CN107652795A - A kind of super-hydrophobic powdery paints and its preparation method and application - Google Patents
A kind of super-hydrophobic powdery paints and its preparation method and application Download PDFInfo
- Publication number
- CN107652795A CN107652795A CN201710886318.8A CN201710886318A CN107652795A CN 107652795 A CN107652795 A CN 107652795A CN 201710886318 A CN201710886318 A CN 201710886318A CN 107652795 A CN107652795 A CN 107652795A
- Authority
- CN
- China
- Prior art keywords
- super
- hydrophobic
- powder
- coating
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of super-hydrophobic powdery paints and its preparation method and application, the coating includes hydrophobic powder and needs the resin-oatmeal of hot setting, and the mass ratio of hydrophobic powder and resin-oatmeal is 1:1~4；Wherein, hydrophobic powder is at least one of the polytetrafluoroethylene (PTFE) that particle diameter is 10~50 μm, Kynoar, hydrophobically modified silica, hydrophobically modified titanium dioxide, hydrophobically modified CNT, carbon black, and resin-oatmeal is that particle diameter is 10~50 μm and can be used at least one of epoxy or polyesters powder of electrostatic plastic spraying.The method of the invention is simple and convenient, prepares rapidly, can be rapidly completed the preparation of super-hydrophobic coat on matrix surface；The coating that the present invention prepares has super-hydrophobicity and super-high wear-resistant concurrently.
Description
Technical field
The invention belongs to technical field of material chemistry, is related to a kind of coating and coating technology, and specially a kind of super-hydrophobic powder applies
Material and its preparation method and application.
Background technology
Many natural materials in nature being present, itself shows certain hydrophobic performance due to special structure,
It is typically include lotus leaf and insect wing etc..People are earliest from the surface observation of lotus leaf to this phenomenon, and by studying lotus
The planform and material of leaf surface, it is proposed that super-hydrophobic concept, and have developed super-hydrophobic surface coating.By largely grinding
Study carefully discovery, the super hydrophobic surface of nature often has coarse nanostructured and low-surface energy substance, thus in low-surface-energy
Rough surface is built on material and the material of low-surface-energy is modified on coarse surface texture, super hydrophobic surface can be prepared
Bionic coating.However, at present in prepared super-hydrophobic coat, the wearability of coating and the ultra-hydrophobicity of coating are often one
To the concept runed counter to simultaneously, it is difficult to improve.While strengthening coating abrasion performance, the decline of coating hydrophobic performance is usually associated with；
It is otherwise also such.Such as Guo Yong just wait by PMMA add tetrahydrofuran in, after being completely dissolved addition hydrophobic silica powder, stir
It is coated in after mixing 2h with dropper on clean slide, PMMA/SiO is obtained after being dried at 40 DEG C2Composite coating.The table of the coating
Face contact angle is up to more than 150 °, and roll angle is less than 3 °.But its wearability is bad, can not ensure upon wear still with very strong
Hydrophobic effect.
The content of the invention
The technical problem of solution：The defects of in order to overcome prior art, obtain one kind and have super-hydrophobicity and super-high wear-resistant concurrently
Property coating, and a kind of operation is easy, and cost is low, simple effective method, and the invention provides a kind of super-hydrophobic powder to apply
Material and its preparation method and application.
Technical scheme：A kind of super-hydrophobic powdery paints, the coating include hydrophobic powder and need the resin-oatmeal of hot setting, dredges
The mass ratio of pigment and resin-oatmeal is 1:1~4；Wherein, hydrophobic powder is the polytetrafluoroethylene (PTFE), polyvinylidene fluoride that particle diameter is 10~50 μm
At least one of alkene, hydrophobically modified silica, hydrophobically modified titanium dioxide, hydrophobically modified CNT, carbon black, resin-oatmeal is
Particle diameter is 10~50 μm and can be used at least one of epoxy or polyesters powder of electrostatic plastic spraying.
Preferably, methods described is that hydrophobic powder and resin-oatmeal are blended in proportion；Or by the two be blended in proportion after pass through again
Melting stirring, extrusion, tabletting, broken, efflorescence process prepare.
