CN107568224A - Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion - Google Patents
Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion Download PDFInfo
- Publication number
- CN107568224A CN107568224A CN201710851138.6A CN201710851138A CN107568224A CN 107568224 A CN107568224 A CN 107568224A CN 201710851138 A CN201710851138 A CN 201710851138A CN 107568224 A CN107568224 A CN 107568224A
- Authority
- CN
- China
- Prior art keywords
- bactericidal composition
- flumorph
- metalaxyl
- active ingredient
- suspension emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of bactericidal composition, its active ingredient is flumorph and Metalaxyl-M, and both mass ratioes are 10:1~1:10, preferably 2:1~1:2, the gross mass percentage composition of active ingredient is 10% ~ 50%.Bactericidal composition of the present invention can be made into suspension emulsion.There is obvious synergistic effect after bactericidal composition compounding of the present invention, especially there is good prevention effect to vegetables, fruit tree downy mildew.
Description
Technical field
The present invention relates to a kind of bactericidal composition, the bactericidal composition especially containing flumorph and Metalaxyl-M, belongs to agriculture
Medicine technical field.
Background technology
Flumorph：English name：Flumorph, chemical name：(E, Z) 4- [3- (3', 4'- Dimethoxyphenyl) -3-
(4- fluorophenyls) acryloyl] morpholine, molecular formula：C21H22FNO4.The medicine is acryloyl morpholine series bactericidal agent, have efficiently, low toxicity,
Low-residual, the longevity of residure be long, protection and therapeutic action are had both, to crop safety the features such as.Cucumber downy mildew is prevented with good
Control effect.
Metalaxyl-M：English name：Metalaxyl-m, chemical name：N-（2,6- xylyls）-N-（Methoxyl group acetyl
Base）- D- alanine methyl esters, No. CAS：70630-17-0, molecular formula：C15H21NO4.Metalaxyl-M to Pseudoperonospora cubensis, phytophthora germ,
The crop diseases such as vegetables, fruit tree, tobacco, oil plant, cotton, grain caused by rotten mildew fungus have the preventing and treating of efficient lasting period length
Effect.
In the real process of agricultural production, single chemical pesticide, which is applied, easily produces resistance, and different active ingredients are compounded,
It is to prevent and treat one of very common method of resistance disease.By inventor's grinding by a large amount of indoor biometricses and field control effectiveness test
Study carefully, it is found that flumorph and Metalaxyl-M are combined application, there is obvious synergistic effect, and about flumorph and Metalaxyl-M phase
Compounding is closed, at present at home and abroad there is not yet relevant report.
The content of the invention
It is an object of the present invention to propose a kind of bactericidal composition containing flumorph and Metalaxyl-M in preventing and treating vegetables, fruit
Set the application in downy mildew.
Bactericidal composition and application proposed by the present invention containing flumorph and Metalaxyl-M suspension emulsion, it is characterised in that：Institute
State bactericidal composition and contain active ingredient flumorph and active ingredient Metalaxyl-M, both mass ratioes are 10:1~1:10；Both
Mass ratio be preferably 2:1~1:2.
The content of active ingredient depends on activity of the active ingredient to target disease in the bactericidal composition of the present invention,
Compound proportion and synergistic effect degree depending on two kinds of active ingredient.Total matter of active ingredient in the usual bactericidal composition
It is 10% ~ 50%, preferably 15% ~ 40% to measure percentage composition.
The bactericidal composition of the present invention can be made into suspension emulsion, and each component mass percent composition is：Active ingredient flumorph
0.5% ~ 50%, active ingredient Metalaxyl-M 0.5% ~ 50%, emulsifying agent 2% ~ 12%, dispersant 2% ~ 10%, defoamer 0.1% ~ 1%, increasing
Thick dose 0.1% ~ 2%, antifreezing agent 0.1% ~ 8%, deionized water add to 100%.
