CN107663436A - A kind of response type laminated adhesive production technology for non-bituminous waterproof roll - Google Patents
A kind of response type laminated adhesive production technology for non-bituminous waterproof roll Download PDFInfo
- Publication number
- CN107663436A CN107663436A CN201610611653.2A CN201610611653A CN107663436A CN 107663436 A CN107663436 A CN 107663436A CN 201610611653 A CN201610611653 A CN 201610611653A CN 107663436 A CN107663436 A CN 107663436A
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- CN
- China
- Prior art keywords
- petropols
- laminated adhesive
- reactor
- response type
- sbs
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of response type laminated adhesive production technology for non-bituminous waterproof roll, its feature is that its component matches by mass percentage and is：SIS：18~25%, SBS：3~8%, age resistor：0.1~0.5%, naphthenic oil：15~23%, polyisobutene：5~10%, C5 Petropols：7~12%, hydrogenate C5 Petropols：20~27%, terpene resin：2~6%, high hydroscopic resin：2~5%, modified double-quick cement：3~5%, silane coupler：0.5~1.0%；The laminated adhesive produced by the response type laminated adhesive production technology has and can keep the good adhesion to high density polyethylene (HDPE), can be directly bonded with moist concrete surface, and cross-linking reaction occurs and forms firm connection, reach the effect of " skin-type " waterproof, synthetic sand or natural sand need not be used, significantly reduce the weight of coiled material, cost is saved, cast-in-place concrete need not be carried out, only need to spray a small amount of water in basal plane, make basal plane keep moistening can auxiliary patch the advantages that.
Description
Technical field
The present invention relates to PUR to manufacture field, particularly a kind of response type overlay film for non-bituminous waterproof roll
Glue production technology.
Background technology
Non-bituminous waterproof roll is a kind of new type waterproof coiled material quickly grown in recent years, and it is by a hdpe layer
（HDPE）Counterdie, one layer scratches in the hot-fusible pressure-sensitive adhesive on counterdie, and one layer is covered in Inorganic synthese sand on hot-fusible pressure-sensitive adhesive（Or day
Right sand）Form.This waterproof roll is the synthetic sand or natural sand by its surface, with cast-in-place concrete occur chemical crosslinking and
Physics mortise and tenon and attachment, it seamless can link and be integrated and form " skin-type " waterproof, thoroughly solve the drawbacks of waterproof layer channeling water.
But the synthetic sand or natural sand weight of such coiled material surface covering are big, easy to fall off, cause coiled material very heavy, add transport,
The cost of warehousing, the position of sand fallout is combined loosely with concrete, and causes hidden danger of quality；In addition, such coiled material must with it is cast-in-place
Concrete match ratio site operation, it is inconvenient using there is certain limitation.
The content of the invention
It is an object of the invention to provide a kind of response type laminated adhesive production technology for non-bituminous waterproof roll, pass through
The laminated adhesive that the response type laminated adhesive production technology is produced have can keep the good adhesion to high density polyethylene (HDPE), can be with
Moist concrete surface is directly bonded, and cross-linking reaction occurs and forms firm connection, so as to reach " skin-type " waterproof
Effect, synthetic sand or natural sand need not be used, significantly reduce the weight of coiled material, saved cost, scene need not be carried out
Pour into a mould concrete, it is only necessary to spray a small amount of water in basal plane, make basal plane keep moistening can auxiliary patch the advantages that.
The technical proposal of the invention is realized in this way：A kind of response type laminated adhesive for non-bituminous waterproof roll produces
Technique, its feature are that its component matches by mass percentage and are：SIS：18~25%, SBS：3~8%, age resistor：0.1~
0.5%, naphthenic oil：15~23%, polyisobutene：5~10%, C5 Petropols：7~12%, hydrogenate C5 Petropols：20~27%,
Terpene resin：2~6%, high hydroscopic resin：2~5%, modified double-quick cement：3~5%, silane coupler：0.5~1.0%；It is described
Age resistor is 1010 types, and the silane coupler is KH-570.
