CN107555423B - 一种用于制备二维纳米材料的剥离溶液及其应用 - Google Patents
一种用于制备二维纳米材料的剥离溶液及其应用 Download PDFInfo
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- CN107555423B CN107555423B CN201710757951.7A CN201710757951A CN107555423B CN 107555423 B CN107555423 B CN 107555423B CN 201710757951 A CN201710757951 A CN 201710757951A CN 107555423 B CN107555423 B CN 107555423B
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- 239000002086 nanomaterial Substances 0.000 title claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 238000010008 shearing Methods 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 12
- 239000000243 solution Substances 0.000 claims description 47
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 37
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 19
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 11
- 239000010439 graphite Substances 0.000 claims description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 238000005520 cutting process Methods 0.000 claims description 10
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- OTYYBJNSLLBAGE-UHFFFAOYSA-N CN1C(CCC1)=O.[N] Chemical compound CN1C(CCC1)=O.[N] OTYYBJNSLLBAGE-UHFFFAOYSA-N 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- CUTSCJHLMGPBEJ-UHFFFAOYSA-N [N].CN(C)C=O Chemical compound [N].CN(C)C=O CUTSCJHLMGPBEJ-UHFFFAOYSA-N 0.000 claims description 7
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 7
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 7
- XGWFJBFNAQHLEF-UHFFFAOYSA-N 9-anthroic acid Chemical compound C1=CC=C2C(C(=O)O)=C(C=CC=C3)C3=CC2=C1 XGWFJBFNAQHLEF-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- FWBAGEDRZQWROK-UHFFFAOYSA-N [3-(ethylcarbamoyl)-5-nitrophenyl]boronic acid Chemical compound CCNC(=O)C1=CC(B(O)O)=CC([N+]([O-])=O)=C1 FWBAGEDRZQWROK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000004945 emulsification Methods 0.000 claims description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 3
- 238000004108 freeze drying Methods 0.000 claims description 2
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- 238000003828 vacuum filtration Methods 0.000 claims description 2
- 239000002135 nanosheet Substances 0.000 abstract description 13
- 239000003960 organic solvent Substances 0.000 abstract description 11
- 239000007787 solid Substances 0.000 abstract description 8
- 230000009471 action Effects 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 6
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- 150000001875 compounds Chemical class 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 3
- 238000004220 aggregation Methods 0.000 abstract description 2
- 230000002776 aggregation Effects 0.000 abstract description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- 229910021389 graphene Inorganic materials 0.000 description 24
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 230000003670 easy-to-clean Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000004299 exfoliation Methods 0.000 description 4
- 239000002060 nanoflake Substances 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
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- 238000006555 catalytic reaction Methods 0.000 description 2
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- 239000007791 liquid phase Substances 0.000 description 2
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- 239000002064 nanoplatelet Substances 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HWQLBKMVMXBGRC-UHFFFAOYSA-M sodium;5-hydroxynaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(O)=CC=CC2=C1S([O-])(=O)=O HWQLBKMVMXBGRC-UHFFFAOYSA-M 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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CN110117029A (zh) * | 2018-02-05 | 2019-08-13 | 云南师范大学 | 一种分散性好并具有高荧光强度的二硫化钽纳米晶的制备方法 |
CN108611684B (zh) * | 2018-04-27 | 2020-01-10 | 清华-伯克利深圳学院筹备办公室 | 一种过渡金属硫族化合物二维原子晶体的可控减薄方法 |
CN110252158B (zh) * | 2019-06-24 | 2022-04-12 | 西南石油大学 | 一种MoS2/GO/CA复合膜及其制备方法 |
CN113104892B (zh) * | 2021-04-26 | 2022-08-23 | 武汉大学 | 一种利用化学插层辅助液相剥离制备大尺寸超薄二硫化钼纳米片的方法及其制备的产品 |
CN113772732B (zh) * | 2021-09-26 | 2022-05-06 | 江南大学 | 一种利用deet剥离制备二维材料纳米片的方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102502607A (zh) * | 2011-11-10 | 2012-06-20 | 郑州大学 | 一种基于超临界二氧化碳和芘基聚合物制备石墨烯溶液的方法 |
CN102530932A (zh) * | 2011-12-21 | 2012-07-04 | 青岛大学 | 一种绿色环保、低缺陷、大尺寸石墨烯的制备方法 |
CN103771517A (zh) * | 2014-01-17 | 2014-05-07 | 哈尔滨工业大学 | 一种基于液相分散的二维MoS2纳米片的制备方法 |
CN105263858A (zh) * | 2013-03-14 | 2016-01-20 | 都柏林圣三一学院教务长、研究员、基金会学者及董事会其他成员 | 可放大的用于大量制备片状剥离的、无缺陷的、非氧化的二维材料的方法 |
CN106029560A (zh) * | 2014-01-31 | 2016-10-12 | 曼彻斯特大学 | 剥离 |
CN106672954A (zh) * | 2017-01-20 | 2017-05-17 | 北京航空航天大学 | 一种液相剥离制备石墨烯二维材料的方法 |
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KR101462401B1 (ko) * | 2008-06-12 | 2014-11-17 | 삼성전자주식회사 | 그라펜 시트로부터 탄소화 촉매를 제거하는 방법, 탄소화촉매가 제거된 그라펜 시트를 소자에 전사하는 방법, 이에따른 그라펜 시트 및 소자 |
US9991391B2 (en) * | 2008-07-25 | 2018-06-05 | The Board Of Trustees Of The Leland Stanford Junior University | Pristine and functionalized graphene materials |
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102502607A (zh) * | 2011-11-10 | 2012-06-20 | 郑州大学 | 一种基于超临界二氧化碳和芘基聚合物制备石墨烯溶液的方法 |
CN102530932A (zh) * | 2011-12-21 | 2012-07-04 | 青岛大学 | 一种绿色环保、低缺陷、大尺寸石墨烯的制备方法 |
CN105263858A (zh) * | 2013-03-14 | 2016-01-20 | 都柏林圣三一学院教务长、研究员、基金会学者及董事会其他成员 | 可放大的用于大量制备片状剥离的、无缺陷的、非氧化的二维材料的方法 |
CN103771517A (zh) * | 2014-01-17 | 2014-05-07 | 哈尔滨工业大学 | 一种基于液相分散的二维MoS2纳米片的制备方法 |
CN106029560A (zh) * | 2014-01-31 | 2016-10-12 | 曼彻斯特大学 | 剥离 |
CN106672954A (zh) * | 2017-01-20 | 2017-05-17 | 北京航空航天大学 | 一种液相剥离制备石墨烯二维材料的方法 |
Non-Patent Citations (1)
Title |
---|
"A simple method for graphene production based on exfoliation of graphite in water using 1-pyrenesulfonic acid sodium salt";H. Yang et al;《Carbon》;20121117;第53卷;第2.1部分材料制备 * |
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