CN107668035A - A kind of composition pesticide and its application on moss is removed - Google Patents

A kind of composition pesticide and its application on moss is removed Download PDF

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Publication number
CN107668035A
CN107668035A CN201710977791.7A CN201710977791A CN107668035A CN 107668035 A CN107668035 A CN 107668035A CN 201710977791 A CN201710977791 A CN 201710977791A CN 107668035 A CN107668035 A CN 107668035A
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China
Prior art keywords
moss
composition pesticide
pesticide
active component
composition
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Pending
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CN201710977791.7A
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Chinese (zh)
Inventor
邓建华
颜亚奇
李锐
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Sichuan Guoguang Agrochemical Co Ltd
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Sichuan Guoguang Agrochemical Co Ltd
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Priority to CN201710977791.7A priority Critical patent/CN107668035A/en
Publication of CN107668035A publication Critical patent/CN107668035A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/08Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention discloses a kind of application of composition pesticide on moss is removed, and the composition pesticide includes:Active components A and active component B;Wherein, the active components A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is acceptable salt in OIT and its Pesticide Science;The active components A and the active component B weight ratio are 1:0.1‑2.The application provides a kind of composition pesticide and its application on moss is removed, said composition can on the basis of effectively tea tree moss is removed, have the advantages that it is efficient, environment-friendly, adverse effect will not be brought to growth of tea plant.