Further, methods described is specially：
(1) powder is mixed：Hydrophobic powder is mixed with resin-oatmeal by proportioning, 5-10min is mixed in high-speed mixer；
(2) melting extrusion：Mixed-powder puts into double-screw agitator, in 120~140 DEG C of screw sleeve temperature, rotating speed 100
Extruded under the conditions of~300r/m；
(3) tabletting and broken：By the slurry of extrusion directly cooled down with twin-roll machine and roll to 1~3mm of thickness, length and width 3~
5mm irregular shape thin slice；
(4) efflorescence：Thin slice after broken is ground, sieving, sieve mesh number is 300 mesh, obtains super-hydrophobic powder.
Application of the described super-hydrophobic powdery paints in super-high wear-resistant super-hydrophobic coat is prepared.
Preferably, the coating is made by following methods：By super-hydrophobic powdery paints organic solvent it is dispersed after match somebody with somebody
Into dispersion liquid, roller coat, brush or be sprayed at workpiece surface；Or workpiece surface is directly coated on by electrostatic spraying mode, then
It is heated to more than solidification temperature, makes its melting, levelling, reaction film-forming, after cooling, you can there is super-high wear-resistant described in obtaining
The coating of property and super-hydrophobicity；The organic solvent is at least one of ethanol, isopropanol, butyl acetate；Dispersion liquid concentration
For 0.1g/mL~1g/mL.
Preferably, the solidification temperature is 150~330 DEG C, and hardening time is 10~30min.
Preferably, the input voltage of the electrostatic spraying mode is 220V, and the output of spray gun electrostatic is 10~100KV, for powder
0.4~0.5MPa of air pressure, spray distance are 150~250mm.
Preferably, the thickness that film is prepared using powdery paints solution roller coat, brushing or spraying is 10~200 μm；Utilize
The coating thickness of electrostatic plastic spraying film forming is 40~120 μm.
Coating described in any of the above, the coating include super-hydrophobic powdery paints.
The specific preparation method of above-mentioned coating is as follows：
(1) preparation of hydrophobically modified powder：The selection of hydrophobically modified powder have a lot, can be silicon fluoride be modified Ludox
Silicon dioxide powder or the gas phase hydrophobic titanium dioxide silica flour of modification, comparatively the former performance is more preferable, and powder diameter is
10~50 μm, hydrophobically modified powder adds Ludox and changed by silicon fluoride and tetraethyl orthosilicate using absolute ethyl alcohol as solvent
Property, dry, pulverize after stirring 24h；
(2) hydrophobically modified powder and resin-oatmeal blending：Resin is heated into melting temperature melts toner, adds thin
Water modified powder simultaneously continues to stir, and by melting extrusion, as being dried at 80 DEG C of baking oven, dried object tabletting, broken is finally ground
Grinds, particle diameter are 10~50 μm.Obtained mixed-powder is dispersed in organic solvent, organic solvent can be second
Alcohol, isopropanol, butyl acetate etc., mixed solution is in slightly thick, the drop of dropwise addition 3~4 silicon fluorides into solution, placement ultrasonoscope
Ultrasound 5~10 minutes in device；
(3) super-hydrophobic coat is prepared in substrate surface：The good solution of ultrasound is uniformly brushed onto substrate, substrate can be
Sheet glass, tinplate sheet and aluminium flake etc.；In addition solution can also be fitted into spray gun, powder solution is sprayed on substrate surface；
(4) resin hot melt solidification：The substrate sample brushed is placed in baking oven and heated, temperature is adjusted to resin solidification temperature
Degree, the toner in coating is set to melt solidify afterwards, hydrophobically modified powder bonding is good, sample can also be placed in thermal station and added
Heat, cooling is taken off after 10~30min, you can obtain the super-hydrophobic coat with excellent wear.
Heating-up temperature is not fixed described in step (4), depending on toner solidification temperature used, when being heating and curing
Between with resin process is different and difference.
Beneficial effect：
(1) the method for the invention is simple and convenient, prepares the system that rapidly, can be rapidly completed super-hydrophobic coat on matrix surface
It is standby.
(2) hydrophobically modified powder can migrate to surface certainly when coating is heated and solidified, and form super-hydrophobic coat (such as Fig. 1 institutes
Show), cold coating then act as good binding agent, coating is had very high anti-wear performance.In addition, prepared with the method
Coating has all advantages of powdery paints, such as reduces environmental pollution, saves the energy, has excellent endurance quality, and applies
Material has very high utilization rate etc.；Meanwhile also with all advantages of super-hydrophobic coat, such as waterproof, antifouling, grease proofing, dust-proof, anti-
Corruption etc., can be applied to road guardrail, building inside and outside wall, house ornamentation furred ceiling of metal material etc., it may also be used for aircraft, naval vessel, high ferro,
The large-scale plant such as automobile surface, application field are wide.
