CN107558236A - A kind of alkaline-resisting high temperature resistant film of cold water solubles and preparation method thereof - Google Patents
A kind of alkaline-resisting high temperature resistant film of cold water solubles and preparation method thereof Download PDFInfo
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- CN107558236A CN107558236A CN201710914375.2A CN201710914375A CN107558236A CN 107558236 A CN107558236 A CN 107558236A CN 201710914375 A CN201710914375 A CN 201710914375A CN 107558236 A CN107558236 A CN 107558236A
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Abstract
The present invention relates to textile treating agent field, and disclosing a kind of alkaline-resisting high temperature resistant film of cold water solubles includes following parts by weight component：37 parts of ammonia end dimethyl silicone polymer；25 parts of dimethyl silicone polymer；20 30 parts of Oxystearin；5 10 parts of aliphatic acid polyethenoxy ether；10 15 parts of polyoxyethylene sorbitan fatty acid ester；5 10 parts of hydroxymethyl cellulose；23 parts of polyvinylpyrrolidone；12 parts of additive.The film be a kind of salt tolerant, it is alkaline-resisting, with reactive dye with bath do not cause color spot floccule precipitation etc., and make it is soft after cloth cover it is soft fluffy, meet the product of the needs of client, preferable effect reached in commercial Application.
Description
Technical field
The present invention relates to textile treating agent field, and in particular to a kind of alkaline-resisting high temperature resistant film of cold water solubles and its preparation
Method.
Background technology
In textile printing and dyeing process, fabric after pre-treatment and dyeing process, due to by multi-chemical and
Strength mechanical work, the feel of fabric can become coarse, therefore after the completion of dyeing process, be both needed to carry out smooth, soft arrangement.
Smooth, soft, which arranges, can not only improve the feel of fabric or yarn, and after further improving and improving fabric or yarn
Processing characteristics.Film is that one kind can improve fabric feeling, reaches soft, lubricates and flexible softening agent, and weaving print
It is most to contaminate kind in post-finishing agent, one of maximum class of yield.One kind that solid softening agent belongs to research and development abroad is new
Type softening agent, be by cation or weak cation be sheet that prime cost forms with other several components compoundings or graininess without
Aquatic products.
It is domestic at present to use relatively broad mainly cation flexible sheet, but these flexible sheets will be at 60-80 DEG C
Hot water in could dissolve, material time length, foam is more, wastes the energy, and xanthochromia degree is high, and non-refractory, not alkaline-resisting, together
When, easily cause dyeing defect etc. in cloth cover.Therefore, I takes charge of a kind of energy salt tolerant of plan research and development, alkaline-resisting and reactive dye do not cause color with bath
Spot floccule precipitation etc., and the soft rear cloth cover of system is soft fluffy, meets the product of the needs of client.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of alkaline-resisting high temperature resistant film of cold water solubles, overcome above-mentioned existing
There is the defects of technology, preferable effect has been reached in commercial Application.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of alkaline-resisting high temperature resistant film of cold water solubles, including following parts by weight component：
Ammonia end dimethyl silicone polymer 3-7 parts；
Dimethyl silicone polymer 2-5 parts；
Oxystearin 20-30 parts；
Aliphatic acid polyethenoxy ether 5-10 parts；
Polyoxyethylene sorbitan fatty acid ester 10-15 parts；
Hydroxymethyl cellulose 5-10 parts；
Polyvinylpyrrolidone 2-3 parts；
Additive 1-2 parts.
Oxystearin, polyoxyethylene sorbitan fatty acid ester can be as the excipient of film.Each component is 50
DEG C or so cold water solubles, cross-linked network is formed in water using polyvinylpyrrolidone and hydroxymethyl cellulose, collocation hydroxyl is hard
The rapid silicone emulsion composition of fat essence, polyoxyethylene sorbitan fatty acid ester, aliphatic acid polyethenoxy ether, drive silicone oil component
Densely distribution is adsorbed in textile surface.
Further, described additive includes at least one in synergist, antiseptic, essence, antistatic additive, chelating agent
Kind.
Further, described synergist includes at least one of magnesia, iron oxide, silica.
