CN107616176A - A kind of composition containing ZJ10520 and ryanodine receptor insecticides - Google Patents
A kind of composition containing ZJ10520 and ryanodine receptor insecticides Download PDFInfo
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Abstract
The invention discloses a kind of Fungicidal insecticidal composition containing ZJ10520 and ryanodine receptor insecticides, the bactericidal and Insecticidal effect of said composition is good, times for spraying is few, drug cost is low, meets the security requirement of pesticidal preparations.
Description
Technical field
The invention belongs to pesticide field, is related to a kind of Fungicidal insecticidal composition for being used to prevent and treat agricultural disease.
Background technology
In agricultural production process, fungal disease and insect are the principal elements for influenceing yield and quality.To improve farming
The yield and quality of thing, the agricultural chemicals of preventing and treating pest and disease damage need to be used, such as insecticide and bactericide.
Conventional insecticide such as four chlorantraniliproles, chlorine fluorine cyanogen insect amide, Rynaxypyr and bromine cyanogen insect amide etc., performance
It is as follows：
Four chlorantraniliproles, chemical name：The bromo- N- of 3- [2,4- bis- chloro- 6- (methyl-carbamoyl) phenyl] -1- (3,5- bis-
Chloro-2-pyridyl) -1H- pyrazoles -5- formamides, it is a kind of bisamide insecticides, it is excellent to lepidoptera pest preventive effect；
Chlorine fluorine cyanogen insect amide, chemical name：The chloro- N1- of 3- (2- methyl -4- sevoflurane isopropyls base)-N2- (1- methyl isophthalic acids -
Cyano ethyl) phthalic amide, it acts on insect ryanodine receptor, promotes the endogenous calcium ion release of insect cell, influences
Contraction of muscle, and then cause insect death；
Rynaxypyr (Chlorantraniliprole), chemical name：The bromo- N- of 3- [4- chloro-2-methyl -6- [(first
Carbamoyl) benzene] -1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- formamides are a kind of Novel ortho formamido benzoyls
Amine insecticide, the ryanodine receptor that it can be in efficient activation insect bodies, the calcium ion in intracellular calcium store is excessively discharged, is caused
Insect paralysis is dead, and various lepidopterous insects are shown with excellent prevention effect；
Bromine cyanogen insect amide (Cyantraniliprole), molecular formula：C19H14BrClN6O2, opened after chlorantraniliprole
The second generation ryanodine receptor inhibitor insecticides of hair, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
But due to much time using, crops show the resistance to the action of a drug to above-mentioned insecticide., will to tackle the resistance to the action of a drug
It is a kind of method therein that insecticide carries out compounding with new type bactericide.Therefore, new type bactericide and insecticide are compounded,
Obtain it is a kind of can controlling disease and can pest control medicament, there is positive effect to agricultural sustainable development.
The content of the invention
It is an object of the invention to provide a kind of composition, have component rationally, pesticide-germicide spectrum is wide, prevention effect is good,
The characteristics of cost is low and dispenser facilitates.
The present invention provides following technical scheme：
A kind of composition, the composition contain two kinds of active components, and the first active component is ZJ10520, second
Active component is selected from ryanodine receptor insecticides.
The first active component that the present invention uses is ZJ10520, and its chemical name is：The fluoro- 1- of 3- (difluoromethyl) -5-
Methyl-N- [2- (the chloro- 4- tri fluoromethy I-phenoxies of 2-) phenyl] pyrazole-4-carboxamide.
The second active ingredient that the present invention uses is selected from ryanodine receptor insecticides.The ryanodine receptor class desinsection
Agent is the ryanodine receptor insecticides that the industry is commonly used.
Preferably, the ryanodine receptor insecticides be selected from chlorantraniliprole, Rynaxypyr, bromine cyanogen insect amide and
At least one of chlorine fluorine cyanogen insect amide.I.e. described ryanodine receptor insecticides can be selected from chlorantraniliprole, chlorine worm benzene first
One kind, two or three of combination of the above in acid amides, bromine cyanogen insect amide and chlorine fluorine cyanogen insect amide.
Sterilizing insecticide sterilizing insecticide sterilizing insecticide composition provided by the invention, to the proportioning of two kinds of active components
Have not a particular requirement.
Preferably, the quality proportioning of described the first active component and second active ingredient is 60:1~1:60.
