CN107652443A - 一种表面及内部均含官能团的超支化聚(酯‑胺)及其制备方法 - Google Patents
一种表面及内部均含官能团的超支化聚(酯‑胺)及其制备方法 Download PDFInfo
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- CN107652443A CN107652443A CN201711040568.6A CN201711040568A CN107652443A CN 107652443 A CN107652443 A CN 107652443A CN 201711040568 A CN201711040568 A CN 201711040568A CN 107652443 A CN107652443 A CN 107652443A
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- amine
- ester
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- monomer
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 125000000524 functional group Chemical group 0.000 title claims abstract description 16
- -1 poly (ester amine Chemical class 0.000 title claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 43
- 239000000178 monomer Substances 0.000 claims abstract description 31
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- 150000003141 primary amines Chemical group 0.000 claims abstract description 4
- 150000003335 secondary amines Chemical class 0.000 claims abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 32
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 22
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical group C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 11
- 239000012263 liquid product Substances 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 10
- 239000003208 petroleum Substances 0.000 claims description 8
- 125000004386 diacrylate group Chemical group 0.000 claims description 7
- 238000001556 precipitation Methods 0.000 claims description 6
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical class CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 3
- 150000002924 oxiranes Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 150000003462 sulfoxides Chemical class 0.000 claims 1
- 238000007306 functionalization reaction Methods 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 19
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 18
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 13
- BTANRVKWQNVYAZ-UHFFFAOYSA-N 2-butanol Substances CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 12
- 239000012299 nitrogen atmosphere Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002390 rotary evaporation Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 2
- 238000006845 Michael addition reaction Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 125000005741 alkyl alkenyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004895 liquid chromatography mass spectrometry Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/002—Dendritic macromolecules
- C08G83/005—Hyperbranched macromolecules
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN201711040568.6A CN107652443B (zh) | 2017-10-31 | 2017-10-31 | 一种表面及内部均含官能团的超支化聚(酯-胺)及其制备方法 |
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CN201711040568.6A CN107652443B (zh) | 2017-10-31 | 2017-10-31 | 一种表面及内部均含官能团的超支化聚(酯-胺)及其制备方法 |
Publications (2)
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CN107652443A true CN107652443A (zh) | 2018-02-02 |
CN107652443B CN107652443B (zh) | 2021-01-15 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112876617A (zh) * | 2021-01-20 | 2021-06-01 | 西北大学 | 一种多孔分子印迹缓释材料的制备方法 |
CN113416290A (zh) * | 2021-05-24 | 2021-09-21 | 洛阳理工学院 | 一种可多重功能化改性的超支化聚氨酯及其制备方法 |
CN117106424A (zh) * | 2023-10-25 | 2023-11-24 | 大庆永铸石油技术开发有限公司 | 一种用于页岩油防塌减阻水基钻井液及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519158A (zh) * | 2016-10-26 | 2017-03-22 | 江南大学 | 一种端基为羟基、内部支化单元带有乙烯基的超支化聚(氨酯‑胺)的制备方法 |
CN106519253A (zh) * | 2016-10-26 | 2017-03-22 | 江南大学 | 一种链段型超支化聚醚的制备方法 |
-
2017
- 2017-10-31 CN CN201711040568.6A patent/CN107652443B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519158A (zh) * | 2016-10-26 | 2017-03-22 | 江南大学 | 一种端基为羟基、内部支化单元带有乙烯基的超支化聚(氨酯‑胺)的制备方法 |
CN106519253A (zh) * | 2016-10-26 | 2017-03-22 | 江南大学 | 一种链段型超支化聚醚的制备方法 |
Non-Patent Citations (2)
Title |
---|
CHENG, WR ET AL: "Michael Addition Polymerization of Trifunctional Amine and Acrylic Monomer: A Versatile Platform for Development of Biomaterials", 《BIOMACROMOLECULES》 * |
WU, DC ET AL: "Effects of Chemistries of Trifunctional Amines on Mechanisms of Michael Addition Polymerizations with Diacrylates", 《MACROMOLECULES》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112876617A (zh) * | 2021-01-20 | 2021-06-01 | 西北大学 | 一种多孔分子印迹缓释材料的制备方法 |
CN113416290A (zh) * | 2021-05-24 | 2021-09-21 | 洛阳理工学院 | 一种可多重功能化改性的超支化聚氨酯及其制备方法 |
CN117106424A (zh) * | 2023-10-25 | 2023-11-24 | 大庆永铸石油技术开发有限公司 | 一种用于页岩油防塌减阻水基钻井液及其制备方法 |
CN117106424B (zh) * | 2023-10-25 | 2024-01-12 | 大庆永铸石油技术开发有限公司 | 一种用于页岩油防塌减阻水基钻井液及其制备方法 |
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CN107652443B (zh) | 2021-01-15 |
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Effective date of registration: 20240618 Address after: 810, 8th Floor, Building 10, Courtyard 1, Tianxing Street, Fangshan District, Beijing, 102400 Patentee after: Beijing Zhichanhui Technology Co.,Ltd. Country or region after: China Address before: 1800 No. 214122 Jiangsu city of Wuxi Province Li Lake Avenue Patentee before: Jiangnan University Country or region before: China |
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Effective date of registration: 20240624 Address after: 518000 408, building 1, No. 1310, Kukeng sightseeing Road, Kukeng community, Guanlan street, Longhua District, Shenzhen, Guangdong Province Patentee after: Shenzhen bailihe new material development Co.,Ltd. Country or region after: China Address before: 810, 8th Floor, Building 10, Courtyard 1, Tianxing Street, Fangshan District, Beijing, 102400 Patentee before: Beijing Zhichanhui Technology Co.,Ltd. Country or region before: China |