Mentioned component produces response type laminated adhesive through following production stage：First step, by the naphthenic oil of the proportioning,
Added after polyisobutene and age resistor metering in reactor, stirring, 100 DEG C of heat temperature raising make above-mentioned substance dissolving complete；Second
Step, will be added after proportioning SIS, SBS metering in reactor, and be warming up to 160~170 DEG C, and stir 2~3h, make SIS,
SBS dissolvings are complete；Third step, it will be added after the C5 Petropols of the proportioning, hydrogenation C5 Petropols, terpene resin metering
In reactor, stirring is completely dissolved and is well mixed to resin for 30~60 minutes；Four steps, temperature of reaction kettle is down to 140
~150 DEG C, added after high hydroscopic resin, modified double-quick cement, silane coupler are pressed into stoichiometry in reactor, stirring
30min is to material substantially uniformity in kettle；5th step, by reactor vacuumizing and defoaming 30min, vacuum is -0.08MPa；The
Six steps, filtering and discharging, metering, packaging.
The present invention can obtain following technique effect as a result of technical scheme noted earlier：
Present invention employs SIS, SBS, age resistor, naphthenic oil, polyisobutene, C5 Petropols, hydrogenation C5 Petropols, terpenes
Resin, high hydroscopic resin, modified double-quick cement, silane coupler, are walked by the mixing of above material and the production of the present invention
Suddenly the laminated adhesive produced have can keep the good adhesion to high density polyethylene (HDPE), can be direct with moist concrete surface
Fitting, and cross-linking reaction occurs and forms firm connection, so as to reach the effect of " skin-type " waterproof, synthetic sand need not be used
Or natural sand, the weight of coiled material is significantly reduced, cost has been saved, cast-in-place concrete need not be carried out, it is only necessary in base
A small amount of water is sprayed in face, make basal plane keep moistening can auxiliary patch the advantages that.
Embodiment
A kind of response type laminated adhesive production technology for non-bituminous waterproof roll of the present invention, its component press quality hundred
Divide than proportioning and be：SIS：18~25%, SBS：3~8%, age resistor：0.1~0.5%, naphthenic oil：15~23%, polyisobutene：5
~10%, C5 Petropols：7~12%, hydrogenate C5 Petropols：20~27%, terpene resin：2~6%, high hydroscopic resin：2~
5%, modified double-quick cement：3~5%, silane coupler：0.5~1.0%；The age resistor is 1010 types；The silane coupler
For KH-570, it is maintained to HDPE sheet materials（Counterdie）Good adhesive property, it is not necessary to, can be using synthetic sand or natural sand
Directly it is bonded on completed concrete surface, and occurs cross-linking reaction and " forming one ", prevents the appearance of " channeling water " drawback.
Mentioned component produces response type laminated adhesive through following production stage：
First step, it will be added after naphthenic oil, polyisobutene and the age resistor metering of the proportioning in reactor, stirring, heating
100 DEG C of heating makes above-mentioned substance dissolving complete；
Second step, it will be added after proportioning SIS, SBS metering in reactor, and be warming up to 160~170 DEG C, and stir 2~
3h, make SIS, SBS dissolving complete；
Third step, reactor will be added after the C5 Petropols of the proportioning, hydrogenation C5 Petropols, terpene resin metering
In, stirring is completely dissolved and is well mixed to resin for 30~60 minutes；
Four steps, temperature of reaction kettle is down to 140~150 DEG C, by high hydroscopic resin, modified double-quick cement, silane coupler
Added by after stoichiometry in reactor, stirring 30min to material substantially uniformity in kettle；
5th step, by reactor vacuumizing and defoaming 30min, vacuum is -0.08MPa；
6th step, filtering and discharging, metering, packaging.