It may further be preferable that the quality proportioning of the first described active component and second active ingredient is 20:1~1:
20。
It is even furthermore preferable that the quality proportioning of the first described active component and second active ingredient is 10:1~
1:10。
Most preferably, the quality proportioning of described the first active component and second active ingredient is 6:1~1:6.
Composition provided by the invention, it can also further include the third active component.It is described the third activity into
Point, can be selected from nicotinic insecticide, pyridine insecticides, Triazinone insecticide, Insecticidal pyrazolines, thiophosphate
Insecticides, pyrethroid insecticides, triazole type sterilizing insecticide, imidazoles sterilizing insecticide, amide-type sterilization and disinsection
Agent, methoxy acrylic sterilizing insecticide, oxazole classes sterilizing insecticide, dicarboximide class sterilizing insecticide, thiazoles
Sterilizing insecticide, pyroles sterilizing insecticide, morpholine class sterilizing insecticide, pyridines sterilizing insecticide, miazines sterilization and disinsection
Agent, quinolines sterilizing insecticide, organic phosphates sterilizing insecticide, carbamate sterilization insecticide and antibioticses kill
At least one of worm agent.
Sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilization and disinsection
This hair of agent sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide sterilizing insecticide
The composition of bright offer, it is suitable for sterilization and desinsection, it is particularly suitable to be used for agricultural sterilization and desinsection.
Preferably, composition provided by the invention, which is suitable for preventing and treating, is selected from cabbage caterpillar, diamondback moth, beet armyworm, tiltedly
Autographa spp, striped rice borer, yellow rice borer, rice leaf roller, bollworm, root-rot, grub, plant hopper, samping off, root rot, banded sclerotial blight, rice
Bent disease, full rot, spot disease, late blight, rice blast, spike rot, black rot, early blight, rust, powdery mildew, black spot, rust
Disease, scab, glume blight, rust, anthracnose, damping-off, gray mold, smut, leaf spot, downy mildew, epidemic disease, leaf blight,
At least one of brown spot, ring spot, sclerotiniose, droop, bakanae disease and head blight.
It may further be preferable that composition provided by the invention is used to prevent and treat selected from rice-stem borer, rice leaf roller, water
At least one of the sheath and culm blight of rice, diamondback moth, bollworm and cotton seedling blight.
The present invention also provides a kind of sterilizing insecticide, and the sterilizing insecticide contains described more than 0.1% by weight
Composition.
Preferably, the sterilizing insecticide is by weight containing 1~90% composition.
It may further be preferable that the sterilizing insecticide is by weight containing 5~80% composition.
Sterilizing insecticide provided by the invention, in addition to the composition, it can also further include agriculturally being subjected to
Carrier and auxiliary agent.
Carrier of the present invention can be solid or liquid, and any carrier for being generally used for preparing pesticide agent composition is equal
It can use.
Suitable solid carrier includes：Mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance includes
Silicates, carbonate, Sulfates and oxide-based.Silicates such as kaolin, sepiolite, nacrite, cover de-
Soil, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example：Calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulphate,
Calcium sulfate.Oxide-based such as quick lime, magnesium lime, diatomite.Plant is for example：Citrus pulp, corncob cellulose, rice husk powder, rice husk,
Big soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class such as winnofil hydrate, winnofil, white carbon.
Inorganic salts such as potassium chloride, sodium chloride.
Liquid-carrier includes water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilized and antifreeze
Effect.Suitable organic solvent includes aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons；Chloro fat
Fat hydrocarbon, such as vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and more chloroethanes；Aliphatic hydrocarbon, such as oil evaporate
Point, hexamethylene, light mineral oil and paraffin.Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, the third two
Alcohol, glycerine, fatty alcohol etc.；Ethers such as Propylene Glycol ether, ethohexadiol ether, petroleum ether.Ketone such as acetone, first and second
Ketone, methyl iso-butyl ketone (MIBK), cyclohexanone and isophorone, N- methyl-pyrrolidons；Special solvent also has dimethylformamide,
Dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile；Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, and also may be used
To be used in mixed way, can also be mixed together with water.
Auxiliary agent of the present invention can include surfactant, defoamer, thickener, suspending agent and antifreezing agent as needed
In one or more, can also as needed include the industry commonly use other auxiliary agents.
