CN109252375B - Silicon fabric treating agent and preparation method thereof - Google Patents
Silicon fabric treating agent and preparation method thereof Download PDFInfo
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- CN109252375B CN109252375B CN201810835820.0A CN201810835820A CN109252375B CN 109252375 B CN109252375 B CN 109252375B CN 201810835820 A CN201810835820 A CN 201810835820A CN 109252375 B CN109252375 B CN 109252375B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses a silicon fabric treating agent which comprises the following components in parts by weight: 0.5-2 parts of hindered amine poly-block-type dimethyl siloxane, 4-10 parts of amino-terminated dimethyl polysiloxane, 5-8 parts of fatty acid polyoxyethylene ether, 1-2 parts of dodecyl glucoside, 0.5-1 part of lactobionic acid, 0.5-2 parts of additive and 85-95 parts of water. The silicon fabric treating agent can endow fabric with better soft hand feeling, yellowing resistance and hydrophobicity.
Description
Technical Field
The invention relates to the technical field of textile treating agents, in particular to a silicon fabric treating agent and a preparation method thereof.
Background
The fabric treating agent is a mixed solution of a polymer added to impart an excellent function to a fabric, and is called a fabric finishing agent. The fabric treating agent comprises an antistatic agent, a softener, a hydrophobic agent, a bacteriostatic agent and the like according to different functions, and comprises a polyacrylic acid treating agent, a polyurethane treating agent, an organic silicon treating agent and an organic fluorine treating agent according to different main effective components.
As a fabric treatment agent, in addition to excellent properties to be imparted to fabric, it is desired to have good safety and durability, for example, it is required to be harmless to the environment, non-irritating and non-toxic to the skin, not to be easily yellowed over a long period of time, and the like.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a silicon fabric treating agent with better yellowing resistance and water resistance.
The second purpose of the invention is to provide a preparation method of the silicon fabric treating agent.
One of the purposes of the invention is realized by adopting the following technical scheme:
the silicon fabric treating agent is characterized by comprising the following components in parts by weight: 0.5-2 parts of hindered amine poly-block-type dimethyl siloxane, 4-10 parts of amino-terminated dimethyl polysiloxane, 5-8 parts of fatty acid polyoxyethylene ether, 1-2 parts of dodecyl glucoside, 0.5-1 part of lactobionic acid, 0.5-2 parts of additive and 85-95 parts of water.
Further, the structural formula of the hindered amine type polydimethylsiloxane is shown as the following formula (I):
further, in formula (I), n is 25 to 40, and m is 5 to 15.
Further, the amino-terminated polydimethylsiloxane is secondary amino-terminated polydimethylsiloxane.
Further, the fatty acid polyoxyethylene ether is AEO7 or AEO 9.
Further, the additive is one or more than two of an antibacterial agent, an antistatic agent or a chelating agent.
Further, 1.2-1.5 parts of hindered amine poly-block-type dimethyl siloxane, 7 parts of amino-terminated dimethyl siloxane, 7 parts of fatty acid polyoxyethylene ether, 1.5 parts of dodecyl glucoside, 0.8 part of lactobionic acid, 0.1 part of cetylpyridinium chloride, 0.3 part of glyceryl monostearate, 0.3 part of EDTA-disodium and 88-92 parts of water.
The second purpose of the invention is realized by the following technical means:
a method for preparing the silicon fabric treating agent comprises the following steps:
1) dissolving fatty acid polyoxyethylene ether, dodecyl glucoside, lactobionic acid and an additive in water;
2) placing hindered amine poly-block-type dimethyl siloxane and secondary amino end-capped dimethyl siloxane in a reaction kettle, and slowly adding the material liquid obtained in the step 1) at the stirring speed of 1500-3000 rpm;
3) and after the materials are completely added, uniformly stirring the materials until microemulsion with blue light is formed, and standing the microemulsion.
Further, in the step 2), the temperature of the system is controlled to be 50-75 ℃.
Further, in the step 3), stirring is carried out at the temperature of 60-70 ℃.
Compared with the prior art, the invention has the beneficial effects that:
the invention provides a silicon fabric treating agent, which adopts amine-blocking poly block type dimethyl siloxane to match with amino-terminated dimethyl siloxane to endow fabric with better softness, yellowing resistance and hydrophobicity; the fatty acid polyoxyethylene ether, the dodecyl glucoside and the lactobionic acid are used as the composite emulsifier, so that the silicone oil can be dispersed into uniform microemulsion emulsion, and the uniform microemulsion emulsion can be uniformly attached to the surface of the fabric with strong adhesive force.
Detailed Description
The present invention is further described below with reference to specific embodiments, and it should be noted that, without conflict, any combination between the embodiments or technical features described below may form a new embodiment.