The bactericidal composition of the present invention, suspension emulsion is adjuvant used to be：Emulsifying agent is selected from alkyl benzene sulfonate calcium salt, styrene gathers
Oxygen vinethene ammonium sulfate, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, phenethyl phenol polyethenoxy ether, NP-10 phosphoric acid
One or more in ester, OP-10 phosphates, castor oil polyoxyethylene ether, sorbester p17, Tween 80.Dispersant is selected from alkylnaphthalene
Sulfonate, naphthalene sulfonic acid-formaldehyde condensation product, arylphenol polyoxyethylene succinate sulfonate, octyl phenol polyoxyethylene ether sulfuric acid
Salt, polycarboxylate, lignosulfonates, APES formaldehyde condensation products sulfat, alkyl benzene sulfonate calcium salt, naphthalene sulphur
Sour formaldehyde condensation products sodium salt, APES, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, ester polyoxy second
One or more in alkene ether.Defoamer is selected from C8~10Aliphatic alcohols, C10~20Saturated fat acids（Such as capric acid）And acid amides, silicon
One or more in oil, organosilicon ketone compound.Thickener be selected from xanthans, hydroxymethyl cellulose, hydroxyethyl cellulose,
One or more in methylcellulose, aluminium-magnesium silicate, polyvinyl alcohol.Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, poly-
One or more in ethylene glycol.
The bactericidal composition of the present invention, has good prevention effect to vegetables, fruit tree downy mildew.
The bactericidal composition of the present invention has the advantage that：
First, said composition shows significant synergistic effect in certain ratio range, both improves protection effect, reduces
Mu dosage and cost, expand fungicidal spectrum again；
Second, due to the problem of cross resistance is not present in each active ingredient in said composition, therefore the application of said composition can reach
To the drug-fast occurrence and development of pathogen are delayed, help to extend the using effect of the medicament, reduce the resistance to the action of a drug and produce probability；
3rd, security is improved, influence of the mixture to environment will be lower, safer.
Therefore, the bactericidal composition has preferable economic benefit and environmental benefit, has larger application value.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not this.Percentage in embodiment is mass percent.
Implementation of an application example one：The Toxicity Determination experiment of flumorph and Metalaxyl-M compounding
Toxicity Determination of the toxicity test embodiment 1 to cucumber downy mildew
Subjects：Cucumber downy mildew
Test method：Standard method NY/T 1156.3-2006, NY/T 1156.6-2006 are surveyed with reference to raw, using plate blade
Method：With micro intravenous drip device by the back side of cucumber leaves of the ready μ L drops of Fresh spores capsule suspension 10 in chemicals treatment,
Each blade inoculation 4 is dripped, and often processing is no less than 5 leaves, and each processing is repeated 4 times.Ware lid is covered after inoculation, is placed on 19 ± 1
DEG C, in the light irradiation biochemical incubator of relative humidity 90%（Light To Dark Ratio is 12:12）Cultivate, carried out after blade inoculation 24h at medicament
Reason.By various concentrations decoction well prepared in advance, ASS-4 types metered dose tower even spraying to ready moisturizing in advance is used
The back side of blade, the MPa of atomisation pressure 0.3.It is standby after decoction natural air drying.Using the aqueous solution containing 0.1% Tween 80 as pair
According to.Ware lid is covered after chemicals treatment, is placed on 19 ± 1 DEG C, in the light irradiation biochemical incubator of relative humidity 90%（Light To Dark Ratio is
12:12）Culture.Investigated according to cucumber leaves incidence in control treatment culture dish, measure 5 scabs of each blade
Size, the longitudinal and transverse footpath of scab is measured with ruler（cm）, each bacterium colony is each once with the longitudinal and transverse footpath of crossing method vertical survey, makes even
Average.According to measurement result, according to the prevention effect of each concentration for the treatment of of formula calculating, then using DPS data processing software meters
Result of the test is calculated, obtains virulence regression equation, the EC of test medicine single dose and different ratio mixture respectively50And EC90And 95%
Confidence limit, and seek the co-toxicity coefficient of two kinds of medicament different ratios（CTC）, filter out the optimum proportioning of test medicine.And record every
The initial data of individual all repetitions of processing.
Growth inhibition ratio (I) %=（The lesion diameter of lesion diameter-processing of blank control）The lesion diameter of/blank control
×100
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100
Mixture theoretical toxicity index (TTI)=medicament A toxicity indexes × A medicaments percentage (%)+medicament B shared in mixture
Toxicity index × B medicaments percentage (%) shared in mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
Co-toxicity coefficient CTC >=120 of complex preparation show as synergistic effect, and 80 ＜ CTC ＜ 120 show as summation action, and CTC≤
80 show as antagonism.Toxicity Determination result of the test, refer to table 1.
Above result of the test shows, flumorph and Metalaxyl-M compounding preventing and treating cucumber downy mildew, matches 10:1~1:10 it
Between when, co-toxicity coefficient has synergistic effect all more than 120；And 2:1~1:When between 2, co-toxicity coefficient is above 180, increases
Effect effect becomes apparent from.