Further, described antistatic additive includes at least one of monostearin, ethyoxyl lauramide.
A kind of preparation method of the described alkaline-resisting high temperature resistant film of cold water solubles, comprises the following steps：
A. proportioning is pressed by ammonia end dimethyl silicone polymer, dimethyl silicone polymer, trihydroxy stearin, aliphatic acid polyethenoxy
Ether, polyoxyethylene sorbitan fatty acid ester, hydroxymethyl cellulose, polyvinylpyrrolidone are put into vacuum-pumping and logical protection
In the reactor of gas, 80-90 degrees Celsius is heated to, is stirred after material melts；
B. lead to protection gas, add additive, be warming up to 100-110 degrees Celsius of stirring 1-2h；
C. protection gas is closed, dehydration 30-50min is vacuumized, is cooled to 25-30 degrees Celsius, finished product of cutting into slices.
The present invention has the advantages that：
1）Selection it is new be free of AEEA raw materials, this product good water solubility, cold water solubles is water-soluble in good condition afterwards；
2）This product high temperature resistant, alkali resistance are especially good, hence it is evident that higher than conventional film, and mix with reactive dye liquid occur without it is cotton-shaped
Thing precipitates；
3）The fluffy softness of fabric feeling after this Product organization, is not easy xanthochromia.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Embodiment 1
A kind of alkaline-resisting high temperature resistant film of cold water solubles, including following parts by weight component：
5 parts of ammonia end dimethyl silicone polymer；
2 parts of dimethyl silicone polymer；
22 parts of Oxystearin；
10 parts of aliphatic acid polyethenoxy ether；
15 parts of polyoxyethylene sorbitan fatty acid ester；
2 parts of polyvinylpyrrolidone；
5 parts of hydroxymethyl cellulose；
1 part of magnesia；
Silica 1 part；
Its preparation method is：
A. by proportioning by ammonia end dimethyl silicone polymer, dimethyl silicone polymer, Oxystearin, aliphatic acid polyethenoxy ether,
Polyoxyethylene sorbitan fatty acid ester, hydroxymethyl cellulose, polyvinylpyrrolidone are put into vacuum-pumping and logical protection gas
Reactor in, be heated to 80-90 degrees Celsius, stirred after material melts；
B. lead to protection gas, add magnesia and silica, be warming up to 100-110 degrees Celsius of stirring 1-2h；
C. protection gas is closed, dehydration 30-50min is vacuumized, is cooled to 25-30 degrees Celsius, finished product of cutting into slices.
Embodiment 2
A kind of alkaline-resisting high temperature resistant film of cold water solubles, including following parts by weight component：
7 parts of ammonia end dimethyl silicone polymer；
5 parts of dimethyl silicone polymer；
20 parts of Oxystearin；
5 parts of aliphatic acid polyethenoxy ether；
10 parts of polyoxyethylene sorbitan fatty acid ester；
3 parts of polyvinylpyrrolidone；
10 parts of hydroxymethyl cellulose；
2 parts of monostearin；
Its preparation method is：
A. by proportioning by ammonia end dimethyl silicone polymer, dimethyl silicone polymer, Oxystearin, aliphatic acid polyethenoxy ether,
Polyoxyethylene sorbitan fatty acid ester, hydroxymethyl cellulose, polyvinylpyrrolidone are put into vacuum-pumping and logical protection gas
Reactor in, be heated to 80-90 degrees Celsius, stirred after material melts；
B. lead to protection gas, add monostearin, be warming up to 100-110 degrees Celsius of stirring 1-2h；
C. protection gas is closed, dehydration 30-50min is vacuumized, is cooled to 25-30 degrees Celsius, finished product of cutting into slices.
