying grease；
0.2-2.0% cation shield type agent；
0.01-0.5% solubilizer；
Surplus is water.
2. the hair shield type composition according to claim 1 using novel cation shield type agent, it is characterised in that also wrap
Include the additive of following percentage by weight：
0.02-0.1% chelating agent；
0.001-0.1% conditioner；
0.02-0.5% preservative；
0-1% essence.
3. the hair shield type composition according to claim 1 or 2 using novel cation shield type agent, it is characterised in that
Described acrylate crosspolymers are selected from acrylic acid（Ester）Analog copolymer, carbomer, acrylic acid（Ester）Class/C10-30 alkane
At least one of alcohol acrylate crosspolymers.
4. the hair shield type composition according to claim 1 or 2 using novel cation shield type agent, it is characterised in that
Described NMF is selected from least one of polyethylene glycol, glycerine, propane diols, Natrulon H-10.
5. the hair shield type composition according to claim 1 or 2 using novel cation shield type agent, it is characterised in that
Described hydrophilic modifying grease is selected from olive oil PEG-7 esters, PEG-6 caprylic/caprics glyceride type, PEG-7 glycerine cocounut oil
At least one of acid esters, glyceryl oleate.
6. the hair shield type composition according to claim 1 or 2 using novel cation shield type agent, it is characterised in that
Described cation shield type agent is selected from acrylic acid（Ester）In analog copolymer AMP salt, polyquaternium -4, Polyquaternium-67 extremely
Few one kind.
7. the hair shield type composition according to claim 1 or 2 using novel cation shield type agent, it is characterised in that
Described solubilizer in PEG-40 rilanit specials, PEG-60 rilanit specials, Tween-20, Tween-40 extremely
Few one kind.
8. the hair shield type composition according to claim 2 using novel cation shield type agent, it is characterised in that described
Chelating agent be selected from disodium EDTA, at least one of disodium salt of ethylenediamine tetra-acetic acid four.
9. the hair shield type composition according to claim 2 using novel cation shield type agent, it is characterised in that described
Conditioner in pomegranate rind extract, tea seed extract, soapberry fruit extract, Sodium Hyaluronate, sugar Thallus Laminariae (Thallus Eckloniae) extract
At least one.
10. the hair shield type composition according to claim 2 using novel cation shield type agent, it is characterised in that institute
The preservative stated is selected from dimethyloldimethylhydantoin, methylisothiazolinone, methyl p-hydroxybenzoate, para hydroxybenzene
At least one of propyl formate, Phenoxyethanol, phenmethylol, Geogard 221.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710757716.XA CN107669510A (en) | 2017-08-29 | 2017-08-29 | A kind of hair shield type composition using novel cation shield type agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710757716.XA CN107669510A (en) | 2017-08-29 | 2017-08-29 | A kind of hair shield type composition using novel cation shield type agent |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101444464A (en) * | 2008-12-29 | 2009-06-03 | 广东拉芳日化有限公司 | Emulsified elastin composition |
| CN102697673A (en) * | 2012-06-25 | 2012-10-03 | 澳宝化妆品（惠州）有限公司 | Hair-used shaping composition applying novel cations |
| CN106619312A (en) * | 2017-01-11 | 2017-05-10 | 广州温雅日用化妆品有限公司 | Elastin composition |
-
2017
- 2017-08-29 CN CN201710757716.XA patent/CN107669510A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101444464A (en) * | 2008-12-29 | 2009-06-03 | 广东拉芳日化有限公司 | Emulsified elastin composition |
| CN102697673A (en) * | 2012-06-25 | 2012-10-03 | 澳宝化妆品（惠州）有限公司 | Hair-used shaping composition applying novel cations |
| CN106619312A (en) * | 2017-01-11 | 2017-05-10 | 广州温雅日用化妆品有限公司 | Elastin composition |
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