Surfactant can be emulsifying agent, dispersant, stabilizer or wetting agent；Can be ionic or nonionic
's.Suitable surfactant includes：The sodium salt and calcium salt of polyacrylic acid and lignin sulfonic acid；Contain at least 12 carbon in molecule
The aliphatic acid or fatty amine of atom and oxirane and the polycondensation product of/expoxy propane；Glycerine, dodecanol -1, tetradecanol -
1st, the fatty acid ester of sorbierite, sucrose or pentaerythrite；And they with oxirane and/or expoxy propane polycondensation product；It
Polycondensation product sulfate or sulfonate；In the molecule at least the alkali metal of the sulfuric acid containing 10 carbon atoms or sulfonic acid or
Alkali salt, preferably sodium salt, such as lauryl sodium sulfate, Teepol, the sodium salt of sulfonated castor oil, alkaryl
Sodium sulfonate and neopelex；The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifying agent includes nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonyl phenyl of nonionic emulsifier
Vinethene, AEO, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, hold hydroxyl
Base polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.
Anionic emulsifier mainly includes calcium dodecyl benzene sulfonate, three phenethyl phenol polyoxy ether phosphate amine salts, and nonyl phenol gathers
Oxygen vinethene phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention includes：Acrylate homopolymer sodium salt, Malaysia acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product
Sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, three
Phenethyl phenol polyethenoxy ether phosphate, AEO phosphoric acid, one kind in p-hydroxyphenyl lignin sulfonic acid sodium salt
It is or several.
Wetting agent of the present invention includes：AEO, naphthalene sulfonate, lauryl sodium sulfate, alkyl
One or both of phenol resin polyoxyethylene ether sulfate combination of the above.
Thickener of the present invention includes xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, Arab
Glue, gelatin, the one or more in polyvinyl alcohol.
Defoamer of the present invention is preferably：Bubble enemy, silicone, C8~10Fatty alcohol, C10~20Saturated fat acids and acyl
Amine etc..
Sterilizing insecticide of the present invention can be configured to any formulation for agriculturally allowing as needed.
Preferably, the sterilizing insecticide can be configured to powderous preparations, granular formulations, dispersible powderous preparations, can
Disperse particulate preparation, dispersible Formulation, soluble solids preparation, solvable liquid preparation, oil formulation, ultra-low volume preparation,
Dispersible body preparation, emulsion formulations, suspension formulation, suspension emulsion or seed coat agent.
Preferably, the powderous preparations are selected from pulvis, tag powder or floating pulvis.
Preferably, the granular formulations are selected from granule, big granula, granula subtilis, fine granule or microcapsulated granule.
Preferably, the dispersible powderous preparations are selected from wettable powder or oil dispersed pulvis.
Preferably, the dispersible granular preparation is selected from water dispersible granules, milk particle agent or granulae effervescentes.
Preferably, the dispersible Formulation is selected from dispersible tablets or effervescent tablet.
Preferably, the soluble solids preparation is selected from solvable pulvis, soluble granule or soluble tablet.
Preferably, the solvable liquid preparation is selected from soluble concentrate, aqua or can glue.
Preferably, the oil formulation is selected from finish or film-spreading oil solution.
Preferably, the ultra-low volume preparation is selected from ultra low volume liquids or ultra-low volume microcapsule suspending agent.
Preferably, the dispersible body preparation is selected from missible oil or dispersible agent.
Preferably, the emulsion formulations are selected from aqueous emulsion, oil emu or microemulsion.
Preferably, the suspension formulation is selected from suspending agent, microcapsule suspending agent or oil-suspending agent.
Preferably, the seed coat agent is selected from aqueous suspension seed coat agent, dispersible pulvis seed coat agent or dispersible granule kind
Clothing agent.
Composition and sterilizing insecticide of the present invention have following advantage compared with prior art：
Two kinds of active components compounds in composition, can reach sterilization and insecticidal effect simultaneously, can reduce times for spraying,
Drug cost is reduced, and with treatment plus protective effect, meets the security requirement of pesticidal preparations.
Embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses may include in Claims scope
All alternatives, improvement project and equivalents.
First, preparation prepares embodiment
Percentage composition is mass percent in all formulations proportioning.
Embodiment 1,75% chlorine fluorine cyanogen insect amide ZJ10520 water dispersible granules
The preparation method of water dispersible granules is：By formula rate, active compound, dispersant, wetting agent and carrier are mixed, ultra micro
Air-flow crushing, addition are granulated in the comminutor equipped with certain specification screen cloth.Then again through drying, sieve produce graininess production
Product.