The invention provides a silicon fabric treating agent which comprises the following components in parts by weight: 0.5-2 parts of hindered amine poly-block-type dimethyl siloxane, 4-10 parts of amino-terminated dimethyl polysiloxane, 5-8 parts of fatty acid polyoxyethylene ether, 1-2 parts of dodecyl glucoside, 0.5-1 part of lactobionic acid, 0.5-2 parts of additive and 85-95 parts of water. The silicon fabric treating agent takes hindered amine poly-block dimethyl siloxane and amino-terminated dimethyl siloxane as effective components, can effectively increase the soft hand feeling of fabrics, improve the luster of the fabrics and improve the waterproof performance and the flame retardant performance of the fabrics, and is particularly suitable for treating the fabrics of outdoor equipment. The composite emulsifier composed of fatty acid polyoxyethylene ether, dodecyl glucoside and lactobionic acid can effectively emulsify amine-resistant and amino-terminated polydimethylsiloxane to form microemulsion, has high adhesive force to fabrics, and has good distribution uniformity on the fabrics.
The structural formula of the amine-retardant polydimethylsiloxane is shown as the following formula (I):
the amine-hindered polydimethylsiloxane can be prepared by the reaction of D4Hexamethyldisilane and methyl 2,2,6, 6-tetramethyl-4-piperidinol propyl dimethoxysilane, or obtained by a commercially available route. Specifically, in the polyamine-resistant polydimethylsiloxane, n is 25-40, and m is 5-15. The amino-terminated polydimethylsiloxane is secondary amino-terminated dimethyl silicone oil, wherein the polymerization degree of the amino-terminated dimethyl silicone oil is 20-100, and the amino-terminated dimethyl silicone oil can be obtained by a commercially available way or is terminated by the dimethyl silicone oil with secondary amino.
Example 1:
a silicon fabric treating agent comprises the following components in parts by weight: 1.2 parts of sterically hindered amine polyblock dimethylsiloxane, 7 parts of secondary amino-terminated dimethylsiloxane, 7 parts of AEO7, 1.5 parts of dodecyl glucoside, 0.8 part of lactobionic acid, 0.1 part of cetylpyridinium chloride, 0.3 part of glycerol monostearate, 0.3 part of EDTA-disodium and 90 parts of water.
The method for preparing the silicon fabric treating agent comprises the following steps:
1) dissolving AEO7, lactobionic acid, cetylpyridinium chloride, glyceryl monostearate and EDTA-disodium in water;
2) placing hindered amine poly-block dimethyl siloxane and secondary amino terminated alkane in a reaction kettle, controlling the system temperature at 60-70 ℃ at a stirring speed of 2500rpm, and slowly adding the feed liquid obtained in the step 1);
3) after the materials are completely added, the mixture is kept at the temperature of 60-70 ℃ and stirred evenly until microemulsion with blue light is formed, and the mixture is kept stand.
Example 2:
a silicon fabric treating agent comprises the following components in parts by weight: 0.5 part of sterically hindered amine polyblock-type dimethylsiloxane, 10 parts of secondary amino-terminated polydimethylsiloxane, 5 parts of AEO7, 1 part of dodecyl glucoside, 1 part of lactobionic acid, 0.2 part of cetylpyridinium chloride, 0.4 part of glycerol monostearate, 0.2 part of EDTA-disodium and 90 parts of water.
The method for preparing the silicon fabric treating agent comprises the following steps:
1) dissolving AEO7, lactobionic acid, cetylpyridinium chloride, glyceryl monostearate and EDTA-disodium in water;
2) placing hindered amine poly-block dimethyl siloxane and secondary amino terminated dimethyl siloxane in a reaction kettle, controlling the system temperature at 60-70 ℃ at a stirring speed of 2500rpm, and slowly adding the feed liquid obtained in the step 1);
3) after the materials are completely added, the mixture is kept at the temperature of 60-70 ℃ and stirred evenly until microemulsion with blue light is formed, and the mixture is kept stand.
Example 3:
a silicon fabric treating agent comprises the following components in parts by weight: 2 parts of sterically hindered amine polyblock-type dimethylsiloxane, 4 parts of secondary amino-terminated polydimethylsiloxane, 8 parts of AEO9, 2 parts of dodecyl glucoside, 1 part of lactobionic acid, 0.1 part of cetylpyridinium chloride, 0.5 part of glycerol monostearate, 0.2 part of EDTA-disodium and 90 parts of water.
The method for preparing the silicon fabric treating agent comprises the following steps:
1) dissolving AEO9, lactobionic acid, cetylpyridinium chloride, glyceryl monostearate and EDTA-disodium in water;
2) placing hindered amine poly-block dimethyl siloxane and secondary amino terminated dimethyl siloxane in a reaction kettle, controlling the system temperature at 60-70 ℃ at a stirring speed of 2500rpm, and slowly adding the feed liquid obtained in the step 1);
3) after the materials are completely added, the mixture is kept at the temperature of 60-70 ℃ and stirred evenly until microemulsion with blue light is formed, and the mixture is kept stand.
