CN106366801A - One-component thermoplastic acrylic matte finish - Google Patents

One-component thermoplastic acrylic matte finish Download PDF

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Publication number
CN106366801A
CN106366801A CN201610743485.2A CN201610743485A CN106366801A CN 106366801 A CN106366801 A CN 106366801A CN 201610743485 A CN201610743485 A CN 201610743485A CN 106366801 A CN106366801 A CN 106366801A
Authority
CN
China
Prior art keywords
thermoplastic acrylic
component thermoplastic
butyl acetate
levelling agent
finishing coat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610743485.2A
Other languages
Chinese (zh)
Inventor
方学平
杨长春
严修才
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG HUAWANG PAINT CO Ltd
Original Assignee
GUANGDONG HUAWANG PAINT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG HUAWANG PAINT CO Ltd filed Critical GUANGDONG HUAWANG PAINT CO Ltd
Priority to CN201610743485.2A priority Critical patent/CN106366801A/en
Publication of CN106366801A publication Critical patent/CN106366801A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses one-component thermoplastic acrylic matte finish. The one-component thermoplastic acrylic matte finish comprises the following components in percent by mass: 58.7-73.55% of thermoplastic acrylic resin, 1-2% of polyethylene wax slurry, 0.5-0.2% of a dispersing agent, 0.15-0.5% of a leveling agent, 0.1-0.3% of a defoaming agent, 3-5% of trimethylbenzene, 3.2-4.8% of matting powder, 0.5% of n-butyl acetate, 6-10% of 20% cellulose acetate, 2-3% of 20% polyamide wax, 1-2% of a light stabilizer, 1-3% of MIBK and 8-10% of n-butyl acetate. The one-component thermoplastic acrylic matte finish is uniformly dispersed till the fineness is smaller than or equal to 25 microns, and the Tu-4 cup viscosity at 25 DEG C is 12-18 seconds. The one-component thermoplastic acrylic matte finish has the characteristics of good covering power, high gloss and the like.