Toxicity test embodiment 2 is tested the Toxicity Determination of downy mildew of garpe
Subjects：Plasmopara viticola（Plasmopara uiticola(Berk.dt Curtis)Berl. Et de Toni）
Test method：Standard method NY/T 1156.3-2006 are surveyed with reference to raw, using plate blade method.
Incidence of leaf is selected, lower blade back side Pseudoperonospora cubensis sporangium is washed with 4 DEG C of distillations, is made into suspension（Concentration control
System is at every milliliter 1 × 105Individual ~ 1 × 107Individual sporangium）, deposit at 4 DEG C standby.The various concentrations decoction prepared is uniformly sprayed
Vacuum side of blade is imposed on, after decoction natural air drying, by each processing blade and blade backwards to upper, moisture preservation box is emitted on after being marked according to processing
In.After chemicals treatment 24 hours, vacuum side of blade is inoculated in ready Fresh spores capsule suspension drop 10uL.Per blade
The drop of inoculation 4, often handles 5 leaves, and experiment sets the processing without medicament and makees blank control.Ware lid is covered after inoculation, is placed in artificial gas
Case is waited, in 12 hours alternatings of daily continuous illumination/dark, temperature is 17 DEG C ~ 22 DEG C, is trained under conditions of relative humidity more than 90%
Support.
Measured depending on processing and blank control incidence and record lesion diameter, unit is millimeter, calculates prevention effect.It is logical
The linear regression analysis crossed between the probit value of prevention effect and the logarithm value of series concentration, obtain the EC of each medicament50Value.Use grandson
Yun Peifa calculates the co-toxicity coefficient of mixture（CTC）, activity of the reagent agent to germ is evaluated with this.
Prevention effect (P) %=[blank control lesion diameter (D0)-processing lesion diameter (D1)]/blank control scab is straight
Footpath (D0)×100
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) × 100
Mixture theoretical toxicity index (TTI)=medicament A toxicity indexes × A medicaments percentage (%)+medicament B shared in mixture
Toxicity index × B medicaments percentage (%) shared in mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
Co-toxicity coefficient CTC >=120 of complex preparation show as synergistic effect, and 80 ＜ CTC ＜ 120 show as summation action, and CTC≤
80 show as antagonism.Toxicity Determination result of the test, refer to table 2.
Above result of the test shows, flumorph and Metalaxyl-M compounding preventing and treating downy mildew of garpe, matches as 10:1~1:10 it
Between when, co-toxicity coefficient has synergistic effect to downy mildew of garpe, especially 2 all more than 120:1~1:When between 2, poison is altogether
Number is more than 180.
Implementation of an application example two：Flumorph and Metalaxyl-M compound product example of formulations（Following content is hundred percentages of folding
Content）, but the present invention is not limited to the proportion in following examples.
The specific procedure of processing of bactericidal composition suspension emulsion is：According to above-mentioned formula by dispersant, defoamer, thickener,
Antifreezing agent, preservative add flumorph by high speed shear is well mixed, and ball milling 2 ~ 3 hours, make diameter of particle in ball mill
All below 5 μm, flumorph suspending agent is made, it is then that Metalaxyl-M, emulsifying agent and various auxiliary agent high speed agitators is straight
Emulsification is connect into suspending agent, you can suspension emulsion of the present invention is made.
The flumorph Metalaxyl-M suspension emulsion of example of formulations 1 40%
Flumorph 15%, Metalaxyl-M 25%, OP-10 phosphates（Emulsifying agent）10%th, octylphenol polyethylene oxyethylene group ether sulfate（Point
Powder）6%th, capric acid（Defoamer）0.5%th, hydroxyethyl cellulose（Thickener）0.1%th, glycerine（Antifreezing agent）0.1%th, sodium benzoate
（Preservative）0.1%th, deionized water adds to 100%, and 40% flumorph Metalaxyl-M suspension emulsion is made.
The flumorph Metalaxyl-M suspension emulsion of example of formulations 2 30%
Flumorph 15%, Metalaxyl-M 15%, sorbester p17（Emulsifying agent）8%th, APES（Dispersant）8%th, silicone oil（Disappear
Infusion）0.6%th, methylcellulose（Thickener）0.2%th, polyethylene glycol（Antifreezing agent）0.2%th, sodium propionate（Preservative）0.2%th, go from
Sub- water adds to 100%, and 30% flumorph Metalaxyl-M suspension emulsion is made.