Description

A kind of composition pesticide and its application on moss is removed
Technical field
The present invention relates to technical field of pesticide, and in particular to a kind of composition pesticide and its application on moss is removed.
Background technology
In the season of damp warm, moss is easily grown on tea tree, and growth harm of the moss to tea tree is huge, it is mainly endangered Evil have it is following some:1) photosynthesis and gas exchanges of plant are influenceed.The moss being grown on blade will directly affect leaf Piece is photosynthetic to be normally carried out, so as to influence the normal growth of plant;And branch, the excessively vigorous moss of dry above growth can also lead to Cross hinder branch, stem organization gas exchanges and light absorption and influence branch or dry normal growth, it is small to result even in some The death of branch.2) young sprout germination is influenceed.If the moss being covered on branches and leaves is overstocked, leaf bud can be caused normally can not to sprout or push away Sprout late, promote the decline progress faster of tea tree.3) moss is that disease pest grows the condition that creates on tea tree, aggravates tea place pest and disease damage Generation.4) quality of tealeaves is reduced.The moss contaminated on tealeaves is difficult to peel off, and into tea product, reduces tea product Quality.
Traditional moss removed on tea tree is frequently with following reagent, such as soda quick lime mixture, 45% resin soap emulsifiable concentrate, stone Sulphur mixture, Bordeaux mixture, 45% ambam aqua, ziram, ferrous sulfate, glyphosate etc., and soda quick lime mixture, 45% Resin soap emulsifiable concentrate, lime sulfur, Bordeaux mixture are Basic pesticides, and the corrosion to tea tree is big, and can only be used in tea tree dormancy season;Good fortune U.S. zinc, ferrous sulfate activity are low, and usage amount is big, and the lasting period is short;There is glyphosate interior suction to kill root characteristics, the life to tea tree to tea tree Length is unfavorable.
The content of the invention
In view of this, the application provides a kind of composition pesticide and its application on moss is removed, and said composition can be Effectively remove tea tree moss on the basis of, have the advantages that it is efficient, environment-friendly, adverse effect will not be brought to growth of tea plant.
To solve above technical problem, technical scheme provided by the invention is a kind of composition pesticide on moss is removed Using the composition pesticide includes:Active components A and active component B;Wherein, the active components A is S-Ethyl ethylthio sulfonate and its agriculture Pharmaceutically acceptable salt, active component B are acceptable salt in OIT and its Pesticide Science;The active components A and The active component B weight ratio is 1: 0.1-2.
Preferably, the moss is the moss on tea tree.
A kind of composition pesticide, the composition pesticide include:Active components A and active component B;Wherein, the activity Composition A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is acceptable in OIT and its Pesticide Science Salt;The active components A and the active component B weight ratio are 1:0.1-2.
Preferably, the active components A and the active component B weight ratio are 1:0.1-1.
Preferably, the active components A and the active component B weight ratio are 1:0.4-0.8.
Preferably, the active components A and the active component B content summation in the composition pesticide are 50%- 80%.
Preferably, the composition pesticide also includes acceptable auxiliary material in Pesticide Science.
Preferably, the composition pesticide includes S-Ethyl ethylthio sulfonate and OIT.
Preferably, the formulation of the composition pesticide is pulvis, granule, wettable powder or water dispersible granules.
A kind of method for removing moss on tea tree, including:Using composition pesticide described in any of the above-described, and applied In on tea tree to remove moss.
Preferably, the application process includes spraying, atomizing, dusts, soaks, spreads fertilizer over the fields or pour.
The invention provides a kind of composition of removable tea tree moss, the composition pesticide includes:Active components A and Active component B;Wherein, the active components A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is isothiazole Acceptable salt on quinoline ketone and its Pesticide Science;The active components A and the active component B weight ratio are 1: 0.1-2.The application The active component of composition pesticide is can in acceptable salt and OIT and its Pesticide Science in S-Ethyl ethylthio sulfonate and its Pesticide Science The salt of receiving;Wherein, acceptable salt is a kind of Effictive nuisancelless wide spectrum bionic fungicide in S-Ethyl ethylthio sulfonate and its Pesticide Science, is had concurrently Plant growth regulation, rudiment can be promoted, improve germination percentage, increase yield and improving quality, the oxygen atom of itself can be with Sulfydryl in cysteine molecule necessary to cell growth breeding is combined, and suppresses the growth and breeding of cell;It is same with this When, because moss institutional framework is lower than tea tree, when both contact with S-Ethyl ethylthio sulfonate simultaneously, S-Ethyl ethylthio sulfonate elder generation and cell growth in moss Sulfydryl in cysteine molecule necessary to breeding is combined, and suppresses the growth of moss, makes growth of tea plant unaffected;This Outside, the S-Ethyl ethylthio sulfonate position prevention effect dense to branches and leaves is also relatively good, and moss is removed without illumination can after medication.The application Also propose to remove tea tree moss using acceptable salt on OIT and its Pesticide Science, OIT belongs to biosynthesis Inhibitor, it is heterocycle compound, it is by the active part on heterocycle and the base shape on DNA molecular in moss internal protein Into hydrogen bond, and it is adsorbed on the cell of moss, plays a part of attack cells nucleophilic, so as to destroys the intracellular DNA knots of moss Structure, it is lost replication capacity, lose relevant physiological, biochemical reaction and metabolic activity;OIT is also blue or green by disconnecting The protein key of tongue and make cell death.The application reaches and effectively removed on tea tree by the way that two active components are used in combination Purpose of the moss without influenceing growth of tea plant, while the addition of OIT can reduce the use of S-Ethyl ethylthio sulfonate, and with certain Synergistic effect, also the growth of tea tree can be prevented to be affected.
The positive achievement that the present invention obtains is:
The application proposes a kind of composition for being applied to remove moss on tea tree, and said composition includes S-Ethyl ethylthio sulfonate and its agricultural chemicals Acceptable salt has not only acted as synergy with acceptable salt, both compound uses on OIT and its Pesticide Science on Effect, and also reduce the use of S-Ethyl ethylthio sulfonate, reduce influence of the agricultural chemicals to growth of tea plant while moss is removed.
Embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment pair The present invention is described in further detail.
Chemical synthetic pesticide is put into one of most important invention of mankind's twentieth century, in preventing and treating crop disease, worm, grass Evil, ensure crops normal growth, improve and played a significantly greater role in per mu yield.According to statistics, in China's grain-production activity, By being prevented using agricultural chemicals to pest and disease damage, 15,000,000,000 kilograms of grain loss can be reduced every year, is made that for China's agricultural production huge Big contribution, but due to not scientifical use chemical pesticide for a long time, phytopathogen, insect and weeds is generated the resistance to the action of a drug, Soil and water source are contaminated, pesticide residue in agricultural products increase, endanger the health of people.Insect is also killed simultaneously Natural enemy and other beneficial organisms, destroy the ecological balance.Increase with the species of agricultural chemicals, usage amount is continuously increased, distribution Agricultural chemicals in soil, air and water body may all have an impact to non-target organism, and by biological magnification by eating Thing chain directly influences the whole ecosystem.Residue problem of the agricultural chemicals in food and the influence to environmental quality and human health Problem also becomes increasingly conspicuous.
Acceptable salt is a kind of efficient, low toxicity, the organic sulfur of low-residual of China's exploitation on S-Ethyl ethylthio sulfonate and its Pesticide Science Bactericide, its sterling are colorless oil transparency liquid, there is garlic and acetic acid stink, strong volatility.- S-S- groups in S-Ethyl ethylthio sulfonate With can be in phage molecule SH bases react, and suppress thalline eubolism.Zhao Yongjing, open big etc. have studied and second is applied on rice After allicin, it can effectively prevent and treat rice disease, especially in Rise's boot period, heading spray at initial stage, can effectively prevent and treat rice Leaf pest, fringe pest, sheath rot disease, brown sheath disease, brown stain fringe, brown stain granulosis evil, preventive effect is up to 87.3%-93.3%.Isothiazoline Acceptable salt has very strong antibacterial ability on ketone and its Pesticide Science, and compatibility is good, and toxicity is low, can simultaneously to various bacteria, Fungi has very strong antibacterial action, and it is non-oxygen type bactericide, is heterocycle compound, and it can pass through the active portion on heterocycle Point with the base new city hydrogen bond in bacterium vivo protein, and destroy intracellular DNA structure, it is lost replication capacity and is led Cause cell death.MorleyJO etc. passes through the research to electronic structure characteristic, it is believed that the sterilization machine of isothiazolinone derivative Reason is:Bactericide enters phage molecule through cell membrane and cell membrane, and is reacted with composition of the intramolecular containing sulfydryl, so as to Make cell death, following formula is the reaction equation of isothiazolinone compound and glutathione:R in formula1Or R2Can be identical or not Together, it also can be H, halogen, C1-C4Alkyl.
The application proposes a kind of composition pesticide, and the active component of the composition is that can be connect in S-Ethyl ethylthio sulfonate and its Pesticide Science The salt received and acceptable salt on OIT and its Pesticide Science, active component in two are carried out removable tea tree is used in combination On moss, while can also reduce the use of S-Ethyl ethylthio sulfonate, be had an impact to prevent the growth to tea tree.
The application that technical scheme provided by the invention is a kind of composition pesticide on moss is removed, the composition pesticide Including:Active components A and active component B;Wherein, the active components A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, living Property composition B be acceptable salt in OIT and its Pesticide Science;The active components A and the active component B weight ratio For 1: 0.1-2;Wherein, the moss is the moss on tea tree.
A kind of composition pesticide, the composition pesticide include:Active components A and active component B;Wherein, the activity Composition A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is acceptable in OIT and its Pesticide Science Salt;The active components A and the active component B weight ratio are 1: 0.1-2;Wherein, the active components A and it is described activity into It is 1: 0.1-1 to divide B weight ratio;The active components A and the active component B weight ratio are 1: 0.4-0.8;The active component A and active component B content summations in the composition pesticide are 50%-80%;The composition pesticide also includes agriculture Pharmaceutically acceptable auxiliary material;The formulation of the composition pesticide is pulvis, granule, wettable powder or water dispersible granules.
A kind of method for removing moss on tea tree, including:Using composition pesticide any one of claim 3-8, And it is applied on tea tree to remove moss;Wherein, the application process include spraying, atomizing, dust, soak, spreading fertilizer over the fields or Pour.
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described, it is clear that Described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the implementation in the present invention Example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, is belonged to The scope of protection of the invention.
Embodiment 1:
A kind of composition pesticide, the composition pesticide include active components A and active component B;Wherein, it is described activity into It is S-Ethyl ethylthio sulfonate to divide A, and active component B is OIT, and the active components A and the active component B weight ratio are 1: 0.1, Meanwhile it is calculated in mass percent, the active components A and the active component B content summation in the composition pesticide 60%;The formulation of the composition pesticide is wettable powder.
Above-mentioned composition is sprayed on tea tree at moss by the method for application of spraying, the results showed that, above-mentioned composition Growth of the tea tree moss without influenceing tea tree can effectively be removed.