(3) the hydrophobically modified particle in coating is firmly bonded after resin mixes with hydrophobically modified powder, during heating and melting
Firmly, the resin that uppermost particle is cured is clung, and improves surface roughness to a certain extent.The silicon prepared based on the method
Sol-gel modified SiO 2 powder and toner mixing hot melt solidify afterwards, obtained super-hydrophobic coat, by various ways
Abrasion, such as finger friction are thousands of secondary, or after the polishing of long-time sand paper or abrasion instrument abrasion, coating surface is still super-hydrophobic, is connect
Feeler is remained to reach more than 155 °, and water droplet roll angle is controlled below 10 °, shows excellent anti-wear performance.
(4) it is powder coating based on the coating prepared by the method, when being molded by electrostatic plastic spraying, avoids organic solvent
The various unsafe factors brought, while also prevent the pollution that organic solvent is brought to environment；Simultaneously in construction application, no
Need to adjust viscosity with seasonal variations, simplify constructing operation.
Brief description of the drawings
Fig. 1 is sample surface scan picture in embodiment 1；
Fig. 2 is the aspect graph that sample stands the μ L water droplets of surface 5 in air after 500 sand paper wear in embodiment 2；
Fig. 3 is the aspect graph that sample stands the μ L water droplets of surface 5 in air after 700 sand paper wear in embodiment 3；
Fig. 4 is sample coating surface macro morphology figure after 700 sand paper wear in embodiment 3；
Fig. 5 is the coating surface macro morphology figure of tinplate sample in embodiment.
Embodiment
Following examples further illustrate present disclosure, but should not be construed as limiting the invention.Without departing substantially from
In the case of spirit and essence of the invention, the modification and replacement made to the inventive method, step or condition, the present invention is belonged to
Scope.Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
(1) preparation of hydrophobically modified powder：The Ludox SiO 2 powder being modified using silicon fluoride and TEOS is as thin
Water modified powder, using absolute ethyl alcohol as solvent, water silica sol is added dropwise after adding ammoniacal liquor and deionized water, is added dropwise when being stirred
Silicon fluoride and TEOS, dry and clay into power after stirring 24h, 10~50 μm of powder diameter；
(2) hydrophobically modified powder and resin-oatmeal blending：Resin uses the PTFE resin of solid powder, and mesh number is 250 mesh, will
Toner is heated to after fusing point is allowed to melting, according to " hydrophobically modified powder：Resin=1：4 " mass ratio, add drainage powder
And continue to stir, by melting extrusion, as being dried at 80 DEG C of baking oven, dried object tabletting, broken is finally pulverized, grain
Footpath is 10~50 μm, is scattered in butyl acetate solution, the drop silicon fluorides of dropwise addition 3~4, ultrasonic 5 in placement ultrasonic instrument~
10min；
(3) super-hydrophobic coat is prepared in substrate surface：The good solution of ultrasound is uniformly brushed at glass chip bottom with brush
On, sample is brushed once；
(4) resin hot melt solidification：The sample brushed is placed and heated in baking oven, temperature is adjusted to 330 DEG C, and hardening time is
10~30min, sample is taken off into cooling after resin solidification is complete, you can obtain wearability super-hydrophobic surface coating.