Description

A kind of one-component thermoplastic acrylic dull finishing coat
Technical field
The present invention relates to a kind of one-component thermoplastic acrylic dull finishing coat.
Background technology
By three layers, that is, seal coat, midway priming paint and finish paint are constituted outdoor woodenware lacquer, and seal coat has permeability By force, the features such as closed performance is excellent, is attached directly to substrate surface, can improve substrate strength, and midway priming paint is used for strengthening finish paint Bonding force, the finish paint being is more plentiful fine and smooth and round and smooth, also has corrosion-resisting function, finish paint is the final painting of application simultaneously Layer, the lacquer painting effect being presented after finishing or mopping is presented by finish paint.
But the dull finishing coat using at present is it is contemplated that be applied on outdoor woodenware, its coating masks power is not good, gloss Degree is not high enough, therefore, it is necessary to improving and optimizing.
Content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the present invention provides that a kind of covering power is good, high glaze one-component thermoplastic Property acrylic acid dull finishing coat.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of one-component thermoplastic acrylic dull finishing coat, according to mass ratio, including following composition:
Thermoplastic acrylic resin 58.7%~73.55%
Polyethylene wax liquor 1%~2%
Dispersant 0.5%~0.2%
Levelling agent 0.15%~0.5%
Defoamer 0.1%~0.3%
Trimethylbenzene 3%~5%
Flatting silica 3.2%~4.8%
N-butyl acetate 0.5%
20% cellulose acetate 6%~10%
20% polyamide wax 2%~3%
Light stabilizer 1%~2%
Mibk 1%~3%
N-butyl acetate 8%~10%
It is uniformly dispersed to fineness≤25um, -4 glasss of viscosity of painting: 12s~18s/25 DEG C.
Further, described polyethylene wax liquor is 4200-10 polyethylene wax liquor.
Further, described dispersant is dispers610s dispersant.
Further, described levelling agent by 0.05%~0.2% levelling agent efka-3600 and 0.1%~0.3% efka- 3033 levelling agents mix.
Further, described light stabilizer be 0.5%~1% 1130 light stabilizers and 0.5%~1% 292 light stabilizers.
Further, described 20% cellulose acetate is prepared via a method which: by the cab-551-0.2 of 20% butanone, 20% And 60% butyl acetate disperses stirring to being completely dissolved, to fineness≤15um.
The invention has the beneficial effects as follows: the present invention being obtained using mentioned component, it is uniformly dispersed to fineness≤25um, apply -4 Cup viscosity: 12s~18s/25 DEG C, have that covering power is good, high glaze the features such as.
Specific embodiment
Below the present invention is described in further detail.
One-component paint does not need to add any auxiliary products when using, and direct spraying or roller coat are curable film-forming.
One-component thermoplastic acrylic dull finishing coat
A kind of one-component thermoplastic acrylic dull finishing coat of the present invention, according to mass ratio, including following composition:
Thermoplastic acrylic resin 58.7%~73.55%
Polyethylene wax liquor 1%~2%
Dispersant 0.5%~0.2%
Levelling agent 0.15%~0.5%
Defoamer 0.1%~0.3%
Trimethylbenzene 3%~5%
Flatting silica 3.2%~4.8%
N-butyl acetate 0.5%
20% cellulose acetate 6%~10%
20% polyamide wax 2%~3%
Light stabilizer 1%~2%
Mibk 1%~3%
N-butyl acetate 8%~10%
It is uniformly dispersed to fineness≤25um, -4 glasss of viscosity of painting: 12s~18s/25 DEG C.
Embodiment 1:
Thermoplastic acrylic resin 58.7%
4200-10 polyethylene wax liquor 2%
Dispers610s dispersant 0.2%
Levelling agent efka-3600 0.2%
Efka-3033 levelling agent 0.3%
Defoamer 0.3%
Trimethylbenzene 5%
Flatting silica 4.8%
N-butyl acetate 0.5%
20% cellulose acetate 10%
20% polyamide wax 3%
1130 light stabilizer light 1%
292 light stabilizers 1%
mibk 3%
N-butyl acetate 10%.
Embodiment 2:
Thermoplastic acrylic resin 73.05%
4200-10 polyethylene wax liquor 1%
Dispers610s dispersant 0.5%
Levelling agent efka-3600 0.05%
Efka-3033 levelling agent 0.1%
Defoamer 0.1%
Trimethylbenzene 3%
Flatting silica 3.2%
N-butyl acetate 0.5%
20% cellulose acetate 6%
20% polyamide wax 2%
1130 light stabilizer light 0.5%
292 light stabilizers 1%
mibk 1%
N-butyl acetate 8%.
Embodiment 3:
Thermoplastic acrylic resin 65.9%
4200-10 polyethylene wax liquor 1.5%
Dispers610s dispersant 0.4%
Efka-3600 levelling agent 0.1%
Efka-3033 levelling agent 0.4%
Defoamer 0.2%
Trimethylbenzene 4%
Flatting silica 4%
N-butyl acetate 0.5%
20% cellulose acetate 8%
20% polyamide wax 2.5%