The invention provides the embodiment that following three kinds of components match by mass percentage based on noted earlier：
Embodiment one：
Component matches by mass percentage：SIS：25%、SBS：3%th, naphthenic oil：18%th, age resistor：0.5%th, C5 Petropols：
11%th, polyisobutene：7%th, C5 Petropols are hydrogenated：24%th, terpene resin：6%th, high hydroscopic resin：1.5%th, modified double-quick cement：
3.5%th, silane coupler：0.5%.
Embodiment two：
Component matches by mass percentage：SIS：22%、SBS：6%th, naphthenic oil：16%th, age resistor：0.5%th, C5 Petropols：
21%th, C5 Petropols are hydrogenated：14%th, terpene resin：6%th, polyisobutene：7%th, modified double-quick cement：3.5%th, silane coupler：
0.5%th, high hydroscopic resin：3.5%.
Embodiment three：
Component matches by mass percentage：SIS：20%、SBS：8%th, naphthenic oil：17%th, polyisobutene：6%th, age resistor：0.5%、
C5 Petropols：12%th, C5 Petropols are hydrogenated：23%th, terpene resin：5%th, modified double-quick cement：4%th, silane coupler：
0.5%th, high hydroscopic resin：4%.
SIS Chineses in the present invention are SIS, SBS Chinese
It is SBS, described SIS, SBS are the film forming matters of the present invention.
The present invention uses naphthenic oil as solvent, for adjusting the laminated adhesive of the invention produced under hot melt state
Viscosity, it is easy to the blade coating of laminated adhesive.
Heretofore described C5 Petropols are also known as light dydrocarbon resin, aliphatic hydrocarbon resin, by using C5 Petropols, hydrogen
Change C5 Petropols as tackifier, the laminated adhesive that the present invention produces viscous material difficult to polyethylene, polypropylene etc. is had preferably
Adhesion.
Present invention employs polyisobutene as low temperature modification agent, ensure the laminated adhesive of the invention produced in low temperature (- 25
DEG C) embrittlement does not occur under state.
The effect of heretofore described silane coupler is to strengthen the adhesive strength between organic substance and inorganic substances.
The effect of heretofore described modification double-quick cement is to crosslink reaction, enhancing volume with base surface of damp concrete
The adhesive strength of material and cement basal plane is with preventing channeling water.
The effect of heretofore described high hydroscopic resin is after ensureing that coiled material is bonded with cement basal plane, in maintenance processes
The moisture content absorbed constantly is discharged, cross-linking reaction is carried out more fully and completely.
Claims (1)
- A kind of 1. response type laminated adhesive production technology for non-bituminous waterproof roll, it is characterised in that：Its component presses quality hundred Divide than proportioning and be：SIS：18~25%, SBS：3~8%, age resistor：0.1~0.5%, naphthenic oil：15~23%, polyisobutene：5 ~10%, C5 Petropols：7~12%, hydrogenate C5 Petropols：20~27%, terpene resin：2~6%, high hydroscopic resin：2~ 5%, modified double-quick cement：3~5%, silane coupler：0.5~1.0%；The age resistor is 1010 types, and the silane coupler is KH-570；Mentioned component produces response type laminated adhesive through following production stage：First step, it will be added after naphthenic oil, polyisobutene and the age resistor metering of the proportioning in reactor, stirring, heating 100 DEG C of heating makes above-mentioned substance dissolving complete；Second step, it will be added after proportioning SIS, SBS metering in reactor, and be warming up to 160~170 DEG C, and stir 2~ 3h, make SIS, SBS dissolving complete；Third step, reactor will be added after the C5 Petropols of the proportioning, hydrogenation C5 Petropols, terpene resin metering In, stirring is completely dissolved and is well mixed to resin for 30~60 minutes；Four steps, temperature of reaction kettle is down to 140~150 DEG C, by high hydroscopic resin, modified double-quick cement, silane coupler Added