It is formulated and is：15% chlorine fluorine cyanogen insect amide, 60%ZJ10520,3% acrylic acid maleic acid homopolymer sodium salt, 2% diffusion
Agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 3% Nekal BX (nekal), 4%K-12 (dodecyl sulphur
Sour sodium), 3% diatomite, 5% glucose, kaolin add to 100%.
Embodiment 2,15% Rynaxypyr ZJ10520 suspending agents
The preparation method of suspending agent is：By formula rate, using water as continuous phase, by active compound, dispersant, wetting agent, suspending
Agent and antifreezing agent etc. are added in batching kettle and are well mixed, and disperse 30min through ball mill or high speed shear, after being sanded with sand mill
Suspending agent is made.
It is formulated to take 3% Rynaxypyr, 12%ZJ10520,4% rosin segmented APEO polyethenoxy ether sulphur
Hydrochlorate, 1% Fatty alcohol polyoxyethylene polyoxypropylene ether, 0.2% xanthans, 3% white carbon, 5% ethylene glycol, 0.3% benzoic acid,
0.5% organic silicon defoamer (trade name：S-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water adds to 100% matter
Measure part.
Embodiment 3,40% 4 chlorantraniliprole ZJ10520 suspending agents
It is formulated and is：15% 4 chlorantraniliprole, 25%ZJ10520,2%NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2%
Acrylate homopolymer sodium salt, 0.1% xanthans, 3% white carbon, 5% propane diols, 0.5% formaldehyde, 0.5% organic silicon defoamer,
Deionized water adds to 100% mass parts.
Prepared according to method in the same manner as in Example 2, obtain 40% 4 chlorantraniliprole ZJ10520 suspending agents.
Embodiment 4,22% bromine cyanogen insect amide ZJ10520 suspending agents
It is formulated and is：20% bromine cyanogen insect amide, 2%ZJ10520,2%NNO, 2% p-hydroxyphenyl lignin sulfonic acid sodium salt,
0.1% xanthans, 3% white carbon, 5% propane diols, 0.5% formaldehyde, 0.5% organic silicon defoamer, deionized water add to 100%
Mass parts.
Prepared according to method in the same manner as in Example 2, obtain 22% bromine cyanogen insect amide ZJ10520 suspending agents.
Embodiment 5,10%ZJ10520 suspending agents
It is formulated and is：10%ZJ10520,5% 3 phenethyl phenol polyoxyethylene ether phosphate, 2% AEO,
5% propane diols, 0.3% defoamer, 0.3% sodium benzoate, 0.2% xanthans, water polishing to 100%.
Prepared according to method in the same manner as in Example 2, obtain 10%ZJ10520 suspending agents.
Embodiment 6,20% chlorine fluorine cyanogen insect amide suspending agent
It is formulated and is：20% bromine cyanogen insect amide, 2%NNO, 3% p-hydroxyphenyl lignin sulfonic acid sodium salt, 0.1% xanthans,
3% white carbon, 5% propane diols, 0.3% sodium benzoate, 0.5% organic silicon defoamer, deionized water add to 100% mass parts.
Prepared according to method in the same manner as in Example 2, obtain 20% chlorine fluorine cyanogen insect amide suspending agent
2nd, Field information test examples
Embodiment 7, preventing and treating rice sheath blight disease field control effectiveness test
Rice sheath blight disease field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " pesticide field efficacy medicine test criterion (one)
GB/T17980.20-2000 bactericidal agent for preventing and treating rice sheath blight disease " carries out field control effectiveness test.Test medicine, comparison medicament and sky
The cell processing compareed in vain is arranged using random district's groups, and plot area 25m2,4 repetitions, this experiment is total to dispenser twice, during dispenser
Rice is in full heading time, and rice sheath blight disease is in early stage.7 days experimental investigation results after 2 medicines.Often experimental plot use pair
5 points of samplings of linea angulata, every investigation are connected 5 clumps, investigate 25 clumps altogether, investigate every clump of every plant of incidence, record disease grade.
Disease scale standard is as follows：
0 grade：It is disease-free；
1 grade：Quaterfoil and its following leaf sheath, blade morbidity are (using sword-like leave as first leaf)；
3 grades：Third blade and its following leaf sheath, blade morbidity；
5 grades：Second blade and its following leaf sheath, blade morbidity；
7 grades：Sword-like leave blade and its following folic acid, blade morbidity；
9 grades：Complete stool falls ill, withered ahead of time.