1130 light stabilizer light 0.75%
292 light stabilizers 0.75%
mibk 2%
N-butyl acetate 9%.
Prime in one-component thermoplastic acrylic:
Prime in a kind of one-component thermoplastic acrylic of the present invention, according to weight ratio, including following composition:
Thermoplastic acrylic resin 72%~81.75%
15% polyamide wax liquor 2%~3%
Dispersant 0.5%~0.2%
Levelling agent 0.15%~0.5%
Defoamer 0.1%~0.3%
Trimethylbenzene 3%~5%
Zinc stearate 2%~3.5%
N-butyl acetate 0.5%
Mibk 1%~3%
Light stabilizer 1%~2%
N-butyl acetate 8%~10%
It is uniformly dispersed to fineness≤35um, -4 glasss of viscosity of painting: 20s~30s/25 DEG C.
Embodiment 1:
Thermoplastic acrylic resin 72%
15% polyamide wax liquor 3%
Dispers610s dispersant 0.2%
Efka-360 levelling agent 0.2%
Efka-3033 levelling agent 0.3%
Byk-066n defoamer 0.3%
Trimethylbenzene 5%
Zinc stearate 3.5%
N-butyl acetate 0.5%
mibk 3%
1130 light stabilizer light stabilizers 1%
292 light stabilizers 1%
N-butyl acetate 10%.
Embodiment 2:
Thermoplastic acrylic resin 81.75%
15% polyamide wax liquor 2%
Dispers610s dispersant 0.5%
Efka-360 levelling agent 0.05%
Efka-3033 levelling agent 0.1%
Byk-066n defoamer 0.1%
Trimethylbenzene 2%
Zinc stearate 2%
N-butyl acetate 0.5%
mibk 1%
1130 light stabilizer light stabilizers 0.5%
292 light stabilizers 0.5%
N-butyl acetate 9%.
Embodiment 3:
Thermoplastic acrylic resin 77.5%
15% polyamide wax liquor 2.5%
Dispers610s dispersant 0.4%
Efka-360 levelling agent 0.1%
Efka-3033 levelling agent 0.2%
Byk-066n defoamer 0.2%
Trimethylbenzene 4%
Zinc stearate 3%
N-butyl acetate 0.5%
mibk 2%
1130 light stabilizer light stabilizers 0.8%
292 light stabilizers 0.8%
N-butyl acetate 8%.
One-component thermoplastic acrylic seal coat
A kind of one-component thermoplastic acrylic seal coat of the present invention, according to mass ratio, including following composition:
Thermoplastic acrylic resin 72%~85.75%
Dispersant 0.05%~0.2%
Levelling agent 0.1%~0.8%
Defoamer 0.1%~0.3%
Trimethylbenzene 3%~6%
Methyl iso-butyl ketone (MIBK) 2%~5%
20% cellulose acetate 5%~8%
N-butyl acetate 3.5%~5%
It is uniformly dispersed to fineness≤15um, -4 glasss of viscosity of painting: 15s~20s/25 DEG C.
Embodiment 1:
Thermoplastic acrylic resin 74.7%
Dispers610s dispersant 0.2%
Glide100 levelling agent 0.3%
Efka-3600 levelling agent 0.5%
Byk-066n defoamer 0.3%
Trimethylbenzene 6%
Methyl iso-butyl ketone (MIBK) 5%
20% cellulose acetate 8%
N-butyl acetate 5%
Embodiment 2:
Thermoplastic acrylic resin 85.75%
Dispers610s dispersant 0.05%
Glide100 levelling agent 0.05%
Efka-3600 levelling agent 0.05%
Byk-066n defoamer 0.1%
Trimethylbenzene 2%
Methyl iso-butyl ketone (MIBK) 2%
20% cellulose acetate 5%
N-butyl acetate 5%
Embodiment 3:
Thermoplastic acrylic resin 80.85%
Dispers610s dispersant 0.1%
Glide100 levelling agent 0.2%
Efka-3600 levelling agent 0.05%
Byk-066n defoamer 0.3%
Trimethylbenzene 5%
Methyl iso-butyl ketone (MIBK) 4%
20% cellulose acetate 6%
N-butyl acetate 3.5%
Wherein, described 20% cellulose acetate is obtained by following preparation:
Butanone 20%
cab-551-0.2 20%
Butyl acetate 60%
Dispersion is stirred to being completely dissolved, to fineness≤15um.
The present invention need to outdoor woodwork coating when, using following coating process:
A, guarantee moisture content < 10%, the sheet material that polishing is cleaned out is constructed;
B, pass through spray/brush application, first with seal coat to openpore completely enclose twice;
C, after drying varniss, after polishing is cleaned out, in prime direct use, by spray/brush application;
D, after drying varniss, by interlayer polish recoating brush out paint film richness;
E, make after richness after paint film, dull finishing coat directly uses, by spray/brush application;
After f, drying varniss after drying varniss, paint film richness is brushed out by interlayer polishing recoating;
G, complete finish paint brushing after it should be ensured that paint film complete be dried before do not touched by the external world.
The outdoor woodenware lacquer of the present invention, after testing and probationary certificate, its coating adhesion is strong, pliability is good, hardness Height, covering power are good, high glaze, and good leveling property during construction can significantly improve wear-resisting scratch-resistant performance during paint film application life-time service.
The above, the simply better embodiment of the present invention, but the present invention is not limited to above-described embodiment, as long as It reaches the technique effect of the present invention with any same or similar means, all should fall under the scope of the present invention.