The flumorph Metalaxyl-M suspension emulsion of example of formulations 3 30%
Flumorph 10%, Metalaxyl-M 20%, castor oil polyoxyethylene ether（Emulsifying agent）8%th, alkylnaphthalene sulfonate（Dispersant）5%、
Organic silicone（Defoamer）0.2%th, polyvinyl alcohol（Thickener）0.3%th, ethylene glycol（Antifreezing agent）0.3%th, dimethyl fumarate（It is anti-
Rotten agent）0.1%th, deionized water adds to 100%, and 30% flumorph Metalaxyl-M suspension emulsion is made.
The flumorph Metalaxyl-M suspension emulsion of example of formulations 4 25%
Flumorph 5%, Metalaxyl-M 20%, styrene polyoxyethylene ether ammonium sulfate salt（Emulsifying agent）8%th, aliphatic amine polyoxyethylene ether
（Dispersant）8%th, organosilicon ketone compound（Defoamer）0.6%th, xanthans（Thickener）0.2%th, polyethylene glycol（Antifreezing agent）
0.2%th, sodium propionate（Preservative）0.2%th, deionized water adds to 100%, and 25% flumorph Metalaxyl-M suspension emulsion is made.
The flumorph Metalaxyl-M suspension emulsion of example of formulations 5 15%
Flumorph 10%, Metalaxyl-M 5%, triethanolamine salt（Emulsifying agent）8%th, polyoxyethylene carboxylate（Dispersant）5%th, it is organic
Silicone（Defoamer）0.2%th, aluminium-magnesium silicate（Thickener）0.3%th, glycerine（Antifreezing agent）0.3%th, dimethyl fumarate（Preservative）
0.1%th, deionized water adds to 100%, and 15% flumorph Metalaxyl-M suspension emulsion is made.
Implementation of an application example three：Flumorph and the field control effectiveness test of Metalaxyl-M compounding
Field information embodiment 1 prevents and treats the field control effectiveness test of cucumber downy mildew
Test site：Cucumber downy mildew is chosen to fall ill throughout the year heavier plot.
Test method：Reference《Pesticide field efficacy medicine test criterion（Two）Bactericide GB/T 17980.26-2000》, experiment
Medicament, the cell processing of blank control use random alignment, plot area 30m2, 4 repetitions are often handled, are handled with equivalent clear water
As blank control.Application process is spraying.In cucumber downy mildew early stage dispenser, whole breeding time dispenser 2 times, 7- is spaced
Dispenser in 10 days 1 time.
Spraying times：2 times, investigation and statistical method：Take 4 points of investigation at random per cell, investigate 2 plants, every plant of investigation at every
Whole blades；State of an illness radix is investigated before medicine, 7-14 days investigation preventive effects before next medicine and after last medicine.
Stage division：
0 grade:Disease-free spot：
1 grade:Lesion area accounts for less than the 5% of whole leaf area；
3 grades:Lesion area accounts for the 6-10% of whole leaf area；
5 grades:Lesion area accounts for the 11-25% of whole leaf area；
7 grades:Lesion area accounts for the 26-50% of whole leaf area；
9 grades:Lesion area accounts for more than the 50% of whole leaf area.
Drug effect metering method：
Disease index=Σ（The sick numbers of sheets at different levels × relative value of series）/（Investigate total number of sheets × 9）×100
Sick leaf rate（%）=sick the number of sheets/investigation total number of sheets × 100
Prevention effect（%）=[1-（Before blank district medicine after disease index × treatment region medicine after disease index/blank district medicine
Disease index before disease index × treatment region medicine）]×100
The result of the test of table 3 shows, flumorph and Metalaxyl-M preventive effect on preventing and treating cucumber downy mildew are notable, preventive effect be 92.80 % ~
96.08%；The flumorph wettable powder preventive effect of comparison medicament 20% is 79.46 %, 68% smart first frost MnZn water dispersible granules preventive effect
For 78.64%；It is substantially better than preventive effect of the comparison medicament to cucumber downy mildew.It is safe to cucumber in the range of this experiment dosage,
Have no adverse effects.
Field information embodiment 2 prevents and treats the field control effectiveness test of downy mildew of garpe
Test site：This test arrangement is chosen downy mildew and fallen ill throughout the year heavier vineyard in Yueyang Junshan District.