Embodiment 2:
A kind of composition pesticide, the composition pesticide include active components A and active component B;Wherein, it is described activity into It is S-Ethyl ethylthio sulfonate to divide A, and active component B is OIT, and the active components A and the active component B weight ratio are 1: 0.4, Meanwhile it is calculated in mass percent, the active components A and the active component B content summation in the composition pesticide 65%;The formulation of the composition pesticide is pulvis.
Above-mentioned composition is sprayed on tea tree at moss by the method for application of spraying, the results showed that, above-mentioned composition Growth of the tea tree moss without influenceing tea tree can effectively be removed.
Embodiment 3:
A kind of composition pesticide, the composition pesticide include active components A and active component B;Wherein, it is described activity into It is S-Ethyl ethylthio sulfonate to divide A, and active component B is OIT, and the active components A and the active component B weight ratio are 1: 0.6, Meanwhile it is calculated in mass percent, the active components A and the active component B content summation in the composition pesticide 80%;The formulation of the composition pesticide is water dispersible granules.
Above-mentioned composition is sprayed on tea tree at moss by the method for application of spraying, the results showed that, above-mentioned composition Growth of the tea tree moss without influenceing tea tree can effectively be removed.
Embodiment 4:
A kind of composition pesticide, the composition pesticide include active components A and active component B;Wherein, it is described activity into It is S-Ethyl ethylthio sulfonate to divide A, and active component B is OIT, and the active components A and the active component B weight ratio are 1: 0.8, Meanwhile it is calculated in mass percent, the active components A and the active component B content summation in the composition pesticide 50%;The formulation of the composition pesticide is granule.
Above-mentioned composition is sprayed on tea tree at moss by the method for application of spraying, the results showed that, above-mentioned composition Growth of the tea tree moss without influenceing tea tree can effectively be removed.
Embodiment 5:
A kind of composition pesticide, the composition pesticide include active components A and active component B;Wherein, it is described activity into It is S-Ethyl ethylthio sulfonate to divide A, and active component B is OIT, and the active components A and the active component B weight ratio are 1: 2, together When, it is calculated in mass percent, the active components A and the active component B content summation in the composition pesticide 70%;The formulation of the composition pesticide is granule.
Above-mentioned composition is sprayed on tea tree at moss by the method for application of spraying, the results showed that, above-mentioned composition Growth of the tea tree moss without influenceing tea tree can effectively be removed.
Embodiment 6:
Colby equations determine effect experiment
1st, test material:Moss on tea tree
2nd, experimental design:13 processing of experimental design, and blank control processing is set, each processing is repeated 4 times, totally 56 small Area, plot area 112m2, random district's groups arrangement.Per minizone every 20cm.
3rd, efficacy survey:30th day investigation drug effect after dispenser, by 0 (no moss), 1 (1%~10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76% ~100% moss is covered with tea tree) level grade scale.Each cell chooses 5 points, and each point is investigated in the range of 0.4m2 to be recorded Each processing cell moss occurs series and compares calculating preventive effect.
4th, data statistic analysis:Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data Go out to calculate removal effect T.
Removal effect calculation formula:T=(C0-C1)/C0×100
In formula:T --- removal effect %.
C0--- the average series of blank district.
C1--- chemicals treatment district averaging.
5th, evaluation method:The clearance E (%) after theoretical use with is obtained using Colby formula.Practical measurement it is mixed after Deliberated index T compared with the theory index E that Colby formula are drawn, actual value be more than theoretical value 12% be Synergistic Effect, actual value is more than effect for addition of the difference between 0% -12% of theoretical value, and actual value is less than theoretical value For antagonism.
Colby formula:E=x+y-xy/100;X, y is the actual clearance obtained by the alone each component of difference.
6th, measurement result
1 single medicine of table or composition are applied to the result of the test of tea tree moss
The present embodiment is to contrast S-Ethyl ethylthio sulfonate, OIT and S-Ethyl ethylthio sulfonate and OIT complexing agent to tea tree moss Removal effect, result of the test shows that the removal effect of more single dose of the removal effect of complexing agent is good, meanwhile, S-Ethyl ethylthio sulfonate with it is different The weight ratio of thiazolinone has compound synergic effect in the range of 1: 0.1-2,1:Synergistic effect is optimal when 0.4.
Embodiment 7:
1st, test material:Moss on tea tree
2nd, experimental design:3 processing of experimental design, and blank control processing is set, each processing is repeated 4 times, totally 16 cells, Plot area 32m2, random district's groups arrangement.Per minizone every 20cm.
3rd, efficacy survey:30th day investigation drug effect after dispenser, by 0 (no moss), 1 (1%~10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~5% moss cakings), 9 (76% ~100% moss is covered with lawn) level grade scale.Each cell chooses 5 points, and each point is in 0.4m2In the range of investigate record Each processing cell moss occurs series and compares calculating preventive effect.
4th, data statistic analysis:Analyzed using DPS6.55 (Duncan) statistical software.Calculated according to test data Go out to calculate removal effect T.
Removal effect calculation formula:T=(C0-C1)/C0×100
In formula:T --- removal effect %.
C0--- the average series of blank district.
C1--- the average series of chemicals treatment district.
Removal effect of the table 2 for contrast S-Ethyl ethylthio sulfonate, OIT with both complex compositions to moss
Wherein, the weight of S-Ethyl ethylthio sulfonate and OIT ratio is 1: 0.4.
By contrasting the removal effect of S-Ethyl ethylthio sulfonate, OIT and both complex compositions to tea tree moss, it is possible to find, Both have obvious removal effect by complex composition compared with single compound, and clearance is up to more than 98%.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch and also should be regarded as protection scope of the present invention.