Drug effect computational methods：
According to investigation result, disease index and preventive effect are calculated according to following (1), (2) formula.Test data uses Deng Kenshi
Duncan's new multiple range method (DMRT) carries out statistical analysis.
In formula：CK1--- disease index after blank district dispenser；
PT1--- disease index after chemicals treatment district dispenser.
Table 1, preventing and treating rice sheath blight disease field control effectiveness test result
Embodiment 8, preventing and treating cotton in seedling stage damping-off field control effectiveness test
Cotton in seedling stage damping-off field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " pesticide field efficacy medicine test criterion
(2) GB/T17980.93-2004 prevents and treats disease in cotton seedling stage " carry out field control effectiveness test.Test medicine, comparison medicament and sky
The cell processing compareed in vain is arranged using random district's groups, plot area 25m2,4 repetitions, Dressing, is sowed within 4 days after seed dressing.
100 plants of cotton seedlings of being chosen at random per cell investigate protection effects.
Disease scale standard is as follows：
0 grade：Basal part of stem disease-free spot；
1 grade：Basal part of stem scab accounts for less than the 1/3 of whole stem girth；
3 grades：Basal part of stem scab accounts for less than the 1/3~1/2 of whole stem girth；
5 grades：Basal part of stem scab accounts for less than the 1/2~3/4 of whole stem girth；
7 grades：Basal part of stem scab accounts for more than the 3/4 of whole stem girth.
Drug effect computational methods：
According to investigation result, disease index and preventive effect are calculated according to following (1), (2) formula.Test data uses Deng Kenshi
Duncan's new multiple range method (DMRT) carries out statistical analysis.
Table 2, preventing and treating cotton seedling blight field test results
| Chemicals treatment | Active ingredient amount (gram/ha) | Preventive effect % |
| 15% Rynaxypyr ZJ10520 suspending agents | 100 | 83.09 |
| 40% 4 chlorantraniliprole ZJ10520 suspending agents | 100 | 85.06 |
| 22% bromine cyanogen insect amide ZJ10520 suspending agents | 100 | 79.66 |
| 10%ZJ10520 suspending agents (self-control) | 100 | 78.23 |
Embodiment 9, preventing and treating rice-stem borer field control effectiveness test
Rice-stem borer field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.1-2000 agricultural chemicals field
The regulation of test of pesticide effectiveness criterion (one) --- insecticide control rice Lepidoptera borer pest ", test medicine, comparison medicament and
The cell processing of blank control is arranged using random district's groups, plot area 25m2, 4 repetitions, this experiment amounts to dispenser twice the
Striped rice borer is in initial phase during dispenser, and secondary medicine is applied in 1 week in interval.This experiment, which amounts to, to be investigated 1 time, per experimental plot using flat
The 5 points of samplings of row great-jump-forward, 25 clumps of rice of every investigation, the blank district present age, which causes harm, determines rear profile investigation withered heart rate.
Withered heart rate %=investigates withered calculation/investigation total strain number
Preventive effect %=(CK-PT) × 100/CK
In formula：CK --- withered heart rate after blank district dispenser；PT --- withered heart rate after chemicals treatment district dispenser.
Table 3, preventing and treating rice-stem borer field control effectiveness test result
Embodiment 10, preventing and treating paddy rice rice leaf roller field control effectiveness test
Paddy rice rice leaf roller field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.2-2000 agricultural chemicals
The regulation of field control effectiveness test criterion (one) --- insecticide control rice leaf roller ", test medicine, comparison medicament and blank pair
According to cell processing using random district's groups arrange, plot area 25m2, 4 repetitions, dispenser is applied for the first time twice altogether for this experiment
Medicine is in rice plant of tillering stage, and second of dispenser is in ovum peak period.This experiment, which amounts to, to be investigated 1 time, and parallel jump is used per experimental plot
5 points of samplings of formula, 25 clumps of rice of every investigation, investigate leaf roll rate.
Withered heart rate %=investigation leaf rolls number/investigation total strain number
Preventive effect %=(CK-PT) × 100/CK
In formula：CK --- leaf roll rate after blank district dispenser；PT --- leaf roll rate after chemicals treatment district dispenser.