The coating sample that embodiment 1 prepares is polished with 1200 mesh sand paper, counts the change of its roll angle, as a result such as
Shown in table 1：
In the embodiment 1 of table 1 super-hydrophobic coat sample with Sandpapering number rolling angular data
Embodiment 2
(1) preparation of hydrophobically modified powder：The Ludox SiO 2 powder being modified using silicon fluoride and TEOS is as thin
Water modified powder, using absolute ethyl alcohol as solvent, water silica sol is added dropwise after adding ammoniacal liquor and deionized water, is added dropwise when being stirred
Silicon fluoride and TEOS, dry and clay into power after stirring 24h, 10~50 μm of powder diameter；
(2) hydrophobically modified powder and resin-oatmeal blending：Resin uses the TPU of solid powder, and mesh number is
800 mesh, toner is heated to after fusing point is allowed to melting, according to " hydrophobically modified powder：Resin=1：1 " mass ratio, addition
Drainage powder simultaneously continues to stir, and by melting extrusion, as being dried at 80 DEG C of baking oven, dried object tabletting, broken is finally ground
Cheng Fen, particle diameter are 10~50 μm, are scattered in butyl acetate solution, and 3~4 drop silicon fluorides are added dropwise, places in ultrasonic instrument and surpasses
5~10min of sound；
(3) super-hydrophobic coat is prepared in substrate surface：The good solution of ultrasound is uniformly brushed at glass chip bottom with brush
On, sample is brushed once；
(4) resin hot melt solidification：The sample brushed is placed and heated in baking oven, temperature is adjusted to 152 DEG C, and hardening time is
10~30min, sample is taken off into cooling after resin solidification is complete, you can obtain wearability super-hydrophobic surface coating.
Fig. 2 stands the form of the μ L water droplets of surface 5 in air, sand paper model for the coating after 500 sand paper wear
1200 mesh, abrasion pressure 200g, horizontal and vertical each polishing 10cm is a circle.
The coating sample Sandpapering that embodiment 2 is prepared, counts the change of its roll angle, as a result such as the institute of table 2
Show：
In the embodiment 2 of table 2 super-hydrophobic coat sample with Sandpapering number rolling angular data
Embodiment 3
(1) preparation of hydrophobically modified powder：The Ludox SiO 2 powder being modified using silicon fluoride and TEOS is as thin
Water modified powder, using absolute ethyl alcohol as solvent, water silica sol is added dropwise after adding ammoniacal liquor and deionized water, is added dropwise when being stirred
Silicon fluoride and TEOS, dry and clay into power after stirring 24h, 10~50 μm of powder diameter；
(2) hydrophobically modified powder and resin-oatmeal blending：Resin uses a kind of polyester resin of solid powder, and mesh number is
500 mesh, toner is heated to after fusing point is allowed to melting, according to " hydrophobically modified powder：Resin=2：1 " mass ratio, addition
Drainage powder simultaneously continues to stir, and by melting extrusion, as being dried at 80 DEG C of baking oven, dried object tabletting, broken is finally ground
Cheng Fen, particle diameter are 10~50 μm, are scattered in butyl acetate solution, and 3~4 drop silicon fluorides are added dropwise, places in ultrasonic instrument and surpasses
5~10min of sound；
(3) super-hydrophobic coat is prepared in substrate surface：The good solution of ultrasound is uniformly brushed at glass chip bottom with brush
On, sample is brushed once；
(4) resin hot melt solidification：The sample brushed is placed and heated in baking oven, temperature is adjusted to 200 DEG C, and hardening time is
10~30min, sample is taken off into cooling after resin solidification is complete, you can obtain wearability super-hydrophobic surface coating.
Fig. 3 stands the form of the μ L water droplets of surface 5 in air, sand paper model for the coating after 700 sand paper wear
1200 mesh, abrasion pressure 200g, horizontal and vertical each polishing 10cm is a circle.
Fig. 4 is coating coating surface macro morphology after 700 sand paper wear.
The coating surface macro morphology of Fig. 5 positions tinplate sample.
Table 4 is the rolling angular data that the coating is polished with abrasion instrument.Abrasion instrument wheel is rubber wheels, abrasion pressure position
250g。
The coating sample Sandpapering that embodiment 3 is prepared, counts the change of its roll angle, as a result such as the institute of table 3
Show：
In the embodiment 3 of table 3 super-hydrophobic coat sample with Sandpapering number rolling angular data
The rolling angular data that the floating coat sample of 4 embodiment of table 3 is polished with abrasion instrument
Claims (9)
1. a kind of super-hydrophobic powdery paints, it is characterised in that the coating includes hydrophobic powder and needs the resin-oatmeal of hot setting, dredges
The mass ratio of pigment and resin-oatmeal is 1:1~4；Wherein, hydrophobic powder is the polytetrafluoroethylene (PTFE), polyvinylidene fluoride that particle diameter is 10~50 μm
At least one of alkene, hydrophobically modified silica, hydrophobically modified titanium dioxide, hydrophobically modified CNT, carbon black, resin-oatmeal is
Particle diameter is 10~50 μm and can be used at least one of epoxy or polyesters powder of electrostatic plastic spraying.