by after stoichiometry in reactor, stirring 30min to material substantially uniformity in kettle；5th step, by reactor vacuumizing and defoaming 30min, vacuum is -0.08MPa；6th step, filtering and discharging, metering, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610611653.2A CN107663436A (en) | 2016-07-30 | 2016-07-30 | A kind of response type laminated adhesive production technology for non-bituminous waterproof roll |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610611653.2A CN107663436A (en) | 2016-07-30 | 2016-07-30 | A kind of response type laminated adhesive production technology for non-bituminous waterproof roll |
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| Publication Number | Publication Date |
|---|---|
| CN107663436A true CN107663436A (en) | 2018-02-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610611653.2A Pending CN107663436A (en) | 2016-07-30 | 2016-07-30 | A kind of response type laminated adhesive production technology for non-bituminous waterproof roll |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108724870A (en) * | 2018-05-07 | 2018-11-02 | 德州科顺建筑材料有限公司 | A kind of wet-laid process adhesive waterproof coil and preparation method thereof |
| CN109735261A (en) * | 2019-01-15 | 2019-05-10 | 江苏嘉好热熔胶股份有限公司 | A kind of waterproof roll special glue of ultra-low temperature surroundings and preparation method thereof |
| CN110724479A (en) * | 2019-10-24 | 2020-01-24 | 上海嘉好胶粘制品有限公司 | Special hot-melt pressure-sensitive adhesive for high-molecular self-adhesive waterproof adhesive tape and preparation method thereof |
| CN111019575A (en) * | 2019-12-19 | 2020-04-17 | 浙江金嘉科技有限公司 | High-temperature-resistant high-peeling-resistance hot-melt pressure-sensitive adhesive and preparation method thereof |
| CN113956825A (en) * | 2021-09-14 | 2022-01-21 | 科建高分子材料（上海）股份有限公司 | Hot melt adhesive and waterproof lap joint adhesive tape |
| CN115785845A (en) * | 2022-12-23 | 2023-03-14 | 苏州市姑苏新型建材有限公司 | Dry-wet dual-purpose waterproof roll and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865458A (en) * | 2014-03-06 | 2014-06-18 | 佛山市科顺建筑材料有限公司 | Hot-melting laminated adhesive for waterproof coiled material of chemical reaction type and preparation method of hot-melting laminated adhesive |
-
2016
- 2016-07-30 CN CN201610611653.2A patent/CN107663436A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865458A (en) * | 2014-03-06 | 2014-06-18 | 佛山市科顺建筑材料有限公司 | Hot-melting laminated adhesive for waterproof coiled material of chemical reaction type and preparation method of hot-melting laminated adhesive |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108724870A (en) * | 2018-05-07 | 2018-11-02 | 德州科顺建筑材料有限公司 | A kind of wet-laid process adhesive waterproof coil and preparation method thereof |
| CN109735261A (en) * | 2019-01-15 | 2019-05-10 | 江苏嘉好热熔胶股份有限公司 | A kind of waterproof roll special glue of ultra-low temperature surroundings and preparation method thereof |
| CN110724479A (en) * | 2019-10-24 | 2020-01-24 | 上海嘉好胶粘制品有限公司 | Special hot-melt pressure-sensitive adhesive for high-molecular self-adhesive waterproof adhesive tape and preparation method thereof |
| CN111019575A (en) * | 2019-12-19 | 2020-04-17 | 浙江金嘉科技有限公司 | High-temperature-resistant high-peeling-resistance hot-melt pressure-sensitive adhesive and preparation method thereof |
| CN111019575B (en) * | 2019-12-19 | 2021-12-24 | 浙江金嘉科技有限公司 | High-temperature-resistant high-peeling-resistance hot-melt pressure-sensitive adhesive and preparation method thereof |
| CN113956825A (en) * | 2021-09-14 | 2022-01-21 | 科建高分子材料（上海）股份有限公司 | Hot melt adhesive and waterproof lap joint adhesive tape |
| CN115785845A (en) * | 2022-12-23 | 2023-03-14 | 苏州市姑苏新型建材有限公司 | Dry-wet dual-purpose waterproof roll and preparation method thereof |
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Application publication date: 20180206 |
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