Table 4, preventing and treating paddy rice rice leaf roller field control effectiveness test result
Embodiment 11, preventing and treating cotton pink bollworm field control effectiveness test
Cotton pink bollworm field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.73-2004 agricultural chemicals field
The regulation of test of pesticide effectiveness criterion (two) --- insecticide control cotton pink bollworm ", test medicine, comparison medicament and blank control
Cell processing is arranged using random district's groups, plot area 30m2, 4 repetitions, dispenser first time dispenser twice exists altogether for this experiment
The first peak period of spawning, second of dispenser is in spawning period.This experiment, which amounts to, to be investigated 2 times, 15 days and 20 days each tune after dispenser
Look into once.50, middle and upper part smalt bell is won at random per cell, often handles and adopts 200 altogether, and stripping verification certificate bell is lived out number.
Insecticidal effect %=(the bell seed of blank district hundred flower amount containing worm-chemicals treatment district hundred bell seed flower amount containing worm) × 100/
The bell seed of blank district hundred spends amount containing worm
Table 5, preventing and treating cotton pink bollworm field control effectiveness test result
Embodiment 12, preventing and treating lopper worm field control effectiveness test
Brassicaceous vegetable lepidopterous larvae field control effectiveness test is prevented and treated with reference to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.13-
The regulation of 2000 pesticide field efficacy medicine test criterions (one) ", test medicine, comparison medicament and the processing of the cell of blank control use
Random district's groups arrangement, plot area 15m2, 4 repetitions, this experiment dispenser 1 time altogether, carried out when having sufficient amount of larva.
This experiment, which amounts to, to be investigated 3 times, before processing investigation radix, is respectively investigated once within 3 days and 14 days after dispenser.Investigated not per cell
The work larva number of different larval instar, investigates whole plant on less than 10 plants crops.
Preventive effect %=(CK1×PT0-CK0×PT1)×100/CK1×PT0
Table 6, preventing and treating lopper worm field control effectiveness test result
It was found from above example, composition provided by the invention can be good at preventing and treating rice-stem borer, cnaphalocrocis
Snout moth's larva, rice sheath blight disease, diamondback moth, bollworm and cotton seedling blight, diseases prevention and vermins-proof effect are notable, and drug cost is low, dispenser side
Just, and to crop safety, the security requirement of pesticidal preparations is met.
Claims (14)
1. a kind of composition, it is characterised in that the composition contains two kinds of active components, and the first active component is
ZJ10520, second active ingredient are selected from ryanodine receptor insecticides.
2. according to the composition described in claim 1, it is characterised in that the ryanodine receptor insecticides are selected from tetrachloro worm acyl
At least one of amine, Rynaxypyr, bromine cyanogen insect amide and chlorine fluorine cyanogen insect amide.
3. according to the composition described in claim 1, it is characterised in that described the first active component and second active ingredient
Quality proportioning be 60:1~1:60.
4. according to the composition described in claim 3, it is characterised in that described the first active component and second active ingredient
Quality proportioning be 20:1~1:20.
5. according to the composition described in claim 4, it is characterised in that described the first active component and second active ingredient
Quality proportioning be 10:1~1:10.
6. according to the composition described in claim 5, it is characterised in that described the first active component and second active ingredient
Quality proportioning be 6:1~1:6.
7. according to the composition described in claim 1, it is characterised in that the composition further containing the third activity into
Point, the third described active component is selected from nicotinic insecticide, pyridine insecticides, Triazinone insecticide, pyrazoles desinsection
Agent, thiophosphate insecticides, pyrethroid insecticides, triazole bactericidal agent, imidazoles series bactericidal agent, amide-type sterilization
Agent, methoxy acrylic bactericide, oxazole series bactericidal agent, dicarboximide series bactericidal agent, thiazole series bactericidal agent, pyroles
Bactericide, morpholine bactericide, pyridine series bactericidal agent, pyrimidine series bactericidal agent, quinoline series bactericidal agent, organic phosphorus type disinfectant, ammonia
At least one of carbamate series bactericidal agent and antibioticses bactericide.
8. a kind of sterilizing insecticide, it is characterised in that the sterilizing insecticide contains the combination more than 0.1% by weight
Thing.
9. according to the sterilizing insecticide described in claim 8, it is characterised in that the sterilizing insecticide by weight containing 1~
90% composition.
10. according to the sterilizing insecticide described in claim 9, it is characterised in that the sterilizing insecticide by weight containing 5~
80% composition.
11. according to the sterilizing insecticide described in claim 8, it is characterised in that the sterilizing insecticide can prepare powdering system
Agent, granular formulations, dispersible powderous preparations, dispersible granular preparation, dispersible Formulation, soluble solids preparation, can
Solution body preparation, oil formulation, ultra-low volume preparation, dispersible body preparation, emulsion formulations, suspension formulation, suspension emulsion or kind clothing
Agent.