Claims (6)

1. a kind of one-component thermoplastic acrylic dull finishing coat is it is characterised in that according to mass ratio, including following composition:
Thermoplastic acrylic resin 58.7%~73.55%
Polyethylene wax liquor 1%~2%
Dispersant 0.5%~0.2%
Levelling agent 0.15%~0.5%
Defoamer 0.1%~0.3%
Trimethylbenzene 3%~5%
Flatting silica 3.2%~4.8%
N-butyl acetate 0.5%
20% cellulose acetate 6%~10%
20% polyamide wax 2%~3%
Light stabilizer 1%~2%
Mibk 1%~3%
N-butyl acetate 8%~10%
It is uniformly dispersed to fineness≤25um, -4 glasss of viscosity of painting: 12s~18s/25 DEG C.
2. a kind of one-component thermoplastic acrylic dull finishing coat according to claim 1 it is characterised in that: described polyethylene Wax liquor is 4200-10 polyethylene wax liquor.
3. profit require a kind of one-component thermoplastic acrylic dull finishing coat described in 1 it is characterised in that: described dispersant is Dispers610s dispersant.
4. a kind of one-component thermoplastic acrylic dull finishing coat according to claim 1 it is characterised in that: described levelling agent Mixed by 0.05%~0.2% levelling agent efka-3600 and 0.1%~0.3% efka-3033 levelling agent.
5. according to a kind of one-component thermoplastic acrylic dull finishing coat described in claim 1 it is characterised in that: described light stabilizer 1130 light stabilizers for 0.5%~1% and 0.5%~1% 292 light stabilizers.
6. according to a kind of one-component thermoplastic acrylic dull finishing coat described in claim 1 it is characterised in that: described 20% acetic acid Cellulose is prepared via a method which: by the butyl acetate dispersion stirring of 20% butanone, 20% cab-551-0.2 and 60% To being completely dissolved, to fineness≤15um.
CN201610743485.2A 2016-08-29 2016-08-29 One-component thermoplastic acrylic matte finish Pending CN106366801A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610743485.2A CN106366801A (en) 2016-08-29 2016-08-29 One-component thermoplastic acrylic matte finish

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610743485.2A CN106366801A (en) 2016-08-29 2016-08-29 One-component thermoplastic acrylic matte finish

Publications (1)

Publication Number Publication Date
CN106366801A true CN106366801A (en) 2017-02-01

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Country Status (1)

Country Link
CN (1) CN106366801A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107298911A (en) * 2017-08-18 2017-10-27 苏州卡佩罗尔高分子材料有限公司 A kind of environmentally friendly one-component metallic paint
CN108531000A (en) * 2018-04-03 2018-09-14 东莞市荣昌化工有限公司 A kind of environment-friendly type EVA paint
CN108948972A (en) * 2018-07-13 2018-12-07 宣全 The preparation method of multi-functional dumb light resin and its application in paint of coating
CN111849293A (en) * 2020-07-27 2020-10-30 东来涂料技术(上海)股份有限公司 Automobile exterior finishing matte varnish coating and preparation method thereof
CN113416478A (en) * 2021-06-18 2021-09-21 紫荆花涂料(上海)有限公司 PU varnish, preparation method and application thereof
CN114773934A (en) * 2022-05-05 2022-07-22 雅图高新材料股份有限公司 Single-component piano black paint and preparation method thereof
CN114921141A (en) * 2022-05-20 2022-08-19 上海立邦长润发涂料有限公司 Non-yellowing odorless matte clear finish paint and preparation method and construction method thereof

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CN102964949A (en) * 2012-11-21 2013-03-13 东来涂料技术(上海)有限公司 Single-component automobile supplementary restraint system cover paint and preparation method thereof
CN103725107A (en) * 2013-12-11 2014-04-16 上海嘉宝莉涂料有限公司 Cellulose acetate butyrate modified thermoplastic acrylic resin woodenware varnish and preparation method thereof

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CN102181211A (en) * 2011-01-25 2011-09-14 深圳市嘉卓成科技发展有限公司 One-component waterborne thermoplastic coating matched with UV-radiation curing coating as well as production method and construction method thereof
CN102964949A (en) * 2012-11-21 2013-03-13 东来涂料技术(上海)有限公司 Single-component automobile supplementary restraint system cover paint and preparation method thereof
CN103725107A (en) * 2013-12-11 2014-04-16 上海嘉宝莉涂料有限公司 Cellulose acetate butyrate modified thermoplastic acrylic resin woodenware varnish and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107298911A (en) * 2017-08-18 2017-10-27 苏州卡佩罗尔高分子材料有限公司 A kind of environmentally friendly one-component metallic paint
CN108531000A (en) * 2018-04-03 2018-09-14 东莞市荣昌化工有限公司 A kind of environment-friendly type EVA paint
CN108948972A (en) * 2018-07-13 2018-12-07 宣全 The preparation method of multi-functional dumb light resin and its application in paint of coating
CN111849293A (en) * 2020-07-27 2020-10-30 东来涂料技术(上海)股份有限公司 Automobile exterior finishing matte varnish coating and preparation method thereof
CN113416478A (en) * 2021-06-18 2021-09-21 紫荆花涂料(上海)有限公司 PU varnish, preparation method and application thereof
CN114773934A (en) * 2022-05-05 2022-07-22 雅图高新材料股份有限公司 Single-component piano black paint and preparation method thereof
CN114921141A (en) * 2022-05-20 2022-08-19 上海立邦长润发涂料有限公司 Non-yellowing odorless matte clear finish paint and preparation method and construction method thereof

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Application publication date: 20170201

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