Comparative example 1:
comparative example 1 differs from example 1 in that 9 parts of hindered amine segmented dimethylsiloxane and 0 part of secondary amino terminated dimethylsiloxane.
Comparative example 2:
comparative example 2 differs from example 1 in that dodecyl glucoside is not added.
Comparative example 2 gave a microemulsion with significantly lower transparency than example 1.
Comparative example 3:
comparative example 3 differs from example 1 in that lactobionic acid was not added.
Comparative example 3 gave a microemulsion with a significantly lower transparency than comparative example 2.
Performance detection and Effect evaluation
The microemulsion of the silicon fabric treating agent obtained in the example 1 to 3 is used for treating pure cotton white cloth at the temperature of 95 to 98 ℃ and is dried.
And treating 3 pieces of pure cotton white cloth by each group of microemulsion, collecting 11 volunteers to score according to softness of hand feeling, scoring from 1-10 points according to the softness, and averaging. Baking in an oven at 100 deg.C for 30min, and testing water contact angle. The results are shown in the following table.
| Softness | Yellow stain | Contact angle | |
| Example 1 | 9.14 | No yellowing | 158° |
| Example 2 | 8.67 | No yellowing | 156° |
| Example 3 | 8.90 | No yellowing | 159° |
| Comparative example 1 | 9.03 | Yellowing of | 149° |
| Comparative example 2 | 7.12 | No yellowing | 151° |
| Comparative example 3 | 7.27 | No yellowing | 150° |
From the table, the silicon fabric treating agent obtained by the method can effectively improve the softness of the fabric, reduce yellowing and increase the water contact angle, namely the fabric treating agent has better durability and waterproofness. Is suitable for the treatment of outdoor textile products.
The above embodiments are only preferred embodiments of the present invention, and the scope of the present invention should not be limited thereby, and any insubstantial changes and substitutions made by those skilled in the art based on the present invention are intended to be covered by the claims.
Claims (7)
1. The silicon fabric treating agent is characterized by comprising the following components in parts by weight: 0.5-2 parts of hindered amine poly-block type dimethyl siloxane, 4-10 parts of amino-terminated dimethyl polysiloxane, 5-8 parts of fatty acid polyoxyethylene ether, 1-2 parts of dodecyl glucoside, 0.5-1 part of lactobionic acid, 0.5-2 parts of an additive and 85-95 parts of water; the structural formula of the hindered amine poly-block type dimethyl siloxane is shown as the following formula (I):
n is 25-40, and m is 5-15; the amino-terminated polydimethylsiloxane is secondary amino-terminated polydimethylsiloxane.
2. The silicon fabric treatment of claim 1, wherein the fatty acid polyoxyethylene ether is AEO7 or AEO 9.
3. The silicon fabric treating agent according to claim 1, wherein the additive is one or more of an antibacterial agent, an antistatic agent, or a chelating agent.
4. The silicon fabric treatment according to claim 1, wherein 1.2 parts of hindered amine polyblock-type dimethylsiloxane, 7 parts of amino-terminated polydimethylsiloxane, 7 parts of fatty acid polyoxyethylene ether, 1.5 parts of dodecyl glucoside, 0.8 part of lactobionic acid, 0.1 part of cetylpyridinium chloride, 0.3 part of glycerol monostearate, 0.3 part of EDTA-disodium and 88-92 parts of water.
5. A method for preparing the silicon fabric treating agent according to any one of claims 1 to 4, comprising the steps of:
1) dissolving fatty acid polyoxyethylene ether, dodecyl glucoside, lactobionic acid and an additive in water;
2) placing hindered amine poly-block-type dimethyl siloxane and secondary amino end-capped dimethyl siloxane in a reaction kettle, and slowly adding the material liquid obtained in the step 1) at the stirring speed of 1500-3000 rpm;
3) and after the materials are completely added, uniformly stirring the materials until microemulsion with blue light is formed, and standing the microemulsion.