Test method：Reference《Pesticide field efficacy medicine test criterion（Two）Bactericidal agent for preventing and treating downy mildew of garpe GB/T
17980.122-2004》, test medicine, the cell processing of blank control use random alignment, each 8 ~ 15 plants of cell, often handled
4 repetitions, blank control is used as using the processing of equivalent clear water.Application process is spraying, until the positive and negative of blade uniformly squirts.
Downy mildew of garpe early stage starts dispenser, whole breeding time dispenser 3 times, 7 ~ 10 days dispenser intervals.
Investigation and statistical method：Pumping is newly climing then for every cell random searching 10, investigates whole blades from top to bottom, presses
Following stage division records the sick numbers of sheets and total number of sheets at different levels.State of an illness radix is investigated before usual dispenser, before next dispenser and last is applied
7 days ~ 14 days investigation prevention effects after medicine, record spraying times, each dispenser date and Crop growing stage.
Blade stage division：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for less than the 5% of whole leaf area；
3 grades：Lesion area accounts for the 6% ~ 25% of whole leaf area；
5 grades：Lesion area accounts for the 26% ~ 50% of whole leaf area；
7 grades：Lesion area accounts for the 51% ~ 75% of whole leaf area；
9 grades：Lesion area accounts for more than the 76% of whole leaf area.
Drug effect metering method：
Disease index=Σ（The sick numbers of sheets at different levels × relative value of series）/（Investigate total number of sheets × 9）×100
Sick leaf rate（%）=sick the number of sheets/investigation total number of sheets × 100
Prevention effect（%）=[1-（Before blank district medicine after disease index × treatment region medicine after disease index/blank district medicine
Disease index before disease index × treatment region medicine）]×100
As can be known from Table 4, bactericidal composition of embodiment of the present invention flumorph and the Metalaxyl-M preventive effect in preventing and treating downy mildew of garpe
Significantly, preventive effect is above 94%；And 20% flumorph wettable powder control preventive effect is 64.61%, 68% smart first frost MnZn moisture
Shot agent control preventive effect is 60.38%；It is substantially better than preventive effect of the control to downy mildew of garpe.Field test results fully show, fluorine
Morpholine and Metalaxyl-M certain proportion compounding have obvious synergistic function to downy mildew of garpe, in this experiment dosage model
In enclosing, to grape safety, have no adverse effects.
Table of field test results afterwards by different places throughout the country is bright, bactericidal composition fluorine of the present invention
Quinoline and Metalaxyl-M compounding, have significant synergistic effect, preventive effect is prevented more than 90% better than single dose to vegetables, fruit tree downy mildew
Effect, synergy are obvious.
Claims (6)
1. bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion, it is characterised in that：The bactericidal composition contains
There are active ingredient flumorph and active ingredient Metalaxyl-M, both mass ratioes are 10:1~1:10.
2. bactericidal composition according to claim 1, it is characterised in that：Active ingredient flumorph and active ingredient essence first frost
Spirit, both mass ratioes are preferably 2:1~1:2.
3. bactericidal composition according to any one of claim 1 to 2, it is characterised in that：In bactericidal composition effectively into
The gross mass percentage composition divided is 10% ~ 50%, preferably 15% ~ 40%.
4. bactericidal composition according to claim 3, it is characterised in that：Composition can be made into suspension emulsion, each component quality
Percentage forms：Active ingredient flumorph 0.5% ~ 50%, active ingredient Metalaxyl-M 0.5% ~ 50%, emulsifying agent 2% ~ 12%,
Dispersant 2% ~ 10%, defoamer 0.1% ~ 1%, thickener 0.1% ~ 2%, antifreezing agent 0.1% ~ 8%, deionized water add to 100%.
5. bactericidal composition according to claim 4, it is characterised in that：It is adjuvant used that suspension emulsion is made in composition：Emulsification
Agent is selected from alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine
Salt, phenethyl phenol polyethenoxy ether, NP-10 phosphates, OP-10 phosphates, castor oil polyoxyethylene ether, sorbester p17, Tween 80
In one or more；Dispersant is selected from alkylnaphthalene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate
Sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the contracting of APES formaldehyde
Compound sulfate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, fatty amine polyoxy second
One or more in alkene ether, polyoxyethylene carboxylate, ester APEO；Defoamer is selected from C8~10Aliphatic alcohols, C10~20
Saturated fat acids（Such as capric acid）And the one or more in acid amides, silicone oil, organosilicon ketone compound；Thickener is selected from xanthan
One or more in glue, hydroxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, aluminium-magnesium silicate, polyvinyl alcohol；It is antifreeze
One or more of the agent in ethylene glycol, propane diols, glycerine, polyethylene glycol.