Claims (10)

1. application of a kind of composition pesticide on moss is removed, it is characterised in that the composition pesticide includes:Active component A and active component B;Wherein, the active components A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is different thiophene Acceptable salt on oxazoline ketone and its Pesticide Science;The active components A and the active component B weight ratio are 1:0.1-2.
A kind of 2. application of the composition pesticide according to claim 1 on moss is removed, it is characterised in that the moss For the moss on tea tree.
3. a kind of composition pesticide, it is characterised in that the composition pesticide includes:Active components A and active component B;Wherein, The active components A is acceptable salt in S-Ethyl ethylthio sulfonate and its Pesticide Science, and active component B is in OIT and its Pesticide Science Acceptable salt;The active components A and the active component B weight ratio are 1:0.1-2.
A kind of 4. composition pesticide according to claim 3, it is characterised in that the active components A and it is described activity into It is 1 to divide B weight ratio:0.1-1.
A kind of 5. composition pesticide according to claim 3, it is characterised in that the active components A and it is described activity into It is 1 to divide B weight ratio:0.4-0.8.
A kind of 6. composition pesticide according to claim 3, it is characterised in that be calculated in mass percent, it is described activity into It is 50%-80% to divide A and active component B content summations in the composition pesticide.
7. a kind of composition pesticide according to claim 3, it is characterised in that the composition pesticide also includes Pesticide Science Upper acceptable auxiliary material.
8. a kind of composition pesticide according to claim 3, it is characterised in that the formulation of the composition pesticide is powder Agent, granule, wettable powder or water dispersible granules.
A kind of 9. method for removing moss on tea tree, it is characterised in that including:Using agriculture any one of claim 3-8 Drug composition, and be applied on tea tree to remove moss.
A kind of 10. method for removing moss on tea tree according to claim 9, it is characterised in that the application process bag Spraying, atomizing are included, dusts, soak, spread fertilizer over the fields or pours.
CN201710977791.7A 2017-10-17 2017-10-17 A kind of composition pesticide and its application on moss is removed Pending CN107668035A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106359405A (en) * 2016-11-11 2017-02-01 江苏辉丰农化股份有限公司 Bactericide composition containing benzisothiazolone and ethylicin

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106359405A (en) * 2016-11-11 2017-02-01 江苏辉丰农化股份有限公司 Bactericide composition containing benzisothiazolone and ethylicin

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
揭益寿等: "《中国农业发展模式创新与农业现代化》", 31 January 2013, 中国矿业大学出版社 *
李本高等: "《现代工业水处理技术与应用》", 30 June 2004, 中国石化出版社 *

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