12. according to the sterilizing insecticide described in claim 11, it is characterised in that：The powderous preparations are selected from pulvis, powder of tagging
Or floating pulvis, the granular formulations are selected from granule, big granula, granula subtilis, fine granule or microcapsulated granule, described dispersible
Powderous preparations are selected from wettable powder or oil dispersed pulvis, the dispersible granular preparation be selected from water dispersible granules, milk particle agent or
Granulae effervescentes, the dispersible Formulation are selected from dispersible tablets or effervescent tablet, and the soluble solids preparation is selected from can
Molten pulvis, soluble granule or soluble tablet, the solvable liquid preparation be selected from soluble concentrate, aqua or can glue, the oil
Preparation is selected from finish or film-spreading oil solution, and the ultra-low volume preparation is selected from ultra low volume liquids or ultra-low volume microcapsule suspending agent,
The dispersible body preparation is selected from missible oil or dispersible agent, and the emulsion formulations are selected from aqueous emulsion, oil emu or microemulsion,
The suspension formulation is selected from suspending agent, microcapsule suspending agent or oil-suspending agent, and the seed coat agent is selected from aqueous suspension seed coat agent, dispersible
Powder seed coating agent or dispersible granule seed coat agent.
13. according to the composition described in claim 1, it is characterised in that the composition, which is used to prevent and treat, is selected from cabbage caterpillar, pickles
Moth, beet armyworm, prodenia litura, striped rice borer, yellow rice borer, rice leaf roller, bollworm, root-rot, grub, plant hopper, samping off, root
It is maize ear rot, banded sclerotial blight, false smut, full rot, spot disease, late blight, rice blast, spike rot, black rot, early blight, rust, white
Powder disease, black spot, rust, scab, glume blight, rust, anthracnose, damping-off, gray mold, smut, leaf spot, downy mildew
At least one of disease, epidemic disease, leaf blight, brown spot, ring spot, sclerotiniose, droop, bakanae disease and head blight.
14. according to the composition described in claim 1, it is characterised in that the composition be used for prevent and treat selected from rice-stem borer,
At least one of rice leaf roller, rice sheath blight disease, diamondback moth, bollworm and cotton seedling blight.
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| CN201610561409.XA CN107616176B (en) | 2016-07-14 | 2016-07-14 | Composition containing ZJ10520 and ryanodine receptor insecticide |
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| CN201610561409.XA CN107616176B (en) | 2016-07-14 | 2016-07-14 | Composition containing ZJ10520 and ryanodine receptor insecticide |
Publications (2)
| Publication Number | Publication Date |
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| CN107616176A true CN107616176A (en) | 2018-01-23 |
| CN107616176B CN107616176B (en) | 2020-06-09 |
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| CN201610561409.XA Active CN107616176B (en) | 2016-07-14 | 2016-07-14 | Composition containing ZJ10520 and ryanodine receptor insecticide |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021062338A1 (en) * | 2019-09-27 | 2021-04-01 | Fmc Corporation | Anthranilamide composition |
| WO2021127126A1 (en) * | 2019-12-19 | 2021-06-24 | Fmc Corporation | Diamide suspension concentrate compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103391925A (en) * | 2010-11-15 | 2013-11-13 | 拜耳知识产权有限责任公司 | 5-halogenopyrazolecarboxamides |
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
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2016
- 2016-07-14 CN CN201610561409.XA patent/CN107616176B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103391925A (en) * | 2010-11-15 | 2013-11-13 | 拜耳知识产权有限责任公司 | 5-halogenopyrazolecarboxamides |
| CN104557709A (en) * | 2013-10-23 | 2015-04-29 | 华中师范大学 | Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021062338A1 (en) * | 2019-09-27 | 2021-04-01 | Fmc Corporation | Anthranilamide composition |
| CN114430657A (en) * | 2019-09-27 | 2022-05-03 | Fmc公司 | Anthranilamide compositions |
| WO2021127126A1 (en) * | 2019-12-19 | 2021-06-24 | Fmc Corporation | Diamide suspension concentrate compositions |
| CN114828628A (en) * | 2019-12-19 | 2022-07-29 | Fmc公司 | Diamide suspension concentrate compositions |
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| Publication number | Publication date |
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| CN107616176B (en) | 2020-06-09 |
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