6. the bactericidal composition according to claim 1-5 has good prevention effect to vegetables, fruit tree downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710851138.6A CN107568224A (en) | 2017-09-20 | 2017-09-20 | Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710851138.6A CN107568224A (en) | 2017-09-20 | 2017-09-20 | Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107568224A true CN107568224A (en) | 2018-01-12 |
Family
ID=61032815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710851138.6A Pending CN107568224A (en) | 2017-09-20 | 2017-09-20 | Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107568224A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114711241A (en) * | 2022-05-05 | 2022-07-08 | 山东亿嘉农化有限公司 | Bactericidal composition containing flumorph and metalaxyl-M and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104957151A (en) * | 2015-06-17 | 2015-10-07 | 湖南化工研究院有限公司 | Sterilization composition |
| CN105409976A (en) * | 2015-12-19 | 2016-03-23 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing efficient metalaxyl-M and flumorph |
-
2017
- 2017-09-20 CN CN201710851138.6A patent/CN107568224A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104957151A (en) * | 2015-06-17 | 2015-10-07 | 湖南化工研究院有限公司 | Sterilization composition |
| CN105409976A (en) * | 2015-12-19 | 2016-03-23 | 青岛奥迪斯生物科技有限公司 | Sterilization composition containing efficient metalaxyl-M and flumorph |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114711241A (en) * | 2022-05-05 | 2022-07-08 | 山东亿嘉农化有限公司 | Bactericidal composition containing flumorph and metalaxyl-M and application thereof |
| CN114711241B (en) * | 2022-05-05 | 2023-10-20 | 山东亿嘉农化有限公司 | Sterilization composition containing flumorph and metalaxyl-M and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106508970B (en) | A kind of combination sterilization composition and its application | |
| CN103719120A (en) | Sterilization composition containing pyraclostrobin and boscalid | |
| CN103828827A (en) | Insecticidal composition containing sulfoxaflor and spirotetramat | |
| CN102308825A (en) | Germicide composition in combination with bupirimate | |
| CN104521988B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of tiger glue adipic acid copper and preparation | |
| CN107439551A (en) | Bactericidal composition containing kasugarnycin and copper rosinate | |
| CN104430375A (en) | Fungicidal composition | |
| CN107568224A (en) | Bactericidal composition and application containing flumorph and Metalaxyl-M suspension emulsion | |
| CN104365611B (en) | A kind of bactericidal composition and application containing amisulbrom and mandipropamid | |
| CN102657179B (en) | Sterilization composition containing phenylate diazole and trifloxystrobin | |
| CN105028423A (en) | Insecticidal composition containing spinetoram and pyridaben and use of insecticidal composition | |
| CN105230639B (en) | A kind of composition pesticide containing matrine and kasugarnycin | |
| CN108770872A (en) | The compound pesticide preparation and its preparation of a kind of carvacrol and Folium Isatidis extract and application | |
| CN108353910A (en) | A kind of agriculture bactericidal composition containing ether azoles sulfanilamide (SN) ester type compound and prothioconazoles | |
| CN104542658B (en) | Compound bactericide and preparation method thereof | |
| CN114190395A (en) | Application of bactericidal composition containing tetramycin and oxine-copper in preventing and treating plant xanthomonas diseases | |
| CN103314986B (en) | Cycloxaprid and spirotetramat-containing insecticidal composition | |
| CN110024785A (en) | It is a kind of for preventing and treating the fungicide of wilt disease | |
| CN112120045A (en) | Agent for killing tea lesser leafhopper | |
| CN104222087A (en) | Nitenpyram and chitosan oligosaccharide compound composition | |
| CN115281199B (en) | Insecticidal composition for preventing and controlling spinach plutella xylostella | |
| CN103651444A (en) | Pesticide combination | |
| CN109122692B (en) | Insecticidal and acaricidal pesticide composition with synergistic effect | |
| CN107980777A (en) | A kind of bactericidal composition containing bromothalonil and eugenol | |
| CN116076519B (en) | Sterilization composition containing pyraclostrobin and myclobutanil and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180112 |