6. The method of claim 5, wherein in the step 2), the temperature of the system is controlled to be 50-75 ℃.
7. The method of claim 5, wherein in step 3), stirring is maintained at a temperature of 60-70 ℃.
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| CN201810835820.0A CN109252375B (en) | 2018-07-26 | 2018-07-26 | Silicon fabric treating agent and preparation method thereof |
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Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116258A (en) * | 1993-12-27 | 1996-02-07 | 罗纳·布朗克化学公司 | Non-yellowing textile softening process in which a composition comprising a polyorganosiloxane is used |
| CN1287130A (en) * | 1999-06-25 | 2001-03-14 | 信越化学工业株式会社 | Polyorganosiloxane containing nitrogen atom its production and fibre and fabric finishing agent composition |
| GB2375547A (en) * | 2001-05-16 | 2002-11-20 | Rhodia Cons Spec Ltd | Waterproofing |
| CN1468336A (en) * | 2000-10-05 | 2004-01-14 | ���ǻ�ѧ��˾ | Treating textile materials with polyorganosiloxanes |
| CN101297077A (en) * | 2005-10-24 | 2008-10-29 | 美利肯公司 | Hindered amine treated textiles |
| CN101323665A (en) * | 2008-07-21 | 2008-12-17 | 华明扬 | Preparation of organosilicon amphoteric microemulsion |
| CN101553521A (en) * | 2006-10-31 | 2009-10-07 | 蓝星有机硅法国公司 | Reactive silanol-Hals amino silicone polymer with improved fabric coating performance |
| CN102725031A (en) * | 2010-01-29 | 2012-10-10 | 赢创高施米特有限公司 | Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof |
| CN102964602A (en) * | 2012-11-27 | 2013-03-13 | 陕西科技大学 | Preparation method of steric hindered amine polyether-group polysiloxane |
| CN105155281A (en) * | 2015-10-14 | 2015-12-16 | 吴江市七都镇庙港雅迪针织制衣厂 | Fabric softening agent |
| CN107129574A (en) * | 2017-06-13 | 2017-09-05 | 江西晨光新材料有限公司 | A kind of synthetic method for synthesizing the amido silicon oil of group containing piperidines |
| CN107558236A (en) * | 2017-09-30 | 2018-01-09 | 惠州市泰和化工有限公司 | A kind of alkaline-resisting high temperature resistant film of cold water solubles and preparation method thereof |
| CN107558235A (en) * | 2017-09-30 | 2018-01-09 | 惠州市泰和化工有限公司 | A kind of quick-acting yarn fabric softening agents and preparation method thereof |
| CN107759794A (en) * | 2017-09-06 | 2018-03-06 | 四川省纺织科学研究院 | A kind of preparation method and application of the embedding Amino End Group silicone oil of main chain of the side chain containing tertiary amine groups |
-
2018
- 2018-07-26 CN CN201810835820.0A patent/CN109252375B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116258A (en) * | 1993-12-27 | 1996-02-07 | 罗纳·布朗克化学公司 | Non-yellowing textile softening process in which a composition comprising a polyorganosiloxane is used |
| CN1287130A (en) * | 1999-06-25 | 2001-03-14 | 信越化学工业株式会社 | Polyorganosiloxane containing nitrogen atom its production and fibre and fabric finishing agent composition |
| CN1468336A (en) * | 2000-10-05 | 2004-01-14 | ���ǻ�ѧ��˾ | Treating textile materials with polyorganosiloxanes |
| GB2375547A (en) * | 2001-05-16 | 2002-11-20 | Rhodia Cons Spec Ltd | Waterproofing |
| CN101297077A (en) * | 2005-10-24 | 2008-10-29 | 美利肯公司 | Hindered amine treated textiles |
| CN101553521A (en) * | 2006-10-31 | 2009-10-07 | 蓝星有机硅法国公司 | Reactive silanol-Hals amino silicone polymer with improved fabric coating performance |
| CN101323665A (en) * | 2008-07-21 | 2008-12-17 | 华明扬 | Preparation of organosilicon amphoteric microemulsion |
| CN102725031A (en) * | 2010-01-29 | 2012-10-10 | 赢创高施米特有限公司 | Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof |
| CN102964602A (en) * | 2012-11-27 | 2013-03-13 | 陕西科技大学 | Preparation method of steric hindered amine polyether-group polysiloxane |
| CN105155281A (en) * | 2015-10-14 | 2015-12-16 | 吴江市七都镇庙港雅迪针织制衣厂 | Fabric softening agent |
| CN107129574A (en) * | 2017-06-13 | 2017-09-05 | 江西晨光新材料有限公司 | A kind of synthetic method for synthesizing the amido silicon oil of group containing piperidines |
| CN107759794A (en) * | 2017-09-06 | 2018-03-06 | 四川省纺织科学研究院 | A kind of preparation method and application of the embedding Amino End Group silicone oil of main chain of the side chain containing tertiary amine groups |
| CN107558236A (en) * | 2017-09-30 | 2018-01-09 | 惠州市泰和化工有限公司 | A kind of alkaline-resisting high temperature resistant film of cold water solubles and preparation method thereof |
| CN107558235A (en) * | 2017-09-30 | 2018-01-09 | 惠州市泰和化工有限公司 | A kind of quick-acting yarn fabric softening agents and preparation method thereof |
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