2. the preparation method of a kind of super-hydrophobic powdery paints described in claim 1, it is characterised in that methods described is will be hydrophobic
Powder and resin-oatmeal are blended in proportion；Or again through melting stirring, extrusion, tabletting, broken, efflorescence process after being blended in proportion by both
Prepare.
3. the preparation method of a kind of super-hydrophobic powdery paints according to claim 2, it is characterised in that methods described is specific
For：
(1) powder is mixed：Hydrophobic powder is mixed with resin-oatmeal by proportioning, 5-10min is mixed in high-speed mixer；
(2) melting extrusion：Mixed-powder puts into double-screw agitator, in 120~140 DEG C of screw sleeve temperature, rotating speed 100~
Extruded under the conditions of 300r/m；
(3) tabletting and broken：The slurry of extrusion is directly cooled down with twin-roll machine and rolled to 1~3mm of thickness, length and width 3~5mm
Irregular shape thin slice；
(4) efflorescence：Thin slice after broken is ground, sieving, sieve mesh number is 300 mesh, obtains super-hydrophobic powder.
4. application of the super-hydrophobic powdery paints in super-high wear-resistant super-hydrophobic coat is prepared described in claim 1.
5. application according to claim 4, it is characterised in that the coating is made by following methods：By super-hydrophobic powder
Coating with organic solvent it is dispersed after be made into dispersion liquid, roller coat, brush or be sprayed at workpiece surface；Or directly pass through electrostatic
Painting mode is coated on workpiece surface, is subsequently heated to more than solidification temperature, makes its melting, levelling, reaction film-forming, cooling
Afterwards, you can obtain the coating with super-high wear-resistant and super-hydrophobicity；The organic solvent is ethanol, isopropanol, acetic acid
At least one of butyl ester；Dispersion liquid concentration is 0.1g/mL~1g/mL.
6. application according to claim 5, it is characterised in that the solidification temperature is 150~330 DEG C, and hardening time is
10~30min.
7. application according to claim 5, it is characterised in that the input voltage of the electrostatic spraying mode is 220V, spray
The output of rifle electrostatic is 10~100KV, and for powder 0.4~0.5MPa of air pressure, spray distance is 150~250mm.
8. application according to claim 5, it is characterised in that prepared using powdery paints solution roller coat, brushing or spraying
The thickness of film is 10~200 μm；Coating thickness using electrostatic plastic spraying film forming is 40~120 μm.
9. any described coating of claim 4~8, it is characterised in that the coating includes super-hydrophobic powdery paints.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710886318.8A CN107652795A (en) | 2017-09-27 | 2017-09-27 | A kind of super-hydrophobic powdery paints and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710886318.8A CN107652795A (en) | 2017-09-27 | 2017-09-27 | A kind of super-hydrophobic powdery paints and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107652795A true CN107652795A (en) | 2018-02-02 |
Family
ID=61115854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710886318.8A Pending CN107652795A (en) | 2017-09-27 | 2017-09-27 | A kind of super-hydrophobic powdery paints and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107652795A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108490021A (en) * | 2018-03-20 | 2018-09-04 | 南京信息工程大学 | A kind of droplets freeze core measuring device and experimental method |
| CN108767473A (en) * | 2018-04-28 | 2018-11-06 | 安徽四创电子股份有限公司 | A kind of manufacturing method of high hydrophobicity antenna house |
| CN108997860A (en) * | 2018-07-28 | 2018-12-14 | 南京艾利克斯电子科技有限公司 | A kind of coating and preparation method thereof of the electronic component with ultra-hydrophobicity |
| CN109678559A (en) * | 2018-12-25 | 2019-04-26 | 同济大学 | A kind of super-hydrophobic, Gao Naijiu Anti-seepage air-permeable sand and preparation method thereof |