Embodiment 3
A kind of alkaline-resisting high temperature resistant film of cold water solubles, including following parts by weight component：
3 parts of ammonia end dimethyl silicone polymer；
3 parts of dimethyl silicone polymer；
30 parts of Oxystearin；
8 parts of aliphatic acid polyethenoxy ether；
13 parts of polyoxyethylene sorbitan fatty acid ester；
2.5 parts of polyvinylpyrrolidone；
7 parts of hydroxymethyl cellulose；
1 part of ethyoxyl lauramide；
Its preparation method is：
A. by proportioning by ammonia end dimethyl silicone polymer, dimethyl silicone polymer, Oxystearin, aliphatic acid polyethenoxy ether,
Polyoxyethylene sorbitan fatty acid ester, hydroxymethyl cellulose, polyvinylpyrrolidone are put into vacuum-pumping and logical protection gas
Reactor in, be heated to 80-90 degrees Celsius, stirred after material melts；
B. lead to protection gas, add ethyoxyl lauramide, be warming up to 100-110 degrees Celsius of stirring 1-2h；
C. protection gas is closed, dehydration 30-50min is vacuumized, is cooled to 25-30 degrees Celsius, finished product of cutting into slices.
The gained sample of embodiment 1 is tested, obtains following experimental result：
（1）50 DEG C, bathe to enter cotton textile altogether with commercially available common cationic coloring agent using embodiment 1 under the conditions of pH8 or so
Row processing；
（2）Agent solution is handled in whole process and does not produce floccule precipitation；
（3）The cotton crossed by the sample treatment of embodiment 1, through observing without color spot is produced, cloth cover is soft fluffy, cotton
10min is toasted through 100 DEG C or so temperature, xanthochromia does not occur.
Claims (5)
1. a kind of alkaline-resisting high temperature resistant film of cold water solubles, it is characterised in that including following parts by weight component：
Ammonia end dimethyl silicone polymer 3-7 parts；
Dimethyl silicone polymer 2-5 parts；
Oxystearin 20-30 parts；
Aliphatic acid polyethenoxy ether 5-10 parts；
Polyoxyethylene sorbitan fatty acid ester 10-15 parts；
Hydroxymethyl cellulose 5-10 parts；
Polyvinylpyrrolidone 2-3 parts；
Additive 1-2 parts.
2. the alkaline-resisting high temperature resistant film of cold water solubles according to claim 1, it is characterised in that described additive includes increasing
Imitate at least one of agent, antiseptic, essence, antistatic additive, chelating agent.
3. the alkaline-resisting high temperature resistant film of cold water solubles according to claim 2, it is characterised in that described synergist includes oxygen
Change at least one of magnesium, iron oxide, silica.
4. the alkaline-resisting high temperature resistant film of cold water solubles according to claim 2, it is characterised in that described antistatic additive includes
At least one of monostearin, ethyoxyl lauramide.
5. a kind of preparation method of the alkaline-resisting high temperature resistant film of cold water solubles described in claim 1-4 any one, its feature exist
In comprising the following steps：
A. by proportioning by ammonia end dimethyl silicone polymer, dimethyl silicone polymer, Oxystearin, aliphatic acid polyethenoxy ether,
Polyoxyethylene sorbitan fatty acid ester, hydroxymethyl cellulose, polyvinylpyrrolidone are put into vacuum-pumping and logical protection gas
Reactor in, be heated to 80-90 degrees Celsius, stirred after material melts；
B. lead to protection gas, add additive, be warming up to 100-110 degrees Celsius of stirring 1-2h；
C. protection gas is closed, dehydration 30-50min is vacuumized, is cooled to 25-30 degrees Celsius, finished product of cutting into slices.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109252375A (en) * | 2018-07-26 | 2019-01-22 | 广东雷邦高新材料有限公司 | A kind of silicon fabric-treating agent and preparation method thereof |
| CN110820327A (en) * | 2019-11-22 | 2020-02-21 | 广州科丰达新材料科技有限公司 | Phosphorus-free soft sheet and preparation method thereof |
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| CN109252375B (en) * | 2018-07-26 | 2022-06-03 | 广东雷邦高新材料有限公司 | Silicon fabric treating agent and preparation method thereof |
| CN110820327A (en) * | 2019-11-22 | 2020-02-21 | 广州科丰达新材料科技有限公司 | Phosphorus-free soft sheet and preparation method thereof |
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| CN107558236B (en) | 2019-11-29 |
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Granted publication date: 20191129 Termination date: 20210930 |