| CN110183929A (en) * | 2019-05-21 | 2019-08-30 | 东南大学 | A kind of thin ice powder coating and preparation method thereof |
| CN110240849A (en) * | 2019-05-21 | 2019-09-17 | 东南大学 | A kind of super abrasive super-amphiphobic coating and its preparation method and application |
| CN112341873A (en) * | 2020-11-04 | 2021-02-09 | 东南大学 | Long-acting anti-icing coating and preparation method and application thereof |
| CN112452691A (en) * | 2020-11-30 | 2021-03-09 | 李涛 | Solar panel coating |
| CN112934630A (en) * | 2021-01-25 | 2021-06-11 | 深圳和力纳米科技有限公司 | Composite bi-component nano waterproof film and preparation method thereof |
| CN113999596A (en) * | 2021-11-05 | 2022-02-01 | 上海纳米技术及应用国家工程研究中心有限公司 | Hydrophobic self-cleaning powder coating and preparation method thereof |
| WO2022127116A1 (en) * | 2020-12-19 | 2022-06-23 | 广东西敦千江粉漆科学研究有限公司 | Preparation method for and application of weather-resistant, wear-resistant and hydrophobic aid |
| CN114790364A (en) * | 2022-04-01 | 2022-07-26 | 哈尔滨工程大学 | Hydrophobic carbon nanotube-based super-hydrophobic coating with anti-icing function and preparation method thereof |
| CN114907759A (en) * | 2022-05-30 | 2022-08-16 | 冯丽明 | Corrosion-resistant waterproof polyurethane coating material |
| CN115944785A (en) * | 2022-12-16 | 2023-04-11 | 上海工程技术大学 | Preparation method of homogeneous fiber tubular scaffold |
| CN116040986A (en) * | 2023-02-08 | 2023-05-02 | 黄丽萍 | Modified asphalt concrete and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101305058A (en) * | 2005-11-14 | 2008-11-12 | 纳幕尔杜邦公司 | Method for producing coatings with specific surface properties |
| CN101497754A (en) * | 2008-01-29 | 2009-08-05 | 罗门哈斯公司 | Acrylic coating powders comprising hydrophobic particles and powder coatings therefrom |
| CN102239224A (en) * | 2008-07-02 | 2011-11-09 | 微粉公司 | Compositions and processes for producing durable hydrophobic and/or olephobic surfaces |
| CN102925028A (en) * | 2012-11-21 | 2013-02-13 | 江苏大学 | Production method for super-hydrophobic powder paint |
-
2017
- 2017-09-27 CN CN201710886318.8A patent/CN107652795A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101305058A (en) * | 2005-11-14 | 2008-11-12 | 纳幕尔杜邦公司 | Method for producing coatings with specific surface properties |
| CN101497754A (en) * | 2008-01-29 | 2009-08-05 | 罗门哈斯公司 | Acrylic coating powders comprising hydrophobic particles and powder coatings therefrom |
| CN102239224A (en) * | 2008-07-02 | 2011-11-09 | 微粉公司 | Compositions and processes for producing durable hydrophobic and/or olephobic surfaces |
| CN102925028A (en) * | 2012-11-21 | 2013-02-13 | 江苏大学 | Production method for super-hydrophobic powder paint |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108490021A (en) * | 2018-03-20 | 2018-09-04 | 南京信息工程大学 | A kind of droplets freeze core measuring device and experimental method |
| CN108767473A (en) * | 2018-04-28 | 2018-11-06 | 安徽四创电子股份有限公司 | A kind of manufacturing method of high hydrophobicity antenna house |
| CN108767473B (en) * | 2018-04-28 | 2021-07-06 | 安徽四创电子股份有限公司 | Manufacturing method of high-hydrophobicity antenna housing |
| CN108997860A (en) * | 2018-07-28 | 2018-12-14 | 南京艾利克斯电子科技有限公司 | A kind of coating and preparation method thereof of the electronic component with ultra-hydrophobicity |
| CN109678559A (en) * | 2018-12-25 | 2019-04-26 | 同济大学 | A kind of super-hydrophobic, Gao Naijiu Anti-seepage air-permeable sand and preparation method thereof |
| CN110240849B (en) * | 2019-05-21 | 2021-12-07 | 东南大学 | Super-wear-resistant super-amphiphobic coating and preparation method and application thereof |
| CN110183929A (en) * | 2019-05-21 | 2019-08-30 | 东南大学 | A kind of thin ice powder coating and preparation method thereof |
| CN110240849A (en) * | 2019-05-21 | 2019-09-17 | 东南大学 | A kind of super abrasive super-amphiphobic coating and its preparation method and application |
| CN112341873A (en) * | 2020-11-04 | 2021-02-09 | 东南大学 | Long-acting anti-icing coating and preparation method and application thereof |
| CN112452691A (en) * | 2020-11-30 | 2021-03-09 | 李涛 | Solar panel coating |
| WO2022127116A1 (en) * | 2020-12-19 | 2022-06-23 | 广东西敦千江粉漆科学研究有限公司 | Preparation method for and application of weather-resistant, wear-resistant and hydrophobic aid |
| CN112934630A (en) * | 2021-01-25 | 2021-06-11 | 深圳和力纳米科技有限公司 | Composite bi-component nano waterproof film and preparation method thereof |
| CN113999596A (en) * | 2021-11-05 | 2022-02-01 | 上海纳米技术及应用国家工程研究中心有限公司 | Hydrophobic self-cleaning powder coating and preparation method thereof |
| CN114790364A (en) * | 2022-04-01 | 2022-07-26 | 哈尔滨工程大学 | Hydrophobic carbon nanotube-based super-hydrophobic coating with anti-icing function and preparation method thereof |
| CN114907759A (en) * | 2022-05-30 | 2022-08-16 | 冯丽明 | Corrosion-resistant waterproof polyurethane coating material |
| CN115944785A (en) * | 2022-12-16 | 2023-04-11 | 上海工程技术大学 | Preparation method of homogeneous fiber tubular scaffold |
| CN116040986A (en) * | 2023-02-08 | 2023-05-02 | 黄丽萍 | Modified asphalt concrete and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107652795A (en) | A kind of super-hydrophobic powdery paints and its preparation method and application | |
| CN103342953B (en) | The method of coating for aircraft coating, its preparation method and formation aviation | |
| CN104910779B (en) | A kind of super-hydrophobic Acrylic Polyurethane Coating and preparation method thereof | |
| CN103360942B (en) | A kind of super-hydrophobic nano coating and preparation method thereof | |
| CN109370418A (en) | A kind of super hydrophobic coating, coating and its preparation method and application | |
| CN105219249B (en) | A kind of smooth reflective heat-insulation paint | |
| CN102002295B (en) | Process for preparing liquid marble paint | |
| CN107418277B (en) | A kind of water nano long-effective corrosion finishing coat and preparation method thereof | |
| CN101857772B (en) | Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof | |
| CN103275571A (en) | Transparent sound-absorption film surface hydrophobic self-cleaning coating and preparation method thereof | |
| CN104312225A (en) | High-flexibility and high-glossiness inorganic coating and preparation method | |
| CN1712470A (en) | Curing nanometer building paint from fluoride carbon resin at normal temperature and production thereof | |
| CN107815215A (en) | A kind of water-based stone-like coating formula and water-based imitative stone terrace | |
| CN106811130A (en) | The elastic aqueous colorful building coating and preparation method of a kind of reflective insulation | |
| CN106366801A (en) | One-component thermoplastic acrylic matte finish | |
| CN105131810A (en) | Antifouling powdery paint for waterproof valve and manufacturing method thereof | |
| Gu et al. | Electrostatic powder spraying process for the fabrication of stable superhydrophobic surfaces | |
| CN101942250A (en) | Fluorocarbon coating | |
| CN101525506A (en) | Liquid granite paint and preparing method thereof | |
| CN109370334A (en) | A kind of insulating moulding coating and preparation method thereof for aqueous acrylamide acid type finishing coat | |
| CN106700675A (en) | External wall substrate antistatic antifouling coating agent and preparation method thereof | |
| CN106752820A (en) | A kind of super-amphiphobic organic inorganic hybridized paint of Fe2O3 doping titanium dioxide | |
| CN108384341A (en) | Ultrafine powder paint and its preparation method and application | |
| CN105153892A (en) | High/low-temperature-resistant valve antifouling powdery paint and manufacturing method thereof | |
| CN110484104A (en) | A kind of super hydrophobic coating and its preparation, application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhang Youfa Inventor after: Liu Chengzhi Inventor after: Yang Yongling Inventor after: Yu Xinquan Inventor before: Zhang Youfa Inventor before: Liu Chengzhi Inventor before: Yu Xinquan |
|
| CB03 | Change of inventor or designer information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180202 |
|
| RJ01 | Rejection of invention patent application after publication |